DE3139090C1 - Plastisole aus Copolymerisaten des Methylmethacrylats mit verbesserter Haftfestigkeit und ihre Verwendung - Google Patents
Plastisole aus Copolymerisaten des Methylmethacrylats mit verbesserter Haftfestigkeit und ihre VerwendungInfo
- Publication number
- DE3139090C1 DE3139090C1 DE3139090A DE3139090A DE3139090C1 DE 3139090 C1 DE3139090 C1 DE 3139090C1 DE 3139090 A DE3139090 A DE 3139090A DE 3139090 A DE3139090 A DE 3139090A DE 3139090 C1 DE3139090 C1 DE 3139090C1
- Authority
- DE
- Germany
- Prior art keywords
- weight
- copolymers
- methyl methacrylate
- plastisols
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001944 Plastisol Polymers 0.000 title claims abstract description 28
- 239000004999 plastisol Substances 0.000 title claims abstract description 28
- 229920001577 copolymer Polymers 0.000 title claims abstract description 17
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 title claims abstract description 10
- 230000001070 adhesive effect Effects 0.000 title description 4
- 239000000853 adhesive Substances 0.000 title 1
- 239000004014 plasticizer Substances 0.000 claims abstract description 17
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 10
- 239000002245 particle Substances 0.000 claims abstract description 7
- 230000009477 glass transition Effects 0.000 claims abstract description 5
- 239000000654 additive Substances 0.000 claims abstract description 4
- 239000000945 filler Substances 0.000 claims abstract description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 150000008064 anhydrides Chemical class 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 abstract description 4
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 abstract description 4
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 description 20
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 12
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 6
- 235000019395 ammonium persulphate Nutrition 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 5
- 239000003995 emulsifying agent Substances 0.000 description 5
- 239000003999 initiator Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- WHHSHXMIKFVAEK-UHFFFAOYSA-N 2-o-benzyl 1-o-octyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 WHHSHXMIKFVAEK-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- 239000002318 adhesion promoter Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 239000011976 maleic acid Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000004971 Cross linker Substances 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- UJMDYLWCYJJYMO-UHFFFAOYSA-N benzene-1,2,3-tricarboxylic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1C(O)=O UJMDYLWCYJJYMO-UHFFFAOYSA-N 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000004815 dispersion polymer Substances 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000001962 electrophoresis Methods 0.000 description 2
- -1 flow aids Substances 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000003021 phthalic acid derivatives Chemical class 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- SOGAXMICEFXMKE-UHFFFAOYSA-N alpha-Methyl-n-butyl acrylate Natural products CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- LBKFHGHXATXEBY-UHFFFAOYSA-N bis(1-methylcyclohexyl) benzene-1,2-dicarboxylate Chemical compound C=1C=CC=C(C(=O)OC2(C)CCCCC2)C=1C(=O)OC1(C)CCCCC1 LBKFHGHXATXEBY-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000012966 redox initiator Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paints Or Removers (AREA)
