DE60013421D1 - Verfahren zur entfernung von schwefelwasserstoff aus gasen - Google Patents

Verfahren zur entfernung von schwefelwasserstoff aus gasen

Info

Publication number
DE60013421D1
DE60013421D1 DE60013421T DE60013421T DE60013421D1 DE 60013421 D1 DE60013421 D1 DE 60013421D1 DE 60013421 T DE60013421 T DE 60013421T DE 60013421 T DE60013421 T DE 60013421T DE 60013421 D1 DE60013421 D1 DE 60013421D1
Authority
DE
Germany
Prior art keywords
liquor
sulfur
dissolved
polysulfide
sorbing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60013421T
Other languages
English (en)
Other versions
DE60013421T2 (de
Inventor
W Deberry
Dennis Dalrymple
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CrystaTech Inc
Original Assignee
CrystaTech Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CrystaTech Inc filed Critical CrystaTech Inc
Application granted granted Critical
Publication of DE60013421D1 publication Critical patent/DE60013421D1/de
Publication of DE60013421T2 publication Critical patent/DE60013421T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/05—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by wet processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1468—Removing hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/52—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/52—Hydrogen sulfide
    • B01D53/523—Mixtures of hydrogen sulfide and sulfur oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/73—After-treatment of removed components

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Physical Water Treatments (AREA)
DE60013421T 1999-02-17 2000-02-16 Verfahren zur entfernung von schwefelwasserstoff aus gasen Expired - Lifetime DE60013421T2 (de)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US12039099P 1999-02-17 1999-02-17
US120390P 1999-02-17
US15654599P 1999-09-29 1999-09-29
US156545P 1999-09-29
US09/503,898 US6416729B1 (en) 1999-02-17 2000-02-15 Process for removing hydrogen sulfide from gas streams which include or are supplemented with sulfur dioxide
US503898 2000-02-15
PCT/US2000/003946 WO2000048712A1 (en) 1999-02-17 2000-02-16 Process for removing hydrogen sulfide from gases

Publications (2)

Publication Number Publication Date
DE60013421D1 true DE60013421D1 (de) 2004-10-07
DE60013421T2 DE60013421T2 (de) 2005-09-08

Family

ID=27382468

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60013421T Expired - Lifetime DE60013421T2 (de) 1999-02-17 2000-02-16 Verfahren zur entfernung von schwefelwasserstoff aus gasen

Country Status (8)

Country Link
US (2) US6416729B1 (de)
EP (1) EP1171222B1 (de)
AT (1) ATE274993T1 (de)
AU (1) AU2997200A (de)
CA (1) CA2371826C (de)
DE (1) DE60013421T2 (de)
ES (1) ES2225099T3 (de)
WO (1) WO2000048712A1 (de)

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US20030057136A1 (en) * 2001-08-22 2003-03-27 Mcintush Kenneth E. Process for recovering sulfur while sponging light hydrocarbons from hydrodesulfurization hydrogen recycle streams
WO2003082455A2 (en) * 2002-03-25 2003-10-09 Tda Research, Inc. Catalysts and process for oxidizing hydrogen sulfide to sulfur dioxide and sulfur
US7060233B1 (en) 2002-03-25 2006-06-13 Tda Research, Inc. Process for the simultaneous removal of sulfur and mercury
US8101243B2 (en) * 2002-04-03 2012-01-24 Colorado School Of Mines Method of making sulfur-resistant composite metal membranes
EP1499452B1 (de) * 2002-04-03 2013-12-18 Colorado School Of Mines Verfahren zur herstellung von palladiumlegierungsverbundwerkstoffmembranen zur verwendung bei wasserstofftrennung
US7413550B2 (en) 2003-10-16 2008-08-19 Kimberly-Clark Worldwide, Inc. Visual indicating device for bad breath
US7582485B2 (en) * 2003-10-16 2009-09-01 Kimberly-Clark Worldride, Inc. Method and device for detecting ammonia odors and helicobacter pylori urease infection
US20090136414A1 (en) * 2004-08-26 2009-05-28 Petrinec Bryan J Method for downhole sulfur removal and recovery
US20060043002A1 (en) * 2004-08-26 2006-03-02 Petrinec Bryan J Method for downhole sulfur removal and recovery
US7381393B2 (en) * 2004-10-07 2008-06-03 The Regents Of The University Of California Process for sulfur removal suitable for treating high-pressure gas streams
US7378068B2 (en) * 2005-06-01 2008-05-27 Conocophillips Company Electrochemical process for decomposition of hydrogen sulfide and production of sulfur
EP2009324A3 (de) * 2005-09-02 2010-03-24 LuK Lamellen und Kupplungsbau Beteiligungs KG Vorrichtung zur Drehmomentübertragung für ein Schaltgetriebe mit zwei Eingängen und Verfahren dafür
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US7655211B2 (en) 2006-08-23 2010-02-02 ThioSolv, LLC Process for producing ammonium thiosulfate
CA2568303C (en) * 2006-10-31 2008-02-12 John Keum-Ho Hwang A method for recovering sulphur from gas streams
US20100018248A1 (en) * 2007-01-19 2010-01-28 Eleanor R Fieler Controlled Freeze Zone Tower
CA2674618C (en) * 2007-01-19 2015-02-10 Exxonmobil Upstream Research Company Integrated controlled freeze zone (cfz) tower and dividing wall (dwc) for enhanced hydrocarbon recovery
US7749481B2 (en) * 2007-06-27 2010-07-06 H R D Corporation System and process for gas sweetening
US9044715B2 (en) * 2007-08-22 2015-06-02 Colorado School Of Mines Unsupported palladium alloy membranes and methods of making same
EP2414078A4 (de) * 2009-04-02 2012-10-17 Procede Gas Treating B V Verfahren zur steigerung der leistung von prozessen zur entfernung von säuregas
MY155414A (en) 2009-04-20 2015-10-15 Exxonmobil Upstream Res Co Cryogenic system for removing acid gases from a hydrocarbon gas stream, and method of removing acid gases
US8052935B2 (en) * 2009-04-30 2011-11-08 General Electric Company System and method for removing sulfur from gas stream
WO2011046658A1 (en) 2009-09-09 2011-04-21 Exxonmobil Upstream Research Company Cryogenic system for removing acid gasses from a hydrocarbon gas stream
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US8778058B2 (en) 2010-07-16 2014-07-15 Colorado School Of Mines Multilayer sulfur-resistant composite metal membranes and methods of making and repairing the same
US8518356B2 (en) 2010-07-27 2013-08-27 Air Products And Chemicals, Inc. Method and apparatus for adjustably treating a sour gas
US8206669B2 (en) 2010-07-27 2012-06-26 Air Products And Chemicals, Inc. Method and apparatus for treating a sour gas
MY164721A (en) 2010-07-30 2018-01-30 Exxonmobil Upstream Res Co Cryogenic systems for removing acid gases from a hydrocarbon gas stream using co-current separation devices
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US8491798B2 (en) 2011-03-14 2013-07-23 ThioSolv, LLC Eliminating hydrogen sulfide from liquid ammonia
MY166180A (en) 2012-03-21 2018-06-07 Exxonmobil Upstream Res Co Separating carbon dioxide and ethane from mixed stream
CN103157348A (zh) * 2013-04-03 2013-06-19 江苏创新石化有限公司 一种高效低能耗脱硫剂
US9334455B2 (en) * 2013-06-28 2016-05-10 Uop Llc Methods and apparatuses for enhanced absorption of acid gas components from sour feed gas
CN105722572B (zh) 2013-12-06 2017-08-22 埃克森美孚上游研究公司 用喷射组件分离烃和杂质的方法和装置
US9562719B2 (en) 2013-12-06 2017-02-07 Exxonmobil Upstream Research Company Method of removing solids by modifying a liquid level in a distillation tower
AU2014357666B2 (en) 2013-12-06 2017-08-10 Exxonmobil Upstream Research Company Method and system of dehydrating a feed stream processed in a distillation tower
US9829247B2 (en) 2013-12-06 2017-11-28 Exxonmobil Upstream Reseach Company Method and device for separating a feed stream using radiation detectors
WO2015084498A2 (en) 2013-12-06 2015-06-11 Exxonmobil Upstream Research Company Method and system for separating a feed stream with a feed stream distribution mechanism
US9823016B2 (en) 2013-12-06 2017-11-21 Exxonmobil Upstream Research Company Method and system of modifying a liquid level during start-up operations
WO2015084495A2 (en) 2013-12-06 2015-06-11 Exxonmobil Upstream Research Company Method and system of maintaining a liquid level in a distillation tower
US9874395B2 (en) 2013-12-06 2018-01-23 Exxonmobil Upstream Research Company Method and system for preventing accumulation of solids in a distillation tower
CA2925955C (en) 2013-12-06 2018-02-27 Exxonmobil Upstream Research Company Method and device for separating hydrocarbons and contaminants with a heating mechanism to destabilize and/or prevent adhesion of solids
US9504984B2 (en) 2014-04-09 2016-11-29 Exxonmobil Upstream Research Company Generating elemental sulfur
MX2017008683A (es) 2015-02-27 2017-10-11 Exxonmobil Upstream Res Co Reduccion de carga de refrigeracion y deshidratacion para una corriente de alimentacion que entra a un proceso de destilacion criogenica.
US9682343B2 (en) * 2015-04-09 2017-06-20 Uop Llc Sour syngas treatment apparatuses and processes for treating sour syngas comprising sulfur components and carbon dioxide
AU2016323618B2 (en) 2015-09-18 2019-06-13 Exxonmobil Upsteam Research Company Heating component to reduce solidification in a cryogenic distillation system
AU2016327820B2 (en) 2015-09-24 2019-08-01 Exxonmobil Upstream Research Company Treatment plant for hydrocarbon gas having variable contaminant levels
CA3024545C (en) 2016-03-30 2020-08-25 Exxonmobile Upstream Research Company Self-sourced reservoir fluid for enhanced oil recovery
WO2020005553A1 (en) 2018-06-29 2020-01-02 Exxonmobil Upstream Research Company (Emhc-N1.4A.607) Mixing and heat integration of melt tray liquids in a cryogenic distillation tower
US11306267B2 (en) 2018-06-29 2022-04-19 Exxonmobil Upstream Research Company Hybrid tray for introducing a low CO2 feed stream into a distillation tower
CN109772134B (zh) * 2019-01-10 2021-12-28 昆明理工大学 一种循环脱除h2s和so2并回收硫的方法
CN113528206B (zh) * 2020-04-13 2022-11-04 中国石油天然气股份有限公司 一种脱硫系统及方法
CN111689476B (zh) * 2020-06-30 2021-09-14 太和气体（荆州）有限公司 高纯硫化氢的制备工艺
US11826699B2 (en) 2021-06-04 2023-11-28 Saudi Arabian Oil Company Stripping H2S off natural gas for multiple isotope analyses
CN113499675B (zh) * 2021-09-10 2021-11-30 东营联合石化有限责任公司 一种硫磺回收设备

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Also Published As

Publication number Publication date
ATE274993T1 (de) 2004-09-15
US6818194B2 (en) 2004-11-16
EP1171222A1 (de) 2002-01-16
EP1171222A4 (de) 2002-11-27
DE60013421T2 (de) 2005-09-08
EP1171222B1 (de) 2004-09-01
CA2371826A1 (en) 2000-08-24
US6416729B1 (en) 2002-07-09
US20030021744A1 (en) 2003-01-30
ES2225099T3 (es) 2005-03-16
CA2371826C (en) 2007-05-08
AU2997200A (en) 2000-09-04
WO2000048712A1 (en) 2000-08-24

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