CA2374238C - Gas diffusion substrate and electrode - Google Patents
Gas diffusion substrate and electrode Download PDFInfo
- Publication number
- CA2374238C CA2374238C CA002374238A CA2374238A CA2374238C CA 2374238 C CA2374238 C CA 2374238C CA 002374238 A CA002374238 A CA 002374238A CA 2374238 A CA2374238 A CA 2374238A CA 2374238 C CA2374238 C CA 2374238C
- Authority
- CA
- Canada
- Prior art keywords
- gas diffusion
- catalytic component
- diffusion electrode
- membrane
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000009792 diffusion process Methods 0.000 title claims abstract description 61
- 239000000758 substrate Substances 0.000 title claims abstract description 42
- 239000003054 catalyst Substances 0.000 claims abstract description 61
- 239000000446 fuel Substances 0.000 claims abstract description 54
- 230000003197 catalytic effect Effects 0.000 claims abstract description 43
- 239000012528 membrane Substances 0.000 claims abstract description 35
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 43
- 239000010410 layer Substances 0.000 claims description 31
- 239000010948 rhodium Substances 0.000 claims description 29
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 27
- 239000010411 electrocatalyst Substances 0.000 claims description 26
- 229910052799 carbon Inorganic materials 0.000 claims description 24
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 18
- 229910052703 rhodium Inorganic materials 0.000 claims description 17
- 239000007787 solid Substances 0.000 claims description 16
- 229910052697 platinum Inorganic materials 0.000 claims description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 11
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 229910000510 noble metal Inorganic materials 0.000 claims description 9
- 229920005597 polymer membrane Polymers 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 9
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 9
- 239000002344 surface layer Substances 0.000 claims description 9
- 229920000642 polymer Polymers 0.000 claims description 8
- 239000000835 fiber Substances 0.000 claims description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000006229 carbon black Substances 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 4
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 4
- 239000010970 precious metal Substances 0.000 claims description 4
- 229910052707 ruthenium Inorganic materials 0.000 claims description 4
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 3
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims description 3
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 3
- 239000002657 fibrous material Substances 0.000 claims description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052737 gold Inorganic materials 0.000 claims description 3
- 239000010931 gold Substances 0.000 claims description 3
- 229910044991 metal oxide Inorganic materials 0.000 claims description 3
- 150000004706 metal oxides Chemical class 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052723 transition metal Inorganic materials 0.000 claims description 3
- 150000003624 transition metals Chemical class 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- 229910001260 Pt alloy Inorganic materials 0.000 claims description 2
- 229910000929 Ru alloy Inorganic materials 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 239000011651 chromium Substances 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 1
- 229910052748 manganese Inorganic materials 0.000 claims 1
- 239000011572 manganese Substances 0.000 claims 1
- 239000012535 impurity Substances 0.000 abstract description 4
- 239000007789 gas Substances 0.000 description 70
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 56
- 229910002092 carbon dioxide Inorganic materials 0.000 description 28
- 239000001569 carbon dioxide Substances 0.000 description 26
- 230000003647 oxidation Effects 0.000 description 23
- 238000007254 oxidation reaction Methods 0.000 description 23
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 21
- 239000001257 hydrogen Substances 0.000 description 20
- 229910052739 hydrogen Inorganic materials 0.000 description 20
- 238000011068 loading method Methods 0.000 description 17
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 239000001301 oxygen Substances 0.000 description 10
- 229910052760 oxygen Inorganic materials 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 9
- 238000007792 addition Methods 0.000 description 7
- 239000003792 electrolyte Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 229920000557 Nafion® Polymers 0.000 description 6
- 150000002431 hydrogen Chemical class 0.000 description 6
- 239000000376 reactant Substances 0.000 description 6
