DE69222633T2 - Reformierungsverfahren mit niedrigem schwefelgehalt - Google Patents
Reformierungsverfahren mit niedrigem schwefelgehaltInfo
- Publication number
- DE69222633T2 DE69222633T2 DE69222633T DE69222633T DE69222633T2 DE 69222633 T2 DE69222633 T2 DE 69222633T2 DE 69222633 T DE69222633 T DE 69222633T DE 69222633 T DE69222633 T DE 69222633T DE 69222633 T2 DE69222633 T2 DE 69222633T2
- Authority
- DE
- Germany
- Prior art keywords
- reforming
- reactor system
- tin
- sulfur
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000002407 reforming Methods 0.000 title claims abstract description 149
- 238000000034 method Methods 0.000 title claims abstract description 119
- 229910052717 sulfur Inorganic materials 0.000 title claims abstract description 93
- 239000011593 sulfur Substances 0.000 title claims abstract description 93
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 229910052751 metal Inorganic materials 0.000 claims abstract description 142
- 239000002184 metal Substances 0.000 claims abstract description 142
- 230000008569 process Effects 0.000 claims abstract description 87
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 73
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 65
- 239000003054 catalyst Substances 0.000 claims abstract description 57
- 239000010457 zeolite Substances 0.000 claims abstract description 35
- 238000010438 heat treatment Methods 0.000 claims abstract description 29
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 27
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 19
- 238000001833 catalytic reforming Methods 0.000 claims abstract description 14
- 229910000831 Steel Inorganic materials 0.000 claims description 84
- 239000010959 steel Substances 0.000 claims description 84
- 239000011135 tin Substances 0.000 claims description 67
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 66
- 229910052718 tin Inorganic materials 0.000 claims description 64
- 239000000463 material Substances 0.000 claims description 62
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 49
- 238000000576 coating method Methods 0.000 claims description 46
- 239000011651 chromium Substances 0.000 claims description 45
- 229910001220 stainless steel Inorganic materials 0.000 claims description 45
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 43
- 229910052804 chromium Inorganic materials 0.000 claims description 42
- 239000000571 coke Substances 0.000 claims description 42
- 239000003973 paint Substances 0.000 claims description 39
- 239000011248 coating agent Substances 0.000 claims description 37
- 239000004215 Carbon black (E152) Substances 0.000 claims description 35
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 35
- 238000004939 coking Methods 0.000 claims description 34
- 239000010935 stainless steel Substances 0.000 claims description 32
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 29
- 239000001257 hydrogen Substances 0.000 claims description 27
- 229910052739 hydrogen Inorganic materials 0.000 claims description 27
- 150000001875 compounds Chemical class 0.000 claims description 26
- -1 sulfur hydrocarbon Chemical class 0.000 claims description 24
- 229910052742 iron Inorganic materials 0.000 claims description 23
- 150000002739 metals Chemical class 0.000 claims description 23
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- 238000006243 chemical reaction Methods 0.000 claims description 20
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
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- 239000010703 silicon Substances 0.000 claims description 18
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims description 17
- 229910000423 chromium oxide Inorganic materials 0.000 claims description 17
- 229910001134 stannide Inorganic materials 0.000 claims description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 16
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 16
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- 239000007789 gas Substances 0.000 claims description 14
- 239000011148 porous material Substances 0.000 claims description 14
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 229910052802 copper Inorganic materials 0.000 claims description 13
- 239000010949 copper Substances 0.000 claims description 13
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 13
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- 238000011282 treatment Methods 0.000 claims description 12
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- 239000002245 particle Substances 0.000 claims description 9
- 229910000765 intermetallic Inorganic materials 0.000 claims description 7
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- 150000003606 tin compounds Chemical class 0.000 claims description 7
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 7
- 229910001887 tin oxide Inorganic materials 0.000 claims description 7
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 6
- 229910052787 antimony Inorganic materials 0.000 claims description 6
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 6
- 229910052785 arsenic Inorganic materials 0.000 claims description 6
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 6
- 229910052797 bismuth Inorganic materials 0.000 claims description 6
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 6
- XZZXKVYTWCYOQX-UHFFFAOYSA-J octanoate;tin(4+) Chemical compound [Sn+4].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O XZZXKVYTWCYOQX-UHFFFAOYSA-J 0.000 claims description 5
- 238000010422 painting Methods 0.000 claims description 5
- 229910001369 Brass Inorganic materials 0.000 claims description 3
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- 229910017755 Cu-Sn Inorganic materials 0.000 claims description 2
- 229910017932 Cu—Sb Inorganic materials 0.000 claims description 2
- 229910017927 Cu—Sn Inorganic materials 0.000 claims description 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 claims description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 150000002506 iron compounds Chemical class 0.000 claims 2
- 229940058905 antimony compound for treatment of leishmaniasis and trypanosomiasis Drugs 0.000 claims 1
- 229940093920 gynecological arsenic compound Drugs 0.000 claims 1
- ZUBZATZOEPUUQF-UHFFFAOYSA-N isopropylhexane Natural products CCCCCCC(C)C ZUBZATZOEPUUQF-UHFFFAOYSA-N 0.000 claims 1
- 238000007747 plating Methods 0.000 claims 1
- 230000002035 prolonged effect Effects 0.000 claims 1
- 238000010410 dusting Methods 0.000 abstract description 4
- 239000010410 layer Substances 0.000 description 53
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 36
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 28
- 230000015572 biosynthetic process Effects 0.000 description 20
- 229910052759 nickel Inorganic materials 0.000 description 15
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 14
- 239000005864 Sulphur Substances 0.000 description 13
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 13
- 238000002474 experimental method Methods 0.000 description 13
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- 210000002268 wool Anatomy 0.000 description 9
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- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 8
- 150000001342 alkaline earth metals Chemical class 0.000 description 8
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- 238000011069 regeneration method Methods 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
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- 229910052788 barium Inorganic materials 0.000 description 5
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- 239000000788 chromium alloy Substances 0.000 description 1
- RPBPCPJJHKASGQ-UHFFFAOYSA-K chromium(3+);octanoate Chemical compound [Cr+3].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O RPBPCPJJHKASGQ-UHFFFAOYSA-K 0.000 description 1
- 238000005254 chromizing Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229940120693 copper naphthenate Drugs 0.000 description 1
- SEVNKWFHTNVOLD-UHFFFAOYSA-L copper;3-(4-ethylcyclohexyl)propanoate;3-(3-ethylcyclopentyl)propanoate Chemical compound [Cu+2].CCC1CCC(CCC([O-])=O)C1.CCC1CCC(CCC([O-])=O)CC1 SEVNKWFHTNVOLD-UHFFFAOYSA-L 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000012013 faujasite Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- YVXHZKKCZYLQOP-UHFFFAOYSA-N hept-1-yne Chemical compound CCCCCC#C YVXHZKKCZYLQOP-UHFFFAOYSA-N 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000013528 metallic particle Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- APGNMHZUERWZME-UHFFFAOYSA-L palladium(2+);3,3,5,5-tetramethylhexanoate Chemical compound [Pd+2].CC(C)(C)CC(C)(C)CC([O-])=O.CC(C)(C)CC(C)(C)CC([O-])=O APGNMHZUERWZME-UHFFFAOYSA-L 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229910000579 plumbide Inorganic materials 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000009420 retrofitting Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- RQZVTOHLJOBKCW-UHFFFAOYSA-M silver;7,7-dimethyloctanoate Chemical compound [Ag+].CC(C)(C)CCCCCC([O-])=O RQZVTOHLJOBKCW-UHFFFAOYSA-M 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000004901 spalling Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
- HDVLQIDIYKIVRE-UHFFFAOYSA-N tetrabutylgermane Chemical compound CCCC[Ge](CCCC)(CCCC)CCCC HDVLQIDIYKIVRE-UHFFFAOYSA-N 0.000 description 1
- MRMOZBOQVYRSEM-UHFFFAOYSA-N tetraethyllead Chemical group CC[Pb](CC)(CC)CC MRMOZBOQVYRSEM-UHFFFAOYSA-N 0.000 description 1
- XOOGZRUBTYCLHG-UHFFFAOYSA-N tetramethyllead Chemical compound C[Pb](C)(C)C XOOGZRUBTYCLHG-UHFFFAOYSA-N 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- BXJWDOYMROEHEN-UHFFFAOYSA-N tributylstibane Chemical compound CCCC[Sb](CCCC)CCCC BXJWDOYMROEHEN-UHFFFAOYSA-N 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- UKHQRARQNZOXRL-UHFFFAOYSA-N trimethyltin Chemical class C[SnH](C)C UKHQRARQNZOXRL-UHFFFAOYSA-N 0.000 description 1
- 238000009966 trimming Methods 0.000 description 1
- BPLUKJNHPBNVQL-UHFFFAOYSA-N triphenylarsine Chemical compound C1=CC=CC=C1[As](C=1C=CC=CC=1)C1=CC=CC=C1 BPLUKJNHPBNVQL-UHFFFAOYSA-N 0.000 description 1
- HVYVMSPIJIWUNA-UHFFFAOYSA-N triphenylstibine Chemical compound C1=CC=CC=C1[Sb](C=1C=CC=CC=1)C1=CC=CC=C1 HVYVMSPIJIWUNA-UHFFFAOYSA-N 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Paints Or Removers (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US66669691A | 1991-03-08 | 1991-03-08 | |
| US80321591A | 1991-12-06 | 1991-12-06 | |
| US80306391A | 1991-12-06 | 1991-12-06 | |
| US80282191A | 1991-12-06 | 1991-12-06 | |
| PCT/US1992/001856 WO1992015653A1 (en) | 1991-03-08 | 1992-03-06 | Low-sulfur reforming processes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69222633D1 DE69222633D1 (de) | 1997-11-13 |
| DE69222633T2 true DE69222633T2 (de) | 1998-04-23 |
Family
ID=27505330
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69222633T Expired - Lifetime DE69222633T2 (de) | 1991-03-08 | 1992-03-06 | Reformierungsverfahren mit niedrigem schwefelgehalt |
| DE69233084T Expired - Lifetime DE69233084T2 (de) | 1991-03-08 | 1992-03-06 | Reformierungsverfahren mit niedrigem Schwefelgehalt |
