DE3000490C2 - Verfahren zur Herstellung von Erdalkali-Alkoxyalanaten - Google Patents
Verfahren zur Herstellung von Erdalkali-AlkoxyalanatenInfo
- Publication number
- DE3000490C2 DE3000490C2 DE3000490A DE3000490A DE3000490C2 DE 3000490 C2 DE3000490 C2 DE 3000490C2 DE 3000490 A DE3000490 A DE 3000490A DE 3000490 A DE3000490 A DE 3000490A DE 3000490 C2 DE3000490 C2 DE 3000490C2
- Authority
- DE
- Germany
- Prior art keywords
- alkaline earth
- mmol
- hours
- solution
- meq
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 5
- 238000009835 boiling Methods 0.000 claims description 18
- 239000002904 solvent Substances 0.000 claims description 13
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 12
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 125000003545 alkoxy group Chemical group 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 238000000354 decomposition reaction Methods 0.000 claims description 3
- 239000002243 precursor Substances 0.000 claims description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 40
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 12
- 239000012299 nitrogen atmosphere Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 239000000047 product Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000012258 stirred mixture Substances 0.000 description 5
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 3
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- -1 halide des Alkaline earth metal Chemical class 0.000 description 2
- UIICPZFWHBJNIG-UHFFFAOYSA-N sodium;2-methoxyethanolate Chemical compound [Na+].COCC[O-] UIICPZFWHBJNIG-UHFFFAOYSA-N 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910001615 alkaline earth metal halide Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/069—Aluminium compounds without C-aluminium linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/68—Preparation of metal alcoholates
- C07C29/685—Preparation of metal alcoholates by converting O-metal groups to other O-metal groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/68—Preparation of metal alcoholates
- C07C29/70—Preparation of metal alcoholates by converting hydroxy groups to O-metal groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/28—Metal alcoholates
- C07C31/32—Aluminium alcoholates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT19125/79A IT1110389B (it) | 1979-01-08 | 1979-01-08 | Processo per la sintesi di alcossialanati di metalli alcalino terrosi |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3000490A1 DE3000490A1 (de) | 1980-07-31 |
| DE3000490C2 true DE3000490C2 (de) | 1983-10-27 |
Family
ID=11154979
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE3000490A Expired DE3000490C2 (de) | 1979-01-08 | 1980-01-08 | Verfahren zur Herstellung von Erdalkali-Alkoxyalanaten |
Country Status (15)
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4837190A (en) * | 1986-05-09 | 1989-06-06 | Akzo America Inc. | Organic solvent soluble polyvalent metal alkoxy alkoxides |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1689356A (en) * | 1925-11-12 | 1928-10-30 | Chem Fab Auf Actien | Method of producing complex metal alcoholates |
| US3147272A (en) * | 1959-08-18 | 1964-09-01 | Herbert C Brown | Method of preparing partially reduced organic compounds |
| US3060216A (en) * | 1959-12-08 | 1962-10-23 | Basf Ag | Complex metal aluminum hydrides and their production |
| US3281443A (en) * | 1961-02-24 | 1966-10-25 | Continental Oil Co | Preparation and use of dialkoxyaluminum hydride reducing agents |
| GB1064654A (en) * | 1963-10-02 | 1967-04-05 | Snam Spa | Process for preparing complex aluminium hydrides partly substituted with alcoholate groups and compounds so obtained |
| US3652622A (en) * | 1965-11-13 | 1972-03-28 | Ceskoslovenska Akademie Ved | Organically substituted sodium aluminum hydrides and method of making and using the same |
| DE1618223B1 (de) * | 1967-03-23 | 1972-07-20 | Ceskoslovenska Akademie Ved | Verfahren zur Herstellung komplexer organischer Natriumaluminiumhydride |
| US3631083A (en) * | 1970-04-24 | 1971-12-28 | Atlas Chem Ind | Magnesium-aluminum complexes of polyhydroxy compounds and their preparation |
| DE2125855A1 (en) * | 1970-05-26 | 1971-12-09 | Owens Illinois Inc | Metal alkoxides prodn - products used as starting - materials for highly pure spinels and refractories |
| US3761500A (en) * | 1970-05-26 | 1973-09-25 | Owens Illinois Inc | Liquid double alkoxides |
| US3903122A (en) * | 1972-12-11 | 1975-09-02 | Owens Illinois Inc | Liquid octa 2-lower alkoxy ethoxides of aluminum and (magnesium or calcium) |
| CA1062692A (en) * | 1974-05-25 | 1979-09-18 | Itsuho Aishima | Process for polymerizing ethylene |
| GB1525527A (en) * | 1975-12-22 | 1978-09-20 | Asahi Chemical Ind | Method for producing an organomagnesium complex |
| IT1088553B (it) * | 1977-11-17 | 1985-06-10 | Snam Progetti | Processo di sintesi di alcrossiderivati indrurici misti di alluminio e di metalli alcalino-terrosi e prodotti cosi'ottenuti |
-
1979
- 1979-01-08 IT IT19125/79A patent/IT1110389B/it active
- 1979-12-28 NO NO794307A patent/NO794307L/no unknown
- 1979-12-28 US US06/108,225 patent/US4278611A/en not_active Expired - Lifetime
-
1980
- 1980-01-02 DK DK980A patent/DK980A/da not_active Application Discontinuation
- 1980-01-04 SE SE8000076A patent/SE8000076L/xx not_active Application Discontinuation
- 1980-01-04 CA CA000343054A patent/CA1134379A/en not_active Expired
- 1980-01-04 GB GB8000292A patent/GB2040286B/en not_active Expired
- 1980-01-06 EG EG09/80A patent/EG14911A/xx active
- 1980-01-07 FR FR8000235A patent/FR2445836A1/fr active Granted
- 1980-01-07 AT AT0005880A patent/AT376681B/de not_active IP Right Cessation
- 1980-01-08 NL NL8000103A patent/NL8000103A/nl not_active Application Discontinuation
- 1980-01-08 JP JP33480A patent/JPS5594327A/ja active Pending
- 1980-01-08 CS CS80181A patent/CS222659B2/cs unknown
- 1980-01-08 BE BE0/198884A patent/BE881042A/fr not_active IP Right Cessation
- 1980-01-08 DE DE3000490A patent/DE3000490C2/de not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| ATA5880A (de) | 1984-05-15 |
| SE8000076L (sv) | 1980-07-18 |
| US4278611A (en) | 1981-07-14 |
| FR2445836A1 (fr) | 1980-08-01 |
| FR2445836B1 (US06534493-20030318-C00166.png) | 1982-11-26 |
| DK980A (da) | 1980-07-09 |
| IT1110389B (it) | 1985-12-23 |
| DE3000490A1 (de) | 1980-07-31 |
| EG14911A (en) | 1985-06-30 |
| JPS5594327A (en) | 1980-07-17 |
| IT7919125A0 (it) | 1979-01-08 |
| AT376681B (de) | 1984-12-27 |
| BE881042A (fr) | 1980-07-08 |
| NL8000103A (nl) | 1980-07-10 |
| CA1134379A (en) | 1982-10-26 |
| NO794307L (no) | 1980-07-09 |
| GB2040286A (en) | 1980-08-28 |
| GB2040286B (en) | 1983-03-23 |
| CS222659B2 (en) | 1983-07-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OAP | Request for examination filed | ||
| OD | Request for examination | ||
| 8125 | Change of the main classification |
Ipc: C07C 31/32 |
|
| 8126 | Change of the secondary classification |
Ipc: C07F 5/06 |
|
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |