DE60210339T2 - Freifliessendes melamincyanuratagglomerat - Google Patents
Freifliessendes melamincyanuratagglomerat Download PDFInfo
- Publication number
- DE60210339T2 DE60210339T2 DE60210339T DE60210339T DE60210339T2 DE 60210339 T2 DE60210339 T2 DE 60210339T2 DE 60210339 T DE60210339 T DE 60210339T DE 60210339 T DE60210339 T DE 60210339T DE 60210339 T2 DE60210339 T2 DE 60210339T2
- Authority
- DE
- Germany
- Prior art keywords
- melamine cyanurate
- agglomerate
- agglomerates
- auxiliary material
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000877 Melamine resin Polymers 0.000 title description 12
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 title description 11
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims abstract description 71
- 229920000642 polymer Polymers 0.000 claims abstract description 57
- 239000000203 mixture Substances 0.000 claims abstract description 25
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 238000002360 preparation method Methods 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims description 47
- 238000000034 method Methods 0.000 claims description 19
- 239000002002 slurry Substances 0.000 claims description 17
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 14
- 238000002844 melting Methods 0.000 claims description 10
- 230000008018 melting Effects 0.000 claims description 10
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 8
- 239000007921 spray Substances 0.000 claims description 8
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 4
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- 239000003063 flame retardant Substances 0.000 abstract description 9
- 239000002245 particle Substances 0.000 description 44
- 239000000428 dust Substances 0.000 description 25
- 238000012360 testing method Methods 0.000 description 18
- 238000003860 storage Methods 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 238000009826 distribution Methods 0.000 description 9
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 239000011164 primary particle Substances 0.000 description 8
- 230000008901 benefit Effects 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 238000013329 compounding Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 229920002292 Nylon 6 Polymers 0.000 description 5
- 239000008187 granular material Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 229920000388 Polyphosphate Polymers 0.000 description 4
- 239000008199 coating composition Substances 0.000 description 4
- 239000004815 dispersion polymer Substances 0.000 description 4
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000001205 polyphosphate Substances 0.000 description 4
- 235000011176 polyphosphates Nutrition 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 3
- 239000000347 magnesium hydroxide Substances 0.000 description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 3
- 238000005204 segregation Methods 0.000 description 3
- 239000004114 Ammonium polyphosphate Substances 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- -1 Sb 2 O 5 Chemical compound 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 2
- 229920001276 ammonium polyphosphate Polymers 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- COAPBYURHXLGMG-UHFFFAOYSA-N azane;1,3,5-triazine-2,4,6-triamine Chemical compound N.NC1=NC(N)=NC(N)=N1 COAPBYURHXLGMG-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 150000007974 melamines Chemical class 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- YZEZMSPGIPTEBA-UHFFFAOYSA-N 2-n-(4,6-diamino-1,3,5-triazin-2-yl)-1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(NC=2N=C(N)N=C(N)N=2)=N1 YZEZMSPGIPTEBA-UHFFFAOYSA-N 0.000 description 1
- MXRGSJAOLKBZLU-UHFFFAOYSA-N 3-ethenylazepan-2-one Chemical compound C=CC1CCCCNC1=O MXRGSJAOLKBZLU-UHFFFAOYSA-N 0.000 description 1
- 229920006045 Akulon® Polymers 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 241000519995 Stachys sylvatica Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- RHNMFWJPEQPWMO-UHFFFAOYSA-N acetic acid;1,3,5-triazine-2,4,6-triamine Chemical compound CC(O)=O.NC1=NC(N)=NC(N)=N1 RHNMFWJPEQPWMO-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- YSKUZVBSHIWEFK-UHFFFAOYSA-N ammelide Chemical compound NC1=NC(O)=NC(O)=N1 YSKUZVBSHIWEFK-UHFFFAOYSA-N 0.000 description 1
- MASBWURJQFFLOO-UHFFFAOYSA-N ammeline Chemical compound NC1=NC(N)=NC(O)=N1 MASBWURJQFFLOO-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- JPNZKPRONVOMLL-UHFFFAOYSA-N azane;octadecanoic acid Chemical class [NH4+].CCCCCCCCCCCCCCCCCC([O-])=O JPNZKPRONVOMLL-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001913 cellulose Chemical class 0.000 description 1
- 229920002678 cellulose Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000002050 diffraction method Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- YSRVJVDFHZYRPA-UHFFFAOYSA-N melem Chemical compound NC1=NC(N23)=NC(N)=NC2=NC(N)=NC3=N1 YSRVJVDFHZYRPA-UHFFFAOYSA-N 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000005029 sieve analysis Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- NSBGJRFJIJFMGW-UHFFFAOYSA-N trisodium;stiborate Chemical compound [Na+].[Na+].[Na+].[O-][Sb]([O-])([O-])=O NSBGJRFJIJFMGW-UHFFFAOYSA-N 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 230000002792 vascular Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 1
- BNEMLSQAJOPTGK-UHFFFAOYSA-N zinc;dioxido(oxo)tin Chemical compound [Zn+2].[O-][Sn]([O-])=O BNEMLSQAJOPTGK-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Paper (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Fireproofing Substances (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL1019234 | 2001-10-25 | ||
| NL1019234 | 2001-10-25 | ||
| PCT/EP2002/011646 WO2003035736A1 (en) | 2001-10-25 | 2002-10-17 | Free flowing melamine cyanurate agglomerate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60210339D1 DE60210339D1 (de) | 2006-05-18 |
| DE60210339T2 true DE60210339T2 (de) | 2006-08-24 |
Family
ID=19774211
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60210339T Expired - Lifetime DE60210339T2 (de) | 2001-10-25 | 2002-10-17 | Freifliessendes melamincyanuratagglomerat |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US20050070642A1 (https=) |
| EP (1) | EP1438353B1 (https=) |
| JP (1) | JP4374568B2 (https=) |
| KR (1) | KR100883557B1 (https=) |
| CN (1) | CN100503702C (https=) |
| AT (1) | ATE321813T1 (https=) |
| AU (1) | AU2002363086B2 (https=) |
| BR (1) | BR0213480B1 (https=) |
| CA (1) | CA2463066C (https=) |
| DE (1) | DE60210339T2 (https=) |
| DK (1) | DK1438353T3 (https=) |
| ES (1) | ES2260517T3 (https=) |
| IL (2) | IL161287A0 (https=) |
| MX (1) | MXPA04003731A (https=) |
| MY (1) | MY130218A (https=) |
| PT (1) | PT1438353E (https=) |
| RU (1) | RU2288241C2 (https=) |
| TW (1) | TWI284126B (https=) |
| WO (1) | WO2003035736A1 (https=) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10347012A1 (de) * | 2003-10-07 | 2005-05-25 | Clariant Gmbh | Phosphorhaltige Flammschutzmittelagglomerate |
| CN101039923B (zh) * | 2004-10-15 | 2010-08-11 | 西巴特殊化学品控股有限公司 | 结晶形态的三聚氰胺氰尿酸酯 |
| CN101128555B (zh) * | 2005-01-07 | 2013-04-03 | 太尔公司 | 用于化学机械平坦化的经设计的非聚合有机颗粒 |
| WO2006095337A2 (en) * | 2005-03-07 | 2006-09-14 | Bromine Compounds Ltd. | A process for the preparation of melamine cyanurate |
| FI120560B (fi) * | 2005-12-21 | 2009-11-30 | Outotec Oyj | Menetelmä alkuaineen ja/tai mineraalin pitoisuuden määrittämiseksi |
| CN102939324B (zh) * | 2010-06-11 | 2014-08-27 | 帝斯曼知识产权资产管理有限公司 | 蜜白胺粒料及其制备方法 |
| US8604105B2 (en) | 2010-09-03 | 2013-12-10 | Eastman Chemical Company | Flame retardant copolyester compositions |
| CN102532604B (zh) * | 2012-01-19 | 2013-05-01 | 北京工商大学 | 一种大粒径三聚氰胺氰脲酸盐的制备方法 |
| DE102014001222A1 (de) | 2014-01-29 | 2015-07-30 | Clariant lnternational Ltd | Halogenfreie feste Flammschutzmittelmischung und ihre Verwendung |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT399157B (de) * | 1990-11-30 | 1995-03-27 | Chemie Linz Gmbh | Feste flammhemmer-agglomerate für thermoplaste und verfahren zur flammhemmenden ausrüstung von thermoplasten |
| DE4040276A1 (de) * | 1990-12-17 | 1992-06-25 | Chemie Linz Deutschland | Feste flammhemmer-agglomerate fuer thermoplaste |
| US5135974A (en) * | 1991-09-23 | 1992-08-04 | Fr Polymers, Inc. | Cyanurate based fire retardant concentrates |
| JP2751815B2 (ja) * | 1994-02-08 | 1998-05-18 | 日産化学工業株式会社 | 表面処理されたメラミンシアヌレート粉末およびその製造方法 |
| JP2001206961A (ja) * | 1999-10-19 | 2001-07-31 | Sekisui Chem Co Ltd | 難燃性フィルム |
-
2002
- 2002-01-22 TW TW091100984A patent/TWI284126B/zh not_active IP Right Cessation
- 2002-10-12 MY MYPI20023817A patent/MY130218A/en unknown
- 2002-10-17 EP EP02801895A patent/EP1438353B1/en not_active Expired - Lifetime
- 2002-10-17 CA CA2463066A patent/CA2463066C/en not_active Expired - Lifetime
- 2002-10-17 DE DE60210339T patent/DE60210339T2/de not_active Expired - Lifetime
- 2002-10-17 BR BRPI0213480-2B1A patent/BR0213480B1/pt active IP Right Grant
- 2002-10-17 CN CNB028208684A patent/CN100503702C/zh not_active Expired - Lifetime
- 2002-10-17 MX MXPA04003731A patent/MXPA04003731A/es active IP Right Grant
- 2002-10-17 PT PT02801895T patent/PT1438353E/pt unknown
- 2002-10-17 IL IL16128702A patent/IL161287A0/xx unknown
- 2002-10-17 US US10/493,269 patent/US20050070642A1/en not_active Abandoned
- 2002-10-17 JP JP2003538248A patent/JP4374568B2/ja not_active Expired - Fee Related
- 2002-10-17 DK DK02801895T patent/DK1438353T3/da active
- 2002-10-17 AT AT02801895T patent/ATE321813T1/de active
- 2002-10-17 RU RU2004116133/04A patent/RU2288241C2/ru active
- 2002-10-17 ES ES02801895T patent/ES2260517T3/es not_active Expired - Lifetime
- 2002-10-17 AU AU2002363086A patent/AU2002363086B2/en not_active Expired
- 2002-10-17 WO PCT/EP2002/011646 patent/WO2003035736A1/en not_active Ceased
- 2002-10-17 KR KR1020047005659A patent/KR100883557B1/ko not_active Expired - Lifetime
-
2004
- 2004-04-04 IL IL161287A patent/IL161287A/en active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| CA2463066C (en) | 2011-08-02 |
| BR0213480B1 (pt) | 2013-12-17 |
| US20050070642A1 (en) | 2005-03-31 |
| IL161287A (en) | 2014-11-30 |
| JP4374568B2 (ja) | 2009-12-02 |
| ES2260517T3 (es) | 2006-11-01 |
| AU2002363086B2 (en) | 2008-09-11 |
| CN100503702C (zh) | 2009-06-24 |
| MXPA04003731A (es) | 2004-07-23 |
| WO2003035736A1 (en) | 2003-05-01 |
| DK1438353T3 (da) | 2006-06-06 |
| KR100883557B1 (ko) | 2009-02-17 |
| IL161287A0 (en) | 2004-09-27 |
| JP2005506426A (ja) | 2005-03-03 |
| ATE321813T1 (de) | 2006-04-15 |
| CN1575318A (zh) | 2005-02-02 |
| MY130218A (en) | 2007-06-29 |
| RU2288241C2 (ru) | 2006-11-27 |
| RU2004116133A (ru) | 2005-07-20 |
| CA2463066A1 (en) | 2003-05-01 |
| EP1438353A1 (en) | 2004-07-21 |
| BR0213480A (pt) | 2004-11-03 |
| EP1438353B1 (en) | 2006-03-29 |
| PT1438353E (pt) | 2006-07-31 |
| TWI284126B (en) | 2007-07-21 |
| DE60210339D1 (de) | 2006-05-18 |
| KR20040060938A (ko) | 2004-07-06 |
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