| DE69232891T Expired - Lifetime DE69232891T2 (de) | 1991-03-08 | 1992-03-06 | Reformierungsverfahren unter niedrigen Schwefelbedingungen |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69233084T Expired - Lifetime DE69233084T2 (de) | 1991-03-08 | 1992-03-06 | Reformierungsverfahren mit niedrigem Schwefelgehalt |
| DE69232891T Expired - Lifetime DE69232891T2 (de) | 1991-03-08 | 1992-03-06 | Reformierungsverfahren unter niedrigen Schwefelbedingungen |
Country Status (16)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE202009005950U1 (de) | 2009-04-27 | 2009-08-20 | Holland-Letz, Peter | Gewebe zur Körperabdeckung zur Applikation von Arzneimitteln |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5413700A (en) * | 1993-01-04 | 1995-05-09 | Chevron Research And Technology Company | Treating oxidized steels in low-sulfur reforming processes |
| US5405525A (en) * | 1993-01-04 | 1995-04-11 | Chevron Research And Technology Company | Treating and desulfiding sulfided steels in low-sulfur reforming processes |
| DE69433634T2 (de) * | 1993-01-04 | 2005-03-10 | Chevron Phillips Chemical Co. Lp, The Woodlands | Verfahren zur Umsetzung von Kohlenwasserstoffen |
| US5658452A (en) * | 1994-01-04 | 1997-08-19 | Chevron Chemical Company | Increasing production in hydrocarbon conversion processes |
| US5575902A (en) * | 1994-01-04 | 1996-11-19 | Chevron Chemical Company | Cracking processes |
| US5516421A (en) * | 1994-08-17 | 1996-05-14 | Brown; Warren E. | Sulfur removal |
| US5565087A (en) * | 1995-03-23 | 1996-10-15 | Phillips Petroleum Company | Method for providing a tube having coke formation and carbon monoxide inhibiting properties when used for the thermal cracking of hydrocarbons |
| AU7006596A (en) * | 1995-06-07 | 1997-01-09 | Chevron Chemical Company | Using hydrocarbon streams to prepare a metallic protective l ayer |
| ES2201194T3 (es) * | 1995-08-18 | 2004-03-16 | Chevron Phillips Chemical Company Lp | Barreras anti-difusion para prevenir el ataque por hidrogeno a elevada temperatura. |
| US6497809B1 (en) * | 1995-10-25 | 2002-12-24 | Phillips Petroleum Company | Method for prolonging the effectiveness of a pyrolytic cracking tube treated for the inhibition of coke formation during cracking |
| CA2243957C (en) * | 1996-02-02 | 2005-09-13 | Chevron Chemical Company Llc | Hydrocarbon processing in equipment having increased halide stress-corrosion cracking resistance |
| CN1043782C (zh) * | 1996-03-21 | 1999-06-23 | 中国石油化工总公司 | 提高低品质汽油辛烷值的催化转化方法 |
| US5914028A (en) * | 1997-01-10 | 1999-06-22 | Chevron Chemical Company | Reforming process with catalyst pretreatment |
| US5879538A (en) * | 1997-12-22 | 1999-03-09 | Chevron Chemical Company | Zeolite L catalyst in conventional furnace |
| US6258330B1 (en) * | 1998-11-10 | 2001-07-10 | International Fuel Cells, Llc | Inhibition of carbon deposition on fuel gas steam reformer walls |
| US6120926A (en) * | 1998-11-10 | 2000-09-19 | International Fuel Cells, Llc | Inhibition of carbon deposition on fuel gas steam reformer walls |
| WO2002000546A1 (fr) * | 2000-06-28 | 2002-01-03 | Sanyo Electric Co., Ltd. | Reacteur de reformage de combustible et son procede de production |
| CN1394981A (zh) * | 2001-07-09 | 2003-02-05 | 李兰根 | 气氛热处理助剂及其用法 |
| RU2292403C2 (ru) * | 2002-07-09 | 2007-01-27 | Ланген ЛИ | Сокатализатор для термообработки атмосферы и способ его применения, способ тепловой обработки и атмосфера термообработки с использованием сокатализатора |
| EP2210929B1 (en) * | 2007-10-31 | 2016-11-23 | China Petroleum & Chemical Corporation | A pre-passivation process for a continuous reforming apparatus |
| US20120277500A1 (en) * | 2011-04-29 | 2012-11-01 | Uop Llc | High Temperature Platforming Process |
| US20120277511A1 (en) * | 2011-04-29 | 2012-11-01 | Uop Llc | High Temperature Platformer |
| CN102898265B (zh) * | 2011-07-29 | 2014-08-06 | 中国石油化工股份有限公司 | 一种烯烃的生产方法 |
| ES2549704B1 (es) * | 2014-04-30 | 2016-09-08 | Abengoa Hidrógeno, S.A. | Tubo reactor de reformado con vapor de agua |
| PL3336055T3 (pl) | 2016-12-19 | 2019-10-31 | Air Liquide | Zabezpieczona przed korozją rura reformera z wewnętrznym wymiennikiem ciepła |
| CN115463662B (zh) * | 2022-10-08 | 2023-06-02 | 中国矿业大学 | 一种负载型金属间化合物催化剂的制备及其在木质素衍生酚类化合物加氢脱氧中的应用 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1149163A (en) * | 1966-03-22 | 1969-04-16 | Ici Ltd | Protection against carburisation |
| GB1362374A (en) * | 1970-06-17 | 1974-08-07 | Wisniewski L | Method of and composition for anti-corrosive protection by reduc tion of ionised metals on metal substrate |
| CH556396A (de) * | 1971-11-03 | 1974-11-29 | Buechler Josef Heinrich | Verfahren zum aufbringen einer korrosionsschutzschicht auf ein metall und vorrichtung zur durchfuehrung des verfahrens. |
| US4348271A (en) * | 1981-07-14 | 1982-09-07 | Exxon Research & Engineering Co. | Catalytic reforming process |
| US4447316A (en) * | 1982-02-01 | 1984-05-08 | Chevron Research Company | Composition and a method for its use in dehydrocyclization of alkanes |
| US4456527A (en) * | 1982-10-20 | 1984-06-26 | Chevron Research Company | Hydrocarbon conversion process |
| US4634515A (en) * | 1985-10-25 | 1987-01-06 | Exxon Research And Engineering Company | Nickel adsorbent for sulfur removal from hydrocarbon feeds |
| US4692234A (en) * | 1986-04-09 | 1987-09-08 | Phillips Petroleum Company | Antifoulants for thermal cracking processes |
| JPS62256946A (ja) * | 1986-04-30 | 1987-11-09 | Nippon Kokan Kk <Nkk> | 耐クリ−プ脆化性および耐低温割れ性に優れたＣｒ−Ｍｏ鋼 |
| FR2600668B1 (fr) * | 1986-06-25 | 1989-05-19 | Inst Francais Du Petrole | Procede de reformage catalytique a travers au moins deux lits de catalyseur |
-
1992
- 1992-03-06 KR KR1019930702697A patent/KR100230727B1/ko not_active Expired - Fee Related
- 1992-03-06 JP JP50830092A patent/JP3836499B2/ja not_active Expired - Fee Related
- 1992-03-06 BR BR9205738A patent/BR9205738A/pt not_active IP Right Cessation
- 1992-03-06 DE DE69222633T patent/DE69222633T2/de not_active Expired - Lifetime
- 1992-03-06 EP EP98100396A patent/EP0845521B1/en not_active Expired - Lifetime
- 1992-03-06 HU HU9302543A patent/HUT75107A/hu unknown
- 1992-03-06 EP EP97110024A patent/EP0798363B1/en not_active Expired - Lifetime
- 1992-03-06 DE DE69233084T patent/DE69233084T2/de not_active Expired - Lifetime
- 1992-03-06 SG SG200004098A patent/SG96561A1/en unknown
- 1992-03-06 ES ES97110024T patent/ES2201223T3/es not_active Expired - Lifetime
- 1992-03-06 ES ES98100396T patent/ES2190551T3/es not_active Expired - Lifetime
- 1992-03-06 EP EP92908806A patent/EP0576571B1/en not_active Expired - Lifetime
- 1992-03-06 WO PCT/US1992/001856 patent/WO1992015653A1/en active IP Right Grant
- 1992-03-06 ES ES92908806T patent/ES2108112T3/es not_active Expired - Lifetime
- 1992-03-06 AU AU15801/92A patent/AU665534B2/en not_active Ceased
- 1992-03-06 SG SG1996009668A patent/SG72690A1/en unknown
- 1992-03-06 AT AT92908806T patent/ATE159040T1/de not_active IP Right Cessation
- 1992-03-06 DE DE69232891T patent/DE69232891T2/de not_active Expired - Lifetime
- 1992-03-07 CN CN92102539A patent/CN1039720C/zh not_active Expired - Fee Related
- 1992-03-07 MY MYPI92000372A patent/MY109992A/en unknown
- 1992-09-05 SA SA92130085A patent/SA92130085B1/ar unknown
-
1993
- 1993-09-06 NO NO933165A patent/NO933165D0/no unknown
- 1993-09-06 OA OA60409A patent/OA09910A/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE202009005950U1 (de) | 2009-04-27 | 2009-08-20 | Holland-Letz, Peter | Gewebe zur Körperabdeckung zur Applikation von Arzneimitteln |
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Owner name: CHEVRON PHILLIPS CHEMICAL CO. LP, THE WOODLANDS, T |