ES2156506B1 - Metodo para la produccion de oxido de propileno. - Google Patents

Metodo para la produccion de oxido de propileno.

Info

Publication number
ES2156506B1
ES2156506B1 ES009802135A ES9802135A ES2156506B1 ES 2156506 B1 ES2156506 B1 ES 2156506B1 ES 009802135 A ES009802135 A ES 009802135A ES 9802135 A ES9802135 A ES 9802135A ES 2156506 B1 ES2156506 B1 ES 2156506B1
Authority
ES
Spain
Prior art keywords
sup
angstron
template
carbon atoms
propylene oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
ES009802135A
Other languages
English (en)
Other versions
ES2156506A1 (es
Inventor
Junpei Tsuji
Jun Yamamoto
Canos Avelino Corma
Garcia Fernando Rey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Priority to ES009802135A priority Critical patent/ES2156506B1/es
Priority to JP26005199A priority patent/JP4355404B2/ja
Priority to JP26005299A priority patent/JP3848027B2/ja
Priority to SG1999004851A priority patent/SG74753A1/en
Priority to US09/414,555 priority patent/US6211388B1/en
Priority to NL1013256A priority patent/NL1013256C2/nl
Priority to KR1019990043723A priority patent/KR100596348B1/ko
Priority to CNB991210905A priority patent/CN100369907C/zh
Publication of ES2156506A1 publication Critical patent/ES2156506A1/es
Application granted granted Critical
Publication of ES2156506B1 publication Critical patent/ES2156506B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/643—Pore diameter less than 2 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/657—Pore diameter larger than 1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/10—Infrared [IR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Un método para producir óxido de propileno por reacción de propileno con hidroperóxido de etilbenceno, donde la citada reacción se lleva a cabo en presencia de un catalizador que comprende un óxido de silicio que contiene titanio y que satisface todas las condiciones (1) a (5) dadas a continuación: (1): Hay al menos un pico que muestra un espaciado interplanar (d) mayor de 18 {angstron}, o no hay pico que muestra espaciado interplanar (d) en difracción de rayos-X. (2): Un tamaño medio de poro de 10 {angstron} o más. (3): Un tamaño de poro del 90% o más del volumen total de poros que es de 5 a 200 {angstron}. (4): Un volumen de poro especifico que es de 0,2 cm{sup,3}/g o más. (5): Se utiliza un ión de amonio cuaternario representado por la siguiente fórmula general (I) como plantilla separando luego esa plantilla por una operación de calcinación: [NR{sup,1}R{sup,2}R{sup,3}R{sup,4}] + (donde R{sup,1} representa una cadena de hidrocarburo lineal o ramificada que tiene 2 a 36 átomos de carbono,y R{sup,2} a R{sup,4} representan grupo alquilo que tiene 1 a 6 átomos de carbono).
ES009802135A 1998-10-14 1998-10-14 Metodo para la produccion de oxido de propileno. Expired - Fee Related ES2156506B1 (es)

Priority Applications (8)

Application Number Priority Date Filing Date Title
ES009802135A ES2156506B1 (es) 1998-10-14 1998-10-14 Metodo para la produccion de oxido de propileno.
JP26005199A JP4355404B2 (ja) 1998-10-14 1999-09-14 オキシラン化合物の製造方法
JP26005299A JP3848027B2 (ja) 1998-10-14 1999-09-14 チタン含有珪素酸化物触媒、該触媒の製造方法及びプロピレンオキサイドの製造方法
SG1999004851A SG74753A1 (en) 1998-10-14 1999-09-28 Method for producing propylene oxide
US09/414,555 US6211388B1 (en) 1998-10-14 1999-10-08 Method for producing propylene oxide
NL1013256A NL1013256C2 (nl) 1998-10-14 1999-10-08 Methode voor het bereiden van propeenoxyde.
KR1019990043723A KR100596348B1 (ko) 1998-10-14 1999-10-11 프로필렌 옥사이드의 제조방법
CNB991210905A CN100369907C (zh) 1998-10-14 1999-10-12 环氧丙烷的制造方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES009802135A ES2156506B1 (es) 1998-10-14 1998-10-14 Metodo para la produccion de oxido de propileno.

Publications (2)

Publication Number Publication Date
ES2156506A1 ES2156506A1 (es) 2001-06-16
ES2156506B1 true ES2156506B1 (es) 2002-03-01

Family

ID=8305442

Family Applications (1)

Application Number Title Priority Date Filing Date
ES009802135A Expired - Fee Related ES2156506B1 (es) 1998-10-14 1998-10-14 Metodo para la produccion de oxido de propileno.

