DE3812428C2 - Gefärbter, partiell stabilisierter Zirkoniumdioxid-Keramikwerkstoff, Verfahren zu seiner Herstellung und seine Verwendung - Google Patents
Gefärbter, partiell stabilisierter Zirkoniumdioxid-Keramikwerkstoff, Verfahren zu seiner Herstellung und seine VerwendungInfo
- Publication number
- DE3812428C2 DE3812428C2 DE3812428A DE3812428A DE3812428C2 DE 3812428 C2 DE3812428 C2 DE 3812428C2 DE 3812428 A DE3812428 A DE 3812428A DE 3812428 A DE3812428 A DE 3812428A DE 3812428 C2 DE3812428 C2 DE 3812428C2
- Authority
- DE
- Germany
- Prior art keywords
- sintering
- ceramic material
- weight
- colored
- stabilizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229910010293 ceramic material Inorganic materials 0.000 title claims abstract description 58
- 229910002077 partially stabilized zirconia Inorganic materials 0.000 title claims description 29
- 238000000034 method Methods 0.000 title claims description 26
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 71
- 238000005245 sintering Methods 0.000 claims abstract description 60
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 35
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 35
- 229910026551 ZrC Inorganic materials 0.000 claims abstract description 30
- OTCHGXYCWNXDOA-UHFFFAOYSA-N [C].[Zr] Chemical compound [C].[Zr] OTCHGXYCWNXDOA-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000013078 crystal Substances 0.000 claims abstract description 29
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000003381 stabilizer Substances 0.000 claims abstract description 21
- 239000000463 material Substances 0.000 claims abstract description 18
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 229910044991 metal oxide Inorganic materials 0.000 claims description 30
- 150000004706 metal oxides Chemical class 0.000 claims description 30
- 239000006103 coloring component Substances 0.000 claims description 20
- 230000001590 oxidative effect Effects 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 8
- 239000003086 colorant Substances 0.000 claims description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 5
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 229910052748 manganese Inorganic materials 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- 229910052720 vanadium Inorganic materials 0.000 claims description 5
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 claims description 4
- 229910020203 CeO Inorganic materials 0.000 claims description 2
- 239000000292 calcium oxide Substances 0.000 claims 2
- 239000000395 magnesium oxide Substances 0.000 claims 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical group [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical group O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000007493 shaping process Methods 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 description 17
- 238000004040 coloring Methods 0.000 description 17
- 239000000843 powder Substances 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 238000010348 incorporation Methods 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 238000005192 partition Methods 0.000 description 4
- 238000010298 pulverizing process Methods 0.000 description 4
- 239000007858 starting material Substances 0.000 description 4
- 230000006735 deficit Effects 0.000 description 3
- 230000001771 impaired effect Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000000737 periodic effect Effects 0.000 description 3
- IVORCBKUUYGUOL-UHFFFAOYSA-N 1-ethynyl-2,4-dimethoxybenzene Chemical compound COC1=CC=C(C#C)C(OC)=C1 IVORCBKUUYGUOL-UHFFFAOYSA-N 0.000 description 2
- 241000974482 Aricia saepiolus Species 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000004071 soot Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- -1 Mention Ti Substances 0.000 description 1
- 229910021541 Vanadium(III) oxide Inorganic materials 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- 239000011195 cermet Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000004756 plant textile Substances 0.000 description 1
- 238000013001 point bending Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229910021332 silicide Inorganic materials 0.000 description 1
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 229910009112 xH2O Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
- C04B35/486—Fine ceramics
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Composite Materials (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61311193A JPH0712978B2 (ja) | 1986-12-27 | 1986-12-27 | 黒色系ジルコニアセラミックス及びその製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3812428A1 DE3812428A1 (de) | 1989-10-26 |
| DE3812428C2 true DE3812428C2 (de) | 1995-03-09 |
Family
ID=18014212
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE3812428A Expired - Fee Related DE3812428C2 (de) | 1986-12-27 | 1988-04-14 | Gefärbter, partiell stabilisierter Zirkoniumdioxid-Keramikwerkstoff, Verfahren zu seiner Herstellung und seine Verwendung |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JPH0712978B2 (enrdf_load_stackoverflow) |
| CH (1) | CH675187GA3 (enrdf_load_stackoverflow) |
| DE (1) | DE3812428C2 (enrdf_load_stackoverflow) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10205197A1 (de) * | 2002-02-08 | 2003-08-28 | Atelier Bunz Gmbh | Schmuckring |
| DE102006052030A1 (de) * | 2006-11-03 | 2008-05-08 | Metoxit Ag | Verfahren zum Herstellen von gefärbten Keramiken |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW476742B (en) * | 1996-12-23 | 2002-02-21 | Smh Man Services Ag | Zirconia based ceramic article for use as a wear resistant exterior part for a wristwatch, and method for obtaining the same |
| EP0850900B1 (fr) * | 1996-12-23 | 2001-10-10 | The Swatch Group Management Services AG | Article à base de zircone, utilisation comme élément d'habillement, résistant à l'usure pour une montre-bracelet d'un tel article et procédé d'obtention d'un tel article |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3346497C2 (de) * | 1982-12-25 | 1994-06-09 | Kyocera Corp | Verfahren zur Herstellung eines schwarzen Schmuckgegenstandes auf der Basis von Zirkoniumdioxid |
| JPS6042276A (ja) * | 1983-08-12 | 1985-03-06 | 日本タングステン株式会社 | ジルコニア質黒色系装飾部材用材料並びにその製造方法 |
| JPS6177664A (ja) * | 1984-09-21 | 1986-04-21 | 住友電気工業株式会社 | ドツトプリンタ−用ピン材 |
| EP0218853B1 (en) * | 1985-09-06 | 1994-11-09 | Toray Industries, Inc. | Method for manufacturing a sintered zirconia material |
| JPS62202859A (ja) * | 1986-02-27 | 1987-09-07 | 日立金属株式会社 | 黒色系ＺｒＯｚセラミツクスおよびその製造方法 |
-
1986
- 1986-12-27 JP JP61311193A patent/JPH0712978B2/ja not_active Expired - Fee Related
-
1988
- 1988-04-14 CH CH137688A patent/CH675187GA3/de not_active IP Right Cessation
- 1988-04-14 DE DE3812428A patent/DE3812428C2/de not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10205197A1 (de) * | 2002-02-08 | 2003-08-28 | Atelier Bunz Gmbh | Schmuckring |
| DE102006052030A1 (de) * | 2006-11-03 | 2008-05-08 | Metoxit Ag | Verfahren zum Herstellen von gefärbten Keramiken |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0712978B2 (ja) | 1995-02-15 |
| DE3812428A1 (de) | 1989-10-26 |
| CH675187GA3 (enrdf_load_stackoverflow) | 1990-09-14 |
| JPS63166758A (ja) | 1988-07-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| 8128 | New person/name/address of the agent |
Representative=s name: TAUCHNER, P., DIPL.-CHEM. DR.RER.NAT. HEUNEMANN, D |
|
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |