KR850006995A - OXo 합성반응 제제로부터 로디움을 환원하는 방법 - Google Patents

OXo 합성반응 제제로부터 로디움을 환원하는 방법 Download PDF

Info

Publication number
KR850006995A
KR850006995A KR1019850001226A KR850001226A KR850006995A KR 850006995 A KR850006995 A KR 850006995A KR 1019850001226 A KR1019850001226 A KR 1019850001226A KR 850001226 A KR850001226 A KR 850001226A KR 850006995 A KR850006995 A KR 850006995A
Authority
KR
South Korea
Prior art keywords
carbon atoms
branched alkyl
straight
group
alkyl group
Prior art date
Application number
KR1019850001226A
Other languages
English (en)
Other versions
KR890002153B1 (ko
Inventor
코닐스 보이 (외 4)
Original Assignee
파 콘콜, 파 닥터 라이헬트
루허케미 악티엔 게셀샤프트
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 파 콘콜, 파 닥터 라이헬트, 루허케미 악티엔 게셀샤프트 filed Critical 파 콘콜, 파 닥터 라이헬트
Publication of KR850006995A publication Critical patent/KR850006995A/ko
Application granted granted Critical
Publication of KR890002153B1 publication Critical patent/KR890002153B1/ko

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
    • C01G55/001—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/80—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/85—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to a chemical modification
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B11/00—Obtaining noble metals
    • C22B11/04—Obtaining noble metals by wet processes
    • C22B11/042—Recovery of noble metals from waste materials
    • C22B11/048—Recovery of noble metals from waste materials from spent catalysts
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
    • C22B3/381—Phosphines, e.g. compounds with the formula PRnH3-n, with n = 0-3
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/006—Wet processes
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/009—General processes for recovering metals or metallic compounds from spent catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/30—Non-coordinating groups comprising sulfur
    • B01J2540/32—Sulfonic acid groups or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/60—Groups characterized by their function
    • B01J2540/64—Solubility enhancing groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0244—Nitrogen containing compounds with nitrogen contained as ring member in aromatic compounds or moieties, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Abstract

내용 없음

Description

OXo 합성반응 제제로부터 로디움을 환원하는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. 독일 특허출원 P33 47 406.0인 복합시약의 수용액과 같이 추출함으로서 OXo 합성제제로 부터의 로디움의 분리환원방법에 추가하여, 복합시약에 Solubiliser를 가하여 되는 것을 특징으로 하는 로디움 분리환원방법.
  2. Solubiliser로서의 일반식
    로 표시되는 화합물을 사용하는 것을 특징으로 하는 제1항에 의한 방법.
    여기서, A는 직쇄 또는 분기알킬, 알콕시, 하이드록시알킬 또는 어떤 경우에는, 6 내지 25개의 탄소원자를 갖는 치환된 아릴군 또는 R7CONH, CH2, CH2, CH2군(R″은 5 내지 11개의 탄소원자를 갖는 직쇄 또는 분기알킬군), B는 1 내지 23개의 탄소원자를 갖는 직쇄 또는 분기알킬군 또는 어떤 경우엔 6 내지 25개의 탄소원자를 갖는 치환된 알릴군, C 및 D는 동일 또는 상이한 1 내지 4개의 탄소원자를 갖는 직쇄 또는 분기알킬군을 표시하고 또는 N과 더불어 헤테로싸이크릭 5 또는 6멤버환을 형성하고, E는 염화물,취화물, 옥화물 및 특히 황산염, 알킬벤젠쎌포네이트, 토루엔쎌포네이트, 유산염 또는 구연산염을 표시한다.
  3. A가 8 내지 12개의 탄소원자를 갖는 직쇄 또는 분기알킬군 또는 어떤 경우엔 10 내지 14개의 탄소원자를 갖는 치환된 아릴군을 표시하는 특징을 갖는 제2항에 의한 방법.
  4. B,C 및 D가 N와 같이 피롤, 피리딘, 몰포린을 표시하는 특징을 갖는 제 2항에 의한 방법.
  5. 수용액속의 용매의 농도가 중량비로 0.005 내지 10％, 그중에서도 중량비로 0.1 내지 2.5％(각 경우의 용액에 따른)인 특징을 갖는 제1내지 제4항의 한 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019850001226A 1984-03-26 1985-02-27 옥소(oxo)합성의 반응 생성물로부터 로듐을 회수하는 방법 KR890002153B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE3411034A DE3411034A1 (de) 1984-03-26 1984-03-26 Verfahren zur rueckgewinnung von rhodium aus reaktionsprodukten der oxosynthese
DEP3411034.8 1984-03-26
DEP3411034·8 1984-03-26

