DE69404612D1 - Verfahren zur Herstellung von 1,4-Cyclohexandimethanol - Google Patents

Verfahren zur Herstellung von 1,4-Cyclohexandimethanol

Info

Publication number
DE69404612D1
DE69404612D1 DE69404612T DE69404612T DE69404612D1 DE 69404612 D1 DE69404612 D1 DE 69404612D1 DE 69404612 T DE69404612 T DE 69404612T DE 69404612 T DE69404612 T DE 69404612T DE 69404612 D1 DE69404612 D1 DE 69404612D1
Authority
DE
Germany
Prior art keywords
dialkyl
cyclohexanedicarboxylate
feed
contg
cyclohexanedimethanol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69404612T
Other languages
English (en)
Other versions
DE69404612T2 (de
Inventor
Colin Rathmell
Richard Clive Spratt
Michael William Marshall Tuck
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Chemical Co
Original Assignee
Eastman Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Chemical Co filed Critical Eastman Chemical Co
Publication of DE69404612D1 publication Critical patent/DE69404612D1/de
Application granted granted Critical
Publication of DE69404612T2 publication Critical patent/DE69404612T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/27—Polyhydroxylic alcohols containing saturated rings
    • C07C31/272—Monocyclic
    • C07C31/276—Monocyclic with a six-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Glass Compositions (AREA)
  • Iron Core Of Rotating Electric Machines (AREA)
DE69404612T 1993-12-02 1994-01-06 Verfahren zur Herstellung von 1,4-Cyclohexandimethanol Expired - Lifetime DE69404612T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB939324752A GB9324752D0 (en) 1993-12-02 1993-12-02 Process

Publications (2)

Publication Number Publication Date
DE69404612D1 true DE69404612D1 (de) 1997-09-04
DE69404612T2 DE69404612T2 (de) 1998-01-15

Family

ID=10746030

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69404612T Expired - Lifetime DE69404612T2 (de) 1993-12-02 1994-01-06 Verfahren zur Herstellung von 1,4-Cyclohexandimethanol

Country Status (16)

