DE60307724D1 - Neue Diphosphinverbindung, Zwischenprodukte für deren Herstellung, Übergangsmetallkomplex enthaltend die Verbindung als Ligand und Katalysator für asymmetrische Hydrierungen, welcher den Komplex enthält - Google Patents

Neue Diphosphinverbindung, Zwischenprodukte für deren Herstellung, Übergangsmetallkomplex enthaltend die Verbindung als Ligand und Katalysator für asymmetrische Hydrierungen, welcher den Komplex enthält

Info

Publication number
DE60307724D1
DE60307724D1 DE60307724T DE60307724T DE60307724D1 DE 60307724 D1 DE60307724 D1 DE 60307724D1 DE 60307724 T DE60307724 T DE 60307724T DE 60307724 T DE60307724 T DE 60307724T DE 60307724 D1 DE60307724 D1 DE 60307724D1
Authority
DE
Germany
Prior art keywords
compound
catalyst
ligand
complex
intermediates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60307724T
Other languages
English (en)
Other versions
DE60307724T2 (de
Inventor
T Yokozawa
Takao Saito
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Takasago International Corp
Original Assignee
Takasago International Corp
Takasago Perfumery Industry Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Takasago International Corp, Takasago Perfumery Industry Co filed Critical Takasago International Corp
Application granted granted Critical
Publication of DE60307724D1 publication Critical patent/DE60307724D1/de
Publication of DE60307724T2 publication Critical patent/DE60307724T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2447—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
    • B01J31/2452—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom
    • B01J31/2457—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings, e.g. Xantphos
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2291—Olefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/36—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by hydrogenation of carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D321/00—Heterocyclic compounds containing rings having two oxygen atoms as the only ring hetero atoms, not provided for by groups C07D317/00 - C07D319/00
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/655—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms
    • C07F9/65525—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a seven-(or more) membered ring
    • C07F9/65527—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a seven-(or more) membered ring condensed with carbocyclic rings or carbocyclic ring systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
DE60307724T 2002-06-04 2003-06-04 Neue Diphosphinverbindung, Zwischenprodukte für deren Herstellung, Übergangsmetallkomplex enthaltend die Verbindung als Ligand und Katalysator für asymmetrische Hydrierungen, welcher den Komplex enthält Expired - Lifetime DE60307724T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2002162463A JP4148702B2 (ja) 2002-06-04 2002-06-04 新規なジホスフィン化合物、その製造中間体、該化合物を配位子とする遷移金属錯体並びに該錯体を含む不斉水素化触媒
JP2002162463 2002-06-04

Publications (2)

Publication Number Publication Date
DE60307724D1 true DE60307724D1 (de) 2006-10-05
DE60307724T2 DE60307724T2 (de) 2007-09-13

Family

ID=29561674

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60307724T Expired - Lifetime DE60307724T2 (de) 2002-06-04 2003-06-04 Neue Diphosphinverbindung, Zwischenprodukte für deren Herstellung, Übergangsmetallkomplex enthaltend die Verbindung als Ligand und Katalysator für asymmetrische Hydrierungen, welcher den Komplex enthält

Country Status (6)

Country Link
US (1) US6794328B2 (de)
EP (1) EP1371655B1 (de)
JP (1) JP4148702B2 (de)
AT (1) ATE337325T1 (de)
DE (1) DE60307724T2 (de)
ES (1) ES2269944T3 (de)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2010221662B2 (en) 2009-03-04 2015-04-02 Chevron Phillips Chemical Company Lp Selective hydrogenation catalyst and methods of making and using same
CN107417726B (zh) * 2017-07-05 2019-11-05 华东师范大学 基于氧杂蒽骨架的手性单膦配体PC-Phos及其全构型的制备方法和应用

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5561937A (en) 1978-11-06 1980-05-10 Ajinomoto Co Inc Catalyst for asymmetric hydrogenation
JPS60199898A (ja) 1984-03-22 1985-10-09 Takasago Corp ロジウム−ホスフイン錯体
JPS6163690A (ja) 1984-09-04 1986-04-01 Takasago Corp ルテニウム−ホスフイン錯体
JPH0768260B2 (ja) 1990-03-01 1995-07-26 高砂香料工業株式会社 ２，２’―ビス〔ジ―（３，５―ジアルキルフェニル）ホスフィノ〕―１，１’―ビナフチル及びこれを配位子とする遷移金属錯体
IT1252043B (it) * 1990-11-20 1995-05-29 Himont Inc Fosfiti organici adatti come stabilizzanti e composizioni polimeriche comprendenti gli stessi.
US6333435B1 (en) * 1995-05-18 2001-12-25 Merck & Co., Inc. Process of synthesizing binaphthyl derivatives
JP3892931B2 (ja) * 1997-03-11 2007-03-14 高砂香料工業株式会社 ２個のビニル基を有する光学活性ホスフィン誘導体、それをモノマーとするポリマー、及びそれらの遷移金属錯体
ATE324943T1 (de) 1999-09-20 2006-06-15 Penn State Res Found Chirale phosphine, deren komplexe mit übergangsmetallen und deren verwendung in asymmetrischen synthesereaktionen
JP2001131192A (ja) 1999-10-29 2001-05-15 Takasago Internatl Corp 新規な光学活性ジホスフィン化合物、その製造中間体、該化合物を配位子とする遷移金属錯体並びに該錯体を含む不斉水素化触媒。
DE10044793A1 (de) * 2000-09-11 2002-04-04 Bayer Ag Diphosphine

Also Published As

Publication number Publication date
US6794328B2 (en) 2004-09-21
US20030228977A1 (en) 2003-12-11
ATE337325T1 (de) 2006-09-15
EP1371655B1 (de) 2006-08-23
DE60307724T2 (de) 2007-09-13
ES2269944T3 (es) 2007-04-01
JP4148702B2 (ja) 2008-09-10
JP2004010500A (ja) 2004-01-15
EP1371655A1 (de) 2003-12-17

Similar Documents

Publication Publication Date Title
Noyori et al. Rapid, productive and stereoselective hydrogenation of ketones
Lu et al. Highly enantioselective synthesis of optically active ketones by iridium-catalyzed asymmetric hydrogenation
Bachmann et al. Cis-Selective Asymmetric cyclopropanation of olefins catalyzed by five-coordinate [RuCl (PNNP)]+ complexes
AU2003271713A1 (en) Ruthenium complexes as (pre)catalysts for metathesis reactions
DE502004011288D1 (de) Auf basis von phosphoramiditliganden
ATE397627T1 (de) Geträgerte diphosphorliganden und ihre verwendung in der katalyse
DE60123093D1 (de) Katalysator für asymmetrische hydrogenierung
DE60203193D1 (de) Neue diphosphine, deren komplexe mit übergangsmetallen und deren verwendung in der asymmetrischen synthese
ATE248181T1 (de) Optisch aktive diphosphinverbindung, zwischenprodukte für seine herstellung, übergangsmetallkomplex enthaltend die verbindung als ligand und katalysator für asymmetrische hydrierungen, welcher den komplex enthält
EP0826691A3 (de) Optisch aktive Diphospin Verbindungen,Verfahren zu ihrer Herstellung, Übergangsmetall Komplexe, die diese Verbindungen als Ligand enthalten und Verfahren zur Herstellung optisch aktiver Substanzen unter Verwendung dieser Komplexe
DK1654266T3 (da) Nye metatesekatalysatorer
DE60307724D1 (de) Neue Diphosphinverbindung, Zwischenprodukte für deren Herstellung, Übergangsmetallkomplex enthaltend die Verbindung als Ligand und Katalysator für asymmetrische Hydrierungen, welcher den Komplex enthält
RU2005138144A (ru) Замещенные ферроценилдифосфины в качестве лигандов для гомогенных катализаторов гидрирования
McManus et al. Preparation of pyrrolidine–oxazoline containing ligands and their application in asymmetric transfer hydrogenation
Kang et al. Stereoselective conjugate addition of diethylzinc to enones and nitroalkenes
Adrio et al. The Phenylsulfonyl Group as an endo Stereochemical Controller in Intramolecular Pauson–Khand Reactions of 3‐Oxygenated 1, 6‐Enynes
Le Maux et al. Application of chiral 2, 6-bis (thiazolinyl) pyridines in asymmetric Ru-catalyzed cyclopropanations with diazoesters
ATE482964T1 (de) Herstellung von katalysatoren
ATE455781T1 (de) Neue asymmetrische phosphin-ligande
Réthoré et al. Chiral tetrathiafulvalene based phosphine-and thiomethyl-oxazoline ligands. Evaluation in palladium catalysed asymmetric allylic alkylation
WO2007020221A3 (en) Amino-phosphinoalkyl-ferrocenes and their use as ligands in catalysts for asymmetric reactions
JP2004537405A5 (de)
Gou et al. Scandium Triflate Catalyzed Tandem Transfer Hydrogenation and Cyclization Reaction of o-Aminobenzaldehydes and o-Aminoacetophenone with Alcohols
Adam et al. Molybdenum-catalyzed episulfidation of (E)-cycloalkenes with elemental sulfurThis work was presented at the XIXth International Symposium on the “Organic Chemistry of Sulfur”, Sheffield, England, 25th–30th June 2000. Dedicated to Professor Manfred Christl on the occasion of his 60th birthday.
JP4377635B2 (ja) 有機スズ化合物及びその製造方法

Legal Events

Date Code Title Description
8364 No opposition during term of opposition