Publications (2)

Publication Number Publication Date
KR850006995A true KR850006995A (ko) 1985-10-30
KR890002153B1 KR890002153B1 (ko) 1989-06-21

Family

ID=6231615

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019850001226A KR890002153B1 (ko) 1984-03-26 1985-02-27 옥소(oxo)합성의 반응 생성물로부터 로듐을 회수하는 방법

Country Status (14)

Country Link
EP (1) EP0156253B1 (ko)
JP (1) JPS60212233A (ko)
KR (1) KR890002153B1 (ko)
AT (1) ATE55280T1 (ko)
AU (1) AU566540B2 (ko)
BR (1) BR8501338A (ko)
CS (1) CS274653B2 (ko)
DE (2) DE3411034A1 (ko)
ES (1) ES8608529A1 (ko)
HU (1) HU198214B (ko)
PL (1) PL149283B1 (ko)
RO (1) RO90827B (ko)
SU (1) SU1333232A3 (ko)
ZA (1) ZA852052B (ko)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3443474A1 (de) * 1984-11-29 1986-05-28 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur rueckgewinnung von rhodium aus reaktionsprodukten der oxosynthese
US4716250A (en) * 1986-07-10 1987-12-29 Union Carbide Corporation Hydroformylation using low volatile/organic soluble phosphine ligands
US4731486A (en) * 1986-11-18 1988-03-15 Union Carbide Corporation Hydroformylation using low volatile phosphine ligands
DE3822037A1 (de) * 1988-06-30 1990-01-04 Hoechst Ag Verfahren zur abtrennung und wiedergewinnung von rhodium aus den produkten der oxosynthese
US4935550A (en) * 1988-08-12 1990-06-19 Union Carbide Chemicals And Plastics Company Inc. Catalytic metal recovery from non-polar organic solutions
US5114473A (en) * 1988-08-25 1992-05-19 Union Carbide Chemicals And Plastics Technology Corporation Transition metal recovery
DE3903909A1 (de) * 1989-02-10 1990-08-16 Hoechst Ag Verfahren zur entfernung metallischer korrosionsprodukte aus einer bei der carbonylierung von methanol und/oder methylacetat und/oder dimethylether anfallenden, verunreinigten katalysatorloesung
US5099047A (en) * 1989-11-17 1992-03-24 Mitsubishi Kasei Corporation Method for recovering a group viii metal solid complex and hydroformylation method
DE4135049A1 (de) * 1991-10-24 1993-05-06 Hoechst Ag, 6230 Frankfurt, De Verfahren zur rueckgewinnung von rhodium aus den reaktionsprodukten der oxosynthese
DE4427428A1 (de) * 1994-08-03 1996-02-29 Basf Ag Verfahren zur Herstellung von Aldehyden
DE19940250B4 (de) * 1999-08-25 2005-06-16 Celanese Chemicals Europe Gmbh Verfahren zur Regenerierung gebrauchter wasserlöslicher Hydroformylierungskatalysatoren
DE19940249A1 (de) * 1999-08-25 2001-03-01 Celanese Chem Europe Gmbh Verfahren zur Herstellung von Aldehyden
DE10005084C1 (de) * 2000-02-04 2001-09-13 Celanese Chem Europe Gmbh Verfahren zur Wiedergewinnung von Rhodium aus Reaktionsprodukten der Oxosynthese
FR2813305B1 (fr) * 2000-08-23 2004-02-13 Inst Francais Du Petrole Procede ameliore d'hydroformylation mettant en oeuvre un catalyseur a base de cobalt et/ou de rhodium dans un solvant ionique non aqueux
FR2838431B1 (fr) 2002-04-11 2005-05-06 Inst Francais Du Petrole Procede d'hydroformylation mettant en oeuvre un catalyseur a base de cobalt dans un liquide ionique non-aqueux avec un recyclage du catalyseur ameliore
CN102336638A (zh) * 2011-07-20 2012-02-01 南京荣欣化工有限公司 一种乙烯氢甲酰化生产丙醛工艺的方法
EP3893264A1 (en) 2020-04-06 2021-10-13 ASML Netherlands B.V. Charged particle assessment tool, inspection method

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4248802A (en) * 1975-06-20 1981-02-03 Rhone-Poulenc Industries Catalytic hydroformylation of olefins
US4292196A (en) * 1979-12-10 1981-09-29 Uop Inc. Catalyst recovery
GB2085874B (en) * 1980-09-04 1984-08-08 Johnson Matthey Plc Hydroformylation of olefins

Also Published As

Publication number Publication date
AU4035185A (en) 1985-10-03
DE3411034A1 (de) 1985-09-26
PL149283B1 (en) 1990-01-31
RO90827A (ro) 1987-01-30
HUT39704A (en) 1986-10-29
CS189885A2 (en) 1991-02-12
EP0156253A2 (de) 1985-10-02
ATE55280T1 (de) 1990-08-15
ES540668A0 (es) 1986-08-01
JPH0356095B2 (ko) 1991-08-27
EP0156253B1 (de) 1990-08-08
DE3579018D1 (de) 1990-09-13
JPS60212233A (ja) 1985-10-24
AU566540B2 (en) 1987-10-22
PL252444A1 (en) 1986-02-25
EP0156253A3 (en) 1987-10-21
ES8608529A1 (es) 1986-08-01
CS274653B2 (en) 1991-09-15
SU1333232A3 (ru) 1987-08-23
HU198214B (en) 1989-08-28
DE3411034C2 (ko) 1992-08-06
RO90827B (ro) 1987-01-31
ZA852052B (en) 1985-11-27
BR8501338A (pt) 1985-11-19
KR890002153B1 (ko) 1989-06-21

Similar Documents

Publication Publication Date Title
KR850006995A (ko) OXo 합성반응 제제로부터 로디움을 환원하는 방법
GB1513709A (en) Copper plating bath and process and additive compositions for use therein
KR860009023A (ko) 치환된 실릴기를 갖는 신규 에테르 화합물의 제조방법
KR920002710A (ko) 음이온 화합물
GB1470712A (en) Oxyalkylated amine derivatives and their use as amphoteric surface active agnets
KR840001181A (ko) 유기 3급 폴리포스핀 모노옥시사이드의 제조방법
US4053400A (en) Purification of nickel and cobalt electroplating solutions
KR860001789A (ko) 디히드로피리딘 유도체의 제조방법
KR960705774A (ko) 티오아릴 화합물의 제조방법(processes for production of thioaryl compound)
KR850002979A (ko) 1,2,3-트리티안화합물의 신규 제조방법
KR830005191A (ko) 푸란유도체의 제조방법
GB1456583A (en) Electroplating composition and process
DE3682816D1 (de) Verfahren zur herstellung von 2-carboxypyrazin-4-oxiden.
KR840005107A (ko) 피리미디온 및 그의 산부가염의 제조방법
GB1396625A (en) Methylene-sulphones from the terpene series
KR830001644A (ko) 아릴알킬-및 아릴옥시알킬포스포네이트의 제조방법
KR840004721A (ko) 5-옥소(oxo)-2-피롤리딘프로파노인산 유도체의 제조방법
ATE6654T1 (de) Loesungen von natriumalkylen in kohlenwasserstoffen und verfahren zur herstellung dieser loesungen.
KR880001528A (ko) 알루미늄 산성염 용액으로부터 철을 제거하는 방법
PE1096A1 (es) Extractantes selectivos del zinc derivados del amido bis (tiofosforilo)
KR850004105A (ko) 티올설폰산 유도체의 제조방법
GB1526660A (en) Brass plating
ATE146456T1 (de) Neue wolfram-hexa-(dialkyldithiocarbamate) und verfahren zu ihrer herstellung
KR840001544A (ko) 벤조페논유도체 제조방법
EP0600908A1 (en) IMPROVED METHOD FOR PRODUCING MO4S4L6.

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 19990518

Year of fee payment: 11

LAPS Lapse due to unpaid annual fee