DE60314629T2 - Ziegler natta katalysator für die polymerisation von olefinen - Google Patents
Ziegler natta katalysator für die polymerisation von olefinen Download PDFInfo
- Publication number
- DE60314629T2 DE60314629T2 DE60314629T DE60314629T DE60314629T2 DE 60314629 T2 DE60314629 T2 DE 60314629T2 DE 60314629 T DE60314629 T DE 60314629T DE 60314629 T DE60314629 T DE 60314629T DE 60314629 T2 DE60314629 T2 DE 60314629T2
- Authority
- DE
- Germany
- Prior art keywords
- weight ratio
- groups
- catalyst component
- catalyst
- ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 29
- 239000011954 Ziegler–Natta catalyst Substances 0.000 title 1
- 239000003054 catalyst Substances 0.000 claims abstract description 57
- 239000010936 titanium Substances 0.000 claims abstract description 43
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000001257 hydrogen Substances 0.000 claims abstract description 16
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 13
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 8
- 125000001033 ether group Chemical group 0.000 claims abstract description 8
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 7
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 7
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims abstract description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 6
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 6
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 6
- 125000005842 heteroatom Chemical group 0.000 claims abstract description 4
- 150000001875 compounds Chemical class 0.000 claims description 35
- -1 alkylaluminum halides Chemical class 0.000 claims description 30
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 26
- 239000005977 Ethylene Substances 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 20
- 125000003118 aryl group Chemical group 0.000 claims description 12
- 150000001336 alkenes Chemical class 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 239000004711 α-olefin Substances 0.000 claims description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 claims description 3
- JGHYBJVUQGTEEB-UHFFFAOYSA-M dimethylalumanylium;chloride Chemical compound C[Al](C)Cl JGHYBJVUQGTEEB-UHFFFAOYSA-M 0.000 claims description 3
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 claims description 2
- HQMRIBYCTLBDAK-UHFFFAOYSA-M bis(2-methylpropyl)alumanylium;chloride Chemical compound CC(C)C[Al](Cl)CC(C)C HQMRIBYCTLBDAK-UHFFFAOYSA-M 0.000 claims description 2
- 125000002877 alkyl aryl group Chemical group 0.000 claims 1
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 150000002899 organoaluminium compounds Chemical class 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 9
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract description 6
- 239000008096 xylene Substances 0.000 abstract description 4
- 229920001038 ethylene copolymer Polymers 0.000 abstract description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 30
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 22
- 229920000642 polymer Polymers 0.000 description 21
- 239000011777 magnesium Substances 0.000 description 19
- 125000000217 alkyl group Chemical group 0.000 description 15
- 229910052736 halogen Inorganic materials 0.000 description 15
- 239000000460 chlorine Substances 0.000 description 14
- 150000002367 halogens Chemical class 0.000 description 14
- 239000000243 solution Substances 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 11
- 230000002140 halogenating effect Effects 0.000 description 11
- 229910052757 nitrogen Inorganic materials 0.000 description 11
- 239000007787 solid Substances 0.000 description 9
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 8
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 8
- 239000003638 chemical reducing agent Substances 0.000 description 8
- 229920000092 linear low density polyethylene Polymers 0.000 description 8
- 230000001603 reducing effect Effects 0.000 description 8
- 239000011949 solid catalyst Substances 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 7
- 239000004707 linear low-density polyethylene Substances 0.000 description 7
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
- 238000009826 distribution Methods 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 6
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 125000005843 halogen group Chemical group 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000012299 nitrogen atmosphere Substances 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 229920000548 poly(silane) polymer Polymers 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 150000003377 silicon compounds Chemical class 0.000 description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- 150000003609 titanium compounds Chemical class 0.000 description 3
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 3
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 3
- BHPDSAAGSUWVMP-UHFFFAOYSA-N 3,3-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(C(C)C)(COC)CCC(C)C BHPDSAAGSUWVMP-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical group 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 2
- 238000007429 general method Methods 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- 238000003760 magnetic stirring Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920005606 polypropylene copolymer Polymers 0.000 description 2
- 230000007928 solubilization Effects 0.000 description 2
- 238000005063 solubilization Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 2
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- SEZHLKZEWYFCRB-UHFFFAOYSA-N 1,2-dimethoxyethane;oxolane Chemical compound C1CCOC1.COCCOC SEZHLKZEWYFCRB-UHFFFAOYSA-N 0.000 description 1
- UUAMLBIYJDPGFU-UHFFFAOYSA-N 1,3-dimethoxypropane Chemical compound COCCCOC UUAMLBIYJDPGFU-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- SHFQQELHDBUGFP-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-2-methyldecane Chemical compound CCCCCCCCC(C)(COC)COC SHFQQELHDBUGFP-UHFFFAOYSA-N 0.000 description 1
- 125000001637 1-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C(*)=C([H])C([H])=C([H])C2=C1[H] 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910018557 Si O Inorganic materials 0.000 description 1
- 229910005096 Si3H8 Inorganic materials 0.000 description 1
- 229910003902 SiCl 4 Inorganic materials 0.000 description 1
- 229910003910 SiCl4 Inorganic materials 0.000 description 1
- 229910003822 SiHCl3 Inorganic materials 0.000 description 1
- 229910004469 SiHx Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000004708 Very-low-density polyethylene Substances 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000004104 aryloxy group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- SLLGVCUQYRMELA-UHFFFAOYSA-N chlorosilicon Chemical compound Cl[Si] SLLGVCUQYRMELA-UHFFFAOYSA-N 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- ORVACBDINATSAR-UHFFFAOYSA-N dimethylaluminum Chemical compound C[Al]C ORVACBDINATSAR-UHFFFAOYSA-N 0.000 description 1
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 1
- 125000005982 diphenylmethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 229920001198 elastomeric copolymer Polymers 0.000 description 1
- 229920013728 elastomeric terpolymer Polymers 0.000 description 1
- 238000004993 emission spectroscopy Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229940078552 o-xylene Drugs 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000003918 potentiometric titration Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000002076 thermal analysis method Methods 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- ZOYFEXPFPVDYIS-UHFFFAOYSA-N trichloro(ethyl)silane Chemical compound CC[Si](Cl)(Cl)Cl ZOYFEXPFPVDYIS-UHFFFAOYSA-N 0.000 description 1
- PKDCQJMRWCHQOH-UHFFFAOYSA-N triethoxysilicon Chemical compound CCO[Si](OCC)OCC PKDCQJMRWCHQOH-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 229920001866 very low density polyethylene Polymers 0.000 description 1
- 238000003221 volumetric titration Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02077418 | 2002-06-13 | ||
| EP02077418 | 2002-06-13 | ||
| PCT/EP2003/005268 WO2003106511A1 (en) | 2002-06-13 | 2003-05-19 | Catalyst components for the polymerization of olefins |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60314629D1 DE60314629D1 (de) | 2007-08-09 |
| DE60314629T2 true DE60314629T2 (de) | 2008-06-05 |
Family
ID=29724510
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60314629T Expired - Lifetime DE60314629T2 (de) | 2002-06-13 | 2003-05-19 | Ziegler natta katalysator für die polymerisation von olefinen |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7208436B2 (enExample) |
| EP (1) | EP1511780B1 (enExample) |
| JP (1) | JP2005529224A (enExample) |
| AT (1) | ATE365752T1 (enExample) |
| DE (1) | DE60314629T2 (enExample) |
| ES (1) | ES2289295T3 (enExample) |
| WO (1) | WO2003106511A1 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TR200400209T1 (tr) * | 2002-06-13 | 2005-04-21 | Basell Poliolefine Italia S.P.A | Etilen kopolimerlerini hazırlamak için işlem |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| BR0315341B1 (pt) | 2002-10-15 | 2014-02-18 | Adesivos compreendendo poliolefina. | |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| EP1856162A1 (en) * | 2005-03-11 | 2007-11-21 | Basell Poliolefine Italia S.r.l. | Catalyst components comprising titanium, magnesium, halogen and 1,2-dimethoxyethane for the polymerization of olefins |
| CA2618856C (en) * | 2005-09-02 | 2014-05-06 | Span Tech Llc | Wear-resistant connector for a modular link conveyor belt |
| RU2417838C2 (ru) * | 2006-02-21 | 2011-05-10 | Базелль Полиолефин Италия С.Р.Л. | Компоненты катализатора для полимеризации олефинов |
| US8034735B2 (en) * | 2006-11-21 | 2011-10-11 | Basell Poliolefine Italia, s.r.l. | Catalyst component for the polymerization of olefins |
| EA029440B1 (ru) | 2011-12-12 | 2018-03-30 | Сауди Бейсик Индастриз Корпорейшн | Способ получения бимодального полиэтилена в присутствии данной системы катализатора |
| US9518135B2 (en) | 2011-12-12 | 2016-12-13 | Saudi Basic Industries Corporation | Catalyst system for the production of ultra-high molecular weight polyethylene |
| BR112015015773A2 (pt) * | 2012-12-31 | 2017-07-11 | Reliance Industries Ltd | sistema de catalisador ziegler-natta heterogêneo e um processo para polimerização de olefina com uso do mesmo |
| AU2014321368B2 (en) | 2013-09-19 | 2017-10-26 | W.L. Gore & Associates, Inc. | Dilator systems and methods |
| US20160325274A1 (en) * | 2014-01-06 | 2016-11-10 | Saudi Basic Industries Corporation | Catalyst compositions for ethylene dimerization |
| JP6598285B2 (ja) * | 2014-11-11 | 2019-10-30 | サンアロマー株式会社 | α−オレフィン類の重合方法 |
| EP3274377B1 (en) | 2015-03-24 | 2023-09-06 | SABIC Global Technologies B.V. | Catalyst system and process for the production of polyethylenes |
| WO2018060116A1 (en) * | 2016-09-30 | 2018-04-05 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins |
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| IT1078995B (it) | 1977-05-24 | 1985-05-08 | Montedison Spa | Catalizzatori per la polimeriazzazione di olefine |
| US4400303A (en) | 1981-03-09 | 1983-08-23 | Phillips Petroleum Company | Catalyst for olefin polymerization |
| IT1178466B (it) | 1984-03-20 | 1987-09-09 | Montedison Spa | Catalizzatori per la omo e copolimerizzazione dell'etilene e polimeri ottenuti |
| IT1227258B (it) | 1988-09-30 | 1991-03-28 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1237812B (it) * | 1989-12-22 | 1993-06-17 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1238387B (it) | 1990-01-10 | 1993-07-16 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| JPH04145105A (ja) | 1990-10-05 | 1992-05-19 | Nippon Oil Co Ltd | エチレン重合体または共重合体の製造方法 |
| IT1245250B (it) | 1991-03-27 | 1994-09-13 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1246614B (it) | 1991-06-03 | 1994-11-24 | Himont Inc | Procedimento per la polimerizzazione in fase gas delle olefine |
| IT1250731B (it) | 1991-07-31 | 1995-04-21 | Himont Inc | Procedimento per la preparazione di polietilene lineare a bassa densita' |
| IT1252205B (it) * | 1991-12-13 | 1995-06-05 | Himont Inc | Processo per la preparazione di poliolefine stabilizzate e prodotti cosi` ottenuti. |
| IT1254279B (it) | 1992-03-13 | 1995-09-14 | Montecatini Tecnologie Srl | Procedimento per la polimerizzazione in fase gas delle olefine |
| US5200502A (en) * | 1992-08-26 | 1993-04-06 | Union Carbide Chemicals & Plastics Technology Corporation | Deactivator reagent for olefin polymerization catalysts |
| IT1264679B1 (it) | 1993-07-07 | 1996-10-04 | Spherilene Srl | Catalizzatori per la (co)polimerizzazione di etilene |
| US6864207B2 (en) * | 1997-01-28 | 2005-03-08 | Fina Technology, Inc. | Ziegler-Natta catalyst for polyolefins |
| SG73622A1 (en) * | 1998-03-11 | 2000-06-20 | Sumitomo Chemical Co | Solid catalyst component and catalyst for olefin polymerization and process for producing olefin polymer |
| KR100528310B1 (ko) * | 1998-03-23 | 2005-11-15 | 바셀 테크놀로지 캄파니 비이브이 | 올레핀 중합용 예비중합된 촉매 성분 |
| ATE258192T1 (de) | 1998-05-06 | 2004-02-15 | Basell Poliolefine Spa | Katalysatorbestandteile für die olefinpolymerisation |
| IT1301990B1 (it) * | 1998-08-03 | 2000-07-20 | Licio Zambon | Catalizzatori per la polimerizzazione delle olefine. |
| EP1082359B1 (en) * | 1999-03-15 | 2006-07-19 | Basell Poliolefine Italia S.r.l. | Components and catalysts for the polymerization of olefins |
| IT1311978B1 (it) * | 1999-03-25 | 2002-03-22 | Polimeri Europa Srl | Catalizzatore bimetallico per la (co) polimerizzazione dellealfa-olefine. |
| WO2000063261A1 (en) * | 1999-04-15 | 2000-10-26 | Basell Technology Company B.V. | Components and catalysts for the polymerization of olefins |
| KR100676661B1 (ko) * | 1999-06-18 | 2007-01-31 | 바셀 테크놀로지 캄파니 비이브이 | 올레핀 중합용 촉매 성분 및 이로부터 수득된 촉매 |
| SG87202A1 (en) * | 2000-02-08 | 2002-03-19 | Sumitomo Chemical Co | Process for pruducing solid catalyst component and catalyst alpha-olefin polymerization, and process for producing alpha-olefin polymer |
| JP2002173504A (ja) * | 2000-11-29 | 2002-06-21 | Basell Technology Co Bv | オレフィン重合用触媒およびオレフィン重合方法 |
| US6841632B2 (en) | 2001-06-13 | 2005-01-11 | Basell Poliolefine Italis S.P.A. | Components and catalysts for the (co)polymerization of olefins |
| US6818711B2 (en) * | 2003-01-01 | 2004-11-16 | Fina Technology, Inc. | Polymerization of olefins using a ziegler-natta catalyst system having an external electron donor |
-
2003
- 2003-05-19 DE DE60314629T patent/DE60314629T2/de not_active Expired - Lifetime
- 2003-05-19 ES ES03730075T patent/ES2289295T3/es not_active Expired - Lifetime
- 2003-05-19 AT AT03730075T patent/ATE365752T1/de not_active IP Right Cessation
- 2003-05-19 WO PCT/EP2003/005268 patent/WO2003106511A1/en not_active Ceased
- 2003-05-19 EP EP03730075A patent/EP1511780B1/en not_active Expired - Lifetime
- 2003-05-19 JP JP2004513341A patent/JP2005529224A/ja active Pending
- 2003-05-19 US US10/517,587 patent/US7208436B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US7208436B2 (en) | 2007-04-24 |
| US20050215424A1 (en) | 2005-09-29 |
| DE60314629D1 (de) | 2007-08-09 |
| ATE365752T1 (de) | 2007-07-15 |
| ES2289295T3 (es) | 2008-02-01 |
| EP1511780B1 (en) | 2007-06-27 |
| EP1511780A1 (en) | 2005-03-09 |
| JP2005529224A (ja) | 2005-09-29 |
| WO2003106511A1 (en) | 2003-12-24 |
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