- Polymerisation Methods In General (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3139090A DE3139090C1 (de) | 1981-10-01 | 1981-10-01 | Plastisole aus Copolymerisaten des Methylmethacrylats mit verbesserter Haftfestigkeit und ihre Verwendung |
| AT82106637T ATE24011T1 (de) | 1981-10-01 | 1982-07-23 | Plastisole aus copolymerisaten des methylmethacrylats mit verbesserter haftfestigkeit und ihre verwendung. |
| EP82106637A EP0076368B1 (de) | 1981-10-01 | 1982-07-23 | Plastisole aus Copolymerisaten des Methylmethacrylats mit verbesserter Haftfestigkeit und ihre Verwendung |
| DE8282106637T DE3274552D1 (en) | 1981-10-01 | 1982-07-23 | Plastisols of copolymers of methylmethacrylate, and their use |
| US06/420,040 US4558084A (en) | 1981-10-01 | 1982-09-20 | Plastisol comprising a copolymer of methyl methacrylate and itaconic or its anhydride |
| ES516078A ES8502465A1 (es) | 1981-10-01 | 1982-09-29 | "procedimiento para la fabricacion de plastisoles". |
| JP57171093A JPS5874741A (ja) | 1981-10-01 | 1982-10-01 | メチルメタクリレ−トの共重合体からなるプラスチゾル及び電気泳動薄板の被覆法 |
| ZA827227A ZA827227B (en) | 1981-10-01 | 1982-10-01 | Methyl methacrylate copolymer plastisols |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3139090A DE3139090C1 (de) | 1981-10-01 | 1981-10-01 | Plastisole aus Copolymerisaten des Methylmethacrylats mit verbesserter Haftfestigkeit und ihre Verwendung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE3139090C1 true DE3139090C1 (de) | 1983-07-28 |
Family
ID=6143175
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE3139090A Expired DE3139090C1 (de) | 1981-10-01 | 1981-10-01 | Plastisole aus Copolymerisaten des Methylmethacrylats mit verbesserter Haftfestigkeit und ihre Verwendung |
| DE8282106637T Expired DE3274552D1 (en) | 1981-10-01 | 1982-07-23 | Plastisols of copolymers of methylmethacrylate, and their use |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE8282106637T Expired DE3274552D1 (en) | 1981-10-01 | 1982-07-23 | Plastisols of copolymers of methylmethacrylate, and their use |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4558084A (enExample) |
| EP (1) | EP0076368B1 (enExample) |
| JP (1) | JPS5874741A (enExample) |
| AT (1) | ATE24011T1 (enExample) |
| DE (2) | DE3139090C1 (enExample) |
| ES (1) | ES8502465A1 (enExample) |
| ZA (1) | ZA827227B (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4008980A1 (de) * | 1990-03-21 | 1991-09-26 | Staedtler Fa J S | Plastische masse zum kneten, modellieren, basteln und dekorieren sowie verfahren zu deren herstellung |
| EP0533026A3 (en) * | 1991-09-17 | 1993-11-24 | Roehm Gmbh | Plastisol system exhibiting improved adhesion |
| DE102007040304A1 (de) | 2007-08-24 | 2009-02-26 | Evonik Röhm Gmbh | Verbesserte Bindemittel für Plastisole |
| EP2236162A2 (de) | 2009-04-02 | 2010-10-06 | InnoTERE GmbH | Bioaktiver Knochenzement und Verfahren zu seiner Herstellung |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3308925A1 (de) * | 1983-03-12 | 1984-09-13 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung lagerstabiler plastisole und organosole |
| DE3402016A1 (de) * | 1984-01-21 | 1985-07-25 | Röhm GmbH, 6100 Darmstadt | Zur beschichtung geeignete polymerpraeparationen mit verbesserter haftung und ihre herstellung |
| US5475056A (en) * | 1991-04-19 | 1995-12-12 | Teroson Gmbh | Plastisols which prevent the yellowing of top coats, process for their preparation and use |
| GB9122594D0 (en) * | 1991-10-24 | 1991-12-04 | Ici Plc | Plastisol compositions |
| FI934406A0 (fi) * | 1992-02-11 | 1993-10-07 | Riverwood Int Corp | Baerfodral foer staplade ariklar |
| DE19542746A1 (de) | 1995-11-16 | 1997-05-22 | Roehm Gmbh | Plastisole auf der Grundlage von durch Weichmacherzusatz weichgemachte Polymermassen |
| DE19914605A1 (de) * | 1999-03-30 | 2000-10-05 | Roehm Gmbh | Polyalkylmethacrylat-Plastisole mit verbesserten Fließeigenschaften |
| DE10058297A1 (de) * | 2000-11-29 | 2002-07-18 | Contitech Holding Gmbh | Kautschukmischung mit Schichtsilikaten |
| DE102004009777A1 (de) * | 2004-02-20 | 2005-09-08 | J. S. Staedtler Gmbh & Co. Kg | Plastische Masse zum Kneten, Modellieren und Dekorieren sowie Verfahren zu deren Herstellung |
| CA2608029C (en) * | 2005-05-27 | 2014-01-28 | Lucite International Uk Limited | An embedment casting composition |
| DE102006038715A1 (de) * | 2006-08-18 | 2008-02-21 | Evonik Röhm Gmbh | Plastisole auf Basis eines Methylmethacrylat-Mischpolymerisats |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2454235C3 (de) * | 1974-11-15 | 1982-01-07 | Teroson Gmbh, 6900 Heidelberg | Plastisole auf der Basis von Acrylat-Polymerisaten |
| GB1516510A (en) * | 1974-11-15 | 1978-07-05 | Teroson Gmbh | Plastisol of an organic polymer and a plasticiser |
| DE2529732C3 (de) * | 1975-07-03 | 1982-11-04 | Teroson Gmbh, 6900 Heidelberg | Plastisole auf der Basis von Acrylatpolymerisaten |
| US4210567A (en) * | 1974-11-15 | 1980-07-01 | Teroson G.M.B.H. | Plastisol of an acrylate polymer and a plasticizer |
| US4020966A (en) * | 1975-03-28 | 1977-05-03 | W. R. Grace & Co. | Plastisol composition and container closure gasket made therefrom |
| DE2812015C3 (de) * | 1977-03-22 | 1984-05-24 | E.I. Du Pont De Nemours And Co., Wilmington, Del. | Thermisch verschmelzbare Acrylharzorganosoldispersionen und ihre Verwendung |
| DE2722752C3 (de) * | 1977-05-20 | 1987-10-22 | Röhm GmbH, 6100 Darmstadt | Plastisole auf Basis von Methylmethacrylat-Mischpolymerisaten |
| JPS5525455A (en) * | 1978-08-11 | 1980-02-23 | Kanegafuchi Chem Ind Co Ltd | Gloss coating composition |
| US4342858A (en) * | 1979-07-11 | 1982-08-03 | Nl Industries, Inc. | Polymeric polyelectrolytes |
-
1981
- 1981-10-01 DE DE3139090A patent/DE3139090C1/de not_active Expired
-
1982
- 1982-07-23 AT AT82106637T patent/ATE24011T1/de not_active IP Right Cessation
- 1982-07-23 EP EP82106637A patent/EP0076368B1/de not_active Expired
- 1982-07-23 DE DE8282106637T patent/DE3274552D1/de not_active Expired
- 1982-09-20 US US06/420,040 patent/US4558084A/en not_active Expired - Lifetime
- 1982-09-29 ES ES516078A patent/ES8502465A1/es not_active Expired
- 1982-10-01 ZA ZA827227A patent/ZA827227B/xx unknown
- 1982-10-01 JP JP57171093A patent/JPS5874741A/ja active Granted
Non-Patent Citations (1)
| Title |
|---|
| NICHTS-ERMITTELT * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4008980A1 (de) * | 1990-03-21 | 1991-09-26 | Staedtler Fa J S | Plastische masse zum kneten, modellieren, basteln und dekorieren sowie verfahren zu deren herstellung |
| EP0533026A3 (en) * | 1991-09-17 | 1993-11-24 | Roehm Gmbh | Plastisol system exhibiting improved adhesion |
| DE102007040304A1 (de) | 2007-08-24 | 2009-02-26 | Evonik Röhm Gmbh | Verbesserte Bindemittel für Plastisole |
| EP2236162A2 (de) | 2009-04-02 | 2010-10-06 | InnoTERE GmbH | Bioaktiver Knochenzement und Verfahren zu seiner Herstellung |
| DE102010003547A1 (de) | 2009-04-02 | 2010-10-14 | Innotere Gmbh | Bioaktiver Knochenzement und Verfahren zu seiner Herstellung |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0076368B1 (de) | 1986-12-03 |
| DE3274552D1 (en) | 1987-01-15 |
| US4558084A (en) | 1985-12-10 |
| ES516078A0 (es) | 1985-01-16 |
| ZA827227B (en) | 1983-11-30 |
| ES8502465A1 (es) | 1985-01-16 |
| EP0076368A3 (en) | 1984-03-28 |
| ATE24011T1 (de) | 1986-12-15 |
| EP0076368A2 (de) | 1983-04-13 |
| JPS5874741A (ja) | 1983-05-06 |
| JPH0424378B2 (enExample) | 1992-04-24 |
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