DE3112761A1 - Verfahren zur erzeugung eines fuer die methanolsynthese geigneten synthesegases - Google Patents
Verfahren zur erzeugung eines fuer die methanolsynthese geigneten synthesegasesInfo
- Publication number
- DE3112761A1 DE3112761A1 DE19813112761 DE3112761A DE3112761A1 DE 3112761 A1 DE3112761 A1 DE 3112761A1 DE 19813112761 DE19813112761 DE 19813112761 DE 3112761 A DE3112761 A DE 3112761A DE 3112761 A1 DE3112761 A1 DE 3112761A1
- Authority
- DE
- Germany
- Prior art keywords
- gas
- coke oven
- partial oxidation
- oven gas
- synthesis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 81
- 238000000034 method Methods 0.000 title claims abstract description 36
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 31
- 238000003786 synthesis reaction Methods 0.000 title claims abstract description 31
- 239000007789 gas Substances 0.000 claims abstract description 128
- 239000000571 coke Substances 0.000 claims abstract description 74
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 47
- 230000003647 oxidation Effects 0.000 claims abstract description 46
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 9
- 239000001301 oxygen Substances 0.000 claims abstract description 9
- 230000006835 compression Effects 0.000 claims abstract description 4
- 238000007906 compression Methods 0.000 claims abstract description 4
- 238000004140 cleaning Methods 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 10
- 238000005201 scrubbing Methods 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 9
- 239000002351 wastewater Substances 0.000 claims description 9
- 238000006477 desulfuration reaction Methods 0.000 claims description 8
- 230000023556 desulfurization Effects 0.000 claims description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 230000008929 regeneration Effects 0.000 claims description 4
- 238000011069 regeneration method Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 3
- 229910002090 carbon oxide Inorganic materials 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 24
- 229910002092 carbon dioxide Inorganic materials 0.000 description 13
- 238000010586 diagram Methods 0.000 description 11
- 241000196324 Embryophyta Species 0.000 description 7
- 238000000926 separation method Methods 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 238000004939 coking Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000002309 gasification Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000004065 wastewater treatment Methods 0.000 description 2
- 241001122767 Theaceae Species 0.000 description 1
- 206010000210 abortion Diseases 0.000 description 1
- 231100000176 abortion Toxicity 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 229940082150 encore Drugs 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
- C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/04—Methanol
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Industrial Gases (AREA)
- Hydrogen, Water And Hydrids (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19813112761 DE3112761A1 (de) | 1981-03-31 | 1981-03-31 | Verfahren zur erzeugung eines fuer die methanolsynthese geigneten synthesegases |
| JP5026382A JPS57183301A (en) | 1981-03-31 | 1982-03-30 | Manufacture of synthetic gas proper to methanol synthesis |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19813112761 DE3112761A1 (de) | 1981-03-31 | 1981-03-31 | Verfahren zur erzeugung eines fuer die methanolsynthese geigneten synthesegases |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3112761A1 true DE3112761A1 (de) | 1982-10-07 |
| DE3112761C2 DE3112761C2 (enrdf_load_stackoverflow) | 1991-12-19 |
Family
ID=6128844
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19813112761 Granted DE3112761A1 (de) | 1981-03-31 | 1981-03-31 | Verfahren zur erzeugung eines fuer die methanolsynthese geigneten synthesegases |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPS57183301A (enrdf_load_stackoverflow) |