- 238000003487 electrochemical reaction Methods 0.000 description 5
- -1 polytetrafluoroethylene Polymers 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 description 4
- 239000004812 Fluorinated ethylene propylene Substances 0.000 description 3
- 238000005266 casting Methods 0.000 description 3
- 239000002322 conducting polymer Substances 0.000 description 3
- 229920001940 conductive polymer Polymers 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 238000007606 doctor blade method Methods 0.000 description 3
- 238000004070 electrodeposition Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000011066 ex-situ storage Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 3
- 229920009441 perflouroethylene propylene Polymers 0.000 description 3
- 231100000572 poisoning Toxicity 0.000 description 3
- 230000000607 poisoning effect Effects 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 238000006722 reduction reaction Methods 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 238000009718 spray deposition Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- 238000001771 vacuum deposition Methods 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- DEXFNLNNUZKHNO-UHFFFAOYSA-N 6-[3-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-3-oxopropyl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)C(CCC1=CC2=C(NC(O2)=O)C=C1)=O DEXFNLNNUZKHNO-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 241000640882 Condea Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229910002849 PtRu Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000006253 pitch coke Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000012078 proton-conducting electrolyte Substances 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- VXNYVYJABGOSBX-UHFFFAOYSA-N rhodium(3+);trinitrate Chemical compound [Rh+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VXNYVYJABGOSBX-UHFFFAOYSA-N 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9075—Catalytic material supported on carriers, e.g. powder carriers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
- H01M4/925—Metals of platinum group supported on carriers, e.g. powder carriers
- H01M4/926—Metals of platinum group supported on carriers, e.g. powder carriers on carbon or graphite
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M2004/8678—Inert electrodes with catalytic activity, e.g. for fuel cells characterised by the polarity
- H01M2004/8684—Negative electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0082—Organic polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
- H01M4/8657—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites layered
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
- H01M4/921—Alloys or mixtures with metallic elements
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
- Y10T29/49115—Electric battery cell making including coating or impregnating
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Sustainable Energy (AREA)
- Sustainable Development (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inert Electrodes (AREA)
- Catalysts (AREA)
- Fuel Cell (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9914023.8 | 1999-06-17 | ||
| GBGB9914023.8A GB9914023D0 (en) | 1999-06-17 | 1999-06-17 | Gas diffusion substrate and electrode |
| PCT/GB2000/002305 WO2000079628A1 (en) | 1999-06-17 | 2000-06-14 | Gas diffusion substrate and electrode |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2374238A1 CA2374238A1 (en) | 2000-12-28 |
| CA2374238C true CA2374238C (en) | 2010-01-12 |
Family
ID=10855473
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002374238A Expired - Fee Related CA2374238C (en) | 1999-06-17 | 2000-06-14 | Gas diffusion substrate and electrode |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US7338732B1 (enExample) |
| EP (1) | EP1192681B1 (enExample) |
| JP (2) | JP2003502827A (enExample) |
| CA (1) | CA2374238C (enExample) |
| DE (1) | DE60006818T2 (enExample) |
| GB (1) | GB9914023D0 (enExample) |
| WO (1) | WO2000079628A1 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1327272A2 (en) | 2000-09-27 | 2003-07-16 | Proton Energy Systems, Inc. | Electrode catalyst composition, electrode and membrane electrode assembly for electrochemical cells |
| DE10130828A1 (de) * | 2001-06-27 | 2003-01-16 | Basf Ag | Brennstoffzelle |
| EP1298751A3 (en) | 2001-09-27 | 2006-04-26 | Matsushita Electric Industrial Co., Ltd. | Polymer electrolyte fuel cell and production method thereof |
| EP1435672A1 (de) * | 2002-12-30 | 2004-07-07 | Umicore AG & Co. KG | Katalysatorhaltiges Gasverteilersubstrat für Brennstoffzellen sowie Verfahren zu dessen Herstellung |
| JP4845077B2 (ja) * | 2003-08-19 | 2011-12-28 | 株式会社豊田中央研究所 | 固体高分子型燃料電池用電解質膜電極接合体および固体高分子型燃料電池 |
