DE69409499T2 - Wässrige elektrochemische Herstellung von Interkalierverbindungen und ihre Verwendung in nichtwässrigen wiederaufladbare Batterien - Google Patents

Wässrige elektrochemische Herstellung von Interkalierverbindungen und ihre Verwendung in nichtwässrigen wiederaufladbare Batterien

Info

Publication number
DE69409499T2
DE69409499T2 DE69409499T DE69409499T DE69409499T2 DE 69409499 T2 DE69409499 T2 DE 69409499T2 DE 69409499 T DE69409499 T DE 69409499T DE 69409499 T DE69409499 T DE 69409499T DE 69409499 T2 DE69409499 T2 DE 69409499T2
Authority
DE
Germany
Prior art keywords
electrolyte
lithium
insertion compound
aqueous
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69409499T
Other languages
German (de)
English (en)
Other versions
DE69409499D1 (de
Inventor
Jeffrey Raymond Dahn
Wu Li
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NEC Moli Energy Canada Ltd
Original Assignee
NEC Moli Energy Canada Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NEC Moli Energy Canada Ltd filed Critical NEC Moli Energy Canada Ltd
Application granted granted Critical
Publication of DE69409499D1 publication Critical patent/DE69409499D1/de
Publication of DE69409499T2 publication Critical patent/DE69409499T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/24—Alkaline accumulators
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/02—Electrolytic production, recovery or refining of metals by electrolysis of solutions of light metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0569—Liquid materials characterised by the solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/134—Electrodes based on metals, Si or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50—Current conducting connections for cells or batteries
    • H01M50/572—Means for preventing undesired use or discharge
    • H01M50/574—Devices or arrangements for the interruption of current
    • H01M50/581—Devices or arrangements for the interruption of current in response to temperature
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/058—Construction or manufacture
    • H01M10/0587—Construction or manufacture of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0025—Organic electrolyte
    • H01M2300/0028—Organic electrolyte characterised by the solvent
    • H01M2300/0037—Mixture of solvents
    • H01M2300/004—Three solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/04—Cells with aqueous electrolyte
    • H01M6/06—Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid
    • H01M6/10—Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid with wound or folded electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
DE69409499T 1994-01-28 1994-12-02 Wässrige elektrochemische Herstellung von Interkalierverbindungen und ihre Verwendung in nichtwässrigen wiederaufladbare Batterien Expired - Fee Related DE69409499T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CA002114492A CA2114492C (en) 1994-01-28 1994-01-28 Aqueous electrochemical preparation of insertion compounds and use in non-aqueous rechargeable batteries

Publications (2)

Publication Number Publication Date
DE69409499D1 DE69409499D1 (de) 1998-05-14
DE69409499T2 true DE69409499T2 (de) 1998-07-30

Family

ID=4152816

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69409499T Expired - Fee Related DE69409499T2 (de) 1994-01-28 1994-12-02 Wässrige elektrochemische Herstellung von Interkalierverbindungen und ihre Verwendung in nichtwässrigen wiederaufladbare Batterien

Country Status (5)

Country Link
US (2) US5599435A (OSRAM)
EP (1) EP0669667B1 (OSRAM)
JP (1) JPH07223819A (OSRAM)
CA (1) CA2114492C (OSRAM)
DE (1) DE69409499T2 (OSRAM)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5871865A (en) 1997-05-15 1999-02-16 Valence Technology, Inc. Methods of fabricating electrochemical cells
US6361822B1 (en) * 1997-05-27 2002-03-26 Tdk Corporation Method of producing an electrode for non-aqueous electrolyte battery
KR100268749B1 (ko) * 1998-02-26 2000-10-16 이 병 길 리튬 이차전지 양극재료용 층상 결정구조 이산화 망간 및 이의 합성 방법
US5939043A (en) * 1998-06-26 1999-08-17 Ga-Tek Inc. Process for preparing Lix Mn2 O4 intercalation compounds
US6110622A (en) 1998-07-22 2000-08-29 Wilson Greatbatch Ltd. Chemically machined current collector design
US6245464B1 (en) 1998-09-21 2001-06-12 Wilson Greatbatch Ltd. Hermetically sealed lithium-ion secondary electrochemical cell
US6280873B1 (en) 1999-04-08 2001-08-28 Quallion, Llc Wound battery and method for making it
JP4274630B2 (ja) * 1999-05-21 2009-06-10 三井金属鉱業株式会社 スピネル型マンガン酸リチウムの製造方法
US7189475B2 (en) * 2000-07-27 2007-03-13 Kabushiki Kaisha Toyota Chuo Kenkyusho Lithium secondary battery
US20050164085A1 (en) * 2004-01-22 2005-07-28 Bofinger Todd E. Cathode material for lithium battery
US7955489B2 (en) * 2006-02-08 2011-06-07 Dynamic Food Ingredients Corporation Methods for the electrolytic production of erythrose or erythritol
US9133554B2 (en) 2006-02-08 2015-09-15 Dynamic Food Ingredients Corporation Methods for the electrolytic production of erythritol
FR2920255B1 (fr) * 2007-08-24 2009-11-13 Commissariat Energie Atomique Generateur electrochimique au lithium fonctionnant avec un electrolyte aqueux.
US8945756B2 (en) 2012-12-12 2015-02-03 Aquion Energy Inc. Composite anode structure for aqueous electrolyte energy storage and device containing same
US9711792B2 (en) 2014-03-10 2017-07-18 Hitachi, Ltd. Positive electrode active material for secondary batteries and lithium ion secondary battery using the same
WO2016160703A1 (en) 2015-03-27 2016-10-06 Harrup Mason K All-inorganic solvents for electrolytes
US10707531B1 (en) 2016-09-27 2020-07-07 New Dominion Enterprises Inc. All-inorganic solvents for electrolytes
US12388115B2 (en) * 2019-01-08 2025-08-12 Tesla, Inc. Electrolytes with lithium difluoro(oxalato)borate and lithium tetrafluoroborate salts for lithium metal and anode-free cells

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0017400B1 (en) * 1979-04-05 1984-05-30 United Kingdom Atomic Energy Authority Electrochemical cell and method of making ion conductors for said cell
US4507371A (en) * 1982-06-02 1985-03-26 South African Inventions Development Corporation Solid state cell wherein an anode, solid electrolyte and cathode each comprise a cubic-close-packed framework structure
US4731309A (en) * 1985-06-14 1988-03-15 The Dow Chemical Company High rate and high energy density cell
US4959282A (en) * 1988-07-11 1990-09-25 Moli Energy Limited Cathode active materials, methods of making same and electrochemical cells incorporating the same
CA2057946A1 (en) * 1990-12-20 1992-06-21 Michael M. Thackeray Electrochemical cell
US5219679A (en) * 1991-01-17 1993-06-15 Eic Laboratories, Inc. Solid electrolytes
DE4101533A1 (de) * 1991-01-19 1992-07-23 Varta Batterie Elektrochemisches sekundaerelement
US5196279A (en) * 1991-01-28 1993-03-23 Bell Communications Research, Inc. Rechargeable battery including a Li1+x Mn2 O4 cathode and a carbon anode
US5316875A (en) * 1991-07-19 1994-05-31 Matsushita Electric Industrial Co., Ltd. Secondary battery with nonaqueous electrolyte and method of manufacturing same
JP3059832B2 (ja) * 1992-07-27 2000-07-04 三洋電機株式会社 リチウム二次電池
ZA936168B (en) * 1992-08-28 1994-03-22 Technology Finance Corp Electrochemical cell

Also Published As

Publication number Publication date
US5733681A (en) 1998-03-31
EP0669667A3 (OSRAM) 1995-09-13
EP0669667B1 (en) 1998-04-08
CA2114492A1 (en) 1995-07-29
EP0669667A2 (en) 1995-08-30
DE69409499D1 (de) 1998-05-14
US5599435A (en) 1997-02-04
CA2114492C (en) 2000-09-05
JPH07223819A (ja) 1995-08-22

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