Country Link
US (1) US5395987A (de)
EP (1) EP0656337B1 (de)
JP (1) JP4153049B2 (de)
KR (1) KR100279316B1 (de)
CN (1) CN1060152C (de)
AT (1) ATE156112T1 (de)
AU (1) AU674460B2 (de)
BR (1) BR9404846A (de)
DE (1) DE69404612T2 (de)
ES (1) ES2105503T3 (de)
GB (1) GB9324752D0 (de)
HK (1) HK1001727A1 (de)
MY (1) MY121943A (de)
SG (1) SG47898A1 (de)
TW (1) TW279850B (de)
ZA (1) ZA948638B (de)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9324823D0 (en) * 1993-12-02 1994-01-19 Davy Mckee London Process
GB9324785D0 (en) * 1993-12-02 1994-01-19 Davy Mckee London Process
GB9324783D0 (en) * 1993-12-02 1994-01-19 Davy Mckee London Process
WO1996011110A1 (fr) * 1994-10-05 1996-04-18 Rohm Co., Ltd. Tete d'impression a del
WO2000058248A1 (en) * 1999-03-25 2000-10-05 Eastman Chemical Company Process for producing 1,4-cyclohexanedimethanol with enhanced cis-isomer content
US6919489B1 (en) 2004-03-03 2005-07-19 Eastman Chemical Company Process for a cyclohexanedimethanol using raney metal catalysts
US20080194398A1 (en) * 2007-02-14 2008-08-14 Eastman Chemical Company Ruthenium-copper chromite hydrogenation catalysts
US7538060B2 (en) * 2007-02-14 2009-05-26 Eastman Chemical Company Palladium-copper chromite hydrogenation catalysts
US20090142981A1 (en) 2007-12-03 2009-06-04 Velsicol Chemical Corporation Novel Compositions Comprising Structural Isomers Of 1,4-Cyclohexanedimethanol Dibenzoate and Polymer Compositions Containing Same
KR101099127B1 (ko) * 2008-10-16 2011-12-26 한화케미칼 주식회사 60%이상의 시스 디(ｃ4-ｃ20)알킬 시클로헥산-1,4-디카르복실레이트의 제조방법
US8394997B2 (en) 2010-12-09 2013-03-12 Eastman Chemical Company Process for the isomerization of 2,2,4,4-tetraalkylcyclobutane-1,3-diols
US8420869B2 (en) 2010-12-09 2013-04-16 Eastman Chemical Company Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols
US8766017B2 (en) * 2011-07-29 2014-07-01 Eastman Chemical Company Integrated process for the preparation of 1,4-cyclohexanedimethanol from terephthalic acid
US8410317B2 (en) 2011-07-29 2013-04-02 Eastman Chemical Company Process for the preparation of 1,4-cyclohexanedimethanol
US8410318B2 (en) * 2011-07-29 2013-04-02 Eastman Chemical Company Process for the preparation of 1,4-cyclohexanedimethanol from terephthalic acid
US8877984B2 (en) 2011-07-29 2014-11-04 Eastman Chemical Company Process for the preparation of 1,3-cyclohexanedimethanol from isophthalic acid
JP6051980B2 (ja) * 2013-03-14 2016-12-27 三菱化学株式会社 １，４−シクロヘキサンジメタノールの製造方法
KR102056291B1 (ko) 2013-06-28 2019-12-16 에스케이케미칼 주식회사 1,4-시클로헥산 디메탄올의 제조방법
US9115155B1 (en) 2014-03-20 2015-08-25 Eastman Chemical Company Low-pressure synthesis of cyclohexanedimethanol and derivatives
CN105620953B (zh) * 2014-11-03 2018-08-10 内蒙古大唐国际克什克腾煤制天然气有限责任公司 一种促进储罐内部热扩散的系统和方法
KR102413118B1 (ko) 2015-11-02 2022-06-24 에스케이케미칼 주식회사 1,4-사이클로헥산디메탄올의 제조 부산물의 처리 방법
CN106748704A (zh) * 2016-11-14 2017-05-31 中海油天津化工研究设计院有限公司 一种联产1,4‑环己烷二甲醇和环己基‑1,4‑二甲醛的方法
US10329235B2 (en) * 2017-08-31 2019-06-25 ClearWaterBay CHDM Technology Limited System and method for producing 1,4-cyclohexanedimethanol and 1,4- cyclohexanedicarboxylic acid from terephthalic acid
KR102188755B1 (ko) * 2017-12-22 2020-12-08 한화솔루션 주식회사 높은 트랜스 함량을 갖는 사이클로헥산 디메탄올 제조방법 및 이에 의해 제조된 사이클로헥산 디메탄올
CN110152565A (zh) * 2018-06-15 2019-08-23 宁波浙铁江宁化工有限公司 一种可调节的反应器及该反应器生产催化剂的制备方法
CN114436771B (zh) * 2020-10-20 2024-06-28 中国石油化工股份有限公司 一种制备环己烷二甲醇的方法
CN115007075B (zh) * 2021-04-30 2024-06-21 青岛京润石化工程有限公司 一种双反应段的催化剂连续循环反应实验装置

Family Cites Families (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2105664A (en) * 1930-04-17 1938-01-18 Du Pont Catalytic hydrogenation of hydroaromatic carboxylic acids and their esters
US2137407A (en) * 1931-05-11 1938-11-22 Du Pont Catalytic hydrogenation process
US2091800A (en) * 1931-09-15 1937-08-31 Rohm & Haas Method of hydrogenating esters
US2079414A (en) * 1932-08-20 1937-05-04 Du Pont Process for producing alcohols from esters of nonaromatic carboxylic acids
US2040944A (en) * 1933-09-22 1936-05-19 Du Pont Process for producing polyhydroxy alcohols
US2755317A (en) * 1952-11-10 1956-07-17 Universal Oil Prod Co Hydrogenation of benzene to cyclohexane
US2818393A (en) * 1953-05-05 1957-12-31 Kellogg M W Co Method of preparing a catalyst
US2830095A (en) * 1953-05-07 1958-04-08 Olin Mathieson Production of ethylene chlorohydrin
BE592181A (de) * 1955-12-22
US2884450A (en) * 1956-04-20 1959-04-28 Du Pont Hydrogenation of unsaturated dilactones to 1,8-octanedioic acids and 1,8-octanediolswith copper chromite catalysts
US2917549A (en) * 1958-01-07 1959-12-15 Eastman Kodak Co Preparation of trans-1,4-cyclohexanedimethanol
NL132671C (de) * 1960-02-09
DE1144703B (de) * 1960-10-06 1963-03-07 Eastman Kodak Co Verfahren zur Herstellung von Alkoholen durch katalytische Hydrierung von Estern
FR1276722A (fr) * 1960-10-11 1961-11-24 Eastman Kodak Co Procédé de préparation d'un catalyseur en vue de la réduction des esters en alcools
NL292315A (de) * 1962-05-05
CH438269A (it) * 1963-05-10 1967-06-30 Snam Spa Processo di idrogenazione di composti acetilenici miscibili con acqua a composti etilenici
US3334149A (en) * 1964-07-21 1967-08-01 Eastman Kodak Co Plural stage hydrogenation of dialkyl terephthalate using palladium and then copper chromite
US4052467A (en) * 1967-11-08 1977-10-04 Phillips Petroleum Company Catalytic reduction of aldehydes to alcohols
GB1454440A (en) * 1974-10-03 1976-11-03 Ucb Sa Process for the production of butane-1,4-diol from but-2-ene- 1,4-dioic acid
GB1464263A (en) * 1974-12-03 1977-02-09 Ucb Sa Production of butane-1,4-diol
US4032458A (en) * 1975-08-08 1977-06-28 Petro-Tex Chemical Corporation Production of 1,4-butanediol
US4172961A (en) * 1975-08-08 1979-10-30 Denka Chemical Corporation Production of 1,4-butanediol
DE2719867A1 (de) * 1977-05-04 1978-11-09 Bayer Ag Verfahren zur herstellung von butandiol-1,4
DE2845905C3 (de) * 1978-10-21 1983-05-26 Chemische Werke Hüls AG, 4370 Marl Verfahren zur kontinuierlichen Herstellung von Butandiol-1,4
DE3106819A1 (de) * 1981-02-24 1982-09-09 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von 1,4-butandiol
IT1190783B (it) * 1981-04-29 1988-02-24 Davy Mckee Oil & Chem Processo per l'idrogenolisi di esteri di acidi carbossilici
GB8331793D0 (en) * 1983-11-29 1984-01-04 Davy Mckee Ltd Process
EP0204730A1 (de) * 1984-11-21 1986-12-17 DAVY McKEE (LONDON) LIMITED Verfahren zur herstellung von butan-1,4-diol
GB8514002D0 (en) * 1985-06-04 1985-07-10 Davy Mckee Ltd Process
GB8514001D0 (en) * 1985-06-04 1985-07-10 Davy Mckee Ltd Process
US4652685A (en) * 1985-11-15 1987-03-24 General Electric Company Hydrogenation of lactones to glycols
