DE3939998A1 - Verfahren zur optischen unterscheidung eines dentalwerkstoffes sowie dentalwerkstoff dafuer - Google Patents
Verfahren zur optischen unterscheidung eines dentalwerkstoffes sowie dentalwerkstoff dafuerInfo
- Publication number
- DE3939998A1 DE3939998A1 DE3939998A DE3939998A DE3939998A1 DE 3939998 A1 DE3939998 A1 DE 3939998A1 DE 3939998 A DE3939998 A DE 3939998A DE 3939998 A DE3939998 A DE 3939998A DE 3939998 A1 DE3939998 A1 DE 3939998A1
- Authority
- DE
- Germany
- Prior art keywords
- derivatives
- dione
- pyrano
- dimethylamino
- methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005548 dental material Substances 0.000 title claims abstract description 44
- 238000000034 method Methods 0.000 title claims abstract description 21
- 230000003287 optical effect Effects 0.000 title abstract description 5
- 239000000758 substrate Substances 0.000 claims abstract description 9
- 238000010521 absorption reaction Methods 0.000 claims abstract description 4
- 239000000126 substance Substances 0.000 claims description 20
- -1 triazol-2-yl Chemical group 0.000 claims description 10
- KYRJCQVWCHDCSP-UHFFFAOYSA-N 3h-chromene-2,5-dione Chemical compound O=C1C=CC=C2OC(=O)CC=C21 KYRJCQVWCHDCSP-UHFFFAOYSA-N 0.000 claims description 9
- KDTAEYOYAZPLIC-UHFFFAOYSA-N coumarin 152 Chemical compound FC(F)(F)C1=CC(=O)OC2=CC(N(C)C)=CC=C21 KDTAEYOYAZPLIC-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 6
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 claims description 6
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 claims description 5
- 150000001251 acridines Chemical class 0.000 claims description 4
- 229940054058 antipsychotic thioxanthene derivative Drugs 0.000 claims description 4
- 229940027998 antiseptic and disinfectant acridine derivative Drugs 0.000 claims description 4
- 125000003914 fluoranthenyl group Chemical class C1(=CC=C2C=CC=C3C4=CC=CC=C4C1=C23)* 0.000 claims description 4
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical class C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 claims description 4
- 150000005075 thioxanthenes Chemical class 0.000 claims description 4
- 125000001834 xanthenyl group Chemical class C1=CC=CC=2OC3=CC=CC=C3C(C12)* 0.000 claims description 4
- 150000004775 coumarins Chemical class 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- PDKPRWFMRVBCOB-JLHYYAGUSA-N (e)-3-[4-(dimethylamino)phenyl]-1-phenylprop-2-en-1-one Chemical compound C1=CC(N(C)C)=CC=C1\C=C\C(=O)C1=CC=CC=C1 PDKPRWFMRVBCOB-JLHYYAGUSA-N 0.000 claims description 2
- TVZQDMRKJSXJPZ-UHFFFAOYSA-N 1,2-dihydronaphthalen-1-ol Chemical compound C1=CC=C2C(O)CC=CC2=C1 TVZQDMRKJSXJPZ-UHFFFAOYSA-N 0.000 claims description 2
- CUTZOCZXONXMAL-UHFFFAOYSA-N 1,6-dihydroquinoline-2,5-dione Chemical compound N1C(=O)C=CC2=C1C=CCC2=O CUTZOCZXONXMAL-UHFFFAOYSA-N 0.000 claims description 2
- SYRBOMODLUADBZ-RNIAWFEPSA-N 1-[(E)-[(E)-(2-hydroxynaphthalen-1-yl)methylidenehydrazinylidene]methyl]naphthalen-2-ol Chemical compound N(\N=C\C1=C(C=CC2=CC=CC=C12)O)=C/C1=C(C=CC2=CC=CC=C12)O SYRBOMODLUADBZ-RNIAWFEPSA-N 0.000 claims description 2
- VCLFGTPLJKNITL-UHFFFAOYSA-N 18-methyl-15-oxapentacyclo[10.6.1.02,7.08,19.013,17]nonadeca-1(18),2,4,6,8,10,12(19),13(17)-octaene-14,16-dione Chemical compound C12=CC=CC=C2C2=CC=CC3=C2C1=C(C)C1=C3C(=O)OC1=O VCLFGTPLJKNITL-UHFFFAOYSA-N 0.000 claims description 2
- SQPGRXNYOOVBIY-UHFFFAOYSA-N 1h-pyrano[2,3-h]quinoline-2,5-dione Chemical class C12=CC=COC2=CC(=O)C2=C1NC(=O)C=C2 SQPGRXNYOOVBIY-UHFFFAOYSA-N 0.000 claims description 2
- RUBPVOQOOZQXET-UHFFFAOYSA-N 2-[[4-(dimethylamino)phenyl]iminomethyl]phenol Chemical compound C1=CC(N(C)C)=CC=C1N=CC1=CC=CC=C1O RUBPVOQOOZQXET-UHFFFAOYSA-N 0.000 claims description 2
- YZACNHJLNWJNRH-UHFFFAOYSA-N 3-ethyl-n,n-dimethyl-1-phenylpyrazolo[4,3-b]quinoxalin-7-amine Chemical compound C12=NC3=CC(N(C)C)=CC=C3N=C2C(CC)=NN1C1=CC=CC=C1 YZACNHJLNWJNRH-UHFFFAOYSA-N 0.000 claims description 2
- BGQDCDRDPCVLJE-UHFFFAOYSA-N 3-methoxybenzo[b]phenalen-7-one Chemical compound C12=CC=CC=C2C(=O)C2=CC=CC3=C2C1=CC=C3OC BGQDCDRDPCVLJE-UHFFFAOYSA-N 0.000 claims description 2
- KSEJNTBYAJRFMU-UHFFFAOYSA-N 5-(dimethylamino)-2-methylisoindole-1,3-dione Chemical compound CN(C)C1=CC=C2C(=O)N(C)C(=O)C2=C1 KSEJNTBYAJRFMU-UHFFFAOYSA-N 0.000 claims description 2
- KZFUMWVJJNDGAU-UHFFFAOYSA-N 7-(diethylamino)-3-(1-methylbenzimidazol-2-yl)chromen-2-one Chemical compound C1=CC=C2N(C)C(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 KZFUMWVJJNDGAU-UHFFFAOYSA-N 0.000 claims description 2
- NRZJOTSUPLCYDJ-UHFFFAOYSA-N 7-(ethylamino)-6-methyl-4-(trifluoromethyl)chromen-2-one Chemical compound O1C(=O)C=C(C(F)(F)F)C2=C1C=C(NCC)C(C)=C2 NRZJOTSUPLCYDJ-UHFFFAOYSA-N 0.000 claims description 2
- JBNOVHJXQSHGRL-UHFFFAOYSA-N 7-amino-4-(trifluoromethyl)coumarin Chemical compound FC(F)(F)C1=CC(=O)OC2=CC(N)=CC=C21 JBNOVHJXQSHGRL-UHFFFAOYSA-N 0.000 claims description 2
- SYUWDSSYDVWBGD-UHFFFAOYSA-N 7-ethoxyacridine-3,9-diamine;hydrochloride Chemical compound Cl.C1=C(N)C=CC2=C(N)C3=CC(OCC)=CC=C3N=C21 SYUWDSSYDVWBGD-UHFFFAOYSA-N 0.000 claims description 2
- JLCDGIZDXAVSJD-UHFFFAOYSA-N C1C2=CC=CC=C2SC2=C1C1=CC=C(C(O)=NCCCCCCCCCCCCCCCCCC)C(C(O)=O)=C1C=C2 Chemical compound C1C2=CC=CC=C2SC2=C1C1=CC=C(C(O)=NCCCCCCCCCCCCCCCCCC)C(C(O)=O)=C1C=C2 JLCDGIZDXAVSJD-UHFFFAOYSA-N 0.000 claims description 2
- BGLGAKMTYHWWKW-UHFFFAOYSA-N acridine yellow Chemical compound [H+].[Cl-].CC1=C(N)C=C2N=C(C=C(C(C)=C3)N)C3=CC2=C1 BGLGAKMTYHWWKW-UHFFFAOYSA-N 0.000 claims description 2
- 125000004190 benzothiazol-2-yl group Chemical group [H]C1=C([H])C([H])=C2N=C(*)SC2=C1[H] 0.000 claims description 2
- CYDMQBQPVICBEU-UHFFFAOYSA-N chlorotetracycline Natural products C1=CC(Cl)=C2C(O)(C)C3CC4C(N(C)C)C(O)=C(C(N)=O)C(=O)C4(O)C(O)=C3C(=O)C2=C1O CYDMQBQPVICBEU-UHFFFAOYSA-N 0.000 claims description 2
- CYDMQBQPVICBEU-XRNKAMNCSA-N chlortetracycline Chemical compound C1=CC(Cl)=C2[C@](O)(C)[C@H]3C[C@H]4[C@H](N(C)C)C(O)=C(C(N)=O)C(=O)[C@@]4(O)C(O)=C3C(=O)C2=C1O CYDMQBQPVICBEU-XRNKAMNCSA-N 0.000 claims description 2
- VBVAVBCYMYWNOU-UHFFFAOYSA-N coumarin 6 Chemical compound C1=CC=C2SC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 VBVAVBCYMYWNOU-UHFFFAOYSA-N 0.000 claims description 2
- DPVLADDAOKZJFL-UHFFFAOYSA-N ctk0h7318 Chemical compound C12=CC=CC=C2C2=CC=CC3=C2C1=CC1=C3C(=O)OC1=O DPVLADDAOKZJFL-UHFFFAOYSA-N 0.000 claims description 2
- VAANEDBEKZZBRU-UHFFFAOYSA-N ethyl 2h-chromene-3-carboxylate Chemical compound C1=CC=C2OCC(C(=O)OCC)=CC2=C1 VAANEDBEKZZBRU-UHFFFAOYSA-N 0.000 claims description 2
- WYVHNCGXVPMYQK-UHFFFAOYSA-N fluorol yellow 088 Chemical compound C1=CC=C2C(C=3C(=CC=C(C=3)C)O3)=C4C3=CC=C(C)C4=CC2=C1 WYVHNCGXVPMYQK-UHFFFAOYSA-N 0.000 claims description 2
- YFMJTLUPSMCTOQ-UHFFFAOYSA-N isoquinoline-5-sulfonic acid Chemical compound N1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 YFMJTLUPSMCTOQ-UHFFFAOYSA-N 0.000 claims description 2
- BXYGQGOZARVRBW-UHFFFAOYSA-N n,n,3-trimethyl-1-phenylpyrazolo[4,3-b]quinoxalin-7-amine Chemical compound C12=NC3=CC(N(C)C)=CC=C3N=C2C(C)=NN1C1=CC=CC=C1 BXYGQGOZARVRBW-UHFFFAOYSA-N 0.000 claims description 2
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 claims description 2
- 159000000000 sodium salts Chemical class 0.000 claims description 2
- DPNRMEJBKMQHMC-UHFFFAOYSA-N tert-butyl 2-[6-(cyanomethyl)-2,2-dimethyl-1,3-dioxan-4-yl]acetate Chemical compound CC(C)(C)OC(=O)CC1CC(CC#N)OC(C)(C)O1 DPNRMEJBKMQHMC-UHFFFAOYSA-N 0.000 claims description 2
- VAQYGOTYKYMSRX-UHFFFAOYSA-N 1h-pyrazole;quinoxaline Chemical class C=1C=NNC=1.N1=CC=NC2=CC=CC=C21 VAQYGOTYKYMSRX-UHFFFAOYSA-N 0.000 claims 1
- GSSXLFACIJSBOM-UHFFFAOYSA-N 2h-pyran-2-ol Chemical compound OC1OC=CC=C1 GSSXLFACIJSBOM-UHFFFAOYSA-N 0.000 claims 1
- PYLQDRIFPVHRDN-UHFFFAOYSA-N 3,6-dihydro-2h-pyran-6-ol Chemical compound OC1OCCC=C1 PYLQDRIFPVHRDN-UHFFFAOYSA-N 0.000 claims 1
- GOLORTLGFDVFDW-UHFFFAOYSA-N 3-(1h-benzimidazol-2-yl)-7-(diethylamino)chromen-2-one Chemical compound C1=CC=C2NC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 GOLORTLGFDVFDW-UHFFFAOYSA-N 0.000 claims 1
- AZRRZGIBBLWSSQ-UHFFFAOYSA-N 4-ethyl-7-phenyl-3,5-diazabicyclo[2.2.2]octane-2,6-dione Chemical class N1C(=O)C2C(=O)NC1(CC)CC2C1=CC=CC=C1 AZRRZGIBBLWSSQ-UHFFFAOYSA-N 0.000 claims 1
- CFNMUZCFSDMZPQ-GHXNOFRVSA-N 7-[(z)-3-methyl-4-(4-methyl-5-oxo-2h-furan-2-yl)but-2-enoxy]chromen-2-one Chemical group C=1C=C2C=CC(=O)OC2=CC=1OC/C=C(/C)CC1OC(=O)C(C)=C1 CFNMUZCFSDMZPQ-GHXNOFRVSA-N 0.000 claims 1
- YLNJGHNUXCVDIX-UHFFFAOYSA-N bis(2-methylpropyl) perylene-3,9-dicarboxylate Chemical compound C=12C3=CC=CC2=C(C(=O)OCC(C)C)C=CC=1C1=CC=CC2=C1C3=CC=C2C(=O)OCC(C)C YLNJGHNUXCVDIX-UHFFFAOYSA-N 0.000 claims 1
- NZBSAAMEZYOGBA-UHFFFAOYSA-N luminogren Chemical compound C12=NC3=CC=CC=C3N2C(=O)C2=CC=CC3=CC=CC1=C23 NZBSAAMEZYOGBA-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 17
- 239000002966 varnish Substances 0.000 description 11
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 8
- 239000002131 composite material Substances 0.000 description 8
- 239000004922 lacquer Substances 0.000 description 8
- 238000006116 polymerization reaction Methods 0.000 description 8
- 230000001681 protective effect Effects 0.000 description 7
- 239000000178 monomer Substances 0.000 description 6
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 description 5
- 229910002020 Aerosil® OX 50 Inorganic materials 0.000 description 5
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 235000019400 benzoyl peroxide Nutrition 0.000 description 5
- 210000004268 dentin Anatomy 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 125000006850 spacer group Chemical group 0.000 description 5
- 229920005372 Plexiglas® Polymers 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 150000002601 lanthanoid compounds Chemical class 0.000 description 4
- 239000011325 microbead Substances 0.000 description 4
- 239000004926 polymethyl methacrylate Substances 0.000 description 4
- VNQXSTWCDUXYEZ-UHFFFAOYSA-N 1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione Chemical compound C1CC2(C)C(=O)C(=O)C1C2(C)C VNQXSTWCDUXYEZ-UHFFFAOYSA-N 0.000 description 3
- YIGGZEJDZIJLBX-UHFFFAOYSA-N 2,2-dihydroxyethyl 2-methylprop-2-enoate;1,6-diisocyanato-5,6-dimethylheptane Chemical compound CC(=C)C(=O)OCC(O)O.O=C=NC(C)(C)C(C)CCCCN=C=O YIGGZEJDZIJLBX-UHFFFAOYSA-N 0.000 description 3
- 125000004174 2-benzimidazolyl group Chemical group [H]N1C(*)=NC2=C([H])C([H])=C([H])C([H])=C12 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000000903 blocking effect Effects 0.000 description 3
- 229930006711 bornane-2,3-dione Natural products 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- UWNADWZGEHDQAB-UHFFFAOYSA-N i-Pr2C2H4i-Pr2 Natural products CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229920004482 WACKER® Polymers 0.000 description 2
- 230000004069 differentiation Effects 0.000 description 2
- 230000005284 excitation Effects 0.000 description 2
- 230000003760 hair shine Effects 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 230000004936 stimulating effect Effects 0.000 description 2
- KQMPMWGWJLNKPC-UHFFFAOYSA-N 1-(2-methylprop-2-enoyloxy)dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCC(OC(=O)C(C)=C)OC(=O)C(C)=C KQMPMWGWJLNKPC-UHFFFAOYSA-N 0.000 description 1
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 1
- JUVSRZCUMWZBFK-UHFFFAOYSA-N 2-[n-(2-hydroxyethyl)-4-methylanilino]ethanol Chemical compound CC1=CC=C(N(CCO)CCO)C=C1 JUVSRZCUMWZBFK-UHFFFAOYSA-N 0.000 description 1
- KWEFAMLBMBNJSH-UHFFFAOYSA-N 2H-pyrano[2,3-c]isoquinoline-3,6-dione Chemical compound C=1CC(OC2=NC(C=3C=CC=CC=3C2=1)=O)=O KWEFAMLBMBNJSH-UHFFFAOYSA-N 0.000 description 1
- VSTRESXSGAUGKC-UHFFFAOYSA-N 4H-benzimidazole Chemical compound C1C=CC=C2N=CN=C12 VSTRESXSGAUGKC-UHFFFAOYSA-N 0.000 description 1
- KMEBUNSLFRQSEM-UHFFFAOYSA-N 5-amino-2-methylisoindole-1,3-dione Chemical compound C1=C(N)C=C2C(=O)N(C)C(=O)C2=C1 KMEBUNSLFRQSEM-UHFFFAOYSA-N 0.000 description 1
- WWSDJQDFBSYQIS-UHFFFAOYSA-N 6,8,19-triazapentacyclo[11.8.0.02,10.05,9.016,21]henicosa-1(13),2(10),3,5(9),7,11,14,16(21),17,19-decaene Chemical compound C1=CC2=CC=C3C=CN=CC3=C2C2=C1C(N=CN1)=C1C=C2 WWSDJQDFBSYQIS-UHFFFAOYSA-N 0.000 description 1
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 1