| DE (1) | DE3112761A1 (enrdf_load_stackoverflow) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4321542C1 (de) * | 1993-06-29 | 1994-09-01 | Bfi Entsorgungstech | Verfahren zur getrennten Entfernung von Schwefelverbindungen und CO¶2¶ aus Gas |
| DE102009016402A1 (de) * | 2009-04-07 | 2010-10-14 | Uhde Gmbh | Verfahren und Anlage zur Behandlung von Synthesegas aus der Vergasung Kohlenstoff-haltiger Feststoffe |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4328685C2 (de) * | 1993-08-26 | 2003-10-30 | Thyssen Krupp Encoke Gmbh | Verfahren zur Partialoxidation von Koksofengas |
| CN100408530C (zh) * | 2004-12-10 | 2008-08-06 | 昆山市迪昆精细化工公司 | 以焦炉气为原料生产甲醇的方法 |
| JP6395493B2 (ja) * | 2014-08-06 | 2018-09-26 | 新日鐵住金株式会社 | 高炉へのガス供給装置及び方法 |
| CN104974014B (zh) * | 2015-07-03 | 2017-07-11 | 赛鼎工程有限公司 | 一种生产甲醇的方法 |
| CN105061264B (zh) * | 2015-07-31 | 2017-09-26 | 赛鼎工程有限公司 | 合成气与焦炉煤气生产低碳醇并联产天然气和尿素的方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB266410A (en) * | 1925-10-23 | 1927-02-23 | Basf Ag | Improvements in the manufacture and production of methanol and other oxygenated organic compounds |
| DE1470697A1 (de) * | 1964-10-27 | 1969-04-10 | Bergwerksverband Gmbh | Verfahren zur Reinigung von rohen Kohlendestillationsgasen unter Erzeugung eines an Kohlenoxyd,Wasserstoff und gegebenenfalls Stickstoff reichen Brenngases |
| DE1810601B1 (de) * | 1968-11-23 | 1970-11-12 | Didier Werke Ag | Verfahren zur Kuehlung und Waschung von Koksofengasen |
| DE2065892B2 (de) * | 1969-11-21 | 1980-11-20 | Texaco Development Corp., White Plains, N.Y. (V.St.A.) | Verfahren zur gleichzeitigen Herstellung von zwei getrennt anfallenden Synthese-Gasströmen |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6048487B2 (ja) * | 1976-03-22 | 1985-10-28 | 千代田化工建設株式会社 | オレフインと還元ガスの製造方法 |
| DE2733785A1 (de) * | 1977-07-27 | 1979-02-08 | Didier Eng | Verfahren zur weiterverarbeitung von koksofengas |
-
1981
- 1981-03-31 DE DE19813112761 patent/DE3112761A1/de active Granted
-
1982
- 1982-03-30 JP JP5026382A patent/JPS57183301A/ja active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB266410A (en) * | 1925-10-23 | 1927-02-23 | Basf Ag | Improvements in the manufacture and production of methanol and other oxygenated organic compounds |
| DE1470697A1 (de) * | 1964-10-27 | 1969-04-10 | Bergwerksverband Gmbh | Verfahren zur Reinigung von rohen Kohlendestillationsgasen unter Erzeugung eines an Kohlenoxyd,Wasserstoff und gegebenenfalls Stickstoff reichen Brenngases |
| DE1810601B1 (de) * | 1968-11-23 | 1970-11-12 | Didier Werke Ag | Verfahren zur Kuehlung und Waschung von Koksofengasen |
| DE2065892B2 (de) * | 1969-11-21 | 1980-11-20 | Texaco Development Corp., White Plains, N.Y. (V.St.A.) | Verfahren zur gleichzeitigen Herstellung von zwei getrennt anfallenden Synthese-Gasströmen |
Non-Patent Citations (2)
| Title |
|---|
| MECKEL, J.F. u. FLOCKENHAUS, C.: Techn. Mitt. 73, H. 10, Okt. 1980, S. 830-836 * |
| WINNACKER-KÜCHLER: Chemische Technologie, Bd. 3, Org. Techn. I, 2. Aufl., 1959, S. 63-64 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4321542C1 (de) * | 1993-06-29 | 1994-09-01 | Bfi Entsorgungstech | Verfahren zur getrennten Entfernung von Schwefelverbindungen und CO¶2¶ aus Gas |
| DE102009016402A1 (de) * | 2009-04-07 | 2010-10-14 | Uhde Gmbh | Verfahren und Anlage zur Behandlung von Synthesegas aus der Vergasung Kohlenstoff-haltiger Feststoffe |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3112761C2 (enrdf_load_stackoverflow) | 1991-12-19 |
| JPS57183301A (en) | 1982-11-11 |
| JPH0319161B2 (enrdf_load_stackoverflow) | 1991-03-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8363 | Opposition against the patent | ||
| 8331 | Complete revocation |