| KR100599808B1 (ko) | 2004-11-09 | 2006-07-12 | 삼성에스디아이 주식회사 | 연료 전지용 전극 및 이를 포함하는 연료 전지 시스템 |
| JP2006210135A (ja) * | 2005-01-28 | 2006-08-10 | Sony Corp | 触媒電極材料、触媒電極、及びこれらの製造方法、電極触媒用の担体材料、並びに電気化学デバイス |
| WO2006124248A2 (en) * | 2005-05-16 | 2006-11-23 | General Motors Global Technology Operations, Inc. | Catalyst for fuel cell electrode |
| US7759017B2 (en) * | 2005-05-18 | 2010-07-20 | Gm Global Technology Operations, Inc. | Membrane electrode assembly (MEA) architecture for improved durability for a PEM fuel cell |
| JP5125461B2 (ja) * | 2007-01-18 | 2013-01-23 | 株式会社豊田中央研究所 | リチウム空気電池 |
| US8247521B2 (en) * | 2007-06-27 | 2012-08-21 | Advent Technologies | Acid-doped polyelectrolyte modified carbon nanotubes and their use in high temperature PEM fuel cell electrodes |
| KR101045207B1 (ko) * | 2009-01-16 | 2011-06-30 | 삼성전자주식회사 | 연료전지 스택 |
| JP5178677B2 (ja) * | 2009-09-30 | 2013-04-10 | 株式会社日立製作所 | 燃料電池用膜／電極接合体 |
| US20120122016A1 (en) * | 2010-11-15 | 2012-05-17 | Gm Global Technology Operations, Inc. | Fuel Cell Durability Through Oxide Supported Precious Metals in Membrane |
| DE102019211127A1 (de) | 2019-07-26 | 2021-01-28 | Greenerity Gmbh | Membranelektrodenanordnung und Brennstoffzelle |
| NL2023696B1 (en) * | 2019-08-23 | 2021-05-04 | Hyet Holding B V | Solid-state electro-chemical compressor |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3992512A (en) * | 1971-06-16 | 1976-11-16 | Prototech Company | Finely particulated colloidal platinum compound and sol for producing the same, and method of preparation |
| US3881957A (en) * | 1972-03-17 | 1975-05-06 | Universal Oil Prod Co | Electrochemical cell comprising a catalytic electrode of a refractory oxide and a carbonaceous pyropolymer |
| US4647359A (en) | 1985-10-16 | 1987-03-03 | Prototech Company | Electrocatalytic gas diffusion electrode employing thin carbon cloth layer |
| JP2761066B2 (ja) | 1989-12-28 | 1998-06-04 | 三菱重工業株式会社 | 固体高分子電解質型燃料電池装置と発電方法 |
| CA2111882A1 (en) | 1992-12-25 | 1994-06-26 | De Nora S.P.A. | Gas electrode, catalyst for gas electrode, and process for production thereof |
| GB9324101D0 (en) | 1993-11-23 | 1994-01-12 | Johnson Matthey Plc | Improved manufacture of electrodes |
| JPH07309603A (ja) | 1994-05-17 | 1995-11-28 | Idemitsu Kosan Co Ltd | 燃料電池用水素含有ガスの製造方法 |
| US5523177A (en) | 1994-10-12 | 1996-06-04 | Giner, Inc. | Membrane-electrode assembly for a direct methanol fuel cell |
| JP3353518B2 (ja) * | 1995-01-31 | 2002-12-03 | 松下電器産業株式会社 | 固体高分子型燃料電池 |
| GB9507012D0 (en) * | 1995-04-05 | 1995-05-31 | Johnson Matthey Plc | Improved electrode |
| JP3570046B2 (ja) * | 1995-11-02 | 2004-09-29 | 株式会社豊田中央研究所 | 低温型燃料電池 |
| US5672439A (en) * | 1995-12-18 | 1997-09-30 | Ballard Power Systems, Inc. | Method and apparatus for reducing reactant crossover in an electrochemical fuel cell |
| US5863673A (en) | 1995-12-18 | 1999-01-26 | Ballard Power Systems Inc. | Porous electrode substrate for an electrochemical fuel cell |
| EP0942482B1 (en) | 1996-02-28 | 2001-11-21 | Johnson Matthey Public Limited Company | Use of catalytically active gas diffusion electrodes comprising a nonwoven fibrous structure in a Direct Methanol Fuel Cell |
| DE19615562C1 (de) * | 1996-04-19 | 1997-10-09 | Zsw | Vorrichtung und Verfahren zur kombinierten Reinigung und Kompression von CO-haltigem Wasserstoff sowie Verwendung des mit dem Verfahren erhaltenen Wasserstoffs als Brenngas in Brennstoffzellen |
| JPH1083825A (ja) * | 1996-07-19 | 1998-03-31 | Asahi Chem Ind Co Ltd | 燃料電池用水素を精製する方法 |
-
1999
- 1999-06-17 GB GBGB9914023.8A patent/GB9914023D0/en not_active Ceased
-
2000
- 2000-06-14 EP EP00938918A patent/EP1192681B1/en not_active Expired - Lifetime
- 2000-06-14 US US10/018,607 patent/US7338732B1/en not_active Expired - Fee Related
- 2000-06-14 WO PCT/GB2000/002305 patent/WO2000079628A1/en not_active Ceased
- 2000-06-14 CA CA002374238A patent/CA2374238C/en not_active Expired - Fee Related
- 2000-06-14 JP JP2001505092A patent/JP2003502827A/ja active Pending
- 2000-06-14 DE DE60006818T patent/DE60006818T2/de not_active Expired - Lifetime
-
2008
- 2008-01-07 US US11/970,334 patent/US7678162B2/en not_active Expired - Fee Related
-
2013
- 2013-04-18 JP JP2013087574A patent/JP5792220B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US7338732B1 (en) | 2008-03-04 |
| US20080187817A1 (en) | 2008-08-07 |
| EP1192681A1 (en) | 2002-04-03 |
| JP2003502827A (ja) | 2003-01-21 |
| JP2013179061A (ja) | 2013-09-09 |
| EP1192681B1 (en) | 2003-11-26 |
| JP5792220B2 (ja) | 2015-10-07 |
| DE60006818T2 (de) | 2004-08-12 |
| DE60006818D1 (de) | 2004-01-08 |
| WO2000079628A1 (en) | 2000-12-28 |
| CA2374238A1 (en) | 2000-12-28 |
| GB9914023D0 (en) | 1999-08-18 |
| US7678162B2 (en) | 2010-03-16 |
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