- AKSWAPUOVZSDLL-UHFFFAOYSA-N CC1=CC=C(C(O1)O)C=1SC2=C(N1)C=CC=C2 Chemical compound CC1=CC=C(C(O1)O)C=1SC2=C(N1)C=CC=C2 AKSWAPUOVZSDLL-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- AMFGWXWBFGVCKG-UHFFFAOYSA-N Panavia opaque Chemical compound C1=CC(OCC(O)COC(=O)C(=C)C)=CC=C1C(C)(C)C1=CC=C(OCC(O)COC(=O)C(C)=C)C=C1 AMFGWXWBFGVCKG-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- NRCNNTRSSNMMJV-UHFFFAOYSA-N benzo[de]isoquinolin-6-one Chemical compound C1=CC(C(=O)C=C2)=C3C2=CN=CC3=C1 NRCNNTRSSNMMJV-UHFFFAOYSA-N 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000002144 chemical decomposition reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- VSSSHNJONFTXHS-UHFFFAOYSA-N coumarin 153 Chemical compound C12=C3CCCN2CCCC1=CC1=C3OC(=O)C=C1C(F)(F)F VSSSHNJONFTXHS-UHFFFAOYSA-N 0.000 description 1
- 239000003479 dental cement Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003955 fissure sealant Substances 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 239000001034 iron oxide pigment Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/60—Preparations for dentistry comprising organic or organo-metallic additives
- A61K6/65—Dyes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/25—Compositions for detecting or measuring, e.g. of irregularities on natural or artificial teeth
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Health & Medical Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Biophysics (AREA)
- Plastic & Reconstructive Surgery (AREA)
- Dental Preparations (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Dental Tools And Instruments Or Auxiliary Dental Instruments (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3939998A DE3939998A1 (de) | 1989-12-02 | 1989-12-02 | Verfahren zur optischen unterscheidung eines dentalwerkstoffes sowie dentalwerkstoff dafuer |
| AT90122703T ATE112483T1 (de) | 1989-12-02 | 1990-11-28 | Verfahren zur optischen unterscheidung eines dentalwerkstoffes sowie dentalwerkstoff dafür. |
| EP90122703A EP0431452B1 (de) | 1989-12-02 | 1990-11-28 | Verfahren zur optischen Unterscheidung eines Dentalwerkstoffes sowie Dentalwerkstoff dafür |
| DE59007387T DE59007387D1 (de) | 1989-12-02 | 1990-11-28 | Verfahren zur optischen Unterscheidung eines Dentalwerkstoffes sowie Dentalwerkstoff dafür. |
| CA002031268A CA2031268C (en) | 1989-12-02 | 1990-11-30 | Process for the optical distinction of a dental material and dental material for said process |
| US07/620,470 US5102461A (en) | 1989-12-02 | 1990-11-30 | Process for the optical distinction of a dental material and dental material for said process |
| AU67670/90A AU629432B2 (en) | 1989-12-02 | 1990-11-30 | Process for the optical distinction of a dental material and dental material for said process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3939998A DE3939998A1 (de) | 1989-12-02 | 1989-12-02 | Verfahren zur optischen unterscheidung eines dentalwerkstoffes sowie dentalwerkstoff dafuer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3939998A1 true DE3939998A1 (de) | 1991-06-06 |
| DE3939998C2 DE3939998C2 (enExample) | 1993-02-11 |
Family
ID=6394740
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE3939998A Granted DE3939998A1 (de) | 1989-12-02 | 1989-12-02 | Verfahren zur optischen unterscheidung eines dentalwerkstoffes sowie dentalwerkstoff dafuer |
| DE59007387T Expired - Fee Related DE59007387D1 (de) | 1989-12-02 | 1990-11-28 | Verfahren zur optischen Unterscheidung eines Dentalwerkstoffes sowie Dentalwerkstoff dafür. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE59007387T Expired - Fee Related DE59007387D1 (de) | 1989-12-02 | 1990-11-28 | Verfahren zur optischen Unterscheidung eines Dentalwerkstoffes sowie Dentalwerkstoff dafür. |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5102461A (enExample) |
| EP (1) | EP0431452B1 (enExample) |
| AT (1) | ATE112483T1 (enExample) |
| AU (1) | AU629432B2 (enExample) |
| CA (1) | CA2031268C (enExample) |
| DE (2) | DE3939998A1 (enExample) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5698020A (en) * | 1995-05-26 | 1997-12-16 | Ivoclar Ag | Photochromic dental material |
| EP1230906A1 (de) * | 2001-02-12 | 2002-08-14 | Ivoclar Vivadent AG | Thermochromer Dentalwerkstoff |
| US6548521B1 (en) | 1992-09-11 | 2003-04-15 | The Regents Of The University Of California | Inhibitors of metazoan parasite proteases |
| DE10146883B4 (de) * | 2001-09-24 | 2006-05-24 | Dentona Ag | Mineralischer Rohstoff zur Herstellung dentaler Gipsmodelle mit fluoreszierender Oberfläche |
| US7147471B2 (en) | 2000-12-08 | 2006-12-12 | 3M Espe Ag | Use of moulding compounds for producing treatment devices |
| EP3513778A1 (de) | 2018-01-23 | 2019-07-24 | Ivoclar Vivadent AG | Photochromer dentalwerkstoff mit verkapselten photochromen farbmittel |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5667840A (en) * | 1996-02-27 | 1997-09-16 | Becton Dickinson And Company | Lubricant soluble fluorescent agent and method for its use in a system for detection of lubricant coatings |
| DE19719955C2 (de) | 1997-05-14 | 2000-09-14 | Deutsche Telekom Mobil | Verfahren zur Erreichbarkeit von Teilnehmern in einem Funkkommunikationssystem |
| DE19926728B4 (de) * | 1999-06-11 | 2011-08-18 | 3M Espe Ag, 82229 | Verwendung von Trägermaterialien und diagnostisch nutzbaren Zusatzstoffen in Abbildungsverfahren für intraorale Diagnosezwecke |
| US7114951B2 (en) | 1999-11-10 | 2006-10-03 | Dentsply International Inc. | Method and shaped product-formed from low tack and fluorescing polymerizable dental material |
| US6391281B1 (en) | 2000-05-18 | 2002-05-21 | Medical College Of Georgia Research Institute | Fluorescent agent for the identification of tooth dentin |
| EP1632211A1 (en) * | 2004-09-07 | 2006-03-08 | S & C Polymer Silicon- und Composite-Spezialitäten GmbH | Dental resin-modified polyalkenoate cement composition |
| EP1634563B1 (en) * | 2004-09-07 | 2011-11-16 | S & C Polymer Silicon- und Composite-Spezialitäten GmbH | Dental polyalkenoate cement composition |
| US7314610B2 (en) | 2005-02-25 | 2008-01-01 | Ultradent Products, Inc. | Dental compositions having anti-stokes up converters and methods of use |
| US20060194895A1 (en) * | 2005-02-25 | 2006-08-31 | Dan Loveridge | Dental compositions having dual dental diagnostic capabilities and methods of use |
| US20060194172A1 (en) * | 2005-02-25 | 2006-08-31 | Dan Loveridge | Dental compositions having a phosphorescent material and methods of use |
| WO2007025636A1 (en) | 2005-08-27 | 2007-03-08 | Universität Zürich | Illumination device for a dental handpiece, use thereof and method for selective removal of a tooth colored intra-coronal restoration |
| ATE487458T1 (de) * | 2005-09-29 | 2010-11-15 | Dentsply Int Inc | Verfahren zur verwendung von dentalzusammensetzungen mit fluoreszierenden mitteln |
| US8263681B2 (en) * | 2006-12-28 | 2012-09-11 | 3M Innovative Properties Company | Dental compositions with natural tooth fluorescence |
| EP2149360A4 (en) * | 2007-05-31 | 2014-01-22 | Tokuyama Dental Corp | LIABILITY FOR DENTAL ELEMENTS |
| WO2010045096A2 (en) * | 2008-10-15 | 2010-04-22 | 3M Innovative Properties Company | Dental compositions with fluorescent pigment |
| JP2010120864A (ja) * | 2008-11-17 | 2010-06-03 | Tokuyama Dental Corp | 齲蝕検知液 |
| FR3023163A1 (fr) * | 2014-07-07 | 2016-01-08 | Pharma G | Dispositif pour le scellement a usage dentaire, de protheses fixes et d'elements orthodontiques, contenant une molecule fluorescente a une concentration comprise entre 1% et 2,5% |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3255079A (en) * | 1963-06-17 | 1966-06-07 | American Cyanamid Co | Therapeutic dental cement and a method for treating carious teeth |
| US3309274A (en) * | 1962-07-23 | 1967-03-14 | Brilliant Herbert | Use of fluorescent dyes in dental diagnostic methods |
| GB1068587A (en) * | 1963-12-06 | 1967-05-10 | Biorex Laboratories Ltd | Dental fillers and bone cements comprising collagen |
| CA983900A (en) * | 1971-05-10 | 1976-02-17 | Emery G. Audesse | Disclosing light |
| GB1428672A (en) * | 1972-04-25 | 1976-03-17 | Amalgamated Dental Co Ltd | Polymerizable compositions suitable for dental use |
| EP0225843A1 (de) * | 1985-11-22 | 1987-06-16 | Coltène AG | Härtbares Silikonabformmaterial, welches beim Mischen eine optische Kontrolle des ausreichenden Durchmischens erlaubt |
| DE3717762A1 (de) * | 1986-05-26 | 1987-12-03 | G C Dental Ind Corp | Beschichtungsmaterialien zum schutz von zahnoberflaechen |
| EP0339841A2 (en) * | 1988-04-13 | 1989-11-02 | The Mead Corporation | Photosensitive compositions and materials |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1544923A1 (de) * | 1965-10-22 | 1969-10-09 | Bayer Ag | Verfahren zur Herstellung von kuenstlichen Zaehnen nach dem Pulver-Fluessigkeits-Verfahren |
| US3960753A (en) * | 1974-05-30 | 1976-06-01 | Rca Corporation | Fluorescent liquid crystals |
| US4600389A (en) * | 1984-10-29 | 1986-07-15 | Magnetic Activated Particle Sorting, Inc. | Dental restoration method and composition therefor |
| US4957441A (en) * | 1988-12-20 | 1990-09-18 | Minnesota Mining And Manufacturing Company | Method of enhancing the curing of a photocurable dental restorative material |
-
1989
- 1989-12-02 DE DE3939998A patent/DE3939998A1/de active Granted
-
1990
- 1990-11-28 AT AT90122703T patent/ATE112483T1/de not_active IP Right Cessation
- 1990-11-28 DE DE59007387T patent/DE59007387D1/de not_active Expired - Fee Related
- 1990-11-28 EP EP90122703A patent/EP0431452B1/de not_active Expired - Lifetime
- 1990-11-30 US US07/620,470 patent/US5102461A/en not_active Expired - Lifetime
- 1990-11-30 AU AU67670/90A patent/AU629432B2/en not_active Ceased
- 1990-11-30 CA CA002031268A patent/CA2031268C/en not_active Expired - Fee Related
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3309274A (en) * | 1962-07-23 | 1967-03-14 | Brilliant Herbert | Use of fluorescent dyes in dental diagnostic methods |
| US3255079A (en) * | 1963-06-17 | 1966-06-07 | American Cyanamid Co | Therapeutic dental cement and a method for treating carious teeth |
| GB1068587A (en) * | 1963-12-06 | 1967-05-10 | Biorex Laboratories Ltd | Dental fillers and bone cements comprising collagen |
| CA983900A (en) * | 1971-05-10 | 1976-02-17 | Emery G. Audesse | Disclosing light |
| GB1428672A (en) * | 1972-04-25 | 1976-03-17 | Amalgamated Dental Co Ltd | Polymerizable compositions suitable for dental use |
| EP0225843A1 (de) * | 1985-11-22 | 1987-06-16 | Coltène AG | Härtbares Silikonabformmaterial, welches beim Mischen eine optische Kontrolle des ausreichenden Durchmischens erlaubt |
| DE3717762A1 (de) * | 1986-05-26 | 1987-12-03 | G C Dental Ind Corp | Beschichtungsmaterialien zum schutz von zahnoberflaechen |
| EP0339841A2 (en) * | 1988-04-13 | 1989-11-02 | The Mead Corporation | Photosensitive compositions and materials |
Non-Patent Citations (1)
| Title |
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| Derwent Abstr. Nr. 89-223 239/31 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6548521B1 (en) | 1992-09-11 | 2003-04-15 | The Regents Of The University Of California | Inhibitors of metazoan parasite proteases |
| US5698020A (en) * | 1995-05-26 | 1997-12-16 | Ivoclar Ag | Photochromic dental material |
| US7147471B2 (en) | 2000-12-08 | 2006-12-12 | 3M Espe Ag | Use of moulding compounds for producing treatment devices |
| EP1230906A1 (de) * | 2001-02-12 | 2002-08-14 | Ivoclar Vivadent AG | Thermochromer Dentalwerkstoff |
| DE10146883B4 (de) * | 2001-09-24 | 2006-05-24 | Dentona Ag | Mineralischer Rohstoff zur Herstellung dentaler Gipsmodelle mit fluoreszierender Oberfläche |
| EP3513778A1 (de) | 2018-01-23 | 2019-07-24 | Ivoclar Vivadent AG | Photochromer dentalwerkstoff mit verkapselten photochromen farbmittel |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0431452B1 (de) | 1994-10-05 |
| AU629432B2 (en) | 1992-10-01 |
| CA2031268A1 (en) | 1991-06-03 |
| EP0431452A3 (en) | 1992-04-15 |
| AU6767090A (en) | 1991-06-06 |
| DE59007387D1 (de) | 1994-11-10 |
| DE3939998C2 (enExample) | 1993-02-11 |
| US5102461A (en) | 1992-04-07 |
| EP0431452A2 (de) | 1991-06-12 |
| CA2031268C (en) | 1995-04-18 |
| ATE112483T1 (de) | 1994-10-15 |
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Legal Events
| Date | Code | Title | Description |
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| OP8 | Request for examination as to paragraph 44 patent law | ||
| 8128 | New person/name/address of the agent |
Representative=s name: STOLBERG-WERNIGERODE, GRAF ZU, U., DIPL.-CHEM. DR. |
|
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |