BR112015015773A2 - sistema de catalisador ziegler-natta heterogêneo e um processo para polimerização de olefina com uso do mesmo - Google Patents
sistema de catalisador ziegler-natta heterogêneo e um processo para polimerização de olefina com uso do mesmoInfo
- Publication number
- BR112015015773A2 BR112015015773A2 BR112015015773A BR112015015773A BR112015015773A2 BR 112015015773 A2 BR112015015773 A2 BR 112015015773A2 BR 112015015773 A BR112015015773 A BR 112015015773A BR 112015015773 A BR112015015773 A BR 112015015773A BR 112015015773 A2 BR112015015773 A2 BR 112015015773A2
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst system
- natta catalyst
- elemental
- present
- heterogeneous ziegler
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
- C08F4/6423—Component of C08F4/64 containing at least two different metals
- C08F4/6425—Component of C08F4/64 containing at least two different metals containing magnesium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
- C08F4/6423—Component of C08F4/64 containing at least two different metals
- C08F4/6426—Component of C08F4/64 containing at least two different metals containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/645—Component covered by group C08F4/64 with a metal or compound covered by group C08F4/44, not provided for in a single group of groups C08F4/642 - C08F4/643
- C08F4/6452—Component of C08F4/64 containing at least two different metals
- C08F4/6455—Component of C08F4/64 containing at least two different metals containing magnesium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/645—Component covered by group C08F4/64 with a metal or compound covered by group C08F4/44, not provided for in a single group of groups C08F4/642 - C08F4/643
- C08F4/6452—Component of C08F4/64 containing at least two different metals
- C08F4/6457—Component of C08F4/64 containing at least two different metals containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/647—Catalysts containing a specific non-metal or metal-free compound
- C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
resumo sistema de catalisador ziegler-natta heterogêneo e um processo para polimerização de olefina com uso do mesmo a presente revelação refere-se a um sistema de catalisador ziegler-natta heterogêneo a ser usado na preparação de polímeros de altíssimo peso molecular (uhmwp). o sistema inclui pelo menos um pró-catalisador, pelo menos um cocatalisador, pelo menos um meio de hidrocarboneto e pelo menos um doador externo, em que a razão de magnésio elemental para titânio elemental para halogeneto, no pró-catalisador, é 1:1,3:3,7, a razão de alumínio elemental, presente no cocatalisador para titânio elemental, presente no pró-catalisador, está situada na faixa entre 6:1 e 12:1 e a razão de silício elemental, presente no doador externo para titânio elemental, presente no pró-catalisador, está situada na faixa entre 1:10 e 10:1. a presente revelação também se refere a um processo para preparação de uhmwpe com uso do sistema de catalisador ziegler-natta heterogêneo da presente revelação.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IN3737MU2012 | 2012-12-31 | ||
PCT/IN2013/000769 WO2014102813A1 (en) | 2012-12-31 | 2013-12-13 | Heterogeneous ziegler-natta catalyst system and a process for olefin polymerization using the same |
Publications (1)
Publication Number | Publication Date |
---|---|
BR112015015773A2 true BR112015015773A2 (pt) | 2017-07-11 |
Family
ID=54169551
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112015015773A BR112015015773A2 (pt) | 2012-12-31 | 2013-12-13 | sistema de catalisador ziegler-natta heterogêneo e um processo para polimerização de olefina com uso do mesmo |
Country Status (6)
Country | Link |
---|---|
US (1) | US9884927B2 (pt) |
EP (1) | EP2938642A4 (pt) |
KR (1) | KR101990665B1 (pt) |
CN (1) | CN104955851A (pt) |
BR (1) | BR112015015773A2 (pt) |
WO (1) | WO2014102813A1 (pt) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10544243B2 (en) * | 2014-02-17 | 2020-01-28 | Reliance Industries Limited | Heterogeneous Ziegler-Natta catalyst composition, a process for its preparation and a process for polymerizing olefin using the same |
WO2016124676A1 (en) | 2015-02-05 | 2016-08-11 | Borealis Ag | Process for producing polyethylene |
US10094399B2 (en) * | 2015-11-30 | 2018-10-09 | Indian Oil Corporation Limited | Process of preparation of drag reducing polymers and usage thereof |
WO2018134007A1 (en) * | 2017-01-20 | 2018-07-26 | Basell Poliolefine Italia S.R.L. | Method for feeding a fluid to a gas phase polymerization reactor |
CN109810398A (zh) * | 2017-11-21 | 2019-05-28 | 中国石油天然气股份有限公司 | 一种超高分子量等规聚丙烯树脂组合物及其制备方法 |
KR20210076701A (ko) | 2019-12-16 | 2021-06-24 | 현대자동차주식회사 | 연료전지용 에틸렌-프로필렌-디엔 공중합체 및 그 제조방법 |
EP4143241A1 (en) | 2020-04-30 | 2023-03-08 | Dow Global Technologies LLC | Ziegler-natta (pro)catalyst systems made with (multi-alkoxy)silane compound |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0717709B2 (ja) | 1987-11-13 | 1995-03-01 | 日本石油株式会社 | 超高分子量ポリエチレンの製造方法 |
GB9010887D0 (en) * | 1990-05-15 | 1990-07-04 | Ici Plc | Olefin copolymers |
FI90083C (fi) | 1990-12-20 | 1993-12-27 | Neste Oy | Foer olefinpolymerisation avsett stereospecifikt katalysatorsystem |
FI104080B (fi) | 1996-05-15 | 1999-11-15 | Borealis As | Olefiinien polymerointiin tarkoitettu stereospesifinen katalyyttisysteemi ja monivaiheiset polymerointiprosessit, joissa tätä systeemiä käytetään |
KR100351386B1 (ko) * | 2000-04-24 | 2002-09-05 | 삼성종합화학주식회사 | 초고분자량 폴리에틸렌 제조용 촉매 및 이를 이용한초고분자량 폴리에틸렌 제조방법 |
EP1260545A1 (en) | 2001-05-21 | 2002-11-27 | Borealis Technology OY | Industrial polyolefin piping system |
EP1260547A1 (en) | 2001-05-21 | 2002-11-27 | Borealis Technology OY | Polyolefin coated steel pipes |
CA2365718A1 (en) | 2001-12-18 | 2003-06-18 | Nova Chemicals Corporation | High temperature ziegler-natta solution catalysts |
JP2003246976A (ja) * | 2001-12-19 | 2003-09-05 | Toyota Industries Corp | 圧縮機用シール材および該圧縮機用シール材を備えた圧縮機、圧縮機における冷媒シール方法 |
WO2003055921A1 (en) * | 2001-12-24 | 2003-07-10 | Basell Poliolefine Italia S.P.A. | Ziegler natta catalyst for the polymerization of olefins |
TR200400209T1 (tr) | 2002-06-13 | 2005-04-21 | Basell Poliolefine Italia S.P.A | Etilen kopolimerlerini hazırlamak için işlem |
JP2005529224A (ja) * | 2002-06-13 | 2005-09-29 | バセル ポリオレフィン イタリア エス.ピー.エー. | オレフィンの重合のための触媒成分 |
JP4558487B2 (ja) | 2002-08-09 | 2010-10-06 | バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | 改質チーグラー触媒、改質チーグラー触媒の製造方法、及び改質チーグラー触媒の存在下におけるポリ−1−オレフィンの製造方法 |
KR101144513B1 (ko) * | 2007-01-04 | 2012-05-11 | 주식회사 엘지화학 | 초고분자량 폴리에틸렌 중합용 촉매, 이의 제조방법 및이를 이용한 초고분자량 폴리에틸렌 중합 방법 |
KR101040388B1 (ko) * | 2007-01-30 | 2011-06-09 | 주식회사 엘지화학 | 트리옥사실로칸을 포함하는 올레핀 중합용 촉매 및 이를이용한 올레핀 중합 방법 |
BRPI0815890A2 (pt) | 2007-08-29 | 2015-02-24 | Basell Poliolefine Srl | Catalisador para a polimerização de olefinas |
US7786237B2 (en) * | 2008-02-01 | 2010-08-31 | Fina Technology, Inc. | Polyethylene materials prepared using mixed ziegler-natta catalysts systems |
US20110159287A1 (en) | 2008-04-17 | 2011-06-30 | Saudi Basic Industries Corporation | Process for the Production of Ultra High Molecular Weight Polyethylene |
EP2308903A1 (en) * | 2009-09-30 | 2011-04-13 | Borealis AG | Procatalyst for olefin polymerization |
EP2366722A1 (en) * | 2010-03-19 | 2011-09-21 | Total Petrochemicals Research Feluy | Bimodal polyethylene for injection stretch blow moulding applications. |
EP2539378B1 (en) | 2010-02-26 | 2018-06-06 | W.R. Grace & CO. - CONN. | Halogenated amide ester and internal electron donor with same |
US10351640B2 (en) * | 2010-04-22 | 2019-07-16 | Fina Technology, Inc. | Formation of Ziegler-Natta catalyst using non-blended components |
US10711077B2 (en) * | 2011-02-07 | 2020-07-14 | Fina Technology, Inc. | Ziegler-natta catalyst composition with controlled morphology |
CN103502348B (zh) | 2011-03-04 | 2016-02-03 | 道达尔研究技术弗吕公司 | 齐格勒-纳塔生产的聚乙烯共混物的制备方法 |
RS56541B1 (sr) * | 2011-03-04 | 2018-02-28 | Total Res & Technology Feluy | Postupak za pripremanje smeše polietilena koja sadrži smole proizvedene sa metalocenom i smole proizvedene sa cigler-nata katalizatorom |
US8685879B2 (en) * | 2011-04-29 | 2014-04-01 | Basf Corporation | Emulsion process for improved large spherical polypropylene catalysts |
-
2013
- 2013-12-13 BR BR112015015773A patent/BR112015015773A2/pt not_active Application Discontinuation
- 2013-12-13 US US14/655,994 patent/US9884927B2/en not_active Expired - Fee Related
- 2013-12-13 WO PCT/IN2013/000769 patent/WO2014102813A1/en active Application Filing
- 2013-12-13 EP EP13867424.7A patent/EP2938642A4/en not_active Withdrawn
- 2013-12-13 KR KR1020157020390A patent/KR101990665B1/ko active IP Right Grant
- 2013-12-13 CN CN201380071360.4A patent/CN104955851A/zh active Pending
Also Published As
Publication number | Publication date |
---|---|
KR101990665B1 (ko) | 2019-06-18 |
KR20150103696A (ko) | 2015-09-11 |
EP2938642A1 (en) | 2015-11-04 |
CN104955851A (zh) | 2015-09-30 |
WO2014102813A1 (en) | 2014-07-03 |
EP2938642A4 (en) | 2016-09-14 |
US9884927B2 (en) | 2018-02-06 |
US20150344593A1 (en) | 2015-12-03 |
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B06F | Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette] | ||
B06F | Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette] | ||
B06I | Publication of requirement cancelled [chapter 6.9 patent gazette] |
Free format text: ANULADA A PUBLICACAO CODIGO 6.6.1 NA RPI NO 2462 DE 13/03/2018 POR TER SIDO INDEVIDA. |
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B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
B11B | Dismissal acc. art. 36, par 1 of ipl - no reply within 90 days to fullfil the necessary requirements |