DE3411034C2 - - Google Patents

Info

Publication number
DE3411034C2
DE3411034C2 DE19843411034 DE3411034A DE3411034C2 DE 3411034 C2 DE3411034 C2 DE 3411034C2 DE 19843411034 DE19843411034 DE 19843411034 DE 3411034 A DE3411034 A DE 3411034A DE 3411034 C2 DE3411034 C2 DE 3411034C2
Authority
DE
Germany
Prior art keywords
rhodium
carbon atoms
straight
chain
branched alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE19843411034
Other languages
German (de)
English (en)
Other versions
DE3411034A1 (de
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Priority to DE3411034A priority Critical patent/DE3411034A1/de
Priority to ES540668A priority patent/ES8608529A1/es
Priority to KR1019850001226A priority patent/KR890002153B1/ko
Priority to AT85102915T priority patent/ATE55280T1/de
Priority to DE8585102915T priority patent/DE3579018D1/de
Priority to EP19850102915 priority patent/EP0156253B1/de
Priority to RO118005A priority patent/RO90827B/ro
Priority to SU853864247A priority patent/SU1333232A3/ru
Priority to CS189885A priority patent/CS274653B2/cs
Priority to ZA852052A priority patent/ZA852052B/xx
Priority to PL1985252444A priority patent/PL149283B1/pl
Priority to HU851025A priority patent/HU198214B/hu
Priority to JP60054757A priority patent/JPS60212233A/ja
Priority to AU40351/85A priority patent/AU566540B2/en
Priority to BR8501338A priority patent/BR8501338A/pt
Priority to CA000477406A priority patent/CA1245056A/en
Priority to CN85103791A priority patent/CN1007347B/zh
Publication of DE3411034A1 publication Critical patent/DE3411034A1/de
Priority to CA000537189A priority patent/CA1338869C/en
Priority to US07/605,939 priority patent/US5091350A/en
Application granted granted Critical
Publication of DE3411034C2 publication Critical patent/DE3411034C2/de
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
    • C01G55/001—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/80—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/85—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to a chemical modification
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B11/00—Obtaining noble metals
    • C22B11/04—Obtaining noble metals by wet processes
    • C22B11/042—Recovery of noble metals from waste materials
    • C22B11/048—Recovery of noble metals from waste materials from spent catalysts
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
    • C22B3/381—Phosphines, e.g. compounds with the formula PRnH3-n, with n = 0-3
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/006—Wet processes
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/009—General processes for recovering metals or metallic compounds from spent catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/30—Non-coordinating groups comprising sulfur
    • B01J2540/32—Sulfonic acid groups or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/60—Groups characterized by their function
    • B01J2540/64—Solubility enhancing groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0244—Nitrogen containing compounds with nitrogen contained as ring member in aromatic compounds or moieties, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Saccharide Compounds (AREA)
  • Extraction Or Liquid Replacement (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
DE3411034A 1984-03-26 1984-03-26 Verfahren zur rueckgewinnung von rhodium aus reaktionsprodukten der oxosynthese Granted DE3411034A1 (de)

Priority Applications (19)

Application Number Priority Date Filing Date Title
DE3411034A DE3411034A1 (de) 1984-03-26 1984-03-26 Verfahren zur rueckgewinnung von rhodium aus reaktionsprodukten der oxosynthese
ES540668A ES8608529A1 (es) 1984-03-26 1985-02-25 Mejoras en los procedimientos para separacion y la recupera-cion del rodio de los productos de reaccion de la oxo-sinte-sis
KR1019850001226A KR890002153B1 (ko) 1984-03-26 1985-02-27 옥소(oxo)합성의 반응 생성물로부터 로듐을 회수하는 방법
AT85102915T ATE55280T1 (de) 1984-03-26 1985-03-14 Verfahren zur rueckgewinnung von rhodium aus reaktionsprodukten der oxosynthese.
DE8585102915T DE3579018D1 (de) 1984-03-26 1985-03-14 Verfahren zur rueckgewinnung von rhodium aus reaktionsprodukten der oxosynthese.
EP19850102915 EP0156253B1 (de) 1984-03-26 1985-03-14 Verfahren zur Rückgewinnung von Rhodium aus Reaktionsprodukten der Oxosynthese
RO118005A RO90827B (ro) 1984-03-26 1985-03-15 Procedeu de recuperare a rodiului din produse de reactie ale oxosintezei
SU853864247A SU1333232A3 (ru) 1984-03-26 1985-03-15 Способ регенерации роди из сырого продукта оксосинтеза
CS189885A CS274653B2 (en) 1984-03-26 1985-03-18 Method of rhodium separation and recuperation from oxo-synthesis products
PL1985252444A PL149283B1 (en) 1984-03-26 1985-03-19 Method of recovering rhodium from oxo-synthesis reaction products
ZA852052A ZA852052B (en) 1984-03-26 1985-03-19 A process for separation of rhodium from a product of the oxo synthesis
JP60054757A JPS60212233A (ja) 1984-03-26 1985-03-20 オキソ合成の生成物からロジウムを分離および回収する方法
HU851025A HU198214B (en) 1984-03-26 1985-03-20 Process for regaining of rhodium from reaction products of oxo-synthese
BR8501338A BR8501338A (pt) 1984-03-26 1985-03-25 Processo para separacao e recuperacao de rodio dos produtos de oxossintese
CA000477406A CA1245056A (en) 1984-03-26 1985-03-25 Process for hydroformylation with rhodium catalysts and the separation of rhodium therefrom
AU40351/85A AU566540B2 (en) 1984-03-26 1985-03-25 Recovery of rhodium from oxo synthesis product
CN85103791A CN1007347B (zh) 1984-03-26 1985-05-13 一种从羰基合成产物中间收铑的工艺
CA000537189A CA1338869C (en) 1984-03-26 1987-05-14 Process for hydroformylation with rhodium catalysts and the separation of rhodium therefrom
US07/605,939 US5091350A (en) 1984-03-26 1990-10-29 Process for hydroformylation with rhodium catalysts and the separation of rhodium therefrom

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE3411034A DE3411034A1 (de) 1984-03-26 1984-03-26 Verfahren zur rueckgewinnung von rhodium aus reaktionsprodukten der oxosynthese

Publications (2)

Publication Number Publication Date
DE3411034A1 DE3411034A1 (de) 1985-09-26
DE3411034C2 true DE3411034C2 (Direct) 1992-08-06

Family

ID=6231615

Family Applications (2)

Application Number Title Priority Date Filing Date
DE3411034A Granted DE3411034A1 (de) 1984-03-26 1984-03-26 Verfahren zur rueckgewinnung von rhodium aus reaktionsprodukten der oxosynthese
DE8585102915T Expired - Fee Related DE3579018D1 (de) 1984-03-26 1985-03-14 Verfahren zur rueckgewinnung von rhodium aus reaktionsprodukten der oxosynthese.

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE8585102915T Expired - Fee Related DE3579018D1 (de) 1984-03-26 1985-03-14 Verfahren zur rueckgewinnung von rhodium aus reaktionsprodukten der oxosynthese.

Country Status (14)

Country Link
EP (1) EP0156253B1 (Direct)
JP (1) JPS60212233A (Direct)
KR (1) KR890002153B1 (Direct)
AT (1) ATE55280T1 (Direct)
AU (1) AU566540B2 (Direct)
BR (1) BR8501338A (Direct)
CS (1) CS274653B2 (Direct)
DE (2) DE3411034A1 (Direct)
ES (1) ES8608529A1 (Direct)
HU (1) HU198214B (Direct)
PL (1) PL149283B1 (Direct)
RO (1) RO90827B (Direct)
SU (1) SU1333232A3 (Direct)
ZA (1) ZA852052B (Direct)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3443474A1 (de) * 1984-11-29 1986-05-28 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur rueckgewinnung von rhodium aus reaktionsprodukten der oxosynthese
US4716250A (en) * 1986-07-10 1987-12-29 Union Carbide Corporation Hydroformylation using low volatile/organic soluble phosphine ligands
US4731486A (en) * 1986-11-18 1988-03-15 Union Carbide Corporation Hydroformylation using low volatile phosphine ligands
DE3822037A1 (de) * 1988-06-30 1990-01-04 Hoechst Ag Verfahren zur abtrennung und wiedergewinnung von rhodium aus den produkten der oxosynthese
US4935550A (en) * 1988-08-12 1990-06-19 Union Carbide Chemicals And Plastics Company Inc. Catalytic metal recovery from non-polar organic solutions
US5114473A (en) * 1988-08-25 1992-05-19 Union Carbide Chemicals And Plastics Technology Corporation Transition metal recovery
DE3903909A1 (de) * 1989-02-10 1990-08-16 Hoechst Ag Verfahren zur entfernung metallischer korrosionsprodukte aus einer bei der carbonylierung von methanol und/oder methylacetat und/oder dimethylether anfallenden, verunreinigten katalysatorloesung
US5099047A (en) * 1989-11-17 1992-03-24 Mitsubishi Kasei Corporation Method for recovering a group viii metal solid complex and hydroformylation method
DE4135049A1 (de) * 1991-10-24 1993-05-06 Hoechst Ag, 6230 Frankfurt, De Verfahren zur rueckgewinnung von rhodium aus den reaktionsprodukten der oxosynthese
DE4427428A1 (de) 1994-08-03 1996-02-29 Basf Ag Verfahren zur Herstellung von Aldehyden
DE19940250B4 (de) * 1999-08-25 2005-06-16 Celanese Chemicals Europe Gmbh Verfahren zur Regenerierung gebrauchter wasserlöslicher Hydroformylierungskatalysatoren
DE19940249A1 (de) * 1999-08-25 2001-03-01 Celanese Chem Europe Gmbh Verfahren zur Herstellung von Aldehyden
DE10005084C1 (de) * 2000-02-04 2001-09-13 Celanese Chem Europe Gmbh Verfahren zur Wiedergewinnung von Rhodium aus Reaktionsprodukten der Oxosynthese
FR2813305B1 (fr) * 2000-08-23 2004-02-13 Inst Francais Du Petrole Procede ameliore d'hydroformylation mettant en oeuvre un catalyseur a base de cobalt et/ou de rhodium dans un solvant ionique non aqueux
FR2838431B1 (fr) 2002-04-11 2005-05-06 Inst Francais Du Petrole Procede d'hydroformylation mettant en oeuvre un catalyseur a base de cobalt dans un liquide ionique non-aqueux avec un recyclage du catalyseur ameliore
CN102336638A (zh) * 2011-07-20 2012-02-01 南京荣欣化工有限公司 一种乙烯氢甲酰化生产丙醛工艺的方法
EP3893264A1 (en) 2020-04-06 2021-10-13 ASML Netherlands B.V. Charged particle assessment tool, inspection method

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4248802A (en) * 1975-06-20 1981-02-03 Rhone-Poulenc Industries Catalytic hydroformylation of olefins
US4292196A (en) * 1979-12-10 1981-09-29 Uop Inc. Catalyst recovery
GB2085874B (en) * 1980-09-04 1984-08-08 Johnson Matthey Plc Hydroformylation of olefins

Also Published As

Publication number Publication date
RO90827B (ro) 1987-01-31
PL252444A1 (en) 1986-02-25
ATE55280T1 (de) 1990-08-15
DE3411034A1 (de) 1985-09-26
KR850006995A (ko) 1985-10-30
JPH0356095B2 (Direct) 1991-08-27
AU4035185A (en) 1985-10-03
ES8608529A1 (es) 1986-08-01
SU1333232A3 (ru) 1987-08-23
DE3579018D1 (de) 1990-09-13
EP0156253A3 (en) 1987-10-21
CS274653B2 (en) 1991-09-15
RO90827A (ro) 1987-01-30
EP0156253A2 (de) 1985-10-02
AU566540B2 (en) 1987-10-22
EP0156253B1 (de) 1990-08-08
PL149283B1 (en) 1990-01-31
JPS60212233A (ja) 1985-10-24
ZA852052B (en) 1985-11-27
HU198214B (en) 1989-08-28
CS189885A2 (en) 1991-02-12
BR8501338A (pt) 1985-11-19
KR890002153B1 (ko) 1989-06-21
ES540668A0 (es) 1986-08-01
HUT39704A (en) 1986-10-29

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