DE60219322T2 - Formmasse aus glasigen und semikristallinen polymeren - Google Patents
Formmasse aus glasigen und semikristallinen polymeren Download PDFInfo
- Publication number
- DE60219322T2 DE60219322T2 DE60219322T DE60219322T DE60219322T2 DE 60219322 T2 DE60219322 T2 DE 60219322T2 DE 60219322 T DE60219322 T DE 60219322T DE 60219322 T DE60219322 T DE 60219322T DE 60219322 T2 DE60219322 T2 DE 60219322T2
- Authority
- DE
- Germany
- Prior art keywords
- polymer
- composition according
- glassy
- poly
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920006126 semicrystalline polymer Polymers 0.000 title claims abstract description 23
- 238000000465 moulding Methods 0.000 title claims description 4
- 229920000642 polymer Polymers 0.000 claims abstract description 40
- 239000007787 solid Substances 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims description 40
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 16
- 239000005977 Ethylene Substances 0.000 claims description 16
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical group [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 16
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 13
- 229920001577 copolymer Polymers 0.000 claims description 12
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 12
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 11
- 239000012764 mineral filler Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000004677 Nylon Substances 0.000 claims description 7
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 7
- 239000011707 mineral Substances 0.000 claims description 7
- 229920001778 nylon Polymers 0.000 claims description 7
- 229920000058 polyacrylate Polymers 0.000 claims description 7
- 229920000728 polyester Polymers 0.000 claims description 6
- LQLQDKBJAIILIQ-UHFFFAOYSA-N Dibutyl terephthalate Chemical compound CCCCOC(=O)C1=CC=C(C(=O)OCCCC)C=C1 LQLQDKBJAIILIQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004952 Polyamide Substances 0.000 claims description 4
- 230000009477 glass transition Effects 0.000 claims description 4
- 229920002647 polyamide Polymers 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- 230000036571 hydration Effects 0.000 claims description 2
- 238000006703 hydration reaction Methods 0.000 claims description 2
- 239000002131 composite material Substances 0.000 abstract description 3
- 239000002904 solvent Substances 0.000 abstract description 3
- 239000000945 filler Substances 0.000 description 33
- 239000011521 glass Substances 0.000 description 11
- 239000000463 material Substances 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 9
- -1 polybutylene terephthalate Polymers 0.000 description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 229920001169 thermoplastic Polymers 0.000 description 8
- 239000004416 thermosoftening plastic Substances 0.000 description 8
- 229920003314 Elvaloy® Polymers 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- 238000001125 extrusion Methods 0.000 description 6
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 6
- 239000000155 melt Substances 0.000 description 6
- 235000010755 mineral Nutrition 0.000 description 6
- 239000004417 polycarbonate Substances 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 229920001707 polybutylene terephthalate Polymers 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 238000006748 scratching Methods 0.000 description 5
- 230000002393 scratching effect Effects 0.000 description 5
- 239000005035 Surlyn® Substances 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000004579 marble Substances 0.000 description 4
- 150000004684 trihydrates Chemical class 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229920006038 crystalline resin Polymers 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical compound ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000004957 Zytel Substances 0.000 description 2
- 229920006102 Zytel® Polymers 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 210000004905 finger nail Anatomy 0.000 description 2
- 239000012767 functional filler Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 2
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 2
- 239000004005 microsphere Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 229920002959 polymer blend Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 230000003678 scratch resistant effect Effects 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- PBUQZKXKYSAJDO-UHFFFAOYSA-N 2-[(2-methylpropan-2-yl)oxycarbonyl]benzoic acid Chemical compound CC(C)(C)OC(=O)C1=CC=CC=C1C(O)=O PBUQZKXKYSAJDO-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920003317 Fusabond® Polymers 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 229920005372 Plexiglas® Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229920006125 amorphous polymer Polymers 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 229910052586 apatite Inorganic materials 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
- 229910001863 barium hydroxide Inorganic materials 0.000 description 1
- 229910052916 barium silicate Inorganic materials 0.000 description 1
- HMOQPOVBDRFNIU-UHFFFAOYSA-N barium(2+);dioxido(oxo)silane Chemical compound [Ba+2].[O-][Si]([O-])=O HMOQPOVBDRFNIU-UHFFFAOYSA-N 0.000 description 1
- WAKZZMMCDILMEF-UHFFFAOYSA-H barium(2+);diphosphate Chemical compound [Ba+2].[Ba+2].[Ba+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O WAKZZMMCDILMEF-UHFFFAOYSA-H 0.000 description 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 229920005605 branched copolymer Polymers 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- 239000001175 calcium sulphate Substances 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 238000009924 canning Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 description 1
- FSBVERYRVPGNGG-UHFFFAOYSA-N dimagnesium dioxido-bis[[oxido(oxo)silyl]oxy]silane hydrate Chemical compound O.[Mg+2].[Mg+2].[O-][Si](=O)O[Si]([O-])([O-])O[Si]([O-])=O FSBVERYRVPGNGG-UHFFFAOYSA-N 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 239000003845 household chemical Substances 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 235000012254 magnesium hydroxide Nutrition 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 235000012245 magnesium oxide Nutrition 0.000 description 1
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 1
- 239000004137 magnesium phosphate Substances 0.000 description 1
- 229910000157 magnesium phosphate Inorganic materials 0.000 description 1
- 229960002261 magnesium phosphate Drugs 0.000 description 1
- 235000010994 magnesium phosphates Nutrition 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229920001910 maleic anhydride grafted polyolefin Polymers 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 210000000282 nail Anatomy 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920001470 polyketone Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000011145 styrene acrylonitrile resin Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 229920006346 thermoplastic polyester elastomer Polymers 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Polyesters Or Polycarbonates (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US919712 | 1986-10-16 | ||
| US09/919,712 US6476111B1 (en) | 2001-08-01 | 2001-08-01 | Extrudable highly filled thermoplastic sheet composition |
