DE602004001789T2 - Mit Silica gefüllte Elastomerenzusammensetzung - Google Patents
Mit Silica gefüllte Elastomerenzusammensetzung Download PDFInfo
- Publication number
- DE602004001789T2 DE602004001789T2 DE602004001789T DE602004001789T DE602004001789T2 DE 602004001789 T2 DE602004001789 T2 DE 602004001789T2 DE 602004001789 T DE602004001789 T DE 602004001789T DE 602004001789 T DE602004001789 T DE 602004001789T DE 602004001789 T2 DE602004001789 T2 DE 602004001789T2
- Authority
- DE
- Germany
- Prior art keywords
- group
- elastomer
- compound
- silica
- basic nitrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 69
- 239000000806 elastomer Substances 0.000 title claims abstract description 61
- 239000000203 mixture Substances 0.000 title claims description 27
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title abstract description 153
- 239000000377 silicon dioxide Substances 0.000 title abstract description 68
- 150000001875 compounds Chemical class 0.000 claims abstract description 80
- 229920005555 halobutyl Polymers 0.000 claims abstract description 38
- 239000000945 filler Substances 0.000 claims abstract description 33
- 125000004968 halobutyl group Chemical group 0.000 claims abstract description 33
- 238000002156 mixing Methods 0.000 claims abstract description 28
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 21
- 239000012764 mineral filler Substances 0.000 claims abstract description 20
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims abstract description 20
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 20
- 229920005557 bromobutyl Polymers 0.000 claims description 58
- 238000000034 method Methods 0.000 claims description 28
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 claims description 22
- 238000005299 abrasion Methods 0.000 claims description 11
- 230000008569 process Effects 0.000 claims description 11
- 238000002360 preparation method Methods 0.000 claims description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 150000004760 silicates Chemical class 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 125000003277 amino group Chemical group 0.000 claims description 3
- 125000000075 primary alcohol group Chemical group 0.000 claims description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 2
- 150000001413 amino acids Chemical class 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 239000010440 gypsum Substances 0.000 claims description 2
- 229910052602 gypsum Inorganic materials 0.000 claims description 2
- 102000004169 proteins and genes Human genes 0.000 claims description 2
- 108090000623 proteins and genes Proteins 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- 125000002843 carboxylic acid group Chemical group 0.000 claims 2
- 229910052570 clay Inorganic materials 0.000 claims 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 9
- 239000011593 sulfur Substances 0.000 abstract description 9
- 229910052717 sulfur Inorganic materials 0.000 abstract description 9
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000654 additive Substances 0.000 abstract description 3
- 150000001412 amines Chemical class 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 3
- 230000000996 additive effect Effects 0.000 abstract 1
- -1 bromobutyl Chemical group 0.000 description 38
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 22
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 15
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Natural products CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 11
- 150000001993 dienes Chemical class 0.000 description 11
- 239000000178 monomer Substances 0.000 description 11
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 11
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 9
- 239000005062 Polybutadiene Substances 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 229920005549 butyl rubber Polymers 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 8
- 239000005060 rubber Substances 0.000 description 8
- 230000006872 improvement Effects 0.000 description 7
- 229910052500 inorganic mineral Inorganic materials 0.000 description 7
- 239000011707 mineral Substances 0.000 description 7
- 235000010755 mineral Nutrition 0.000 description 7
- 239000011787 zinc oxide Substances 0.000 description 7
- 235000021355 Stearic acid Nutrition 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 238000013329 compounding Methods 0.000 description 6
- 238000009826 distribution Methods 0.000 description 6
- 230000003993 interaction Effects 0.000 description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 239000004848 polyfunctional curative Substances 0.000 description 6
- 238000005096 rolling process Methods 0.000 description 6
- 239000004071 soot Substances 0.000 description 6
- 239000008117 stearic acid Substances 0.000 description 6
- 229920003048 styrene butadiene rubber Polymers 0.000 description 6
- 229920002554 vinyl polymer Polymers 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 239000012074 organic phase Substances 0.000 description 5
- 229920002857 polybutadiene Polymers 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- 229920000459 Nitrile rubber Polymers 0.000 description 4
- 239000002174 Styrene-butadiene Substances 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 239000006229 carbon black Substances 0.000 description 4
- 238000007306 functionalization reaction Methods 0.000 description 4
- 229920000578 graft copolymer Polymers 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 150000004756 silanes Chemical class 0.000 description 4
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical group CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 3
- 229910052794 bromium Inorganic materials 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
- 229920001084 poly(chloroprene) Polymers 0.000 description 3
- UAJRSHJHFRVGMG-UHFFFAOYSA-N 1-ethenyl-4-methoxybenzene Chemical compound COC1=CC=C(C=C)C=C1 UAJRSHJHFRVGMG-UHFFFAOYSA-N 0.000 description 2
- RCJMVGJKROQDCB-UHFFFAOYSA-N 2-methylpenta-1,3-diene Chemical compound CC=CC(C)=C RCJMVGJKROQDCB-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229920005556 chlorobutyl Polymers 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
- 235000012254 magnesium hydroxide Nutrition 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- GVOISEJVFFIGQE-YCZSINBZSA-N n-[(1r,2s,5r)-5-[methyl(propan-2-yl)amino]-2-[(3s)-2-oxo-3-[[6-(trifluoromethyl)quinazolin-4-yl]amino]pyrrolidin-1-yl]cyclohexyl]acetamide Chemical compound CC(=O)N[C@@H]1C[C@H](N(C)C(C)C)CC[C@@H]1N1C(=O)[C@@H](NC=2C3=CC(=CC=C3N=CN=2)C(F)(F)F)CC1 GVOISEJVFFIGQE-YCZSINBZSA-N 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000011164 primary particle Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- PCCCQOGUVCNYOI-FNORWQNLSA-N (3e)-2,3-dimethylpenta-1,3-diene Chemical compound C\C=C(/C)C(C)=C PCCCQOGUVCNYOI-FNORWQNLSA-N 0.000 description 1
- AHAREKHAZNPPMI-AATRIKPKSA-N (3e)-hexa-1,3-diene Chemical compound CC\C=C\C=C AHAREKHAZNPPMI-AATRIKPKSA-N 0.000 description 1
- QTYUSOHYEPOHLV-FNORWQNLSA-N 1,3-Octadiene Chemical compound CCCC\C=C\C=C QTYUSOHYEPOHLV-FNORWQNLSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- KXYAVSFOJVUIHT-UHFFFAOYSA-N 2-vinylnaphthalene Chemical compound C1=CC=CC2=CC(C=C)=CC=C21 KXYAVSFOJVUIHT-UHFFFAOYSA-N 0.000 description 1
- IGLWCQMNTGCUBB-UHFFFAOYSA-N 3-methylidenepent-1-ene Chemical compound CCC(=C)C=C IGLWCQMNTGCUBB-UHFFFAOYSA-N 0.000 description 1
- ZSNRMRKAYAJYRZ-UHFFFAOYSA-N 4-methylidenehex-2-ene Chemical compound CCC(=C)C=CC ZSNRMRKAYAJYRZ-UHFFFAOYSA-N 0.000 description 1
- YBPXZRWAVVJHBP-UHFFFAOYSA-N 4-methylocta-1,3-diene Chemical compound CCCCC(C)=CC=C YBPXZRWAVVJHBP-UHFFFAOYSA-N 0.000 description 1
- YGQQJSWILPTCPE-UHFFFAOYSA-N 5-ethylidene-6-methylidenedecane Chemical compound CCCCC(=C)C(=CC)CCCC YGQQJSWILPTCPE-UHFFFAOYSA-N 0.000 description 1
- SLXKOJJOQWFEFD-UHFFFAOYSA-N 6-aminohexanoic acid Chemical compound NCCCCCC(O)=O SLXKOJJOQWFEFD-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 241001441571 Hiodontidae Species 0.000 description 1
- 239000006237 Intermediate SAF Substances 0.000 description 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 241000872198 Serjania polyphylla Species 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 1
- GJWAPAVRQYYSTK-UHFFFAOYSA-N [(dimethyl-$l^{3}-silanyl)amino]-dimethylsilicon Chemical compound C[Si](C)N[Si](C)C GJWAPAVRQYYSTK-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- HIMXYMYMHUAZLW-UHFFFAOYSA-N [[[dimethyl(phenyl)silyl]amino]-dimethylsilyl]benzene Chemical compound C=1C=CC=CC=1[Si](C)(C)N[Si](C)(C)C1=CC=CC=C1 HIMXYMYMHUAZLW-UHFFFAOYSA-N 0.000 description 1
