DE69421813D1 - Katalysator zur herstellung von styrol-polymeren und verfahren zur herstellung von styrol-polymeren unter dessen verwendung - Google Patents

Katalysator zur herstellung von styrol-polymeren und verfahren zur herstellung von styrol-polymeren unter dessen verwendung

Info

Publication number
DE69421813D1
DE69421813D1 DE69421813T DE69421813T DE69421813D1 DE 69421813 D1 DE69421813 D1 DE 69421813D1 DE 69421813 T DE69421813 T DE 69421813T DE 69421813 T DE69421813 T DE 69421813T DE 69421813 D1 DE69421813 D1 DE 69421813D1
Authority
DE
Germany
Prior art keywords
styrene polymers
producing styrene
catalyst
producing
polymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69421813T
Other languages
English (en)
Other versions
DE69421813T2 (de
Inventor
Mizutomo Takeuchi
Hajime Shouzaki
Norio Tomotsu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Idemitsu Kosan Co Ltd
Original Assignee
Idemitsu Kosan Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Idemitsu Kosan Co Ltd filed Critical Idemitsu Kosan Co Ltd
Publication of DE69421813D1 publication Critical patent/DE69421813D1/de
Application granted granted Critical
Publication of DE69421813T2 publication Critical patent/DE69421813T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/28—Titanium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
DE69421813T 1993-07-02 1994-07-01 Katalysator zur herstellung von styrol-polymeren und verfahren zur herstellung von styrol-polymeren unter dessen verwendung Expired - Fee Related DE69421813T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP5164529A JPH0733812A (ja) 1993-07-02 1993-07-02 スチレン系重合体製造触媒及びそれを用いたスチレン系重合体の製造方法
PCT/JP1994/001078 WO1995001378A1 (fr) 1993-07-02 1994-07-01 Catalyseur de production d'un polymere de styrene et procede de production d'un polymere de styrene l'utilisant

Publications (2)

Publication Number Publication Date
DE69421813D1 true DE69421813D1 (de) 1999-12-30
DE69421813T2 DE69421813T2 (de) 2000-05-18

Family

ID=15794904

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69421813T Expired - Fee Related DE69421813T2 (de) 1993-07-02 1994-07-01 Katalysator zur herstellung von styrol-polymeren und verfahren zur herstellung von styrol-polymeren unter dessen verwendung

Country Status (6)

Country Link
US (1) US5747614A (de)
EP (1) EP0707013B1 (de)
JP (1) JPH0733812A (de)
KR (1) KR960703413A (de)
DE (1) DE69421813T2 (de)
WO (1) WO1995001378A1 (de)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3369294B2 (ja) * 1994-03-11 2003-01-20 出光興産株式会社 遷移金属化合物、それを用いた重合用触媒及び該重合用触媒を用いたスチレン系重合体の製造方法
DE4431838A1 (de) * 1994-09-07 1996-03-14 Basf Ag Geträgerte Metallocen-Katalysatorsysteme
DE19522013A1 (de) * 1995-06-21 1997-01-02 Hoechst Ag Übergangsmetallverbindung
CA2192156C (en) * 1995-12-08 2006-07-11 Nobuhiro Tsujimoto Catalyst and process for producing conjugated diene polymer
IT1283282B1 (it) * 1996-03-21 1998-04-16 Enichem Spa Procedimento per la preparazione di polimeri vinilaromatici cristallini a struttura predominantemente sindiotattica
US6225426B1 (en) * 1996-04-10 2001-05-01 Uniroyal Chemical Company, Inc. Process for producing polyolefin elastomer employing a metallocene catalyst
JP2000248015A (ja) 1999-02-26 2000-09-12 Idemitsu Petrochem Co Ltd オレフィン−スチレン類共重合用触媒及びオレフィン−スチレン系共重合体の製造方法
US6291386B1 (en) * 1999-05-25 2001-09-18 Equistar Chemicals, Lp Process for the in-situ preparation of single-site transition metal catalysts and polymerization process
JP4542657B2 (ja) * 2000-02-21 2010-09-15 日本ポリオレフィン株式会社 多置換インデン誘導体およびその製造方法
JP2002179714A (ja) * 2000-12-12 2002-06-26 Idemitsu Petrochem Co Ltd 重合体混合物の製造方法
ITMN20070043A1 (it) 2007-11-30 2009-06-01 Pe Labellers Spa Macchina etichettatrice per etichette stampate su film continuo.