DE3610698A1 (de) * 1986-03-29 1987-10-01 Henkel Kgaa Katalysator und verfahren zur katalytischen hydrierung von fettsaeuremethylestern im festbett
EP0277168A1 (de) * 1986-08-01 1988-08-10 DAVY McKEE (LONDON) LIMITED Verfahren zur gleichzeitigen herstellung von 1,4-butandiol und gamma-butyrolakton
GB8717989D0 (en) * 1987-07-29 1987-09-03 Davy Mckee Ltd Catalyst
DE3885302T2 (de) * 1987-08-03 1994-05-19 Eastman Kodak Co., Rochester, N.Y. KATALYTISCHE NIEDERDRUCKHYDRIERUNG VON CARBONYLHALTIGEN ZUSAMMENSETZUNGEN UND KATALYSATOREN DAFüR.
US4837368A (en) * 1988-02-01 1989-06-06 Eastman Kodak Company Low pressure catalytic hydrogenation of carbonyl-containing compounds and supported catalysts therefor
US4999090A (en) * 1988-04-10 1991-03-12 Towa Chemical Industry Co., Ltd. Process for preparing trans-1,4-cyclohexanedimethanol and powder of the same
DE3823457A1 (de) * 1988-07-11 1990-01-18 Henkel Kgaa Verfahren zum hydrieren von fettsaeureestern, fetten, fettsaeuren und vorrichtung zum durchfuehren des verfahrens
US5185476A (en) * 1988-07-15 1993-02-09 Eastman Kodak Company Low pressure catalytic hydrogenation of carbonyl-containing compounds and supported catalysts therefor
DE3843956A1 (de) * 1988-12-24 1990-06-28 Huels Chemische Werke Ag Verfahren zur herstellung von aliphatischen und cycloaliphatischen diolen durch katalytische hydrierung von dicarbonsaeureestern
US5124435A (en) * 1988-12-28 1992-06-23 Mitsubishi Rayon Co., Ltd. Polyester copolymer from terephthalic acid glycol and cycloaliphatic diol
ES2064715T3 (es) * 1989-01-17 1995-02-01 Davy Mckee London Procedimiento para la obtencion de alcoholes grasos.
US4929777A (en) * 1989-02-13 1990-05-29 Eastman Kodak Company Catalyst compositions and the use thereof in the hydrogenation of carboxylic acid esters
GB8917862D0 (en) * 1989-08-04 1989-09-20 Davy Mckee London Process
US5142067A (en) * 1989-12-21 1992-08-25 Union Carbide Chemicals & Plastics Technology Corporation Hydrogenation with Cu-Al-X catalysts
US5191091A (en) * 1989-12-21 1993-03-02 Union Carbide Chemicals & Plastics Technology Corporation Hydrogenation with Cu-Al catalysts
GB9025708D0 (en) * 1990-11-27 1991-01-09 Unilever Plc Fatty ester hydrogenation
DE4141199A1 (de) * 1991-12-13 1993-06-17 Sued Chemie Ag Chromfreier katalysator fuer die hydrierung von organischen verbindungen, die die carbonylfunktionen enthalten
US9986395B2 (en) * 2015-09-15 2018-05-29 Rok Mobile International Ltd. Method and system for bundling multiple services through a mobile platform

Also Published As

Publication number Publication date
AU674460B2 (en) 1996-12-19
KR950017892A (ko) 1995-07-20
JPH07196559A (ja) 1995-08-01
MY121943A (en) 2006-03-31
KR100279316B1 (ko) 2001-02-01
CN1060152C (zh) 2001-01-03
CN1112102A (zh) 1995-11-22
ATE156112T1 (de) 1997-08-15
ZA948638B (en) 1995-07-07
AU7914594A (en) 1995-06-08
GB9324752D0 (en) 1994-01-19
JP4153049B2 (ja) 2008-09-17
EP0656337A1 (de) 1995-06-07
SG47898A1 (en) 1998-04-17
ES2105503T3 (es) 1997-10-16
BR9404846A (pt) 1995-08-01
TW279850B (en) 1996-07-01
HK1001727A1 (en) 1998-07-03
US5395987A (en) 1995-03-07
EP0656337B1 (de) 1997-07-30
DE69404612T2 (de) 1998-01-15

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Legal Events

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