DE60003530D1 - Gewinnung von nickel und kobalt aus erzmaterialien - Google Patents
Gewinnung von nickel und kobalt aus erzmaterialienInfo
- Publication number
- DE60003530D1 DE60003530D1 DE60003530T DE60003530T DE60003530D1 DE 60003530 D1 DE60003530 D1 DE 60003530D1 DE 60003530 T DE60003530 T DE 60003530T DE 60003530 T DE60003530 T DE 60003530T DE 60003530 D1 DE60003530 D1 DE 60003530D1
- Authority
- DE
- Germany
- Prior art keywords
- cobalt
- nickel
- solution
- ion exchange
- impure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910017052 cobalt Inorganic materials 0.000 title abstract 8
- 239000010941 cobalt Substances 0.000 title abstract 8
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title abstract 8
- 238000000605 extraction Methods 0.000 title abstract 3
- 239000000463 material Substances 0.000 title 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 14
- 229910052759 nickel Inorganic materials 0.000 abstract 7
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 3
- 239000003456 ion exchange resin Substances 0.000 abstract 3
- 229920003303 ion-exchange polymer Polymers 0.000 abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 239000012074 organic phase Substances 0.000 abstract 2
- KXZQYLBVMZGIKC-UHFFFAOYSA-N 1-pyridin-2-yl-n-(pyridin-2-ylmethyl)methanamine Chemical compound C=1C=CC=NC=1CNCC1=CC=CC=N1 KXZQYLBVMZGIKC-UHFFFAOYSA-N 0.000 abstract 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 239000011575 calcium Substances 0.000 abstract 1
- BFGKITSFLPAWGI-UHFFFAOYSA-N chromium(3+) Chemical compound [Cr+3] BFGKITSFLPAWGI-UHFFFAOYSA-N 0.000 abstract 1
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 abstract 1
- 238000007796 conventional method Methods 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 238000005868 electrolysis reaction Methods 0.000 abstract 1
- 238000005363 electrowinning Methods 0.000 abstract 1
- 229910001710 laterite Inorganic materials 0.000 abstract 1
- 239000011504 laterite Substances 0.000 abstract 1
- 238000002386 leaching Methods 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0084—Treating solutions
- C22B15/0089—Treating solutions by chemical methods
- C22B15/0093—Treating solutions by chemical methods by gases, e.g. hydrogen or hydrogen sulfide
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0407—Leaching processes
- C22B23/0415—Leaching processes with acids or salt solutions except ammonium salts solutions
- C22B23/043—Sulfurated acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0476—Separation of nickel from cobalt
- C22B23/0484—Separation of nickel from cobalt in acidic type solutions
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/06—Refining
- C22B23/065—Refining carbonyl methods
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/384—Pentavalent phosphorus oxyacids, esters thereof
- C22B3/3842—Phosphinic acid, e.g. H2P(O)(OH)
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Electrolytic Production Of Metals (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US265279 | 1999-03-09 | ||
| US09/265,279 US20010001650A1 (en) | 1999-03-09 | 1999-03-09 | Recovery of nickel and cobalt from ore |
| PCT/US2000/005913 WO2000053820A1 (en) | 1999-03-09 | 2000-03-08 | Recovery of nickel and cobalt from ore |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60003530D1 true DE60003530D1 (de) | 2003-07-31 |
| DE60003530T2 DE60003530T2 (de) | 2004-05-06 |
Family
ID=23009806
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60003530T Expired - Lifetime DE60003530T2 (de) | 1999-03-09 | 2000-03-08 | Gewinnung von nickel und kobalt aus erzmaterialien |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20010001650A1 (de) |