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5155080A (en) * 1988-07-15 1992-10-13 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
DE69023846T2 (de) * 1989-03-20 1996-04-11 Idemitsu Kosan Co Styrencopolymer und verfahren zur herstellung.
AU628194B2 (en) * 1989-07-28 1992-09-10 Idemitsu Kosan Co. Ltd Process for producing styrene polymers
CA2027145C (en) * 1989-10-10 2002-12-10 Michael J. Elder Metallocene catalysts with lewis acids and aluminum alkyls
DE69018376T3 (de) * 1989-10-30 2002-05-16 Fina Technology Herstellung von Metallocenkatalysatoren für Olefinpolymerisation.
DE69026679T3 (de) * 1989-10-30 2005-10-06 Fina Technology, Inc., Houston Addition von Alkylaluminium zum Verbessern eines Metallocenkatalysators
US5387568A (en) * 1989-10-30 1995-02-07 Fina Technology, Inc. Preparation of metallocene catalysts for polymerization of olefins
JP2883695B2 (ja) * 1990-08-06 1999-04-19 三井化学株式会社 新規遷移金属化合物
JP2888648B2 (ja) * 1990-12-28 1999-05-10 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
JP2840462B2 (ja) * 1990-12-28 1998-12-24 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
JP2939354B2 (ja) * 1991-03-26 1999-08-25 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
DE69219932T2 (de) * 1991-03-29 1997-09-11 Idemitsu Kosan Co Verfahren zur Herstellung eines Homo- oder Copolymerisates des Styrols
JP2951438B2 (ja) * 1991-06-12 1999-09-20 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
JPH04366109A (ja) * 1991-06-12 1992-12-18 Idemitsu Kosan Co Ltd スチレン系重合体の製造方法及びその触媒
JP2988071B2 (ja) * 1991-10-14 1999-12-06 東ソー株式会社 芳香族ビニル化合物重合用触媒および芳香族ビニル化合物重合体の製造方法
EP0544308B1 (de) * 1991-11-28 1998-02-18 Showa Denko Kabushikikaisha Neues Metallocen und Verfahren zur Herstellung von Polyolefinen unter Verwendung desselben
JP3194438B2 (ja) * 1992-01-08 2001-07-30 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
US5434115A (en) * 1992-05-22 1995-07-18 Tosoh Corporation Process for producing olefin polymer
JP3216662B2 (ja) * 1992-10-08 2001-10-09 出光興産株式会社 スチレン系重合体の製造方法
DE4344688A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
US5594080A (en) * 1994-03-24 1997-01-14 Leland Stanford, Jr. University Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor

Also Published As

Publication number Publication date
WO1995001378A1 (fr) 1995-01-12
DE69421813T2 (de) 2000-05-18
EP0707013A1 (de) 1996-04-17
US5747614A (en) 1998-05-05
KR960703413A (ko) 1996-08-17
EP0707013A4 (de) 1996-06-12
EP0707013B1 (de) 1999-11-24
JPH0733812A (ja) 1995-02-03

Similar Documents

Publication Publication Date Title
DE69510812T2 (de) Verfahren zur herstellung von polymerisationskatalysatorsystemen und ihre verwendung
DE69520332D1 (de) Katalysator zur Polymerisation von Olefinen und Verfahren zur Herstellung von Polyolefinen unter dessen Verwendung
DE69620760D1 (de) Verfahren zur herstellung von polymerisierten geträgerten metallocenkatalysatorsystemen
DE69127811T2 (de) Verfahren zur herstellung von olefinpolymeren
DE69420670D1 (de) Katalysatoren, Verfahren unter Verwendung dieser Katalysatoren und Verfahren zur Herstellung dieser Katalysatoren
DE69326560D1 (de) Polymerisationskatalysator und verfahren zur herstellung von polymeren unter dessen verwendung
DE69426648T2 (de) Verfahren zur herstellung von olefinpolymeren und katalysator zur olefinpolymerisation
DE69611789T2 (de) Verfahren zur herstellung von metallocen-katalysator-systemen
DE69314137T2 (de) Olefinpolymerisationkatalysator und Verfahren zur Olefinpolymerisation unter Verwendung desselben,
DE69513623T2 (de) Verfahren zur herstellung von isobutenpolymer
DE69421813T2 (de) Katalysator zur herstellung von styrol-polymeren und verfahren zur herstellung von styrol-polymeren unter dessen verwendung
DE69426665T2 (de) Katalysator für die Herstellung von vinylaromatischem Polymer und Verfahren zur Herstellung von vinylaromatischem Polymer unter Anwendung desselben
DE69534410D1 (de) Übergangsmetallverbindung, Polymerisationskatalysator enthaltende dieselbe und Verfahren zur Herstellung von Polystyrene unter Anwendung dieses Katalysators
DE69619209T2 (de) Verfahren zur herstellung von alkoxylierungskatalysatoren und alkoxylierungsverfahren
DE69306219D1 (de) Verfahren zur herstellung von polymerlatex
DE69614272D1 (de) Verfahren zur herstellung von isomerisierungskatalysatoren, so hergestellte katalysatore und ihre verwendung
DE69428990T2 (de) Katalysator zur herstellung von vinylpolymer und verfahren zur herstellung von vinylaromatischem polymer
DE69625466D1 (de) Verfahren zur herstellung von polyethylennaphathalat
DE69503355D1 (de) Polymerisationskatalysator und verfahren zur herstellung von polystyrol mit diesem katalysator
DE69605269T2 (de) Verfahren zur herstellung von styrolpolymer
DE69613464T2 (de) Katalysator und verfahren zur herstellung von amiden
AT397723B (de) Verfahren zur herstellung radiokonjugierter polymerer und verwendung derselben
DE69533310D1 (de) Verfahren zur herstellung von ethylenpolymer und ethylenpolymer
DE69605845D1 (de) Olefinpolymerisationkatalysator und Verfahren zur Herstellung von Polyolefinen unter Verwendung desselben
DE69718171D1 (de) Verfahren zur herstellung von diiod flourverbindungen unter verwendung von cf2i2 und olefinen

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee