DE577432C - Process for the production of colored disinfectant solutions from fluorine and silica fluorine compounds - Google Patents

Process for the production of colored disinfectant solutions from fluorine and silica fluorine compounds

Info

Publication number
DE577432C
DE577432C DEH109756D DEH0109756D DE577432C DE 577432 C DE577432 C DE 577432C DE H109756 D DEH109756 D DE H109756D DE H0109756 D DEH0109756 D DE H0109756D DE 577432 C DE577432 C DE 577432C
Authority
DE
Germany
Prior art keywords
fluorine
production
silica
disinfectant solutions
compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEH109756D
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHEM FAB GmbH
BRANDER FARBWERKE
Original Assignee
CHEM FAB GmbH
BRANDER FARBWERKE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHEM FAB GmbH, BRANDER FARBWERKE filed Critical CHEM FAB GmbH
Priority to DEH109756D priority Critical patent/DE577432C/en
Application granted granted Critical
Publication of DE577432C publication Critical patent/DE577432C/en
Expired legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/10Fluorides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)

Description

Verfahren zur Herstellung von gefärbten Desinfektionslösungen aus Fluor- und Kieselfluorverbindungen Die Durchführung von Desinfektionsarbeiten, insbesondere in der Gärungsindustrie, Nahrungsmittelfabrikation, Molkerei usw., litt bisher an dem Mangel, daß infolge der Farblosigkeit der Desinfektionsflüssigkeiten die Kontrolle der Arbeit schwierig und umständlich war, da sich nicht sofort durch den Augenschein feststellen ließ, ob die zu desinfizierenden Gefäße, wie Bottiche, Eimer, Lagergefäße, Rohrleitungen, mit den Desinfektionslösungen oder mit Wasser gefüllt waren.Process for the production of colored disinfectant solutions Fluorine and silica fluorine compounds The implementation of disinfection work, in particular in the fermentation industry, food processing, dairy, etc., so far suffered the lack of control due to the colorlessness of the disinfectant liquids The work was difficult and cumbersome as it wasn't immediately apparent determined whether the vessels to be disinfected, such as vats, buckets, storage vessels, Pipelines that were filled with disinfectant solutions or with water.

Im Gegensatz zu der Möglichkeit, aus neutralen Salzen bestehende Desinfektionsmittel und ihre Lösungen mit gebräuchlichen Farbstoffen zu färben, wie dies beispielsweise beim Sublimat mittels Eosin geschieht, scheitern bei stark sauren Verbindungen, wie den. Fluor- und Kieselfluorverbinduagen, bisher alle Versuche, aus diesen Verbindungen bestehende Desinfektionslösungen zu färben, entweder an der geringen Widerstandsfähigkeit der Farbstoffe, besonders bei längerer Einwirkungszeit, oder daran, daß die bei dem konzentrierten Präparat erzielte Färbung bei starker Verdünnung der Lösung verschwand. Es hat sich nun gezeigt, daß ein verhältnismäßig geringer Zusatz von Chromsäureanhydrid zu stark sauren konzentrierten Lösungen von Fluor- oder Fluorsiliciumpräparaten genügt, um auch .Lösungen der stärksten in der Praxis verwendeten Verdünnungen noch deutlich gelb zu färben. Ausführungsbeispiel Zu ioo Teilen Kieselfluorwasserstoffsäure vom spez. Gewicht 1,3 werden 2o Teile einer 5o°iaigen wäßrigen Lösung von Chromsäureanhydrid hinzugefügt. Eine aus i Teil dieser Mischung und 99 Teilen Wasser hergestellte Desinfektionslösung ist von deutlich gelber dauerhafter Färbung.In contrast to the possibility of disinfectants consisting of neutral salts and to color their solutions with common dyes, such as this for example happens with the sublimate by means of eosin, fail with strongly acidic compounds, like that. Fluorine and silica fluorine compounds, so far all attempts, from these compounds to color existing disinfectant solutions, either because of their low resistance of the dyes, especially with prolonged exposure time, or the fact that the with The color obtained with the concentrated preparation disappeared when the solution was greatly diluted. It has now been shown that a relatively small addition of chromic anhydride to strongly acidic concentrated solutions of fluorine or fluorosilicon preparations is sufficient to also .Solutions of the strongest dilutions still used in practice to be colored clearly yellow. Exemplary embodiment: To 100 parts of hydrofluoric acid from spec. Weight 1.3 is 2o parts of a 50 ° iaigen aqueous solution of chromic anhydride added. A disinfectant solution made from 1 part of this mixture and 99 parts of water is of a clearly yellow permanent color.

Claims (1)

PATE NTANSPRUCFI: Verfahren zur Herstellung von gefärbten; stark sauren, konzentrierten und auch in starker Verdünnung noch deutlich gefärbt bleibenden Desinfektionslösungen aus Fluor- und Kieselfluorverbindungen, gekennzeichnet durch einen. Zusatz von Chromsäureanhydrid.PATE NTANSPRUCFI: process for the production of colored; strongly acidic, concentrated disinfectant solutions that remain clearly colored even when strongly diluted made of fluorine and silica fluorine compounds, characterized by a. Addition of chromic anhydride.
DEH109756D 1927-01-21 1927-01-21 Process for the production of colored disinfectant solutions from fluorine and silica fluorine compounds Expired DE577432C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEH109756D DE577432C (en) 1927-01-21 1927-01-21 Process for the production of colored disinfectant solutions from fluorine and silica fluorine compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEH109756D DE577432C (en) 1927-01-21 1927-01-21 Process for the production of colored disinfectant solutions from fluorine and silica fluorine compounds

Publications (1)

Publication Number Publication Date
DE577432C true DE577432C (en) 1933-05-31

Family

ID=7170894

Family Applications (1)

Application Number Title Priority Date Filing Date
DEH109756D Expired DE577432C (en) 1927-01-21 1927-01-21 Process for the production of colored disinfectant solutions from fluorine and silica fluorine compounds

Country Status (1)

Country Link
DE (1) DE577432C (en)

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