- WYUIWUCVZCRTRH-UHFFFAOYSA-N [[[ethenyl(dimethyl)silyl]amino]-dimethylsilyl]ethene Chemical compound C=C[Si](C)(C)N[Si](C)(C)C=C WYUIWUCVZCRTRH-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- YLEIFZAVNWDOBM-ZTNXSLBXSA-N ac1l9hc7 Chemical compound C([C@H]12)C[C@@H](C([C@@H](O)CC3)(C)C)[C@@]43C[C@@]14CC[C@@]1(C)[C@@]2(C)C[C@@H]2O[C@]3(O)[C@H](O)C(C)(C)O[C@@H]3[C@@H](C)[C@H]12 YLEIFZAVNWDOBM-ZTNXSLBXSA-N 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 229910052915 alkaline earth metal silicate Inorganic materials 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 229960002684 aminocaproic acid Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000003704 aspartic acid Nutrition 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
- 230000031709 bromination Effects 0.000 description 1
- 238000005893 bromination reaction Methods 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- SXSNZRHGAMVNJE-UHFFFAOYSA-N chloro-[[[chloromethyl(dimethyl)silyl]amino]-dimethylsilyl]methane Chemical compound ClC[Si](C)(C)N[Si](C)(C)CCl SXSNZRHGAMVNJE-UHFFFAOYSA-N 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000009950 felting Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000006232 furnace black Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229920006168 hydrated nitrile rubber Polymers 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000006233 lamp black Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 235000011160 magnesium carbonates Nutrition 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229960000816 magnesium hydroxide Drugs 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- ZSMNRKGGHXLZEC-UHFFFAOYSA-N n,n-bis(trimethylsilyl)methanamine Chemical compound C[Si](C)(C)N(C)[Si](C)(C)C ZSMNRKGGHXLZEC-UHFFFAOYSA-N 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000010690 paraffinic oil Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA2418822A CA2418822C (en) | 2003-02-13 | 2003-02-13 | Method to produce silica reinforced elastomer compounds |
| CA2418822 | 2003-02-13 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE602004001789D1 DE602004001789D1 (de) | 2006-09-21 |
| DE602004001789T2 true DE602004001789T2 (de) | 2007-08-23 |
Family
ID=32660956
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE602004001789T Expired - Lifetime DE602004001789T2 (de) | 2003-02-13 | 2004-02-06 | Mit Silica gefüllte Elastomerenzusammensetzung |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US7649033B2 (enExample) |
| EP (1) | EP1447424B1 (enExample) |
| JP (1) | JP4610204B2 (enExample) |
| KR (1) | KR101095263B1 (enExample) |
| CN (1) | CN100591717C (enExample) |
| AT (1) | ATE335785T1 (enExample) |
| BR (1) | BRPI0400270A (enExample) |
| CA (1) | CA2418822C (enExample) |
| DE (1) | DE602004001789T2 (enExample) |
| ES (1) | ES2270189T3 (enExample) |
| MX (1) | MXPA04001352A (enExample) |
| RU (1) | RU2395533C2 (enExample) |
| TW (1) | TWI329118B (enExample) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2446474C (en) * | 2003-10-24 | 2011-11-29 | Rui Resendes | Silica-filled elastomeric compounds |
| CA2465301C (en) | 2004-04-28 | 2012-02-07 | John Scott Parent | Process to produce silica-filled elastomeric compounds |
| CA2471006A1 (en) * | 2004-06-23 | 2005-12-23 | Bayer Inc. | Silica reinforced elastomer compounds prepared with dry liquid modifiers |
| JP4472596B2 (ja) * | 2005-08-04 | 2010-06-02 | 住友ゴム工業株式会社 | タイヤトレッド用ゴム組成物 |
| EP1913077A4 (en) | 2005-08-05 | 2009-11-04 | Lanxess Inc | halobutyl elastomers |
| CA2551997C (en) | 2005-08-26 | 2014-05-27 | Lanxess Inc. | Novel methods for the preparation of butyl graft copolymers |
| US20070100041A1 (en) * | 2005-11-03 | 2007-05-03 | Rui Resendes | Filled elastomeric compounds |
| CA2564446A1 (en) * | 2005-11-04 | 2007-05-04 | Lanxess Inc. | Method to produce reinforced halobutyl elastomer compounds |
| BRPI0818579A2 (pt) | 2007-10-19 | 2011-09-13 | Lanxess Inc | compostos de borracha de butila compreendendo um sistema modificador de três componentes mistos |
| US20090255613A1 (en) | 2008-04-09 | 2009-10-15 | Ping Zhang | Tire with tread having an intermediate rubber layer containing a microsphere dispersion |
| US8240351B2 (en) | 2009-02-10 | 2012-08-14 | The Goodyear Tire & Rubber Company | Pneumatic tire having air retention innerliner containing anchored glass microspheres |
| ITRM20130424A1 (it) * | 2013-07-18 | 2015-01-19 | Bridgestone Corp | Metodo per la preparazione di una mescola in gomma per pneumatici |
| SI3055359T1 (sl) * | 2013-10-07 | 2023-07-31 | Ppg Industries Ohio, Inc. | Obdelana polnila, sestavki, ki jih vsebujejo, in iz njih pripravljeni izdelki |
| US10544268B2 (en) | 2014-12-18 | 2020-01-28 | Bridgestone Americas Tire Operations, Llc | Rubber compositions containing carbon black and whey protein |
| WO2016099599A1 (en) | 2014-12-18 | 2016-06-23 | Bridgestone Americas Tire Operations, Llc | Rubber compositions containing whey protein |
| US10227480B2 (en) | 2014-12-18 | 2019-03-12 | Bridgestone Americas Tire Operations, Inc. | Rubber compositions containing whey protein |
| WO2016099598A1 (en) | 2014-12-18 | 2016-06-23 | Bridgestone Americas Tire Operations, Llc | Rubber compositions containing whey protein |
| EP4005821A4 (en) | 2019-12-27 | 2023-03-08 | Sumitomo Rubber Industries, Ltd. | RUBBER AND TIRE COMPOSITION |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3337391A (en) * | 1963-12-24 | 1967-08-22 | Exxon Research Engineering Co | Bonding siliceous materials to organic polymers with organic titanates |
| JP3847360B2 (ja) * | 1995-12-20 | 2006-11-22 | 日鉱金属株式会社 | 表面処理されたフィラーおよびそれを用いた樹脂組成物 |
| US5872176A (en) * | 1997-07-11 | 1999-02-16 | Bridgestone Corporation | Addition of salts to improve the interaction of silica with rubber |
| US6386784B1 (en) | 1997-11-24 | 2002-05-14 | Paul Edward Ruble | Fully interchangeable and recyclable binder cover and binding mechanism |
| CA2254559A1 (en) * | 1998-11-20 | 2000-05-20 | Ahti August Koski | Process for hydrophobicizing particles, and their use in dispersions |
| CA2293149A1 (en) | 1999-12-24 | 2001-06-24 | Bayer Inc. | Elastomeric butyl compounds with improved chemical bonding between the butyl elastomer and the filler |
| CA2339080C (en) * | 2001-03-02 | 2009-11-17 | Bayer Inc. | Filled elastomeric butyl compounds |
| CA2364174A1 (en) * | 2001-11-27 | 2003-05-27 | Bayer Inc. | Filled elastomeric butyl compounds with improved scorch safety |
| CA2368363A1 (en) * | 2002-01-17 | 2003-07-17 | Rui Resendes | Silica-filled elastomeric compounds |
| CA2386098C (en) * | 2002-05-13 | 2010-07-06 | Bayer Inc. | Silica-filled elastomeric compounds |
| JP2004137430A (ja) * | 2002-10-21 | 2004-05-13 | Sumitomo Rubber Ind Ltd | ゴム組成物およびそれを用いた空気入りタイヤ |
-
2003
- 2003-02-13 CA CA2418822A patent/CA2418822C/en not_active Expired - Fee Related
-
2004
- 2004-02-06 ES ES04002664T patent/ES2270189T3/es not_active Expired - Lifetime
- 2004-02-06 DE DE602004001789T patent/DE602004001789T2/de not_active Expired - Lifetime
- 2004-02-06 AT AT04002664T patent/ATE335785T1/de not_active IP Right Cessation
- 2004-02-06 EP EP04002664A patent/EP1447424B1/en not_active Expired - Lifetime
- 2004-02-09 US US10/774,722 patent/US7649033B2/en not_active Expired - Fee Related
- 2004-02-12 TW TW093103257A patent/TWI329118B/zh not_active IP Right Cessation
- 2004-02-12 MX MXPA04001352A patent/MXPA04001352A/es active IP Right Grant
- 2004-02-13 RU RU2004104109/04A patent/RU2395533C2/ru not_active IP Right Cessation
- 2004-02-13 CN CN200410028354A patent/CN100591717C/zh not_active Expired - Fee Related
- 2004-02-13 JP JP2004036805A patent/JP4610204B2/ja not_active Expired - Fee Related
- 2004-02-13 BR BR0400270-9A patent/BRPI0400270A/pt active Search and Examination
- 2004-02-13 KR KR1020040009524A patent/KR101095263B1/ko not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CA2418822C (en) | 2010-11-30 |
| ES2270189T3 (es) | 2007-04-01 |
| CN1526760A (zh) | 2004-09-08 |
| BRPI0400270A (pt) | 2004-12-28 |
| TW200502286A (en) | 2005-01-16 |
| EP1447424B1 (en) | 2006-08-09 |
| RU2395533C2 (ru) | 2010-07-27 |
| JP2004244635A (ja) | 2004-09-02 |
| CN100591717C (zh) | 2010-02-24 |
| EP1447424A1 (en) | 2004-08-18 |
| RU2004104109A (ru) | 2005-07-27 |
| MXPA04001352A (es) | 2004-12-06 |
| DE602004001789D1 (de) | 2006-09-21 |
| ATE335785T1 (de) | 2006-09-15 |
| JP4610204B2 (ja) | 2011-01-12 |
| US7649033B2 (en) | 2010-01-19 |
| KR20040073394A (ko) | 2004-08-19 |
| US20050075422A1 (en) | 2005-04-07 |
| HK1069408A1 (zh) | 2005-05-20 |
| CA2418822A1 (en) | 2004-08-13 |
| TWI329118B (en) | 2010-08-21 |
| KR101095263B1 (ko) | 2011-12-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition |