ATE274993T1 - Verfahren zur entfernung von schwefelwasserstoff aus gasen - Google Patents
Verfahren zur entfernung von schwefelwasserstoff aus gasenInfo
- Publication number
- ATE274993T1 ATE274993T1 AT00908670T AT00908670T ATE274993T1 AT E274993 T1 ATE274993 T1 AT E274993T1 AT 00908670 T AT00908670 T AT 00908670T AT 00908670 T AT00908670 T AT 00908670T AT E274993 T1 ATE274993 T1 AT E274993T1
- Authority
- AT
- Austria
- Prior art keywords
- liquor
- sulfur
- dissolved
- polysulfide
- sorbing
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title 1
- 239000007789 gas Substances 0.000 title 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 title 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 7
- 229910052717 sulfur Inorganic materials 0.000 abstract 7
- 239000011593 sulfur Substances 0.000 abstract 7
- 229920001021 polysulfide Polymers 0.000 abstract 4
- 239000005077 polysulfide Substances 0.000 abstract 4
- 150000008117 polysulfides Polymers 0.000 abstract 4
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 abstract 2
- 239000006096 absorbing agent Substances 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 150000003512 tertiary amines Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/05—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by wet processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1468—Removing hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
- B01D53/523—Mixtures of hydrogen sulfide and sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/73—After-treatment of removed components
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Physical Water Treatments (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12039099P | 1999-02-17 | 1999-02-17 | |
US15654599P | 1999-09-29 | 1999-09-29 | |
US09/503,898 US6416729B1 (en) | 1999-02-17 | 2000-02-15 | Process for removing hydrogen sulfide from gas streams which include or are supplemented with sulfur dioxide |
PCT/US2000/003946 WO2000048712A1 (en) | 1999-02-17 | 2000-02-16 | Process for removing hydrogen sulfide from gases |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE274993T1 true ATE274993T1 (de) | 2004-09-15 |
Family
ID=27382468
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT00908670T ATE274993T1 (de) | 1999-02-17 | 2000-02-16 | Verfahren zur entfernung von schwefelwasserstoff aus gasen |
Country Status (8)
Country | Link |
---|---|
US (2) | US6416729B1 (de) |
EP (1) | EP1171222B1 (de) |
AT (1) | ATE274993T1 (de) |
AU (1) | AU2997200A (de) |
CA (1) | CA2371826C (de) |
DE (1) | DE60013421T2 (de) |
ES (1) | ES2225099T3 (de) |
WO (1) | WO2000048712A1 (de) |
Families Citing this family (59)
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US6416729B1 (en) | 1999-02-17 | 2002-07-09 | Crystatech, Inc. | Process for removing hydrogen sulfide from gas streams which include or are supplemented with sulfur dioxide |
US6887452B1 (en) * | 2000-10-31 | 2005-05-03 | United States Filter Corporation | System and method for precipitating salts |
US20030057136A1 (en) * | 2001-08-22 | 2003-03-27 | Mcintush Kenneth E. | Process for recovering sulfur while sponging light hydrocarbons from hydrodesulfurization hydrogen recycle streams |
AU2003222204A1 (en) * | 2002-03-25 | 2003-10-13 | Tda Research, Inc. | Catalysts and process for oxidizing hydrogen sulfide to sulfur dioxide and sulfur |
US7060233B1 (en) | 2002-03-25 | 2006-06-13 | Tda Research, Inc. | Process for the simultaneous removal of sulfur and mercury |
US20030190486A1 (en) * | 2002-04-03 | 2003-10-09 | Fernando Roa | Process for Preparing Palladium Alloy Composite Membranes for Use in Hydrogen Separation, Palladium Alloy Composite Membranes and Products Incorporating or Made from the Membranes |
US8101243B2 (en) * | 2002-04-03 | 2012-01-24 | Colorado School Of Mines | Method of making sulfur-resistant composite metal membranes |
US7413550B2 (en) | 2003-10-16 | 2008-08-19 | Kimberly-Clark Worldwide, Inc. | Visual indicating device for bad breath |
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US20060043002A1 (en) * | 2004-08-26 | 2006-03-02 | Petrinec Bryan J | Method for downhole sulfur removal and recovery |
US20090136414A1 (en) * | 2004-08-26 | 2009-05-28 | Petrinec Bryan J | Method for downhole sulfur removal and recovery |
US7381393B2 (en) * | 2004-10-07 | 2008-06-03 | The Regents Of The University Of California | Process for sulfur removal suitable for treating high-pressure gas streams |
US7378068B2 (en) * | 2005-06-01 | 2008-05-27 | Conocophillips Company | Electrochemical process for decomposition of hydrogen sulfide and production of sulfur |
JP2009507183A (ja) * | 2005-09-02 | 2009-02-19 | ルーク ラメレン ウント クツプルングスバウ ベタイリグングス コマンディートゲゼルシャフト | トルクコンバータに用いられるクラッチアッセンブリ、2つの入力体を備えた手動変速機に用いられるトルクコンバータおよびこれらに対する方法 |
BRPI0711026B1 (pt) | 2006-05-17 | 2022-02-08 | ThioSolv, LLC | Processo para tratamento de fluxo de gás |
US7655211B2 (en) | 2006-08-23 | 2010-02-02 | ThioSolv, LLC | Process for producing ammonium thiosulfate |
CA2568303C (en) * | 2006-10-31 | 2008-02-12 | John Keum-Ho Hwang | A method for recovering sulphur from gas streams |
US20100018248A1 (en) * | 2007-01-19 | 2010-01-28 | Eleanor R Fieler | Controlled Freeze Zone Tower |
AU2007345353B2 (en) * | 2007-01-19 | 2013-02-21 | Exxonmobil Upstream Research Company | Integrated controlled freeze zone (CFZ) tower and dividing wall (DWC) for enhanced hydrocarbon recovery |
US7749481B2 (en) * | 2007-06-27 | 2010-07-06 | H R D Corporation | System and process for gas sweetening |
US9044715B2 (en) * | 2007-08-22 | 2015-06-02 | Colorado School Of Mines | Unsupported palladium alloy membranes and methods of making same |
US20120090466A1 (en) * | 2009-04-02 | 2012-04-19 | Geert Frederic Versteeg | Method for Enhancing the Performance of Processes for the Removal of Acid Gas |
WO2010123598A1 (en) | 2009-04-20 | 2010-10-28 | Exxonmobil Upstream Research Company | Cryogenic system for removing acid gases from a hyrdrocarbon gas stream, and method of removing acid gases |
US8052935B2 (en) * | 2009-04-30 | 2011-11-08 | General Electric Company | System and method for removing sulfur from gas stream |
CA2771566C (en) | 2009-09-09 | 2017-07-18 | Exxonmobil Upstream Research Company | Cryogenic system for removing acid gases from a hydrocarbon gas stream |
CN102597671B (zh) * | 2009-11-02 | 2015-11-25 | 埃克森美孚上游研究公司 | 从烃气流中去除酸性气体以及去除硫化氢的低温系统 |
WO2011090553A1 (en) | 2010-01-22 | 2011-07-28 | Exxonmobil Upstream Research Company | Removal of acid gases from a gas stream, with co2 capture and sequestration |
CA2786498C (en) | 2010-02-03 | 2018-06-26 | Exxonmobil Upstream Research Company | Systems and methods for using cold liquid to remove solidifiable gas components from process gas streams |
US8778058B2 (en) | 2010-07-16 | 2014-07-15 | Colorado School Of Mines | Multilayer sulfur-resistant composite metal membranes and methods of making and repairing the same |
US8206669B2 (en) | 2010-07-27 | 2012-06-26 | Air Products And Chemicals, Inc. | Method and apparatus for treating a sour gas |
US8518356B2 (en) | 2010-07-27 | 2013-08-27 | Air Products And Chemicals, Inc. | Method and apparatus for adjustably treating a sour gas |
US9829246B2 (en) | 2010-07-30 | 2017-11-28 | Exxonmobil Upstream Research Company | Cryogenic systems for removing acid gases from a hydrocarbon gas stream using co-current separation devices |
US8512449B1 (en) | 2010-12-03 | 2013-08-20 | Jacam Chemical Company 2013, Llc | Oil-soluble triazine sulfide scavenger |
WO2012125643A2 (en) | 2011-03-14 | 2012-09-20 | Thiosolv, L.L.C. | Elimination of hydrogen sulfide in aqueous ammonia |
MY166180A (en) | 2012-03-21 | 2018-06-07 | Exxonmobil Upstream Res Co | Separating carbon dioxide and ethane from mixed stream |
CN103157348A (zh) * | 2013-04-03 | 2013-06-19 | 江苏创新石化有限公司 | 一种高效低能耗脱硫剂 |
US9334455B2 (en) * | 2013-06-28 | 2016-05-10 | Uop Llc | Methods and apparatuses for enhanced absorption of acid gas components from sour feed gas |
US9874395B2 (en) | 2013-12-06 | 2018-01-23 | Exxonmobil Upstream Research Company | Method and system for preventing accumulation of solids in a distillation tower |
EA031531B1 (ru) | 2013-12-06 | 2019-01-31 | Эксонмобил Апстрим Рисерч Компани | Способ и устройство для разделения углеводородов и загрязняющих примесей с помощью нагревательного устройства для дестабилизации и/или предотвращения адгезии твердых веществ |
US9562719B2 (en) | 2013-12-06 | 2017-02-07 | Exxonmobil Upstream Research Company | Method of removing solids by modifying a liquid level in a distillation tower |
WO2015084494A2 (en) | 2013-12-06 | 2015-06-11 | Exxonmobil Upstream Research Company | Method and device for separating hydrocarbons and contaminants with a spray assembly |
AU2014357665B2 (en) | 2013-12-06 | 2017-06-22 | Exxonmobil Upstream Research Company | Method and device for separating a feed stream using radiation detectors |
AU2014357668B2 (en) | 2013-12-06 | 2017-05-25 | Exxonmobil Upstream Research Company | Method and system of modifying a liquid level during start-up operations |
MY177942A (en) | 2013-12-06 | 2020-09-28 | Exxonmobil Upstream Res Co | Method and system for separating a feed stream with a feed stream distribution mechanism |
AU2014357666B2 (en) | 2013-12-06 | 2017-08-10 | Exxonmobil Upstream Research Company | Method and system of dehydrating a feed stream processed in a distillation tower |
WO2015084495A2 (en) | 2013-12-06 | 2015-06-11 | Exxonmobil Upstream Research Company | Method and system of maintaining a liquid level in a distillation tower |
US9504984B2 (en) | 2014-04-09 | 2016-11-29 | Exxonmobil Upstream Research Company | Generating elemental sulfur |
MY184436A (en) | 2015-02-27 | 2021-04-01 | Exxonmobil Upstream Res Co | Reducing refrigeration and dehydration load for a feed stream entering a cryogenic distillation process |
US9682343B2 (en) * | 2015-04-09 | 2017-06-20 | Uop Llc | Sour syngas treatment apparatuses and processes for treating sour syngas comprising sulfur components and carbon dioxide |
AU2016323618B2 (en) | 2015-09-18 | 2019-06-13 | Exxonmobil Upsteam Research Company | Heating component to reduce solidification in a cryogenic distillation system |
MY187623A (en) | 2015-09-24 | 2021-10-04 | Exxonmobil Upstream Res Co | Treatment plant for hydrocarbon gas having variable contaminant levels |
WO2017172321A1 (en) | 2016-03-30 | 2017-10-05 | Exxonmobil Upstream Research Company | Self-sourced reservoir fluid for enhanced oil recovery |
US11306267B2 (en) | 2018-06-29 | 2022-04-19 | Exxonmobil Upstream Research Company | Hybrid tray for introducing a low CO2 feed stream into a distillation tower |
WO2020005553A1 (en) | 2018-06-29 | 2020-01-02 | Exxonmobil Upstream Research Company (Emhc-N1.4A.607) | Mixing and heat integration of melt tray liquids in a cryogenic distillation tower |
CN109772134B (zh) * | 2019-01-10 | 2021-12-28 | 昆明理工大学 | 一种循环脱除h2s和so2并回收硫的方法 |
CN113528206B (zh) * | 2020-04-13 | 2022-11-04 | 中国石油天然气股份有限公司 | 一种脱硫系统及方法 |
CN111689476B (zh) * | 2020-06-30 | 2021-09-14 | 太和气体(荆州)有限公司 | 高纯硫化氢的制备工艺 |
US11826699B2 (en) | 2021-06-04 | 2023-11-28 | Saudi Arabian Oil Company | Stripping H2S off natural gas for multiple isotope analyses |
CN113499675B (zh) * | 2021-09-10 | 2021-11-30 | 东营联合石化有限责任公司 | 一种硫磺回收设备 |
Family Cites Families (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US927342A (en) | 1909-07-06 | Walther Feld | Process of recovering sulfur. | |
US2094939A (en) | 1936-06-17 | 1937-10-05 | Derives Du Soufre Soc Ind Des | Process for the preparation of stable colloidal sulphur |
US2251216A (en) | 1939-10-04 | 1941-07-29 | Du Pont | Sulphur removal from gases |
US2534063A (en) | 1945-02-12 | 1950-12-12 | Stauffer Chemical Co | Manufacture of insoluble sulfur |
US2881047A (en) | 1956-05-29 | 1959-04-07 | Laurence S Reid | Method of simultaneously removing hydrogen sulfide from gaseous mixtures and producing sulfur therefrom |
US2998304A (en) | 1958-12-08 | 1961-08-29 | Universal Oil Prod Co | Production of sulfur |
US3103411A (en) | 1959-06-11 | 1963-09-10 | Method of removing hydrogen sulfide | |
US3023088A (en) | 1960-07-05 | 1962-02-27 | Universal Oil Prod Co | Production of sulfur |
US3363989A (en) | 1965-11-04 | 1968-01-16 | Shell Oil Co | Method of removing sulfur containing gases from gaseous mixtures and recovering sulfur therefrom |
GB1223732A (en) * | 1968-07-29 | 1971-03-03 | Inst Francais Du Petrole | Process for purifying a gas containing hydrogen sulfide with production of sulfur |
DE2108282A1 (en) * | 1971-02-20 | 1972-08-24 | Basf Ag | Elementary sulphur prepn - from hydrogen sulphide and sulphur dioxide using polar aprotic solvents |
FR2187680B1 (de) | 1972-06-01 | 1974-10-25 | Inst Francais Du Petrole | |
JPS5116186B2 (de) | 1972-12-15 | 1976-05-22 | ||
US3914399A (en) * | 1973-12-26 | 1975-10-21 | Marathon Oil Co | Elemental sulfur produced by wet oxidation of hydrogen sulfide |
US4020149A (en) | 1975-05-02 | 1977-04-26 | Exxon Research And Engineering Company | Process for the production of sulfur |
FR2358186A2 (fr) * | 1976-07-12 | 1978-02-10 | Raffinage Cie Francaise | Procede d'elimination de l'hydrogene sulfure contenu dans des melanges gazeux |
DE2648190C3 (de) | 1976-10-25 | 1980-02-21 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur Herstellung von Schwefel nach dem Claus-Verfahren |
GB8301968D0 (en) | 1983-01-25 | 1983-02-23 | Powlesland Eng Ltd | Removal of hydrogen sulphide from gaseous streams |
US4647397A (en) | 1984-01-23 | 1987-03-03 | Chevron Research Company | Composition for removing sulfides from industrial gas |
US4539189A (en) | 1984-01-23 | 1985-09-03 | Chevron Research Company | Method for removing sulfides from industrial gas |
DE3607029A1 (de) | 1985-03-08 | 1986-10-02 | Jgc Corp., Tokio/Tokyo | Verfahren zur entschwefelung von schwefelwasserstoff enthaltendem gas |
US5202107A (en) | 1988-06-08 | 1993-04-13 | Societe National Elf Aquitaine (Prod.) | Process for improving the sulphur yield of a complex for the production of sulphur followed by a purification unit |
US5520818A (en) | 1989-12-06 | 1996-05-28 | The University Of Toronto Innovations Foundation | Method for effecting gas-liquid contact |
US4976635A (en) | 1990-04-09 | 1990-12-11 | Molex Incorporated | Locking electrical connector |
AU666522B2 (en) * | 1992-04-06 | 1996-02-15 | Boc Group Plc, The | Treatment of gas streams |
US5389351A (en) | 1992-11-04 | 1995-02-14 | Hasebe; Nobuyasu | Method for desulfurizing a gas |
US5648054A (en) * | 1995-01-31 | 1997-07-15 | Gas Research Institute | Double loop liquid-liquid H2 S removal process |
WO1998004337A1 (en) | 1996-07-29 | 1998-02-05 | Apollo Environmental Systems Corp. | Natural gas treatment process |
US5733516A (en) * | 1996-09-09 | 1998-03-31 | Gas Research Institute | Process for removal of hydrogen sulfide from a gas stream |
US5928620A (en) | 1997-09-10 | 1999-07-27 | The Regents Of The University Of California | Process employing single-stage reactor for recovering sulfur from H2 S- |
AU1137999A (en) | 1997-11-12 | 1999-05-31 | Apollo Environmental Systems Corp. | Hydrogen sulfide removal process |
JP2002521181A (ja) * | 1998-07-21 | 2002-07-16 | クリスタテック インク. | ガス流から硫化水素を除去するプロセスのための改良再生方法 |
US6416729B1 (en) | 1999-02-17 | 2002-07-09 | Crystatech, Inc. | Process for removing hydrogen sulfide from gas streams which include or are supplemented with sulfur dioxide |
-
2000
- 2000-02-15 US US09/503,898 patent/US6416729B1/en not_active Expired - Lifetime
- 2000-02-16 DE DE60013421T patent/DE60013421T2/de not_active Expired - Lifetime
- 2000-02-16 AU AU29972/00A patent/AU2997200A/en not_active Abandoned
- 2000-02-16 ES ES00908670T patent/ES2225099T3/es not_active Expired - Lifetime
- 2000-02-16 CA CA002371826A patent/CA2371826C/en not_active Expired - Lifetime
- 2000-02-16 EP EP00908670A patent/EP1171222B1/de not_active Expired - Lifetime
- 2000-02-16 WO PCT/US2000/003946 patent/WO2000048712A1/en active IP Right Grant
- 2000-02-16 AT AT00908670T patent/ATE274993T1/de not_active IP Right Cessation
-
2002
- 2002-07-05 US US10/190,448 patent/US6818194B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP1171222B1 (de) | 2004-09-01 |
US6818194B2 (en) | 2004-11-16 |
EP1171222A4 (de) | 2002-11-27 |
US6416729B1 (en) | 2002-07-09 |
CA2371826A1 (en) | 2000-08-24 |
US20030021744A1 (en) | 2003-01-30 |
EP1171222A1 (de) | 2002-01-16 |
DE60013421T2 (de) | 2005-09-08 |
WO2000048712A1 (en) | 2000-08-24 |
AU2997200A (en) | 2000-09-04 |
ES2225099T3 (es) | 2005-03-16 |
CA2371826C (en) | 2007-05-08 |
DE60013421D1 (de) | 2004-10-07 |
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