| PCT/US2002/024314 WO2003011966A1 (en) | 2001-08-01 | 2002-08-01 | Molding composition formed from glassy and semicrystalline polymer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60219322D1 DE60219322D1 (de) | 2007-05-16 |
| DE60219322T2 true DE60219322T2 (de) | 2008-01-03 |
Family
ID=25442518
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60219322T Expired - Lifetime DE60219322T2 (de) | 2001-08-01 | 2002-08-01 | Formmasse aus glasigen und semikristallinen polymeren |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6476111B1 (enExample) |
| EP (1) | EP1414898B1 (enExample) |
| JP (1) | JP2004536942A (enExample) |
| KR (1) | KR100840096B1 (enExample) |
| AT (1) | ATE358695T1 (enExample) |
| AU (1) | AU2002317606B2 (enExample) |
| BR (1) | BR0211675A (enExample) |
| CA (1) | CA2451137C (enExample) |
| DE (1) | DE60219322T2 (enExample) |
| MX (1) | MXPA04000916A (enExample) |
| NZ (1) | NZ530444A (enExample) |
| WO (1) | WO2003011966A1 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2259744T3 (es) * | 2003-08-08 | 2006-10-16 | A. Schulman Plastics | Masterbatch conteniendo pmma y su empleo para la produccion de films de poliolefina. |
| KR100622600B1 (ko) * | 2004-05-11 | 2006-09-19 | 엘에스전선 주식회사 | 폴리에스테르 비할로겐 조성물 및 이를 이용한 전선 |
| US20050279775A1 (en) * | 2004-06-07 | 2005-12-22 | John Polimeno | Container for distribution of non-catalyzed resin and filler mixture |
| US20060118989A1 (en) * | 2004-12-07 | 2006-06-08 | 3M Innovative Properties Company | Method of making composite material |
| US20080067713A1 (en) * | 2004-12-14 | 2008-03-20 | Robert Bordener | Method of producing and business model for applying a thin laminate sheet of a decorative material |
| US20070251603A1 (en) * | 2006-04-26 | 2007-11-01 | Olson Barry D | Novel surface aesthetics employing magnetic particles |
| US20070254106A1 (en) * | 2006-04-26 | 2007-11-01 | Olson Barry D | Novel aesthetics in surfaces employing deformation and magnetic means |
| US20070252300A1 (en) * | 2006-04-26 | 2007-11-01 | Paplham William P | Novel aesthetics in surfaces |
| WO2007136282A2 (en) * | 2006-05-23 | 2007-11-29 | Nu Clear Systems Limited | Laminate material |
| DE102007005432A1 (de) * | 2007-01-30 | 2008-07-31 | Evonik Röhm Gmbh | Formmassen für mattierte Polyacrylat-Formkörper |
| US20090043031A1 (en) * | 2007-08-06 | 2009-02-12 | Keith William Pollak | Compatibilized multipolymer composition containing particulate filler |
| US8858850B2 (en) * | 2009-07-02 | 2014-10-14 | E I Du Pont De Nemours And Company | Process for preparing decorative surface appearance in acrylic material employing anisotropic particles |
| US10042395B2 (en) * | 2013-10-11 | 2018-08-07 | Dell Products, Lp | Method of forming composite fiber laminate with variable elasticity and device thereof |
| US11008438B2 (en) * | 2016-12-02 | 2021-05-18 | Composite Technologies International, Llc | Composition and method to form a composite core material |
| CN110819082B (zh) * | 2019-09-30 | 2021-07-06 | 广东轻工职业技术学院 | 一种高熔接痕强度玻纤增强pbt复合材料及其制备方法 |
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| US3847865A (en) | 1972-04-28 | 1974-11-12 | Du Pont | Use of alumina trihydrate in a polymethyl methacrylate article |
| GB1584400A (en) | 1976-12-24 | 1981-02-11 | Bayer Ag | (2-oxo-imidazoliden-1-yl(carbonylamino)-acetamido-cephalosporins and penicillins |
| US4369282A (en) * | 1979-07-03 | 1983-01-18 | General Electric Company | Modified polyester compositions |
| US4880866A (en) | 1984-10-31 | 1989-11-14 | Hoechst Celanese | Thermoplastic polyester compositions containing certain low molecular weight diepoxide resins and having improved impact behavior |
| CA1332015C (en) * | 1987-08-17 | 1994-09-13 | Yuichi Orikasa | Thermoplastic resin composition and method for preparing the same |
