DE69421172T2 - Synthetises detergensstueck und herstellung davon - Google Patents
Synthetises detergensstueck und herstellung davonInfo
- Publication number
- DE69421172T2 DE69421172T2 DE69421172T DE69421172T DE69421172T2 DE 69421172 T2 DE69421172 T2 DE 69421172T2 DE 69421172 T DE69421172 T DE 69421172T DE 69421172 T DE69421172 T DE 69421172T DE 69421172 T2 DE69421172 T2 DE 69421172T2
- Authority
- DE
- Germany
- Prior art keywords
- weight
- water
- detergent
- soap
- bars
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000271 synthetic detergent Substances 0.000 title claims description 19
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 239000000203 mixture Substances 0.000 claims description 74
- 239000000463 material Substances 0.000 claims description 38
- 239000000344 soap Substances 0.000 claims description 38
- 239000003599 detergent Substances 0.000 claims description 35
- 229920001223 polyethylene glycol Polymers 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 15
- 239000000194 fatty acid Substances 0.000 claims description 15
- 229930195729 fatty acid Natural products 0.000 claims description 15
- 239000002202 Polyethylene glycol Substances 0.000 claims description 13
- 239000007788 liquid Substances 0.000 claims description 13
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 claims description 3
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 3
- 239000002195 soluble material Substances 0.000 claims description 3
- 235000021357 Behenic acid Nutrition 0.000 claims description 2
- AOHAPDDBNAPPIN-UHFFFAOYSA-N 3-Methoxy-4,5-methylenedioxybenzoic acid Chemical compound COC1=CC(C(O)=O)=CC2=C1OCO2 AOHAPDDBNAPPIN-UHFFFAOYSA-N 0.000 claims 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims 2
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 claims 2
- 229940116226 behenic acid Drugs 0.000 claims 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims 1
- -1 alkyl ether sulfates Chemical class 0.000 description 14
- 150000004665 fatty acids Chemical class 0.000 description 13
- 239000003795 chemical substances by application Substances 0.000 description 12
- 238000000034 method Methods 0.000 description 8
- 239000007787 solid Substances 0.000 description 7
- 229920001400 block copolymer Polymers 0.000 description 5
- 239000000155 melt Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 235000021355 Stearic acid Nutrition 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- 239000002198 insoluble material Substances 0.000 description 4
- 239000004014 plasticizer Substances 0.000 description 4
- 244000060011 Cocos nucifera Species 0.000 description 3
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229920002494 Zein Polymers 0.000 description 3
- 125000002252 acyl group Chemical group 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 150000008051 alkyl sulfates Chemical class 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000003605 opacifier Substances 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 239000005019 zein Substances 0.000 description 3
- 229940093612 zein Drugs 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229920002023 Pluronic® F 87 Polymers 0.000 description 2
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 description 2
- 229920001030 Polyethylene Glycol 4000 Polymers 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 230000002070 germicidal effect Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
- RMTFNDVZYPHUEF-XZBKPIIZSA-N 3-O-methyl-D-glucose Chemical class O=C[C@H](O)[C@@H](OC)[C@H](O)[C@H](O)CO RMTFNDVZYPHUEF-XZBKPIIZSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- 244000021150 Orbignya martiana Species 0.000 description 1
- 235000014643 Orbignya martiana Nutrition 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 235000021342 arachidonic acid Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229960000878 docusate sodium Drugs 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000021588 free fatty acids Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical class OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000006069 physical mixture Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- NQLVQOSNDJXLKG-UHFFFAOYSA-N prosulfocarb Chemical compound CCCN(CCC)C(=O)SCC1=CC=CC=C1 NQLVQOSNDJXLKG-UHFFFAOYSA-N 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/006—Detergents in the form of bars or tablets containing mainly surfactants, but no builders, e.g. syndet bar
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB939305377A GB9305377D0 (en) | 1993-03-16 | 1993-03-16 | Synthetic detergent bar and manufacture thereof |
| PCT/EP1994/000792 WO1994021778A1 (en) | 1993-03-16 | 1994-03-14 | Synthetic detergent bar and manufacture thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69421172D1 DE69421172D1 (de) | 1999-11-18 |
| DE69421172T2 true DE69421172T2 (de) | 2000-01-20 |
Family
ID=10732138
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69421172T Expired - Fee Related DE69421172T2 (de) | 1993-03-16 | 1994-03-14 | Synthetises detergensstueck und herstellung davon |
Country Status (16)
| Country | Link |
|---|---|
| EP (1) | EP0689584B1 (sk) |
| JP (1) | JP2740355B2 (sk) |
| KR (1) | KR100200456B1 (sk) |
| AU (1) | AU694728B2 (sk) |
| BR (1) | BR9406008A (sk) |
| CA (1) | CA2157773C (sk) |
| CZ (1) | CZ287044B6 (sk) |
| DE (1) | DE69421172T2 (sk) |
| ES (1) | ES2139738T3 (sk) |
| GB (1) | GB9305377D0 (sk) |
| HU (1) | HU217658B (sk) |
| IN (1) | IN181612B (sk) |
| PL (1) | PL177068B1 (sk) |
| SK (1) | SK113995A3 (sk) |
| WO (1) | WO1994021778A1 (sk) |
| ZA (1) | ZA941813B (sk) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018001603A1 (de) * | 2016-06-29 | 2018-01-04 | Buck-Chemie Gmbh | Stückförmiges reinigungsmittel für den wc-bereich |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5520840A (en) * | 1995-03-22 | 1996-05-28 | Lever Brothers Company | Detergent bars comprising water soluble starches |
| US5540854A (en) * | 1995-04-28 | 1996-07-30 | Lever Brothers Company, Division Of Conopco, Inc. | Polyalkylene structured detergent bars comprising organic amide |
| EP0781838A1 (en) * | 1995-12-29 | 1997-07-02 | Colgate-Palmolive Company | Detergent composition having improved cleaning power |
| US5683973A (en) * | 1996-02-15 | 1997-11-04 | Lever Brothers Company, Division Of Conopco, Inc. | Mild bar compositions comprising blends of higher melting point polyalkylene glycol(s) and lower melting point polyalkylene glycol(s) as processing aids |
| US5780405A (en) * | 1996-03-18 | 1998-07-14 | Lever Brothers Company, Division Of Conopco, Inc. | Bar composition comprising copolymer mildness actives |
| AU724338B2 (en) * | 1996-04-24 | 2000-09-21 | Unilever Plc | Synthetic bar composition comprising alkoxylated surfactants |
| US5795852A (en) * | 1996-04-24 | 1998-08-18 | Lever Brothers Company, Division Of Conopco, Inc. | Bar composition comprising nonionic polymeric surfacing as mildness enhancement agents |
| US5786312A (en) * | 1996-06-12 | 1998-07-28 | Lever Brothers Company, Division Of Conopco, Inc. | Bar composition comprising copolymer mildness actives |
| GB2316088A (en) * | 1996-08-06 | 1998-02-18 | Cussons Int Ltd | Lotion Bar |
| US5916856A (en) * | 1996-10-16 | 1999-06-29 | Lever Brothers Company | Pourable cast melt bar compositions comprising low levels of water and minimum ratios of polyol to water |
| ATE276350T1 (de) * | 1997-11-26 | 2004-10-15 | Procter & Gamble | Verfahren zur herstellung einer waschmitteltablette |
| WO1999027069A1 (en) * | 1997-11-26 | 1999-06-03 | The Procter & Gamble Company | Detergent tablet |
| DK0960188T3 (da) * | 1997-11-26 | 2002-09-23 | Procter & Gamble | Opvaskefremgangsmåde |
| CZ297811B6 (cs) * | 1998-08-26 | 2007-04-04 | Unilever N. V. | Mycí prostredek |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE541084A (sk) * | 1954-09-06 | |||
| US2987484A (en) * | 1959-05-29 | 1961-06-06 | Procter & Gamble | Closed die molding a detergent bar |
| US3376229A (en) * | 1964-12-11 | 1968-04-02 | Lever Brothers Ltd | Synthetic detergent bar |
| US3671545A (en) * | 1969-05-05 | 1972-06-20 | Synergistics Inc | Polyvinylpyrrolidone-iodine compounds |
| GB1294754A (en) * | 1969-12-01 | 1972-11-01 | Unilever Ltd | Synthetic detergent toilet bars |
| AU1350192A (en) * | 1991-01-28 | 1992-08-27 | Procter & Gamble Company, The | Binder systems for bar soaps |
-
1993
- 1993-03-16 GB GB939305377A patent/GB9305377D0/en active Pending
-
1994
- 1994-03-14 CZ CZ19952359A patent/CZ287044B6/cs unknown
- 1994-03-14 PL PL94310619A patent/PL177068B1/pl unknown
- 1994-03-14 ES ES94911169T patent/ES2139738T3/es not_active Expired - Lifetime
- 1994-03-14 SK SK1139-95A patent/SK113995A3/sk unknown
- 1994-03-14 EP EP94911169A patent/EP0689584B1/en not_active Expired - Lifetime
- 1994-03-14 DE DE69421172T patent/DE69421172T2/de not_active Expired - Fee Related
- 1994-03-14 HU HU9501988A patent/HU217658B/hu not_active IP Right Cessation
- 1994-03-14 WO PCT/EP1994/000792 patent/WO1994021778A1/en active IP Right Grant
- 1994-03-14 CA CA002157773A patent/CA2157773C/en not_active Expired - Fee Related
- 1994-03-14 BR BR9406008A patent/BR9406008A/pt not_active IP Right Cessation
- 1994-03-14 AU AU63771/94A patent/AU694728B2/en not_active Ceased
- 1994-03-14 KR KR1019950703925A patent/KR100200456B1/ko not_active IP Right Cessation
- 1994-03-14 JP JP6520625A patent/JP2740355B2/ja not_active Expired - Fee Related
- 1994-03-15 IN IN97BO1994 patent/IN181612B/en unknown
- 1994-03-15 ZA ZA941813A patent/ZA941813B/xx unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018001603A1 (de) * | 2016-06-29 | 2018-01-04 | Buck-Chemie Gmbh | Stückförmiges reinigungsmittel für den wc-bereich |
| AU2017288312B2 (en) * | 2016-06-29 | 2019-10-31 | Buck-Chemie Gmbh | Granular cleaning agent for bathrooms |
Also Published As
| Publication number | Publication date |
|---|---|
| IN181612B (sk) | 1998-07-25 |
| DE69421172D1 (de) | 1999-11-18 |
| HU217658B (hu) | 2000-03-28 |
| HUT73042A (en) | 1996-06-28 |
| SK113995A3 (en) | 1997-07-09 |
| CZ235995A3 (en) | 1996-01-17 |
| WO1994021778A1 (en) | 1994-09-29 |
| BR9406008A (pt) | 1995-12-26 |
| ZA941813B (en) | 1995-09-15 |
| CA2157773A1 (en) | 1994-09-29 |
| JPH08507816A (ja) | 1996-08-20 |
| HU9501988D0 (en) | 1995-09-28 |
| PL310619A1 (en) | 1995-12-27 |
| GB9305377D0 (en) | 1993-05-05 |
| KR100200456B1 (ko) | 1999-06-15 |
| CA2157773C (en) | 2000-07-18 |
| AU694728B2 (en) | 1998-07-30 |
| JP2740355B2 (ja) | 1998-04-15 |
| PL177068B1 (pl) | 1999-09-30 |
| EP0689584B1 (en) | 1999-10-13 |
| CZ287044B6 (en) | 2000-08-16 |
| EP0689584A1 (en) | 1996-01-03 |
| AU6377194A (en) | 1994-10-11 |
| ES2139738T3 (es) | 2000-02-16 |
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