FR2441424A1 - Procede de preparation d'un catalyseur pour l'oxydation des olefines, et catalyseur ainsi obtenu et procede d'oxydation des olefines l'utilisant - Google Patents

Procede de preparation d'un catalyseur pour l'oxydation des olefines, et catalyseur ainsi obtenu et procede d'oxydation des olefines l'utilisant

Info

Publication number
FR2441424A1
FR2441424A1 FR7927809A FR7927809A FR2441424A1 FR 2441424 A1 FR2441424 A1 FR 2441424A1 FR 7927809 A FR7927809 A FR 7927809A FR 7927809 A FR7927809 A FR 7927809A FR 2441424 A1 FR2441424 A1 FR 2441424A1
Authority
FR
France
Prior art keywords
catalyst
oxidation
olefin
approximately
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR7927809A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese Corp
Original Assignee
Celanese Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Corp filed Critical Celanese Corp
Publication of FR2441424A1 publication Critical patent/FR2441424A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'INVENTION CONCERNE UN PROCEDE DE PREPARATION D'UN CATALYSEUR D'OXYDATION CORRESPONDANT A LA FORMULE: (CF DESSIN DANS BOPI) OU MO, NI, BI, CO, FE, SB, ZN ET O SONT RESPECTIVEMENT LES ELEMENTS DE MOLYBDENE, NICKEL, BISMUTH, COBALT, FER, ANTIMOINE, ZINC ET OXYGENE; M EST AU MOINS UN ELEMENT CHOISI PARMI LE POTASSIUM ET LE RUBIDIUM; ET X REPRESENTE LE NOMBRE D'ATOMES D'OXYGENE ENTRE ENVIRON 35 ET 75, SUFFISANTS POUR SATISFAIRE AUX NECESSITES DE VALENCE DES AUTRES ELEMENTS. SELON L'INVENTION, LE PROCEDE COMPREND LES ETAPES DE MELANGER ET TRANSFORMER EN BOUILLIE, DANS UN MILIEU AQUEUX, RESPECTIVEMENT, LES COMPOSES DE MO, CO, NI, BI, SB, ZN ET M QUI SONT AU MOINS PARTIELLEMENT SOLUBLES DANS L'EAU, AJUSTER LE PH FINAL DU MELANGE EN BOUILLIE AQUEUSE A UNE VALEUR COMPRISE ENTRE ENVIRON 1 ET 5, CONCENTRER LE MELANGE EN BOUILLIE AQUEUSE PAR ENLEVEMENT D'EAU, POUR DONNER UN COPRECIPITE DU CATALYSEUR, CHAUFFER LE COPRECIPITE A UNE TEMPERATURE COMPRISE ENTRE ENVIRON 200 ET 250C EN PRESENCE D'OXYGENE MOLECULAIRE, ET CALCINER LA COMPOSITION DU CATALYSEUR A UNE TEMPERATURE ENTRE ENVIRON 400 ET 600C EN PRESENCE D'OXYGENE MOLECULAIRE. L'INVENTION S'APPLIQUE NOTAMMENT A L'OXYDATION EN PHASE VAPEUR DU PROPYLENE OU DE L'ISOBUTYLENE.
FR7927809A 1978-11-13 1979-11-12 Procede de preparation d'un catalyseur pour l'oxydation des olefines, et catalyseur ainsi obtenu et procede d'oxydation des olefines l'utilisant Withdrawn FR2441424A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/960,202 US4224193A (en) 1978-11-13 1978-11-13 Olefin oxidation catalyst and process for its preparation

Publications (1)

Publication Number Publication Date
FR2441424A1 true FR2441424A1 (fr) 1980-06-13

Family

ID=25502935

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7927809A Withdrawn FR2441424A1 (fr) 1978-11-13 1979-11-12 Procede de preparation d'un catalyseur pour l'oxydation des olefines, et catalyseur ainsi obtenu et procede d'oxydation des olefines l'utilisant

Country Status (8)

Country Link
US (1) US4224193A (fr)
JP (1) JPS5567340A (fr)
BE (1) BE879967A (fr)
CA (1) CA1122960A (fr)
DE (1) DE2943704A1 (fr)
FR (1) FR2441424A1 (fr)
GB (1) GB2036583A (fr)
NL (1) NL7908134A (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0813332B2 (ja) * 1989-09-25 1996-02-14 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸の製造用触媒の調製法
JP3793317B2 (ja) * 1996-05-14 2006-07-05 日本化薬株式会社 触媒及び不飽和アルデヒドおよび不飽和酸の製造方法
US6337424B1 (en) 2000-04-28 2002-01-08 Saudi Basic Industries Corporation Catalysts oxidation of lower olefins to unsaturated aldehydes, methods of making and using the same
US7851397B2 (en) 2005-07-25 2010-12-14 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7732367B2 (en) 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649111B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
US7649112B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US8921257B2 (en) 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
US8722940B2 (en) 2012-03-01 2014-05-13 Saudi Basic Industries Corporation High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE749305A (fr) * 1969-05-02 1970-10-01 Nippon Kayaku Kk Catalyseur d'oxydation et son utilisation (
JPS5112603B1 (fr) * 1971-05-26 1976-04-21
GB1490683A (en) * 1975-03-12 1977-11-02 Mitsubishi Rayon Co Process and a catalyst for producing unsaturated aldehydes unsaturated carboxylic acids or conjugated diene

Also Published As

Publication number Publication date
NL7908134A (nl) 1980-05-16
JPS5567340A (en) 1980-05-21
BE879967A (fr) 1980-05-12
US4224193A (en) 1980-09-23
GB2036583A (en) 1980-07-02
CA1122960A (fr) 1982-05-04
DE2943704A1 (de) 1980-05-22

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