DE3323135C2 - Stabilisierter roter Phosphor und Verfahren zu seiner Herstellung - Google Patents
Stabilisierter roter Phosphor und Verfahren zu seiner HerstellungInfo
- Publication number
- DE3323135C2 DE3323135C2 DE3323135A DE3323135A DE3323135C2 DE 3323135 C2 DE3323135 C2 DE 3323135C2 DE 3323135 A DE3323135 A DE 3323135A DE 3323135 A DE3323135 A DE 3323135A DE 3323135 C2 DE3323135 C2 DE 3323135C2
- Authority
- DE
- Germany
- Prior art keywords
- red phosphorus
- titanium
- udf54
- udf53
- treated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims abstract description 96
- 238000000034 method Methods 0.000 title claims description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 78
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 32
- JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 claims abstract description 13
- 235000011007 phosphoric acid Nutrition 0.000 claims abstract description 9
- 239000002245 particle Substances 0.000 claims description 41
- 239000010936 titanium Substances 0.000 claims description 25
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 18
- 230000003647 oxidation Effects 0.000 claims description 18
- 238000007254 oxidation reaction Methods 0.000 claims description 18
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 14
- 239000002002 slurry Substances 0.000 claims description 14
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 14
- 229910052719 titanium Inorganic materials 0.000 claims description 12
- 239000003381 stabilizer Substances 0.000 claims description 10
- 238000001556 precipitation Methods 0.000 claims description 8
- DCKVFVYPWDKYDN-UHFFFAOYSA-L oxygen(2-);titanium(4+);sulfate Chemical compound [O-2].[Ti+4].[O-]S([O-])(=O)=O DCKVFVYPWDKYDN-UHFFFAOYSA-L 0.000 claims description 7
- 229910000348 titanium sulfate Inorganic materials 0.000 claims description 7
- 150000003609 titanium compounds Chemical class 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 2
- 239000008240 homogeneous mixture Substances 0.000 claims description 2
- 230000001376 precipitating effect Effects 0.000 claims 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract description 21
- 229910000073 phosphorus hydride Inorganic materials 0.000 abstract description 11
- 150000003016 phosphoric acids Chemical class 0.000 abstract description 2
- 238000010525 oxidative degradation reaction Methods 0.000 abstract 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 17
- 239000011574 phosphorus Substances 0.000 description 17
- 229910052698 phosphorus Inorganic materials 0.000 description 17
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 10
- 229910052782 aluminium Inorganic materials 0.000 description 10
- 239000002253 acid Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- JJLJMEJHUUYSSY-UHFFFAOYSA-L Copper hydroxide Chemical compound [OH-].[OH-].[Cu+2] JJLJMEJHUUYSSY-UHFFFAOYSA-L 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 3
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 229910021514 lead(II) hydroxide Inorganic materials 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 3
- 239000005750 Copper hydroxide Substances 0.000 description 2
- 206010016807 Fluid retention Diseases 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910001956 copper hydroxide Inorganic materials 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910001679 gibbsite Inorganic materials 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 2
- 235000019799 monosodium phosphate Nutrition 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical class [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical class [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical class [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 150000001399 aluminium compounds Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229940077746 antacid containing aluminium compound Drugs 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Chemical class 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- AEJIMXVJZFYIHN-UHFFFAOYSA-N copper;dihydrate Chemical compound O.O.[Cu] AEJIMXVJZFYIHN-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- 239000011777 magnesium Chemical class 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- OBSZRRSYVTXPNB-UHFFFAOYSA-N tetraphosphorus Chemical compound P12P3P1P32 OBSZRRSYVTXPNB-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 239000011701 zinc Chemical class 0.000 description 1
- 229910052725 zinc Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/003—Phosphorus
- C01B25/006—Stabilisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA000406319A CA1178788A (en) | 1982-06-29 | 1982-06-29 | Stabilization of red phosphorus |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3323135A1 DE3323135A1 (de) | 1984-02-09 |
| DE3323135C2 true DE3323135C2 (de) | 1987-04-30 |
Family
ID=4123124
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE3323135A Expired DE3323135C2 (de) | 1982-06-29 | 1983-06-27 | Stabilisierter roter Phosphor und Verfahren zu seiner Herstellung |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS5913612A (enrdf_load_stackoverflow) |
| CA (1) | CA1178788A (enrdf_load_stackoverflow) |
| DE (1) | DE3323135C2 (enrdf_load_stackoverflow) |
| GB (1) | GB2128598B (enrdf_load_stackoverflow) |
| IT (1) | IT1162883B (enrdf_load_stackoverflow) |
| SE (1) | SE460471B (enrdf_load_stackoverflow) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1214314A (en) * | 1983-12-08 | 1986-11-25 | Helena Twardowska | Stabilization of red phosphorus |
| JP2014208737A (ja) * | 2013-03-25 | 2014-11-06 | 富士ゼロックス株式会社 | 樹脂組成物、樹脂成形体および表面処理赤燐 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2000033B2 (de) * | 1970-01-02 | 1971-11-11 | Knapsack AG, 5033 Hürth-Knapsack | Verfahren zum herstellen von passiviertem rotem phosphor |
| DE2249638B2 (de) * | 1972-10-11 | 1981-01-15 | Hoechst Ag, 6000 Frankfurt | Phlegmatisierter roter Phosphor |
| FR2314221A1 (fr) * | 1975-06-10 | 1977-01-07 | Rhone Poulenc Ind | Compositions destinees a l'ignifugation de matieres plastiques |
| FR2314219A1 (fr) * | 1975-06-10 | 1977-01-07 | Rhone Poulenc Ind | Compositions destinees a l'ignifugation de matieres plastiques |
| FR2344615A1 (fr) * | 1976-03-19 | 1977-10-14 | Rhone Poulenc Ind | Compositions destinees a l'ignifugation de matieres plastiques |
| JPS5949942B2 (ja) * | 1976-04-27 | 1984-12-05 | 日本化学工業株式会社 | 難燃化熱硬化性樹脂組成物 |
| DE2631532C2 (de) * | 1976-07-14 | 1984-09-13 | Hoechst Ag, 6230 Frankfurt | Stabilisierter pulverförmiger roter Phosphor sowie Verfahren zu seiner Herstellung |
| DE2632296C2 (de) * | 1976-07-17 | 1979-02-01 | Hoechst Ag, 6000 Frankfurt | Stabilisierter roter Phosphor sowie Verfahren zu seiner Herstellung |
| DE2647093C2 (de) * | 1976-10-19 | 1984-12-06 | Hoechst Ag, 6230 Frankfurt | Stabilisierter pulverförmiger roter Phosphor sowie Verfahren zu seiner Herstellung |
| DE2705042A1 (de) * | 1977-02-08 | 1978-08-10 | Hoechst Ag | Stabilisierter roter phosphor sowie verfahren zu seiner herstellung |
| DE2655739C2 (de) * | 1976-12-09 | 1978-12-14 | Hoechst Ag, 6000 Frankfurt | Stabilisierter roter Phosphor sowie Verfahren zu seiner Herstellung |
| DE2813151A1 (de) * | 1978-03-25 | 1979-09-27 | Hoechst Ag | Stabilisierter roter phosphor |
-
1982
- 1982-06-29 CA CA000406319A patent/CA1178788A/en not_active Expired
-
1983
- 1983-06-27 DE DE3323135A patent/DE3323135C2/de not_active Expired
- 1983-06-27 SE SE8303669A patent/SE460471B/sv not_active IP Right Cessation
- 1983-06-28 IT IT67705/83A patent/IT1162883B/it active
- 1983-06-29 GB GB08317656A patent/GB2128598B/en not_active Expired
- 1983-06-29 JP JP58116235A patent/JPS5913612A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| SE8303669L (sv) | 1983-12-30 |
| SE460471B (sv) | 1989-10-16 |
| DE3323135A1 (de) | 1984-02-09 |
| GB2128598A (en) | 1984-05-02 |
| JPS5913612A (ja) | 1984-01-24 |
| JPH0549604B2 (enrdf_load_stackoverflow) | 1993-07-26 |
| SE8303669D0 (sv) | 1983-06-27 |
| IT1162883B (it) | 1987-04-01 |
| GB8317656D0 (en) | 1983-08-03 |
| GB2128598B (en) | 1987-02-18 |
| CA1178788A (en) | 1984-12-04 |
| IT8367705A0 (it) | 1983-06-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OM8 | Search report available as to paragraph 43 lit. 1 sentence 1 patent law | ||
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8327 | Change in the person/name/address of the patent owner |
Owner name: TENNECO CANADA INC., TORONTO, ONTARIO, CA |
|
| 8328 | Change in the person/name/address of the agent |
Free format text: BERENDT, T., DIPL.-CHEM. DR. LEYH, H., DIPL.-ING. DR.-ING. HERING, H., DIPL.-ING., PAT.-ANWAELTE, 8000 MUENCHEN |
|
| 8328 | Change in the person/name/address of the agent |
Free format text: KERN, W., DIPL.-ING. BREHM, H., DIPL.-CHEM. DR.PHIL.NAT. VOLPERT, M., DIPL.-ING. DR.-ING., PAT.-ANWAELTE, 81369 MUENCHEN |
|
| 8339 | Ceased/non-payment of the annual fee |