| US4981898A (en) * | 1987-12-31 | 1991-01-01 | General Electric Company | Polycarbonate-polyester blends |
| JPH01229065A (ja) | 1988-03-09 | 1989-09-12 | Polyplastics Co | 熱可塑性ポリエステル樹脂組成物 |
| US4927870A (en) * | 1988-08-25 | 1990-05-22 | The Dow Chemical Company | Ignition resistant modified thermoplastic composition |
| JP2627132B2 (ja) * | 1993-01-19 | 1997-07-02 | 三洋化成工業株式会社 | 顔料マスターバッチ用樹脂組成物 |
| EP0616013B1 (en) * | 1993-03-19 | 1999-06-02 | Mitsubishi Chemical Corporation | Thermoplastic resin composition |
| JPH08208916A (ja) * | 1994-11-08 | 1996-08-13 | Sumitomo Chem Co Ltd | ポリスチレン系樹脂組成物及びその成形品 |
| US5444115A (en) * | 1994-11-21 | 1995-08-22 | E. I. Du Pont De Nemours And Company | Fire resistant poly(methyl methacrylate) composition |
| US6005050A (en) * | 1994-11-28 | 1999-12-21 | Idemitsu Petrochemical Co., Ltd. | Impact resistant polystyrene composition |
| ES2112071T3 (es) | 1995-03-27 | 1998-03-16 | Basf Ag | Procedimiento para la obtencion de termoplasticos. |
| JPH08302117A (ja) * | 1995-05-08 | 1996-11-19 | Idemitsu Kosan Co Ltd | ポリスチレン系樹脂組成物 |
| BE1010713A3 (fr) * | 1996-10-25 | 1998-12-01 | Ucb Sa | Compositions en poudre a base de polyesters semi-cristallins et de copolymeres acryliques; contenant des groupes (meth)acrylyle. |
| JPH10298312A (ja) | 1997-04-24 | 1998-11-10 | Mitsubishi Chem Corp | 樹脂シート |
| JPH1129685A (ja) * | 1997-07-09 | 1999-02-02 | Asahi Chem Ind Co Ltd | 帯電防止性アクリル系樹脂組成物 |
| JPH11100479A (ja) * | 1997-07-30 | 1999-04-13 | Mitsubishi Rayon Co Ltd | 熱可塑性樹脂組成物およびそれを含むマスターバッチ |
| US6013686A (en) | 1998-02-13 | 2000-01-11 | General Electric Company | Blowing agent concentrate |
| BR9902678A (pt) * | 1998-07-10 | 2002-03-26 | Pirelli Cables & Systems Llc | Material compósito polimérico condutor, e, processo para produzir o mesmo |
| JP2000159994A (ja) * | 1998-11-25 | 2000-06-13 | Kanegafuchi Chem Ind Co Ltd | 難燃性熱可塑性樹脂組成物 |
| JP3996716B2 (ja) * | 1998-12-21 | 2007-10-24 | テクノポリマー株式会社 | 熱可塑性樹脂組成物 |
| JP2000336226A (ja) * | 1999-05-28 | 2000-12-05 | Toray Ind Inc | 難燃性樹脂組成物、その製造方法および成形品 |
| JP2001131308A (ja) * | 1999-10-29 | 2001-05-15 | Daicel Chem Ind Ltd | 熱可塑性樹脂組成物シート |
| JP2002080728A (ja) * | 2000-09-08 | 2002-03-19 | Sumitomo Chem Co Ltd | 熱可塑性樹脂組成物成形体の製造方法 |
-
2001
- 2001-08-01 US US09/919,712 patent/US6476111B1/en not_active Expired - Lifetime
-
2002
- 2002-08-01 EP EP02748278A patent/EP1414898B1/en not_active Expired - Lifetime
- 2002-08-01 BR BR0211675-8A patent/BR0211675A/pt not_active IP Right Cessation
- 2002-08-01 NZ NZ530444A patent/NZ530444A/en not_active IP Right Cessation
- 2002-08-01 KR KR1020037017282A patent/KR100840096B1/ko not_active Expired - Fee Related
- 2002-08-01 DE DE60219322T patent/DE60219322T2/de not_active Expired - Lifetime
- 2002-08-01 CA CA2451137A patent/CA2451137C/en not_active Expired - Lifetime
- 2002-08-01 MX MXPA04000916A patent/MXPA04000916A/es active IP Right Grant
- 2002-08-01 AU AU2002317606A patent/AU2002317606B2/en not_active Ceased
- 2002-08-01 WO PCT/US2002/024314 patent/WO2003011966A1/en not_active Ceased
- 2002-08-01 JP JP2003517149A patent/JP2004536942A/ja active Pending
- 2002-08-01 AT AT02748278T patent/ATE358695T1/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| JP2004536942A (ja) | 2004-12-09 |
| CA2451137A1 (en) | 2003-02-13 |
| WO2003011966A1 (en) | 2003-02-13 |
| ATE358695T1 (de) | 2007-04-15 |
| EP1414898B1 (en) | 2007-04-04 |
| US6476111B1 (en) | 2002-11-05 |
| NZ530444A (en) | 2006-11-30 |
| MXPA04000916A (es) | 2004-04-02 |
| KR100840096B1 (ko) | 2008-06-19 |
| KR20040022443A (ko) | 2004-03-12 |
| AU2002317606B2 (en) | 2007-01-18 |
| EP1414898A1 (en) | 2004-05-06 |
| CA2451137C (en) | 2010-06-15 |
| BR0211675A (pt) | 2004-07-13 |
| DE60219322D1 (de) | 2007-05-16 |
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