DE60220599T2 - Thermisch modifizierte Stärke und Verfahren zu deren Herstellung - Google Patents
Thermisch modifizierte Stärke und Verfahren zu deren Herstellung Download PDFInfo
- Publication number
- DE60220599T2 DE60220599T2 DE60220599T DE60220599T DE60220599T2 DE 60220599 T2 DE60220599 T2 DE 60220599T2 DE 60220599 T DE60220599 T DE 60220599T DE 60220599 T DE60220599 T DE 60220599T DE 60220599 T2 DE60220599 T2 DE 60220599T2
- Authority
- DE
- Germany
- Prior art keywords
- starch
- strength
- acid
- converted
- reactor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 57
- 229920000881 Modified starch Polymers 0.000 title description 6
- 235000019426 modified starch Nutrition 0.000 title description 5
- 238000002360 preparation method Methods 0.000 title description 4
- 239000004368 Modified starch Substances 0.000 title 1
- 229920002472 Starch Polymers 0.000 claims description 68
- 235000019698 starch Nutrition 0.000 claims description 68
- 239000008107 starch Substances 0.000 claims description 50
- 239000002253 acid Substances 0.000 claims description 25
- 239000007789 gas Substances 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 5
- 239000011363 dried mixture Substances 0.000 claims description 4
- 239000012159 carrier gas Substances 0.000 claims description 3
- 238000010923 batch production Methods 0.000 claims description 2
- 238000011437 continuous method Methods 0.000 claims 1
- 238000010792 warming Methods 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
- 239000000047 product Substances 0.000 description 18
- 229920001353 Dextrin Polymers 0.000 description 15
- 238000010438 heat treatment Methods 0.000 description 10
- 239000004375 Dextrin Substances 0.000 description 8
- 235000019425 dextrin Nutrition 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 240000003183 Manihot esculenta Species 0.000 description 4
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 4
- 235000009508 confectionery Nutrition 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 229920000856 Amylose Polymers 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 108090000637 alpha-Amylases Proteins 0.000 description 3
- 102000004139 alpha-Amylases Human genes 0.000 description 3
- 229940024171 alpha-amylase Drugs 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000010411 cooking Methods 0.000 description 3
- 235000013312 flour Nutrition 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000000717 retained effect Effects 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000005538 encapsulation Methods 0.000 description 2
- 229940088598 enzyme Drugs 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 230000003301 hydrolyzing effect Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 230000035772 mutation Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 240000001592 Amaranthus caudatus Species 0.000 description 1
- 235000009328 Amaranthus caudatus Nutrition 0.000 description 1
- 229920000945 Amylopectin Polymers 0.000 description 1
- 235000005273 Canna coccinea Nutrition 0.000 description 1
- 240000008555 Canna flaccida Species 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 206010020772 Hypertension Diseases 0.000 description 1
- 244000017020 Ipomoea batatas Species 0.000 description 1
- 235000002678 Ipomoea batatas Nutrition 0.000 description 1
- 244000151018 Maranta arundinacea Species 0.000 description 1
- 235000010804 Maranta arundinacea Nutrition 0.000 description 1
- 240000008790 Musa x paradisiaca Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 240000004713 Pisum sativum Species 0.000 description 1
- 235000010582 Pisum sativum Nutrition 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 240000006394 Sorghum bicolor Species 0.000 description 1
- 235000011684 Sorghum saccharatum Nutrition 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 235000012419 Thalia geniculata Nutrition 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 238000005903 acid hydrolysis reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 235000012735 amaranth Nutrition 0.000 description 1
- 239000004178 amaranth Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000011260 aqueous acid Substances 0.000 description 1
- 235000015173 baked goods and baking mixes Nutrition 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 210000000349 chromosome Anatomy 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000112 colonic effect Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 238000009402 cross-breeding Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 235000021374 legumes Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 150000002482 oligosaccharides Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000005945 translocation Effects 0.000 description 1
