DE60006818T2 - Gasdiffusionssubstrat und elektrode - Google Patents
Gasdiffusionssubstrat und elektrode Download PDFInfo
- Publication number
- DE60006818T2 DE60006818T2 DE60006818T DE60006818T DE60006818T2 DE 60006818 T2 DE60006818 T2 DE 60006818T2 DE 60006818 T DE60006818 T DE 60006818T DE 60006818 T DE60006818 T DE 60006818T DE 60006818 T2 DE60006818 T2 DE 60006818T2
- Authority
- DE
- Germany
- Prior art keywords
- gas diffusion
- diffusion substrate
- catalytic component
- substrate according
- electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000009792 diffusion process Methods 0.000 title claims description 67
- 239000000758 substrate Substances 0.000 title claims description 57
- 239000003054 catalyst Substances 0.000 claims description 59
- 239000000446 fuel Substances 0.000 claims description 50
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 41
- 230000003197 catalytic effect Effects 0.000 claims description 38
- 239000010410 layer Substances 0.000 claims description 32
- 239000012528 membrane Substances 0.000 claims description 31
- 239000010411 electrocatalyst Substances 0.000 claims description 28
- 239000010948 rhodium Substances 0.000 claims description 24
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 17
- 229910052799 carbon Inorganic materials 0.000 claims description 16
- 239000007787 solid Substances 0.000 claims description 14
- 229910052697 platinum Inorganic materials 0.000 claims description 11
- 229910052703 rhodium Inorganic materials 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 229920005597 polymer membrane Polymers 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000002344 surface layer Substances 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 4
- 239000000835 fiber Substances 0.000 claims description 4
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 4
- 229910052707 ruthenium Inorganic materials 0.000 claims description 4
- 239000004071 soot Substances 0.000 claims description 4
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 3
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims description 3
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 3
- 238000011049 filling Methods 0.000 claims description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052737 gold Inorganic materials 0.000 claims description 3
- 239000010931 gold Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 239000010970 precious metal Substances 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- 229910001260 Pt alloy Inorganic materials 0.000 claims description 2
- 229910000929 Ru alloy Inorganic materials 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- 239000000969 carrier Substances 0.000 claims description 2
- 239000002657 fibrous material Substances 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 150000004706 metal oxides Chemical class 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 229910052723 transition metal Inorganic materials 0.000 claims description 2
- 150000003624 transition metals Chemical class 0.000 claims description 2
- 239000010953 base metal Substances 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims 1
- 239000007789 gas Substances 0.000 description 71
- 230000003647 oxidation Effects 0.000 description 23
- 238000007254 oxidation reaction Methods 0.000 description 23
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 21
- 229910052739 hydrogen Inorganic materials 0.000 description 21
- 239000001257 hydrogen Substances 0.000 description 20
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 14
- 238000011068 loading method Methods 0.000 description 13
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 11
- 239000001301 oxygen Substances 0.000 description 11
- 229910052760 oxygen Inorganic materials 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000003792 electrolyte Substances 0.000 description 7
- -1 furnace blacks Substances 0.000 description 7
- 229920000557 Nafion® Polymers 0.000 description 6
- 150000002431 hydrogen Chemical class 0.000 description 6
- 229910000510 noble metal Inorganic materials 0.000 description 6
- 239000000376 reactant Substances 0.000 description 6
- 229920001940 conductive polymer Polymers 0.000 description 4
- 238000003487 electrochemical reaction Methods 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000004812 Fluorinated ethylene propylene Substances 0.000 description 3
- 238000005266 casting Methods 0.000 description 3
- 239000002322 conducting polymer Substances 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000004070 electrodeposition Methods 0.000 description 3
- 238000011066 ex-situ storage Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 229920009441 perflouroethylene propylene Polymers 0.000 description 3
- 231100000572 poisoning Toxicity 0.000 description 3
- 230000000607 poisoning effect Effects 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 238000006722 reduction reaction Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000010345 tape casting Methods 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 241000640882 Condea Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229910002849 PtRu Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910021383 artificial graphite Inorganic materials 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 230000001706 oxygenating effect Effects 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000006253 pitch coke Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000012078 proton-conducting electrolyte Substances 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- VXNYVYJABGOSBX-UHFFFAOYSA-N rhodium(3+);trinitrate Chemical compound [Rh+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VXNYVYJABGOSBX-UHFFFAOYSA-N 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000009718 spray deposition Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9075—Catalytic material supported on carriers, e.g. powder carriers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
- H01M4/925—Metals of platinum group supported on carriers, e.g. powder carriers
- H01M4/926—Metals of platinum group supported on carriers, e.g. powder carriers on carbon or graphite
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M2004/8678—Inert electrodes with catalytic activity, e.g. for fuel cells characterised by the polarity
- H01M2004/8684—Negative electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0082—Organic polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
- H01M4/8657—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites layered
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
- H01M4/921—Alloys or mixtures with metallic elements
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
- Y10T29/49115—Electric battery cell making including coating or impregnating
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Inert Electrodes (AREA)
- Catalysts (AREA)
- Fuel Cell (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB9914023.8A GB9914023D0 (en) | 1999-06-17 | 1999-06-17 | Gas diffusion substrate and electrode |
| GB9914023 | 1999-06-17 | ||
| PCT/GB2000/002305 WO2000079628A1 (en) | 1999-06-17 | 2000-06-14 | Gas diffusion substrate and electrode |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60006818D1 DE60006818D1 (de) | 2004-01-08 |
| DE60006818T2 true DE60006818T2 (de) | 2004-08-12 |
Family
ID=10855473
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60006818T Expired - Lifetime DE60006818T2 (de) | 1999-06-17 | 2000-06-14 | Gasdiffusionssubstrat und elektrode |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US7338732B1 (enExample) |
| EP (1) | EP1192681B1 (enExample) |
| JP (2) | JP2003502827A (enExample) |
| CA (1) | CA2374238C (enExample) |
| DE (1) | DE60006818T2 (enExample) |
| GB (1) | GB9914023D0 (enExample) |
| WO (1) | WO2000079628A1 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006022862B4 (de) * | 2005-05-18 | 2011-01-20 | GM Global Technology Operations, Inc., Detroit | Fluidverteilungselement für eine Brennstoffzelle sowie Verfahren zur Herstellung einer Brennstoffzelle mit solch einem Element |
| DE102019211127A1 (de) * | 2019-07-26 | 2021-01-28 | Greenerity Gmbh | Membranelektrodenanordnung und Brennstoffzelle |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6828056B2 (en) | 2000-09-27 | 2004-12-07 | Proton Energy Systems, Inc. | Electrode catalyst composition, electrode, and membrane electrode assembly for electrochemical cells |
| DE10130828A1 (de) * | 2001-06-27 | 2003-01-16 | Basf Ag | Brennstoffzelle |
| EP1298751A3 (en) | 2001-09-27 | 2006-04-26 | Matsushita Electric Industrial Co., Ltd. | Polymer electrolyte fuel cell and production method thereof |
| EP1435672A1 (de) * | 2002-12-30 | 2004-07-07 | Umicore AG & Co. KG | Katalysatorhaltiges Gasverteilersubstrat für Brennstoffzellen sowie Verfahren zu dessen Herstellung |
| JP4845077B2 (ja) * | 2003-08-19 | 2011-12-28 | 株式会社豊田中央研究所 | 固体高分子型燃料電池用電解質膜電極接合体および固体高分子型燃料電池 |
| KR100599808B1 (ko) | 2004-11-09 | 2006-07-12 | 삼성에스디아이 주식회사 | 연료 전지용 전극 및 이를 포함하는 연료 전지 시스템 |
| JP2006210135A (ja) * | 2005-01-28 | 2006-08-10 | Sony Corp | 触媒電極材料、触媒電極、及びこれらの製造方法、電極触媒用の担体材料、並びに電気化学デバイス |
| DE112006001209T5 (de) * | 2005-05-16 | 2008-04-30 | General Motors Global Technology Operations, Inc., Detroit | Katalysator für Brennstoffzellenelektrode |
| JP5125461B2 (ja) * | 2007-01-18 | 2013-01-23 | 株式会社豊田中央研究所 | リチウム空気電池 |
| US8247521B2 (en) * | 2007-06-27 | 2012-08-21 | Advent Technologies | Acid-doped polyelectrolyte modified carbon nanotubes and their use in high temperature PEM fuel cell electrodes |
| KR101045207B1 (ko) * | 2009-01-16 | 2011-06-30 | 삼성전자주식회사 | 연료전지 스택 |
| JP5178677B2 (ja) * | 2009-09-30 | 2013-04-10 | 株式会社日立製作所 | 燃料電池用膜／電極接合体 |
| US20120122016A1 (en) * | 2010-11-15 | 2012-05-17 | Gm Global Technology Operations, Inc. | Fuel Cell Durability Through Oxide Supported Precious Metals in Membrane |
| NL2023696B1 (en) * | 2019-08-23 | 2021-05-04 | Hyet Holding B V | Solid-state electro-chemical compressor |
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| US3992512A (en) * | 1971-06-16 | 1976-11-16 | Prototech Company | Finely particulated colloidal platinum compound and sol for producing the same, and method of preparation |
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| US4647359A (en) | 1985-10-16 | 1987-03-03 | Prototech Company | Electrocatalytic gas diffusion electrode employing thin carbon cloth layer |
| JP2761066B2 (ja) | 1989-12-28 | 1998-06-04 | 三菱重工業株式会社 | 固体高分子電解質型燃料電池装置と発電方法 |
| CA2111882A1 (en) | 1992-12-25 | 1994-06-26 | De Nora S.P.A. | Gas electrode, catalyst for gas electrode, and process for production thereof |
| GB9324101D0 (en) | 1993-11-23 | 1994-01-12 | Johnson Matthey Plc | Improved manufacture of electrodes |
| JPH07309603A (ja) | 1994-05-17 | 1995-11-28 | Idemitsu Kosan Co Ltd | 燃料電池用水素含有ガスの製造方法 |
| US5523177A (en) | 1994-10-12 | 1996-06-04 | Giner, Inc. | Membrane-electrode assembly for a direct methanol fuel cell |
| JP3353518B2 (ja) * | 1995-01-31 | 2002-12-03 | 松下電器産業株式会社 | 固体高分子型燃料電池 |
| GB9507012D0 (en) | 1995-04-05 | 1995-05-31 | Johnson Matthey Plc | Improved electrode |
| JP3570046B2 (ja) * | 1995-11-02 | 2004-09-29 | 株式会社豊田中央研究所 | 低温型燃料電池 |
| US5863673A (en) | 1995-12-18 | 1999-01-26 | Ballard Power Systems Inc. | Porous electrode substrate for an electrochemical fuel cell |
| US5672439A (en) * | 1995-12-18 | 1997-09-30 | Ballard Power Systems, Inc. | Method and apparatus for reducing reactant crossover in an electrochemical fuel cell |
| EP0791974B2 (en) | 1996-02-28 | 2005-08-17 | Johnson Matthey Public Limited Company | Catalytically active gas diffusion electrodes comprising a nonwoven fibrous structure |
| DE19615562C1 (de) * | 1996-04-19 | 1997-10-09 | Zsw | Vorrichtung und Verfahren zur kombinierten Reinigung und Kompression von CO-haltigem Wasserstoff sowie Verwendung des mit dem Verfahren erhaltenen Wasserstoffs als Brenngas in Brennstoffzellen |
| JPH1083825A (ja) * | 1996-07-19 | 1998-03-31 | Asahi Chem Ind Co Ltd | 燃料電池用水素を精製する方法 |
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1999
- 1999-06-17 GB GBGB9914023.8A patent/GB9914023D0/en not_active Ceased
-
2000
- 2000-06-14 JP JP2001505092A patent/JP2003502827A/ja active Pending
- 2000-06-14 WO PCT/GB2000/002305 patent/WO2000079628A1/en not_active Ceased
- 2000-06-14 US US10/018,607 patent/US7338732B1/en not_active Expired - Fee Related
- 2000-06-14 CA CA002374238A patent/CA2374238C/en not_active Expired - Fee Related
- 2000-06-14 DE DE60006818T patent/DE60006818T2/de not_active Expired - Lifetime
- 2000-06-14 EP EP00938918A patent/EP1192681B1/en not_active Expired - Lifetime
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2008
- 2008-01-07 US US11/970,334 patent/US7678162B2/en not_active Expired - Fee Related
-
2013
- 2013-04-18 JP JP2013087574A patent/JP5792220B2/ja not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006022862B4 (de) * | 2005-05-18 | 2011-01-20 | GM Global Technology Operations, Inc., Detroit | Fluidverteilungselement für eine Brennstoffzelle sowie Verfahren zur Herstellung einer Brennstoffzelle mit solch einem Element |
| DE102019211127A1 (de) * | 2019-07-26 | 2021-01-28 | Greenerity Gmbh | Membranelektrodenanordnung und Brennstoffzelle |
| US12294092B2 (en) | 2019-07-26 | 2025-05-06 | Greenerity Gmbh | Membrane electrode assembly including anode having hydrogen reducion catalyst and carbon monoxide oxidation catalyst and fuel cell |
Also Published As
| Publication number | Publication date |
|---|---|
| US7338732B1 (en) | 2008-03-04 |
| CA2374238A1 (en) | 2000-12-28 |
| JP5792220B2 (ja) | 2015-10-07 |
| CA2374238C (en) | 2010-01-12 |
| WO2000079628A1 (en) | 2000-12-28 |
| JP2013179061A (ja) | 2013-09-09 |
| US7678162B2 (en) | 2010-03-16 |
| EP1192681A1 (en) | 2002-04-03 |
| US20080187817A1 (en) | 2008-08-07 |
| JP2003502827A (ja) | 2003-01-21 |
| DE60006818D1 (de) | 2004-01-08 |
| EP1192681B1 (en) | 2003-11-26 |
| GB9914023D0 (en) | 1999-08-18 |
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