FR2447364A1 - Procede pour preparer de la methacroleine et de l'acide methacrylique par oxydation catalytique en phase vapeur de l'aldehyde isobutylique - Google Patents

Procede pour preparer de la methacroleine et de l'acide methacrylique par oxydation catalytique en phase vapeur de l'aldehyde isobutylique

Info

Publication number
FR2447364A1
FR2447364A1 FR8001338A FR8001338A FR2447364A1 FR 2447364 A1 FR2447364 A1 FR 2447364A1 FR 8001338 A FR8001338 A FR 8001338A FR 8001338 A FR8001338 A FR 8001338A FR 2447364 A1 FR2447364 A1 FR 2447364A1
Authority
FR
France
Prior art keywords
xene
methacrylic acid
methacrolein
preparation
elements
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR8001338A
Other languages
English (en)
Other versions
FR2447364B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Kayaku Co Ltd
Original Assignee
Nippon Kayaku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP558479A external-priority patent/JPS55100324A/ja
Priority claimed from JP719279A external-priority patent/JPS55100325A/ja
Application filed by Nippon Kayaku Co Ltd filed Critical Nippon Kayaku Co Ltd
Publication of FR2447364A1 publication Critical patent/FR2447364A1/fr
Application granted granted Critical
Publication of FR2447364B1 publication Critical patent/FR2447364B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/65—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

POUR PRODUIRE DE LA METHACROLEINE ET DE L'ACIDE METHACRYLIQUE, ON UTILISE UN CATALYSEUR AYANT UNE STRUCTURE D'HETEROPOLYACIDE DE FORMULE: MOVPXYO OU MO, V, P ET O REPRESENTENT RESPECTIVEMENT LE MOLYBDENE, LE VANADIUM, LE PHOSPHORE ET L'OXYGENE, X REPRESENTE UN OU PLUSIEURS ELEMENTS CHOISIS PARMI LE CUIVRE, L'ETAIN, LE THORIUM, L'ALUMINIUM, LE GERMANIUM, LE NICKEL, LE FER, LE COBALT, LE ZINC, LE TITANE, LE PLOMB, LE RHENIUM, LE ZIRCONIUM, LE CERIUM, LE CHROME, LE BISMUTH ET L'ARSENIC, Y REPRESENTE UN OU PLUSIEURS ELEMENTS CHOISIS PARMI LE POTASSIUM, LE RUBIDIUM, LE CESIUM ET LE THALLIUM ET A, B, C, D, E ET F REPRESENTENT LE RAPPORT ATOMIQUE DES ELEMENTS OU A EST EGAL A 10, B EST UN NOMBRE EGAL OU INFERIEUR A 6 A L'EXCLUSION DE 0, C EST UN NOMBRE DE 0,5 A 6, D EST UN NOMBRE EGAL OU INFERIEUR A 3 A L'EXCLUSION DE O, E EST UN NOMBRE DE 0 A 0,8 ET F EST UN NOMBRE DETERMINE SELON LA VALENCE ET LE RAPPORT ATOMIQUE DES AUTRES ELEMENTS.
FR8001338A 1979-01-23 1980-01-22 Procede pour preparer de la methacroleine et de l'acide methacrylique par oxydation catalytique en phase vapeur de l'aldehyde isobutylique Granted FR2447364A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP558479A JPS55100324A (en) 1979-01-23 1979-01-23 Preparation of methacrolein and methacrylic acid
JP719279A JPS55100325A (en) 1979-01-26 1979-01-26 Preparation of methacrolein and methacrylic acid

Publications (2)

Publication Number Publication Date
FR2447364A1 true FR2447364A1 (fr) 1980-08-22
FR2447364B1 FR2447364B1 (fr) 1984-05-11

Family

ID=26339547

Family Applications (1)

Application Number Title Priority Date Filing Date
FR8001338A Granted FR2447364A1 (fr) 1979-01-23 1980-01-22 Procede pour preparer de la methacroleine et de l'acide methacrylique par oxydation catalytique en phase vapeur de l'aldehyde isobutylique

Country Status (13)

Country Link
US (1) US4320227A (fr)
CA (1) CA1125785A (fr)
CS (1) CS226406B2 (fr)
DE (1) DE3001911A1 (fr)
ES (1) ES8101533A1 (fr)
FR (1) FR2447364A1 (fr)
GB (1) GB2045635B (fr)
IT (1) IT1129709B (fr)
NL (1) NL8000441A (fr)
RO (1) RO80120B (fr)
SE (1) SE437150B (fr)
SU (1) SU1055329A3 (fr)
YU (1) YU41495B (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0102688A1 (fr) * 1982-06-07 1984-03-14 Rohm And Haas Company Catalyseurs, leur préparation et utilisation pendant l'oxydation d'aldéhydes non saturés en phase vapeur

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS552619A (en) * 1978-06-21 1980-01-10 Nippon Kayaku Co Ltd Preparation of methacrylic acid and catalyst
US4301030A (en) * 1980-08-05 1981-11-17 The Standard Oil Company Bi-containing methacrolein oxidation catalysts
US4301031A (en) * 1980-08-05 1981-11-17 The Standard Oil Company Methacrolein oxidation catalysts
DE3030243A1 (de) * 1980-08-09 1982-03-18 Basf Ag, 6700 Ludwigshafen Oxidationskatalysator insbesondere fuer die herstellung von methacrylsaeure durch gasphasenoxidation von methacrolein
US4307247A (en) * 1980-09-05 1981-12-22 Standard Oil Company Process for the production of unsaturated acids and esters
US4314075A (en) * 1980-09-05 1982-02-02 The Standard Oil Company Process for the production of olefinic acids and esters
US4347163A (en) * 1980-10-03 1982-08-31 Standard Oil Company Te-containing methacrolein oxidation catalysts and their use
DE3260477D1 (en) * 1981-02-05 1984-09-06 Ube Industries Process for producing methacrolein and methacrylic acid
US4358610A (en) * 1981-03-02 1982-11-09 The Standard Oil Company Process for the production of methacrylic acid from isobutyraldehyde
US4522934A (en) * 1981-04-27 1985-06-11 Atlantic Richfield Company Vanadotungstomolybdophosphoric acid oxidation catalyst
DE3142487A1 (de) * 1981-10-27 1983-05-05 Chemische Werke Hüls AG, 4370 Marl Verfahren zur herstellung von methacrylsaeure aus isobutyraldehyd
US4596784A (en) * 1982-06-07 1986-06-24 Rohm And Haas Company Catalyst compositions and their use for the preparation of unsaturated carboxylic acids
JPS5916850A (ja) * 1982-07-20 1984-01-28 Mitsubishi Chem Ind Ltd メタクリル酸および／またはメタクリル酸エステルの製造方法
US4410723A (en) * 1982-08-09 1983-10-18 Ashland Oil, Inc. Oxydehydrogenation process
JPS59115750A (ja) * 1982-12-22 1984-07-04 Nippon Shokubai Kagaku Kogyo Co Ltd メタクリル酸合成用触媒
DE3562482D1 (en) * 1984-07-18 1988-06-09 Mitsubishi Rayon Co Process for producing methacrolein and methacrylic acid
US4803302A (en) * 1986-01-08 1989-02-07 Mitsubishi Rayon Co., Ltd. Process for the production of methacrylic acid
JPH0753686B2 (ja) * 1986-10-27 1995-06-07 三菱レイヨン株式会社 メタクリル酸の製造法
BRPI0306797B1 (pt) * 2002-01-11 2016-07-12 Mitsubishi Chem Corp reator multitubular, e, métodos de oxidação catalítica em fase vapor e para iniciar um reator tipo casco-tubo
US7851397B2 (en) * 2005-07-25 2010-12-14 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649111B2 (en) * 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
US7732367B2 (en) * 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649112B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US8178718B2 (en) * 2007-02-05 2012-05-15 Saudi Basic Industries Corporation Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof
US7799946B2 (en) * 2007-02-14 2010-09-21 Saudi Basic Industries Corporation Process for separating methacrolein from methacrylic acid in a gas phase product from the partial oxidation of isobutene
EP2085376B1 (fr) 2008-01-30 2012-09-05 Evonik Röhm GmbH Procédé pour la préparation d'acide méthacrylique de grande pureté
US8404887B2 (en) 2008-12-26 2013-03-26 Nippon Shokubai Co., Ltd. Process for producing acrylic acid
US8921257B2 (en) 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
US8722940B2 (en) 2012-03-01 2014-05-13 Saudi Basic Industries Corporation High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
CN105772087B (zh) 2014-12-26 2019-03-22 上海华谊新材料有限公司 杂多酸盐催化剂及其制备方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4001316A (en) * 1973-06-15 1977-01-04 Nippon Kayaku Kabushiki Kaisha Method for manufacture of methacrylic acid
GB1464711A (en) * 1974-04-02 1977-02-16 Asahi Glass Co Ltd Process for preparing 3-4-methacrylic acid
JPS573657B2 (fr) * 1974-05-24 1982-01-22

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
ABJP/79 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0102688A1 (fr) * 1982-06-07 1984-03-14 Rohm And Haas Company Catalyseurs, leur préparation et utilisation pendant l'oxydation d'aldéhydes non saturés en phase vapeur

Also Published As

Publication number Publication date
GB2045635A (en) 1980-11-05
SE437150B (sv) 1985-02-11
IT1129709B (it) 1986-06-11
ES488611A0 (es) 1980-12-16
SE8000535L (sv) 1980-07-24
DE3001911A1 (de) 1980-07-31
CA1125785A (fr) 1982-06-15
RO80120B (ro) 1983-02-28
GB2045635B (en) 1983-02-23
US4320227A (en) 1982-03-16
IT8019363A0 (it) 1980-01-22
SU1055329A3 (ru) 1983-11-15
RO80120A (fr) 1983-02-15
CS226406B2 (en) 1984-03-19
FR2447364B1 (fr) 1984-05-11
YU41495B (en) 1987-08-31
NL8000441A (nl) 1980-07-25
ES8101533A1 (es) 1980-12-16
YU310979A (en) 1982-08-31

Similar Documents

Publication Publication Date Title
FR2447364A1 (fr) Procede pour preparer de la methacroleine et de l'acide methacrylique par oxydation catalytique en phase vapeur de l'aldehyde isobutylique
FR2451907A1 (fr) Procede pour produire de l'acide methacrylique par oxydation en phase vapeur de la methacroleine
FR2407022A1 (fr) Procede et catalyseur pour produire de l'acide methacrylique
GB1492267A (en) Production of unsaturated acids from the corresponding aldehydes
FR2443876A1 (fr) Nouveau procede de preparation de l'acide methacrylique
FR2441423A1 (fr) Procede de preparation d'un catalyseur pour l'oxydation des olefines, catalyseur ainsi obtenu et procede d'oxydation des olefines en l'utilisant
JPS5585535A (en) Preparation of methacrolein
JPH03238051A (ja) メタクリル酸製造用触媒の調製法
US4258217A (en) Process for producing methacrolein
FR2407906A1 (fr) Procede d'oxydation catalytique de l'isobutylene
GB1477029A (en) Catalyst compositions especially useful for preparation of unsaturated acids
FR2363372A1 (fr) Catalyseur et procede pour la production d'acide methacrylique par oxydation de la methacroleine
US3840595A (en) Process for the conversion of unsaturated aldehydes to acids
CA2027323A1 (fr) Procede de preparation de catalyseurs pour la fabrication d'acide methacrylique
GB1465916A (en) Preparation of acrylic acid and methacrylic acid
DE3365122D1 (en) Catalysts, their preparation and use in vapour phase oxidation of unsaturated aldehydes
EP0350862A2 (fr) Procédé pour la fabrication de l'acide méthacrylique
US4166190A (en) Process for the preparation of methacrylic acid from methacrolein
FR2441424A1 (fr) Procede de preparation d'un catalyseur pour l'oxydation des olefines, et catalyseur ainsi obtenu et procede d'oxydation des olefines l'utilisant
ES446289A1 (es) Un procedimiento mejorado para la produccion de acido acri- lico o de acido metacrilico.
US5136104A (en) Method for production of substituted benzaldehyde
GB1421956A (en) Catalysts for the conversion of unsaturated aldehydes to acids
JP2814321B2 (ja) メタクリル酸の製造方法
DE2746135C2 (de) Katalysator und dessen Verwendung zur Herstellung von Acrylsäure und Methacrylsäure
ES8300501A1 (es) Un procedimiento de preparacion de catalizadores.

Legal Events

Date Code Title Description
ST Notification of lapse