| EP (1) | EP1159461B1 (de) |
| AT (1) | ATE243773T1 (de) |
| AU (1) | AU757360B2 (de) |
| DE (1) | DE60003530T2 (de) |
| ES (1) | ES2202079T3 (de) |
| GT (1) | GT200000028A (de) |
| WO (1) | WO2000053820A1 (de) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20210277497A1 (en) * | 2020-03-06 | 2021-09-09 | Scandium International Mining Corporation | Recovery of critical metals from sx-ew copper raffinate and other solutions derived from leaching ores with sulfuric acid |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AUPQ812700A0 (en) * | 2000-06-13 | 2000-07-06 | Wmc Resources Limited | Solvent extraction of impurities from concentrated metal sulphate solutions |
| US20040219082A1 (en) * | 2000-08-29 | 2004-11-04 | Matjie Ratale Henry | Selective recovery of aluminium, cobalt and platinum values from a spent catalyst composition |
| AU2001281597B2 (en) * | 2001-08-24 | 2007-06-21 | Qni Technology Pty Ltd | Organic reagent cleaning |
| US7214256B2 (en) * | 2002-09-03 | 2007-05-08 | Cognis Corporation | Solvent extraction process |
| US20050209328A1 (en) * | 2004-03-19 | 2005-09-22 | Allgood Charles C | Alphahydroxyacids with ultra-low metal concentration |
| EA012644B1 (ru) * | 2004-09-17 | 2009-12-30 | БиЭйчПи БИЛЛИТОН ЭсЭсЭм ТЕКНОЛОДЖИ ПТИ ЛТД. | Получение ферроникелевого или никелевого штейна совмещённым гидрометаллургическим и пирометаллургическим способом |
| EP1841891A4 (de) * | 2004-12-30 | 2008-06-25 | Bhp Billiton Ssm Tech Pty Ltd | Extraktion von nickel und cobalt aus einem harzeluatstrom |
| BRPI0600901B1 (pt) * | 2006-02-02 | 2018-04-03 | Vale S.A. | Processo híbrido de resinas de troca iônica na recuperação seletiva de níquel e cobalto de efluentes de lixiviação |
| US7935171B2 (en) | 2006-08-23 | 2011-05-03 | Bhp Billiton Ssm Development Pty Ltd. | Production of metallic nickel with low iron content |
| WO2008034189A1 (en) * | 2006-09-21 | 2008-03-27 | Metallica Minerals Ltd | Improved process and plant for producing nickel |
| BRPI0604853B1 (pt) * | 2006-10-27 | 2016-03-08 | Vale Do Rio Doce Co | método para produção de cobalto metálico a partir de refinado de extração por solventes de níquel |
| BRPI0612374B1 (pt) * | 2006-11-10 | 2015-08-11 | Vale Sa | Processo de recuperação de níquel e cobalto a partir de minérios lateríticos empregando resina de troca iônica e produto contendo níquel ou cobalto |
| BRPI0605892B1 (pt) * | 2006-12-29 | 2015-09-01 | Vale Sa | Processo de recuperação de níquel e cobalto a partir de um eluato de resina de troca iônica |
| BRPI0701068B1 (pt) * | 2007-04-12 | 2018-02-27 | Vale S.A. | Processo de recuperação de níquel e cobalto a partir de um eluato empregando extração por solventes |
| AU2008251010B2 (en) * | 2007-05-14 | 2012-07-12 | Cerro Matoso Sa | Nickel recovery from a high ferrous content laterite ore |
| CN101328537B (zh) * | 2007-06-18 | 2010-04-21 | 中国恩菲工程技术有限公司 | 从高镁镍精矿中综合回收镍、铜、钴、硫和镁的工艺 |
| WO2010037169A1 (en) * | 2008-10-01 | 2010-04-08 | The University Of Queensland | Process for extraction of mined material |
| JP5245768B2 (ja) * | 2008-11-28 | 2013-07-24 | 住友金属鉱山株式会社 | ニッケル及びコバルトを含む硫化物の製造方法 |
| TWI401213B (zh) * | 2010-02-02 | 2013-07-11 | 廢加氫脫硫觸媒中鎳鈷精礦資源化回收方法 | |
| JP2011214132A (ja) * | 2010-03-17 | 2011-10-27 | Jx Nippon Mining & Metals Corp | コバルトを回収する方法 |
| CA2740249C (en) | 2010-05-25 | 2015-08-04 | Dow Global Technologies Llc | A process for separating copper and nickel from cobalt containing solutions |
| US8986424B2 (en) | 2010-12-20 | 2015-03-24 | Asarco Llc | Rhenium recovery |
| ZA201207465B (en) * | 2011-10-09 | 2013-05-29 | Mintek | Direct electrowinning of cobalt |
| US9068247B2 (en) | 2012-05-01 | 2015-06-30 | Dow Global Technologies Llc | Nickel and cobalt recovery using continuous ion exchange |
| CN102703696B (zh) * | 2012-06-15 | 2013-09-11 | 芦秀琴 | 一种从红土镍矿中综合回收有价金属的方法 |
| JP6263171B2 (ja) * | 2012-06-22 | 2018-01-17 | ビーエイチピー ビリトン エスエスエム ディベロップメント プロプライエタリー リミテッド | 大気圧下での赤鉄鉱としての第二鉄の除去 |
| WO2014025568A1 (en) * | 2012-08-06 | 2014-02-13 | Dow Global Technologies Llc | Recovery of nickel using integrated continuous ion exchange and electo-winning process |
| AU2014231718B2 (en) | 2013-03-14 | 2015-06-25 | Orway Mineral Consultants (Wa) Pty Ltd | Hydrometallurgical method for the removal of radionuclides from radioactive copper concentrates |
| CN104745813B (zh) * | 2013-12-31 | 2017-02-15 | 北京有色金属研究总院 | 高镁低镍硫化矿生物浸出过程中综合回收镍镁的方法 |
| CN106399687B (zh) * | 2016-08-31 | 2018-07-06 | 中南大学 | 一种用离子交换树脂从钴电解液中深度除铜的方法 |
| CN106544528B (zh) * | 2016-10-27 | 2018-07-03 | 环境保护部华南环境科学研究所 | 一种从酸洗废水中回收金属镍的方法 |
| CN110980876A (zh) * | 2019-11-21 | 2020-04-10 | 武汉百富环保工程有限公司 | 一种从钝化液中回收铜并回用铬的处理工艺 |
| CN112575189B (zh) * | 2020-11-20 | 2023-01-24 | 金川集团股份有限公司 | 一种高铬高镁铂族金属选矿精矿强化浸出液的处理方法 |
| CN115161495B (zh) * | 2022-08-18 | 2023-08-18 | 上海锦源晟新能源材料有限公司 | 一种从高杂质硫酸钴溶液中分离富集钴的方法 |
| CN116947269B (zh) * | 2023-09-20 | 2023-12-05 | 成都铬科高化工技术有限责任公司 | 一种含铬硫酸氢钠废水回收铬及钠盐的方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2208983B2 (de) * | 1972-12-01 | 1978-06-02 | Nickel Le | |
| CA1119416A (en) * | 1979-08-14 | 1982-03-09 | Juraj Babjak | Process for nickel removal from concentrated aqueous cobaltous sulfate solutions |
| US4382016A (en) * | 1981-05-14 | 1983-05-03 | American Cyanamid Company | Extractant for the selective removal of cobalt(II) from aqueous solutions |
| US5378262A (en) * | 1994-03-22 | 1995-01-03 | Inco Limited | Process for the extraction and separation of nickel and/or cobalt |
| BR9510115A (pt) * | 1994-12-27 | 1997-12-30 | Bhp Minerals Int Inc | Recuperação de níquel e cobalto a partir de minériosde laterita |
| US5626648A (en) * | 1995-07-17 | 1997-05-06 | Bhp Minerals International Inc. | Recovery of nickel from bioleach solution |
-
1999
- 1999-03-09 US US09/265,279 patent/US20010001650A1/en not_active Abandoned
-
2000
- 2000-03-08 AT AT00913778T patent/ATE243773T1/de not_active IP Right Cessation
- 2000-03-08 EP EP00913778A patent/EP1159461B1/de not_active Expired - Lifetime
- 2000-03-08 AU AU35154/00A patent/AU757360B2/en not_active Ceased
- 2000-03-08 DE DE60003530T patent/DE60003530T2/de not_active Expired - Lifetime
- 2000-03-08 WO PCT/US2000/005913 patent/WO2000053820A1/en active IP Right Grant
- 2000-03-08 ES ES00913778T patent/ES2202079T3/es not_active Expired - Lifetime
- 2000-03-09 GT GT200000028A patent/GT200000028A/es unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20210277497A1 (en) * | 2020-03-06 | 2021-09-09 | Scandium International Mining Corporation | Recovery of critical metals from sx-ew copper raffinate and other solutions derived from leaching ores with sulfuric acid |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1159461A1 (de) | 2001-12-05 |
| DE60003530T2 (de) | 2004-05-06 |
| WO2000053820A1 (en) | 2000-09-14 |
| US20010001650A1 (en) | 2001-05-24 |
| ATE243773T1 (de) | 2003-07-15 |
| AU757360B2 (en) | 2003-02-20 |
| AU3515400A (en) | 2000-09-28 |
| GT200000028A (es) | 2001-08-31 |
| ES2202079T3 (es) | 2004-04-01 |
| EP1159461B1 (de) | 2003-06-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition |