DE3853692T2 - Bis-(di-, tri- oder tetra-substituierte-cyclopentadienyl)-Zirconium-Dihalogenide. - Google Patents
Bis-(di-, tri- oder tetra-substituierte-cyclopentadienyl)-Zirconium-Dihalogenide.Info
- Publication number
- DE3853692T2 DE3853692T2 DE3853692T DE3853692T DE3853692T2 DE 3853692 T2 DE3853692 T2 DE 3853692T2 DE 3853692 T DE3853692 T DE 3853692T DE 3853692 T DE3853692 T DE 3853692T DE 3853692 T2 DE3853692 T2 DE 3853692T2
- Authority
- DE
- Germany
- Prior art keywords
- tri
- bis
- substituted cyclopentadienyl
- tetra substituted
- dihalides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62054368A JPH0662643B2 (ja) | 1987-03-10 | 1987-03-10 | ビス(3置換シクロペンタジエニル)ジルコニウムジハライド |
JP62054367A JPH0662642B2 (ja) | 1987-03-10 | 1987-03-10 | ビス(2置換シクロペンタジエニル)ジルコニウムジハライド |
JP62054369A JPH0662644B2 (ja) | 1987-03-10 | 1987-03-10 | ビス(4置換シクロペンタジエニル)ジルコニウムジハライド |
JP62068630A JPH0794500B2 (ja) | 1987-03-23 | 1987-03-23 | ポリオレフィンの製造方法 |
JP62071157A JPH07103185B2 (ja) | 1987-03-25 | 1987-03-25 | ポリオレフィン製造用触媒 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE3853692D1 DE3853692D1 (de) | 1995-06-08 |
DE3853692T2 true DE3853692T2 (de) | 1995-10-19 |
Family
ID=27523149
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE3853692T Expired - Fee Related DE3853692T2 (de) | 1987-03-10 | 1988-02-23 | Bis-(di-, tri- oder tetra-substituierte-cyclopentadienyl)-Zirconium-Dihalogenide. |
Country Status (3)
Country | Link |
---|---|
US (1) | US4874880A (de) |
EP (1) | EP0283739B2 (de) |
DE (1) | DE3853692T2 (de) |
Families Citing this family (75)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5001244A (en) * | 1988-06-22 | 1991-03-19 | Exxon Chemical Patents Inc. | Metallocene, hydrocarbylaluminum and hydrocarbylboroxine olefin polymerization catalyst |
US5004820A (en) * | 1989-08-07 | 1991-04-02 | Massachusetts Institute Of Technology | Preparation of chiral metallocene dihalides |
DE4005947A1 (de) * | 1990-02-26 | 1991-08-29 | Basf Ag | Loesliche katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen |
JP3193066B2 (ja) * | 1991-05-02 | 2001-07-30 | 三菱化学株式会社 | プロピレンランダム共重合体の製造法 |
DE4120009A1 (de) * | 1991-06-18 | 1992-12-24 | Basf Ag | Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen |
US5451555A (en) * | 1991-06-27 | 1995-09-19 | Nippon Oil Co., Ltd. | Catalyst components for polymerization of olefins |
DE69210480T2 (de) * | 1991-06-27 | 1996-11-28 | Nippon Oil Co Ltd | Katalysatorbestandteil für die Olefinpolymerisation |
EP0540108B1 (de) * | 1991-10-28 | 1996-01-03 | Shell Internationale Researchmaatschappij B.V. | Katalisatorzusammensetzung |
JP3378598B2 (ja) * | 1991-10-28 | 2003-02-17 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 触媒組成物 |
US5359015A (en) * | 1991-11-07 | 1994-10-25 | Exxon Chemical Patents Inc. | Metallocene catalysts and their production and use |
DE4205932A1 (de) * | 1992-02-27 | 1993-09-02 | Basf Ag | Verfahren zur herstellung von propenoligomeren |
US6143854A (en) * | 1993-08-06 | 2000-11-07 | Exxon Chemical Patents, Inc. | Polymerization catalysts, their production and use |
US5434116A (en) * | 1992-06-05 | 1995-07-18 | Tosoh Corporation | Organic transition metal compound having π-bonding heterocyclic ligand and method of polymerizing olefin by using the same |
US5939346A (en) * | 1992-11-02 | 1999-08-17 | Akzo Nobel N.V. | Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group |
US5391793A (en) * | 1992-11-02 | 1995-02-21 | Akzo Nobel N.V. | Aryloxyaluminoxanes |
US5332706A (en) * | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
US5602067A (en) * | 1992-12-28 | 1997-02-11 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
EP0719287B1 (de) * | 1993-08-06 | 1999-12-29 | Exxon Chemical Patents Inc. | Polymerisationskataylsatoren, ihre herstellung und verwendung |
US5594080A (en) * | 1994-03-24 | 1997-01-14 | Leland Stanford, Jr. University | Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor |
IT1273662B (it) | 1994-07-20 | 1997-07-09 | Spherilene Srl | Procedimento per la preparazione di polimeri amorfi del propiline' |
US5569746A (en) * | 1995-01-23 | 1996-10-29 | Albemarle Corporation | Process for preparing alkylsubstituted cyclopentadienyl metallocene compounds |
ES2120642T3 (es) * | 1995-02-17 | 1998-11-01 | Witco Gmbh | Proceso para la preparacion de complejos de metales de transicion con ligandos ciclopentadienilo. |
JPH08325327A (ja) * | 1995-06-02 | 1996-12-10 | Chisso Corp | 高立体規則性ポリプロピレン |
DE19527652A1 (de) * | 1995-07-28 | 1997-01-30 | Hoechst Ag | Metallocenverbindung |
EP0857179A1 (de) * | 1995-08-18 | 1998-08-12 | Basell Polyolefine GmbH | Katalysatorkomponente und katalysatorsystem mit hoher polymerisationsaktivität zur herstellung von polymeren |
AT403919B (de) * | 1996-02-02 | 1998-06-25 | Danubia Petrochem Polymere | Verfahren zur herstellung von katalysatorträgern und geträgerter polyolefin-katalysatoren sowie deren verwendung für die herstellung von polyolefinen |
EP0960144B1 (de) | 1997-02-17 | 2002-05-29 | Bayer Aktiengesellschaft | Neues kalalysatorsystem, dessen verwendung zur polymerisation von dienen in lösung, suspension und gasphase und verwendung der somit herstellbaren dienkautschuke |
US6921794B2 (en) | 1997-08-12 | 2005-07-26 | Exxonmobil Chemical Patents Inc. | Blends made from propylene ethylene polymers |
US6635715B1 (en) | 1997-08-12 | 2003-10-21 | Sudhin Datta | Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers |
US7232871B2 (en) | 1997-08-12 | 2007-06-19 | Exxonmobil Chemical Patents Inc. | Propylene ethylene polymers and production process |
WO2002083754A1 (en) | 2001-04-12 | 2002-10-24 | Exxonmobil Chemical Patents Inc. | Propylene ethylene polymers and production process |
US6046346A (en) * | 1997-12-26 | 2000-04-04 | Honshu Chemical Industry Co., Ltd. | Production of alkali metal cyclopentadienylide and production of dihalobis (η-substituted-cyclopentadienyl) zirconium from alkali metal cyclopentadienylide |
WO2000001766A1 (en) | 1998-07-01 | 2000-01-13 | Exxon Chemical Patents Inc. | Elastic blends comprising crystalline polymer and crystallizable polymers of propylene |
US6894131B2 (en) * | 1998-08-21 | 2005-05-17 | Univation Technologies, Llc | Polymerization process using a metallocene catalyst system |
US6632901B2 (en) | 1998-08-21 | 2003-10-14 | Univation Technologies, Llc | Polymerization process using an improved bulky ligand metallocene-type catalyst system |
DE19908938A1 (de) | 1999-03-02 | 2000-09-07 | Targor Gmbh | Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
JP4246871B2 (ja) | 2000-02-03 | 2009-04-02 | 本州化学工業株式会社 | 架橋環式シクロペンタジエン類およびそれを配位子とするジハロビス金属化合物 |
KR100404780B1 (ko) | 2000-02-18 | 2003-11-07 | 대림산업 주식회사 | 메탈로센 화합물과 이로부터 제조되는 메탈로센 촉매 및이를 이용한 올레핀의 중합 방법 |
US7053157B2 (en) | 2001-07-20 | 2006-05-30 | University Of Maryland, College Park | Method for production of multimodal polyolefins of tunable composition, molecular weight, and polydispersity |
US6960635B2 (en) * | 2001-11-06 | 2005-11-01 | Dow Global Technologies Inc. | Isotactic propylene copolymers, their preparation and use |
US6927256B2 (en) * | 2001-11-06 | 2005-08-09 | Dow Global Technologies Inc. | Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent |
EP1444276A1 (de) | 2001-11-06 | 2004-08-11 | Dow Global Technologies, Inc. | Isotaktische propylencopolymere, ihre herstellung und ihre verwendung |
US6906160B2 (en) * | 2001-11-06 | 2005-06-14 | Dow Global Technologies Inc. | Isotactic propylene copolymer fibers, their preparation and use |
US6943215B2 (en) | 2001-11-06 | 2005-09-13 | Dow Global Technologies Inc. | Impact resistant polymer blends of crystalline polypropylene and partially crystalline, low molecular weight impact modifiers |
US7132471B2 (en) * | 2002-04-25 | 2006-11-07 | Asahi Kasei Chemicals Corporation | Rubber composition and process for production thereof |
US6884748B2 (en) * | 2002-09-04 | 2005-04-26 | Univation Technologies, Llc | Process for producing fluorinated catalysts |
US6875828B2 (en) | 2002-09-04 | 2005-04-05 | Univation Technologies, Llc | Bimodal polyolefin production process and films therefrom |
US6753390B2 (en) | 2002-09-04 | 2004-06-22 | Univation Technologies, Llc | Gas phase polymerization process |
JP4728643B2 (ja) * | 2002-10-02 | 2011-07-20 | ダウ グローバル テクノロジーズ エルエルシー | 液状およびゲル状の低分子量エチレンポリマー類 |
ATE402222T1 (de) * | 2002-10-17 | 2008-08-15 | Dow Global Technologies Inc | Hochgefüllte polymerzusammensetzungen |
US7459500B2 (en) | 2002-11-05 | 2008-12-02 | Dow Global Technologies Inc. | Thermoplastic elastomer compositions |
US7579407B2 (en) * | 2002-11-05 | 2009-08-25 | Dow Global Technologies Inc. | Thermoplastic elastomer compositions |
US6890876B2 (en) * | 2002-11-26 | 2005-05-10 | Univation Technologies, Llc | Processes for producing fluorided catalysts from nitrogenous metallocenes |
EP2169025B1 (de) | 2003-08-19 | 2012-10-24 | Dow Global Technologies LLC | Interpolymere geeignet für die Verwendung in Heissschmelzkleber |
KR100677869B1 (ko) * | 2004-07-01 | 2007-02-02 | 대림산업 주식회사 | 다중핵 금속 화합물, 이를 포함하는 촉매 시스템 및 이를이용한 올레핀의 중합 방법 |
EP1805229A1 (de) | 2004-10-28 | 2007-07-11 | Dow Gloval Technologies Inc. | Verfahren zur steuerung eines polymerisierungsreaktors |
DE112006001733T5 (de) | 2005-07-01 | 2008-07-31 | Albemarle Corporation | Aluminoxanatsalzzusammensetzungen mit verbesserter Stabilität in aromatischen und aliphatischen Lösungsmitteln |
KR100681302B1 (ko) * | 2005-12-16 | 2007-02-09 | 대림산업 주식회사 | 올레핀 중합용 촉매 및 이를 이용한 올레핀의 중합방법 |
KR100976666B1 (ko) | 2008-07-21 | 2010-08-18 | 대림산업 주식회사 | 올레핀 중합 촉매 및 이를 이용한 폴리올레핀 중합체의제조방법 |
WO2010040235A1 (en) * | 2008-10-09 | 2010-04-15 | Eth Zurich | Living and quasi-living, metallocenecatalyzed polimerization of olefins |
EP2643366B1 (de) | 2010-11-22 | 2015-03-25 | Albemarle Corporation | Aktivatorzusammensetzungen, ihre herstellung und verwendung in der katalyse |
EP2841471B1 (de) | 2012-04-27 | 2020-05-06 | W. R. Grace & Co. - Conn. | Aktivatorzusammensetzungen, deren herstellung und deren verwendung in katalysatoren |
EP2679594A1 (de) | 2012-06-25 | 2014-01-01 | Daelim Industrial Co., Ltd. | Metallocenverbindung, Katalysatorzusammensetzung damit und Olefinpolymerisierungsverfahren damit |
JP6618891B2 (ja) | 2014-03-28 | 2019-12-11 | 三井化学株式会社 | エチレン/α−オレフィン共重合体および潤滑油 |
US10227543B2 (en) | 2014-09-10 | 2019-03-12 | Mitsui Chemicals, Inc. | Lubricant compositions |
US10882932B2 (en) | 2016-10-05 | 2021-01-05 | Exxonmobil Chemical Patents Inc. | Sterically hindered metallocenes, synthesis and use |
US10968290B2 (en) | 2017-03-28 | 2021-04-06 | Exxonmobil Chemical Patents Inc. | Metallocene-catalyzed polyalpha-olefins |
US11078308B2 (en) | 2018-02-12 | 2021-08-03 | Exxonmobil Chemical Patents Inc. | Processes to produce poly alpha-olefin trimers |
US11021553B2 (en) | 2018-02-12 | 2021-06-01 | Exxonmobil Chemical Patents Inc. | Metallocene dimer selective catalysts and processes to produce poly alpha-olefin dimers |
CN111868106B (zh) | 2018-02-12 | 2023-02-17 | 埃克森美孚化学专利公司 | 用于具有高乙烯叉基含量的聚α-烯烃的催化剂体系及方法 |
CN112912357B (zh) | 2018-09-17 | 2024-06-04 | 埃克森美孚化学专利公司 | 聚α-烯烃三聚物的制备方法和制备设备 |
KR102139882B1 (ko) | 2019-03-12 | 2020-07-31 | 대림산업 주식회사 | 폴리올레핀 수지 제조를 위한 신규한 메탈로센 촉매 화합물 또는 이의 제조방법 |
CN114845980A (zh) | 2019-10-28 | 2022-08-02 | 埃克森美孚化学专利公司 | 二聚物选择性金属茂催化剂、非芳族烃可溶性活化剂和用其制备聚α-烯烃低聚物的方法 |
CN115485311A (zh) | 2020-02-24 | 2022-12-16 | 埃克森美孚化学专利公司 | 用于生产乙烯叉基封端的聚α-烯烃的柄型-双(茚-2-基)催化剂 |
CN115943197A (zh) | 2020-04-29 | 2023-04-07 | 埃克森美孚化学专利公司 | 聚α-烯烃组合物和生产聚α-烯烃的方法 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2864843A (en) * | 1953-05-06 | 1958-12-16 | Ethyl Corp | Cyclopentadienyl moiety-containing metal monohalides |
US2983740A (en) * | 1953-06-15 | 1961-05-09 | Du Pont | Compounds of a group iv-a metal directly bonded to two cyclopentadienyl nuclei and to at least one inorganic anion and their preparation |
US2983741A (en) * | 1953-09-23 | 1961-05-09 | Union Carbide Corp | Cyclopentadienyl titanium halides |
BE551283A (de) * | 1955-09-27 | |||
US2868751A (en) * | 1956-01-18 | 1959-01-13 | Union Carbide Corp | Method of curing silicone water repellents with cyclopentadienyl transition element catalysts and aqueous compositions of same |
US2911424A (en) * | 1956-06-01 | 1959-11-03 | Nat Lead Co | Titanium and zirconium organic compounds and process of preparation |
US2952670A (en) * | 1957-08-26 | 1960-09-13 | Shell Oil Co | Polymerization and catalyst therefor |
US3080305A (en) * | 1958-07-31 | 1963-03-05 | Ethyl Corp | Manufacture of cyclopentadienyl metal halides |
US3347887A (en) * | 1963-08-05 | 1967-10-17 | American Cyanamid Co | Process of preparing titanoxane metaloxane polymers |
US4147709A (en) * | 1977-05-02 | 1979-04-03 | Monsanto Company | Zirconium halohydride preparation |
DE3127133A1 (de) * | 1981-07-09 | 1983-01-27 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von polyolefinen und deren copolymerisaten |
US4530914A (en) * | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
-
1988
- 1988-02-22 US US07/158,924 patent/US4874880A/en not_active Expired - Lifetime
- 1988-02-23 EP EP88102620A patent/EP0283739B2/de not_active Expired - Lifetime
- 1988-02-23 DE DE3853692T patent/DE3853692T2/de not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP0283739B1 (de) | 1995-05-03 |
US4874880A (en) | 1989-10-17 |
EP0283739B2 (de) | 1998-10-21 |
EP0283739A3 (en) | 1989-11-02 |
DE3853692D1 (de) | 1995-06-08 |
EP0283739A2 (de) | 1988-09-28 |
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