DE3001911A1 - Verfahren zur herstellung von methacrolein und methacrylsaeure - Google Patents

Verfahren zur herstellung von methacrolein und methacrylsaeure

Info

Publication number
DE3001911A1
DE3001911A1 DE19803001911 DE3001911A DE3001911A1 DE 3001911 A1 DE3001911 A1 DE 3001911A1 DE 19803001911 DE19803001911 DE 19803001911 DE 3001911 A DE3001911 A DE 3001911A DE 3001911 A1 DE3001911 A1 DE 3001911A1
Authority
DE
Germany
Prior art keywords
catalyst
acid
reaction
elements
yield
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE19803001911
Other languages
German (de)
English (en)
Inventor
Mutsumi Matsumoto
Kouichi Wada
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Kayaku Co Ltd
Original Assignee
Nippon Kayaku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP558479A external-priority patent/JPS55100324A/ja
Priority claimed from JP719279A external-priority patent/JPS55100325A/ja
Application filed by Nippon Kayaku Co Ltd filed Critical Nippon Kayaku Co Ltd
Publication of DE3001911A1 publication Critical patent/DE3001911A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/65—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
DE19803001911 1979-01-23 1980-01-19 Verfahren zur herstellung von methacrolein und methacrylsaeure Withdrawn DE3001911A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP558479A JPS55100324A (en) 1979-01-23 1979-01-23 Preparation of methacrolein and methacrylic acid
JP719279A JPS55100325A (en) 1979-01-26 1979-01-26 Preparation of methacrolein and methacrylic acid

Publications (1)

Publication Number Publication Date
DE3001911A1 true DE3001911A1 (de) 1980-07-31

Family

ID=26339547

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19803001911 Withdrawn DE3001911A1 (de) 1979-01-23 1980-01-19 Verfahren zur herstellung von methacrolein und methacrylsaeure

Country Status (13)

Country Link
US (1) US4320227A (US08063081-20111122-C00044.png)
CA (1) CA1125785A (US08063081-20111122-C00044.png)
CS (1) CS226406B2 (US08063081-20111122-C00044.png)
DE (1) DE3001911A1 (US08063081-20111122-C00044.png)
ES (1) ES8101533A1 (US08063081-20111122-C00044.png)
FR (1) FR2447364A1 (US08063081-20111122-C00044.png)
GB (1) GB2045635B (US08063081-20111122-C00044.png)
IT (1) IT1129709B (US08063081-20111122-C00044.png)
NL (1) NL8000441A (US08063081-20111122-C00044.png)
RO (1) RO80120B (US08063081-20111122-C00044.png)
SE (1) SE437150B (US08063081-20111122-C00044.png)
SU (1) SU1055329A3 (US08063081-20111122-C00044.png)
YU (1) YU41495B (US08063081-20111122-C00044.png)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0046333A1 (en) * 1980-08-05 1982-02-24 The Standard Oil Company Bismuth-containing catalyst compositions of use in the oxidation of methacrolein, production thereof and oxidation of methacrolein utilizing them
EP0047581A1 (en) * 1980-09-05 1982-03-17 The Standard Oil Company A process for the production of olefinic acids and esters by catalytic oxydehydrogenation
EP0047578A1 (en) * 1980-09-05 1982-03-17 The Standard Oil Company Process for the production of unsaturated acids and esters
EP0051348A1 (en) * 1980-08-05 1982-05-12 The Standard Oil Company Phosphomolybdic-acid catalysts, production thereof and their use in the oxidation of methacrolein to methacrylic acid
EP0060066A1 (en) * 1981-03-02 1982-09-15 The Standard Oil Company Process for the production of methacrylic acid from isobutyraldehyde employing a catalyst
EP0079432A1 (de) * 1981-10-27 1983-05-25 Hüls Aktiengesellschaft Verfahren zur Herstellung von Methacrylsäure aus Isobutyraldehyd
EP0168826A1 (en) * 1984-07-18 1986-01-22 Mitsubishi Rayon Co., Ltd. Process for producing methacrolein and methacrylic acid

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS552619A (en) * 1978-06-21 1980-01-10 Nippon Kayaku Co Ltd Preparation of methacrylic acid and catalyst
DE3030243A1 (de) * 1980-08-09 1982-03-18 Basf Ag, 6700 Ludwigshafen Oxidationskatalysator insbesondere fuer die herstellung von methacrylsaeure durch gasphasenoxidation von methacrolein
US4347163A (en) * 1980-10-03 1982-08-31 Standard Oil Company Te-containing methacrolein oxidation catalysts and their use
EP0058046B1 (en) * 1981-02-05 1984-08-01 Ube Industries, Ltd. Process for producing methacrolein and methacrylic acid
US4522934A (en) * 1981-04-27 1985-06-11 Atlantic Richfield Company Vanadotungstomolybdophosphoric acid oxidation catalyst
US4596784A (en) * 1982-06-07 1986-06-24 Rohm And Haas Company Catalyst compositions and their use for the preparation of unsaturated carboxylic acids
CA1199905A (en) * 1982-06-07 1986-01-28 William J. Kennelly Catalyst compositions and their use for the preparation of unsaturated carboxylic acids
JPS5916850A (ja) * 1982-07-20 1984-01-28 Mitsubishi Chem Ind Ltd メタクリル酸および／またはメタクリル酸エステルの製造方法
US4410723A (en) * 1982-08-09 1983-10-18 Ashland Oil, Inc. Oxydehydrogenation process
JPS59115750A (ja) * 1982-12-22 1984-07-04 Nippon Shokubai Kagaku Kogyo Co Ltd メタクリル酸合成用触媒
DE3772655D1 (de) * 1986-01-08 1991-10-10 Mitsubishi Rayon Co Herstellung von methakrylsaeure und katalysatoren dazu.
JPH0753686B2 (ja) * 1986-10-27 1995-06-07 三菱レイヨン株式会社 メタクリル酸の製造法
CN1597080A (zh) * 2002-01-11 2005-03-23 三菱化学株式会社 使用多管反应器的气相催化氧化法
US7851397B2 (en) * 2005-07-25 2010-12-14 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649112B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US7649111B2 (en) * 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
US7732367B2 (en) * 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US8178718B2 (en) * 2007-02-05 2012-05-15 Saudi Basic Industries Corporation Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof
US7799946B2 (en) * 2007-02-14 2010-09-21 Saudi Basic Industries Corporation Process for separating methacrolein from methacrylic acid in a gas phase product from the partial oxidation of isobutene
EP2085376B1 (en) * 2008-01-30 2012-09-05 Evonik Röhm GmbH Process for preparation of high purity methacrylic acid
WO2010074177A1 (ja) * 2008-12-26 2010-07-01 株式会社日本触媒 アクリル酸の製造方法
US8921257B2 (en) 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
US8722940B2 (en) 2012-03-01 2014-05-13 Saudi Basic Industries Corporation High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
CN105772087B (zh) 2014-12-26 2019-03-22 上海华谊新材料有限公司 杂多酸盐催化剂及其制备方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4001316A (en) * 1973-06-15 1977-01-04 Nippon Kayaku Kabushiki Kaisha Method for manufacture of methacrylic acid
GB1464711A (en) * 1974-04-02 1977-02-16 Asahi Glass Co Ltd Process for preparing 3-4-methacrylic acid
JPS573657B2 (US08063081-20111122-C00044.png) * 1974-05-24 1982-01-22

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Chem.Abstr., 1979, 90, 104599b *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0046333A1 (en) * 1980-08-05 1982-02-24 The Standard Oil Company Bismuth-containing catalyst compositions of use in the oxidation of methacrolein, production thereof and oxidation of methacrolein utilizing them
EP0051348A1 (en) * 1980-08-05 1982-05-12 The Standard Oil Company Phosphomolybdic-acid catalysts, production thereof and their use in the oxidation of methacrolein to methacrylic acid
EP0047581A1 (en) * 1980-09-05 1982-03-17 The Standard Oil Company A process for the production of olefinic acids and esters by catalytic oxydehydrogenation
EP0047578A1 (en) * 1980-09-05 1982-03-17 The Standard Oil Company Process for the production of unsaturated acids and esters
EP0060066A1 (en) * 1981-03-02 1982-09-15 The Standard Oil Company Process for the production of methacrylic acid from isobutyraldehyde employing a catalyst
US4358610A (en) 1981-03-02 1982-11-09 The Standard Oil Company Process for the production of methacrylic acid from isobutyraldehyde
EP0079432A1 (de) * 1981-10-27 1983-05-25 Hüls Aktiengesellschaft Verfahren zur Herstellung von Methacrylsäure aus Isobutyraldehyd
EP0168826A1 (en) * 1984-07-18 1986-01-22 Mitsubishi Rayon Co., Ltd. Process for producing methacrolein and methacrylic acid

Also Published As

Publication number Publication date
SE8000535L (sv) 1980-07-24
IT8019363A0 (it) 1980-01-22
RO80120A (ro) 1983-02-15
FR2447364B1 (US08063081-20111122-C00044.png) 1984-05-11
GB2045635B (en) 1983-02-23
US4320227A (en) 1982-03-16
SU1055329A3 (ru) 1983-11-15
FR2447364A1 (fr) 1980-08-22
ES488611A0 (es) 1980-12-16
RO80120B (ro) 1983-02-28
YU310979A (en) 1982-08-31
CA1125785A (en) 1982-06-15
SE437150B (sv) 1985-02-11
GB2045635A (en) 1980-11-05
NL8000441A (nl) 1980-07-25
IT1129709B (it) 1986-06-11
YU41495B (en) 1987-08-31
CS226406B2 (en) 1984-03-19
ES8101533A1 (es) 1980-12-16

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Legal Events

Date Code Title Description
8128 New person/name/address of the agent

Representative=s name: TUERK, D., DIPL.-CHEM. DR.RER.NAT. GILLE, C., DIPL

8110 Request for examination paragraph 44
8125 Change of the main classification

Ipc: C07C 57/055

8139 Disposal/non-payment of the annual fee