ES2165773B1 - Proceso para producir oxido de propileno. - Google Patents

Proceso para producir oxido de propileno.

Info

Publication number
ES2165773B1
ES2165773B1 ES9901744A ES9901744A ES2165773B1 ES 2165773 B1 ES2165773 B1 ES 2165773B1 ES 9901744 A ES9901744 A ES 9901744A ES 9901744 A ES9901744 A ES 9901744A ES 2165773 B1 ES2165773 B1 ES 2165773B1
Authority
ES
Spain
Prior art keywords
sup
propylene oxide
angstron
template
carbon atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
ES9901744A
Other languages
English (en)
Other versions
ES2165773A1 (es
Inventor
Jun Yamamoto
Junpei Tsuji
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP15639499A external-priority patent/JP4495272B2/ja
Priority claimed from JP11156392A external-priority patent/JP2000109469A/ja
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Publication of ES2165773A1 publication Critical patent/ES2165773A1/es
Application granted granted Critical
Publication of ES2165773B1 publication Critical patent/ES2165773B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/643—Pore diameter less than 2 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Proceso para producir óxido de propileno. Un proceso para producir óxido de propileno por reacción de propileno con hidroperóxido de etilbenceno en presencia de un catalizador de óxido de silicio que contiene titanio que satisface todas las condiciones (1) a (4) que se exponen a continuación: (1) Tamaño de poro medio de 10 {angstron} o más, (2) Tamaño de poro de 90% o más del volumen de poro total de 5 a 200{angstron}. (3) Volumen de poro específico de 0,2 cm{sup,3}/g o más, y (4) Uso de un ion de amonio cuaternario representado por la siguiente fórmula general (I) como plantilla eliminándose después dicha plantilla a través de una operación de extracción con disolvente;[NR{sup,1}R{sup,2}R{sup,3}R{sup,4}]{sup,+} (I) donde, R{sup,1} representa una cadena de hidrocarburos lineal o ramificada que tiene de 2 a 36 átomos de carbono y R{sup,2} a R{sup,4} representan un grupo alquilo que tiene de 1 a 6 átomos de carbono.
ES9901744A 1998-08-04 1999-07-30 Proceso para producir oxido de propileno. Expired - Fee Related ES2165773B1 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP22066598 1998-08-04
JP15639499A JP4495272B2 (ja) 1998-08-04 1999-06-03 オキシラン化合物の製造方法
JP11156392A JP2000109469A (ja) 1998-08-04 1999-06-03 プロピレンオキサイドの製造方法

Publications (2)

Publication Number Publication Date
ES2165773A1 ES2165773A1 (es) 2002-03-16
ES2165773B1 true ES2165773B1 (es) 2003-05-01

Family

ID=27320996

Family Applications (1)

Application Number Title Priority Date Filing Date
ES9901744A Expired - Fee Related ES2165773B1 (es) 1998-08-04 1999-07-30 Proceso para producir oxido de propileno.

Country Status (6)

Country Link
US (1) US6096910A (es)
KR (1) KR100626104B1 (es)
CN (1) CN1216048C (es)
ES (1) ES2165773B1 (es)
NL (1) NL1012748C2 (es)
SG (1) SG73663A1 (es)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG82626A1 (en) 1998-08-04 2001-08-21 Sumitomo Chemical Co Titanium-containing silicon oxide catalyst
JP4399913B2 (ja) * 1999-08-25 2010-01-20 住友化学株式会社 オキシラン化合物の製造方法
JP4325045B2 (ja) 1999-11-09 2009-09-02 住友化学株式会社 チタン含有珪素酸化物触媒の製造方法、該触媒及び該触媒を用いたオキシラン化合物の製造方法
WO2001056693A1 (fr) * 2000-02-02 2001-08-09 Sumitomo Chemical Company, Limited Catalyseur moule et son procede de fabrication, et procede de fabrication de compose d'oxirane
US6337412B1 (en) 2000-04-25 2002-01-08 Chemical Research & Licensing Company Three stage propylene oxide process
JP4889865B2 (ja) * 2001-01-31 2012-03-07 住友化学株式会社 チタン含有珪素酸化物触媒の製造方法
JP2002239381A (ja) * 2001-02-22 2002-08-27 Sumitomo Chem Co Ltd チタン含有珪素酸化物触媒の製造方法及び触媒
US7273941B2 (en) * 2001-12-05 2007-09-25 Dow Global Technologies Inc. Process of preparing an olefin oxide from olefin and organic hydroperoxide
JP4265212B2 (ja) * 2002-12-19 2009-05-20 住友化学株式会社 チタン含有珪素酸化物触媒の製造方法
JP2006289341A (ja) * 2005-03-17 2006-10-26 Sumitomo Chemical Co Ltd チタン含有珪素酸化物触媒の保存方法
EP1919976A1 (en) * 2005-08-29 2008-05-14 Shell Internationale Research Maatschappij B.V. Integrated process for the preparation of a polyester resin
ATE417877T1 (de) * 2005-08-29 2009-01-15 Shell Int Research Integriertes verfahren zur herstellung eines polyesterharzes
CN101348472B (zh) * 2007-07-18 2011-05-18 中国石油化工股份有限公司 用于制备环氧化物的方法
CN101429176B (zh) * 2007-11-07 2011-05-18 中国石油化工股份有限公司 烯烃环氧化的方法
CN101519391B (zh) * 2008-02-28 2011-07-20 中国科学院大连化学物理研究所 一种制备环氧丙烷的方法
CN102295533B (zh) * 2010-06-24 2013-12-18 中国石油化工股份有限公司 α，α-二甲基苄醇的制备方法
CN107930610B (zh) 2017-11-29 2019-09-20 万华化学集团股份有限公司 一种烯烃环氧化催化剂的制备方法及由此制备的催化剂
SG11202109384VA (en) * 2020-01-14 2021-09-29 Wanhua Chemical Group Co Ltd Preparation method for propylene epoxidation catalyst and use thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4367342A (en) * 1969-04-02 1983-01-04 Shell Oil Company Olefin epoxidation
CH568792A5 (es) * 1970-10-01 1975-11-14 Shell Int Research
ES2092428B1 (es) * 1993-06-15 1997-08-01 Univ Valencia Politecnica Material de estructura tipo zeolita de poros ultragrandes con un red constituida por oxidos de silicio y titanio; su sintesis y utilizacion para la oxidacion selectiva de productos organicos.
US5723637A (en) * 1995-12-06 1998-03-03 Sumitomo Chemical Company, Limited Process for producing propylene oxide

Also Published As

Publication number Publication date
KR20000017002A (ko) 2000-03-25
ES2165773A1 (es) 2002-03-16
CN1248579A (zh) 2000-03-29
CN1216048C (zh) 2005-08-24
KR100626104B1 (ko) 2006-09-20
NL1012748C2 (nl) 2000-06-06
SG73663A1 (en) 2000-06-20
US6096910A (en) 2000-08-01
NL1012748A1 (nl) 2000-02-08

Similar Documents

Publication Publication Date Title
ES2166271B1 (es) Catalizador de oxido de silicio con contenido en titanio.
ES2165773B1 (es) Proceso para producir oxido de propileno.
ES2156506B1 (es) Metodo para la produccion de oxido de propileno.
CO5160377A1 (es) Polimerizacion de oxido de etileno utilizando catalizadores de cianuro de metal
ATE21896T1 (de) Verfahren zur epoxidierung von olefinischen verbindungen.
BR112017003687A2 (pt) processo para remoção de gases ácidos a partir de uma corrente de fluido, e, absorvente para remoção seletiva de sulfeto de hidrogênio a partir de uma corrente de fluido.
BR112016007350A2 (pt) processo para fabricar uma solução aquosa de peróxido de hidrogênio purificada; e processo para fabricar óxido de propileno (1,2-epoxipropano)
ES2057593T3 (es) Una preparacion de microperoxidasa que contiene un hemopeptido como componente activo.
BR9812516A (pt) Processo de fabricação de um oxirano
ES2127203T3 (es) Vacunas y metodos para su produccion.
DE60044739D1 (de) Chemischer in situ generator und verfahren
BR0005488A (pt) Processo para a preparação de carbonato de vinileno, e o uso do mesmo
MX2020013359A (es) Procedimiento de preparacion de carbonatos mediante la adicion de co2 con un epoxido.
ES2193946T3 (es) Procedimientos para la preparacion de alcosiaminas a partir de nitroxidos.
CO5070583A1 (es) Composiciones reguladoras del crecimiento de las plantas
CO2018003674A2 (es) Método para la remoción selectiva de sulfuro de hidrógeno
BR9003423A (pt) Processos para a reacao de um substrato contendo amina secundaria ou terciaria e para melhorar o efeito deleterio de de metais de transicao
BR0107953A (pt) Catalisador moldado, processo para produção de catalisador moldado e processo para produção de composto de oxirano
ES2185260T3 (es) Procedimiento para la preparacion de epoxidos olefinicos.
ATE385495T1 (de) Herstellung von oxiranen mittels einer peroxi- verbindung
ES2037708T3 (es) Un procedimiento para preparar un derivado de bencimidazol.
GB1156925A (en) Process for Purifying Sulphur Containing Gases and for Producing Sulphur
BR112015019024A2 (pt) carreador modificado para catalisador de óxido de etileno baseado em prata
KR920006028A (ko) 순수하거나 기체 혼합물중에 존재하는 산화 이질소의 촉매식 분해
DE60113116T2 (de) Verfahren zur herstellung von oxiranen

Legal Events

Date Code Title Description
EC2A Search report published

Date of ref document: 20020316

Kind code of ref document: A1

Effective date: 20020316

FG2A Definitive protection

Ref document number: 2165773B1

Country of ref document: ES

FD2A Announcement of lapse in spain

Effective date: 20180807