Country Status (7)

Country Link
US (1) US6211388B1 (es)
JP (2) JP3848027B2 (es)
KR (1) KR100596348B1 (es)
CN (1) CN100369907C (es)
ES (1) ES2156506B1 (es)
NL (1) NL1013256C2 (es)
SG (1) SG74753A1 (es)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG82626A1 (en) 1998-08-04 2001-08-21 Sumitomo Chemical Co Titanium-containing silicon oxide catalyst
JP2001031662A (ja) * 1999-07-14 2001-02-06 Sumitomo Chem Co Ltd プロピレンオキサイドの製造方法
ES2165771B1 (es) * 1999-07-20 2003-05-01 Sumitomo Chemical Co Catalizador de oxido de silicio que contiene titanio.
EP1252928B1 (en) * 2000-02-02 2006-08-02 Sumitomo Chemical Company, Limited Molded catalyst, process for producing the molded catalyst, and process for producing oxirane compound
JP4889865B2 (ja) * 2001-01-31 2012-03-07 住友化学株式会社 チタン含有珪素酸化物触媒の製造方法
JP2002239381A (ja) * 2001-02-22 2002-08-27 Sumitomo Chem Co Ltd チタン含有珪素酸化物触媒の製造方法及び触媒
FR2824565B1 (fr) * 2001-05-09 2003-07-04 Solvay Procede de desulfuration d'un melange d'hydrocarbures
US9186322B2 (en) * 2002-08-02 2015-11-17 Insmed Incorporated Platinum aggregates and process for producing the same
AU2004264394B2 (en) * 2003-08-19 2008-01-03 Shell Internationale Research Maatschappij B.V. Process for the preparation of alkylene oxide
KR20070089693A (ko) * 2004-11-08 2007-08-31 트랜세이브, 인코포레이티드 지질-기재 플래티넘 화합물 제형을 복막내 투여하여 암을치료하는 방법
JP2006289341A (ja) * 2005-03-17 2006-10-26 Sumitomo Chemical Co Ltd チタン含有珪素酸化物触媒の保存方法
US9107824B2 (en) 2005-11-08 2015-08-18 Insmed Incorporated Methods of treating cancer with high potency lipid-based platinum compound formulations administered intraperitoneally
WO2007056264A2 (en) * 2005-11-08 2007-05-18 Transave, Inc. Methods of treating cancer with high potency lipid-based platinum compound formulations administered intraperitoneally
US8993714B2 (en) * 2007-10-26 2015-03-31 Imiplex Llc Streptavidin macromolecular adaptor and complexes thereof
US9102526B2 (en) 2008-08-12 2015-08-11 Imiplex Llc Node polypeptides for nanostructure assembly
US9285363B2 (en) 2009-05-11 2016-03-15 Imiplex Llc Method of protein nanostructure fabrication
EP2892524B1 (en) 2012-09-04 2020-11-25 Eleison Pharmaceuticals, LLC Preventing pulmonary recurrence of cancer with lipid-complexed cisplatin
TWI628146B (zh) * 2016-11-28 2018-07-01 東聯化學股份有限公司 Preparation method and application of titanium-containing cerium oxide material with high thermal stability
CN107715868B (zh) 2017-10-27 2019-07-23 万华化学集团股份有限公司 一种丙烯环氧化催化剂的制备方法及其用途
CN107930610B (zh) 2017-11-29 2019-09-20 万华化学集团股份有限公司 一种烯烃环氧化催化剂的制备方法及由此制备的催化剂
EP3878554A4 (en) 2020-01-14 2022-07-13 Wanhua Chemical Group Co., Ltd. PROCESS FOR THE PREPARATION OF A CATALYST FOR THE EPOXYDATION OF PROPYLENE AND ITS USE

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4367342A (en) * 1969-04-02 1983-01-04 Shell Oil Company Olefin epoxidation
ES2092428B1 (es) * 1993-06-15 1997-08-01 Univ Valencia Politecnica Material de estructura tipo zeolita de poros ultragrandes con un red constituida por oxidos de silicio y titanio; su sintesis y utilizacion para la oxidacion selectiva de productos organicos.
US5453511A (en) * 1993-12-23 1995-09-26 Arco Chemical Technology, L.P. Bis-piperidinium compounds
JPH07300312A (ja) 1994-03-09 1995-11-14 Nippon Shokubai Co Ltd メソポアチタノシリケートおよびその合成方法
US5795555A (en) * 1994-11-24 1998-08-18 Alive; Keshavaraja Micro-meso porous amorphous titanium silicates and a process for preparing the same
US5723637A (en) * 1995-12-06 1998-03-03 Sumitomo Chemical Company, Limited Process for producing propylene oxide
US5663384A (en) * 1996-03-06 1997-09-02 Arco Chemical Technology, L.P. Asymetric epoxidation using a titanium-containing zeolite and a chiral hydroperoxide
US6011162A (en) * 1997-05-05 2000-01-04 Arco Chemical Technology, L.P. Epoxidation process using improved heterogeneous catalyst composition

Also Published As

Publication number Publication date
NL1013256C2 (nl) 2001-10-24
CN1250775A (zh) 2000-04-19
CN100369907C (zh) 2008-02-20
KR100596348B1 (ko) 2006-07-05
JP3848027B2 (ja) 2006-11-22
KR20000028973A (ko) 2000-05-25
ES2156506A1 (es) 2001-06-16
US6211388B1 (en) 2001-04-03
SG74753A1 (en) 2000-08-22
JP4355404B2 (ja) 2009-11-04
NL1013256A1 (nl) 2000-04-17
JP2000117101A (ja) 2000-04-25
JP2000119266A (ja) 2000-04-25

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