- 238000010977 unit operation Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
- A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
- A23G3/36—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
- A23G3/42—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds characterised by the carbohydrates used, e.g. polysaccharides
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/30—Foods or foodstuffs containing additives; Preparation or treatment thereof containing carbohydrate syrups; containing sugars; containing sugar alcohols, e.g. xylitol; containing starch hydrolysates, e.g. dextrin
- A23L29/35—Degradation products of starch, e.g. hydrolysates, dextrins; Enzymatically modified starches
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B30/00—Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
- C08B30/12—Degraded, destructured or non-chemically modified starch, e.g. mechanically, enzymatically or by irradiation; Bleaching of starch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B30/00—Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
- C08B30/12—Degraded, destructured or non-chemically modified starch, e.g. mechanically, enzymatically or by irradiation; Bleaching of starch
- C08B30/18—Dextrin, e.g. yellow canari, white dextrin, amylodextrin or maltodextrin; Methods of depolymerisation, e.g. by irradiation or mechanically
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Food Science & Technology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Molecular Biology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Nutrition Science (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US922186 | 2001-08-03 | ||
| US09/922,186 US6746705B2 (en) | 2001-08-03 | 2001-08-03 | Thermally converted starches and the method of preparation thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60220599D1 DE60220599D1 (de) | 2007-07-26 |
| DE60220599T2 true DE60220599T2 (de) | 2008-02-21 |
Family
ID=25446656
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60220599T Expired - Lifetime DE60220599T2 (de) | 2001-08-03 | 2002-08-01 | Thermisch modifizierte Stärke und Verfahren zu deren Herstellung |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6746705B2 (enExample) |
| EP (1) | EP1281721B1 (enExample) |
| JP (1) | JP4365073B2 (enExample) |
| CN (1) | CN1244597C (enExample) |
| AR (1) | AR034973A1 (enExample) |
| AT (1) | ATE364634T1 (enExample) |
| BR (1) | BR0203047A (enExample) |
| DE (1) | DE60220599T2 (enExample) |
| DK (1) | DK1281721T3 (enExample) |
| ES (1) | ES2287207T3 (enExample) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2469542T3 (es) * | 2003-11-13 | 2014-06-18 | Cerestar Holding B.V. | Método para modificar almidón o derivados de almidón |
| KR101249120B1 (ko) * | 2006-08-31 | 2013-03-29 | 킴벌리-클라크 월드와이드, 인크. | 고도 통기성 생분해성 필름 |
| US8227658B2 (en) | 2007-12-14 | 2012-07-24 | Kimberly-Clark Worldwide, Inc | Film formed from a blend of biodegradable aliphatic-aromatic copolyesters |
| US7998888B2 (en) * | 2008-03-28 | 2011-08-16 | Kimberly-Clark Worldwide, Inc. | Thermoplastic starch for use in melt-extruded substrates |
| US8338508B2 (en) * | 2008-05-14 | 2012-12-25 | Kimberly-Clark Worldwide, Inc. | Water-sensitive film containing an olefinic elastomer |
| US8147965B2 (en) | 2008-05-14 | 2012-04-03 | Kimberly-Clark Worldwide, Inc. | Water-sensitive film containing thermoplastic polyurethane |
| US8927617B2 (en) * | 2008-06-30 | 2015-01-06 | Kimberly-Clark Worldwide, Inc. | Fragranced water-sensitive film |
| US8759279B2 (en) * | 2008-06-30 | 2014-06-24 | Kimberly-Clark Worldwide, Inc. | Fragranced biodegradable film |
| US8188185B2 (en) * | 2008-06-30 | 2012-05-29 | Kimberly-Clark Worldwide, Inc. | Biodegradable packaging film |
| US8329601B2 (en) | 2008-12-18 | 2012-12-11 | Kimberly-Clark Worldwide, Inc. | Biodegradable and renewable film |
| US8283006B2 (en) * | 2008-12-18 | 2012-10-09 | Kimberly-Clark Worldwide, Inc. | Injection molding material containing starch and plant protein |
| US8471003B2 (en) * | 2009-04-14 | 2013-06-25 | Corn Products Development Inc. | Thermally inhibited polysaccharides and process of preparing |
| US11173106B2 (en) | 2009-10-07 | 2021-11-16 | Johnson & Johnson Consumer Inc. | Compositions comprising a superhydrophilic amphiphilic copolymer and a micellar thickener |
| US8399590B2 (en) * | 2009-10-07 | 2013-03-19 | Akzo Nobel Chemicals International B.V. | Superhydrophilic amphiphilic copolymers and processes for making the same |
| FR2992983B1 (fr) | 2012-07-06 | 2014-07-04 | Roquette Freres | Sauces de couchage pour papier et carton contenant une dextrine a teneur elevee en amylopectine |
| FR3024874B1 (fr) | 2014-08-14 | 2016-09-02 | Roquette Freres | Copolymere de dextrine avec du styrene et un ester acrylique, son procede de fabrication et son utilisation pour le couchage papetier |
| US11180575B2 (en) * | 2018-12-28 | 2021-11-23 | Corn Products Development, Inc. | Thermally inhibited starch and process for making |
| EP4397185A1 (en) | 2017-09-12 | 2024-07-10 | Corn Products Development, Inc. | Thermally inhibited waxy cassava starch |
| JP6853558B2 (ja) * | 2019-02-01 | 2021-03-31 | 鹿児島県 | 加熱処理により特性を改質した低温糊化性でん粉 |
| CN110551225A (zh) * | 2019-10-12 | 2019-12-10 | 广西农垦明阳生化集团股份有限公司 | 一种热粘度稳定性糊精的制备方法 |
| US20230002512A1 (en) | 2019-11-27 | 2023-01-05 | Cargill, Incorporated | Clean label starch compositions |
| WO2023049675A1 (en) | 2021-09-23 | 2023-03-30 | Cargill, Incorporated | Thermally inhibited, ozone treated starch or flour, and a method of manufacturing a thermally inhibited, ozone treated starch or flour |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2845368A (en) | 1954-05-27 | 1958-07-29 | Staley Mfg Co A E | Dextrinization process |
| GB853828A (en) | 1958-07-21 | 1960-11-09 | Staley Mfg Co A E | Methods for treating starch |
| US3479220A (en) | 1966-03-24 | 1969-11-18 | Keep Chem Co | Acid-modified starches and flours and method of making the same |
| US3967975A (en) | 1974-11-25 | 1976-07-06 | Cpc International Inc. | Fluidization apparatus |
| US4280851A (en) | 1979-12-14 | 1981-07-28 | General Foods Corporation | Process for cooking or gelatinizing materials |
| DD157347A1 (de) | 1981-01-28 | 1982-11-03 | Rolf Schirner | Verbesserung der herstellung von dextrin |
| US4465702A (en) | 1982-11-01 | 1984-08-14 | A. E. Staley Manufacturing Company | Cold-water-soluble granular starch for gelled food compositions |
| US4510166A (en) | 1984-01-19 | 1985-04-09 | National Starch And Chemical Corporation | Converted starches for use as a fat- or oil-replacement in foodstuffs |
| US4587332A (en) | 1984-02-28 | 1986-05-06 | Ogilvie Mills Ltd. | Modified wheat "B" starch for corrugating adhesives |
| DE68914401T2 (de) | 1988-10-07 | 1994-08-25 | Matsutani Kagaku Kogyo Kk | Verfahren zur Herstellung von Dextrin enthaltenden faserigen Nahrungsprodukten. |
| US5149799A (en) | 1990-01-26 | 1992-09-22 | National Starch And Chemical Investment Holding Corporation | Method and apparatus for cooking and spray-drying starch |
| JPH0728694B2 (ja) | 1990-02-22 | 1995-04-05 | 松谷化学工業株式会社 | 整腸作用を有する食品組成物 |
| JPH0745521B2 (ja) | 1990-08-07 | 1995-05-17 | 松谷化学工業株式会社 | 高血圧降下作用を有する高血圧降下剤 |
| US5037929A (en) * | 1990-08-22 | 1991-08-06 | Kansas State University Research Found. | Process for the preparation of granular cold water-soluble starch |
| JPH04173094A (ja) | 1990-11-08 | 1992-06-19 | Matsutani Kagaku Kogyo Kk | 低カロリー・デキストリンの製造法 |
| JP3146086B2 (ja) | 1993-03-24 | 2001-03-12 | 松谷化学工業株式会社 | 鶏飼料 |
| US6221420B1 (en) | 1993-07-30 | 2001-04-24 | National Starch And Chemical Investment Holding Corporation | Foods containing thermally-inhibited starches and flours |
| US6191116B1 (en) | 1998-04-27 | 2001-02-20 | National Starch And Chemical Investment Holding Corporation | Highly soluble, hydratable, viscous, solution stable pyrodextrins, process of making and use thereof |
-
2001
- 2001-08-03 US US09/922,186 patent/US6746705B2/en not_active Expired - Lifetime
-
2002
- 2002-08-01 AT AT02016934T patent/ATE364634T1/de not_active IP Right Cessation
- 2002-08-01 EP EP02016934A patent/EP1281721B1/en not_active Expired - Lifetime
- 2002-08-01 ES ES02016934T patent/ES2287207T3/es not_active Expired - Lifetime
- 2002-08-01 DK DK02016934T patent/DK1281721T3/da active
- 2002-08-01 DE DE60220599T patent/DE60220599T2/de not_active Expired - Lifetime
- 2002-08-02 AR ARP020102962A patent/AR034973A1/es active IP Right Grant
- 2002-08-02 JP JP2002226128A patent/JP4365073B2/ja not_active Expired - Lifetime
- 2002-08-03 CN CNB021425647A patent/CN1244597C/zh not_active Expired - Lifetime
- 2002-08-05 BR BR0203047-0A patent/BR0203047A/pt not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| JP2003128701A (ja) | 2003-05-08 |
| ATE364634T1 (de) | 2007-07-15 |
| JP4365073B2 (ja) | 2009-11-18 |
| BR0203047A (pt) | 2003-05-27 |
| DE60220599D1 (de) | 2007-07-26 |
| CN1405186A (zh) | 2003-03-26 |
| AR034973A1 (es) | 2004-03-24 |
| DK1281721T3 (da) | 2007-09-24 |
| EP1281721B1 (en) | 2007-06-13 |
| US20030031775A1 (en) | 2003-02-13 |
| US6746705B2 (en) | 2004-06-08 |
| ES2287207T3 (es) | 2007-12-16 |
| CN1244597C (zh) | 2006-03-08 |
| EP1281721A1 (en) | 2003-02-05 |
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