DE2961540D1 - A process for producing methacrylic acid and a catalyst - Google Patents

A process for producing methacrylic acid and a catalyst

Info

Publication number
DE2961540D1
DE2961540D1 DE7979102044T DE2961540T DE2961540D1 DE 2961540 D1 DE2961540 D1 DE 2961540D1 DE 7979102044 T DE7979102044 T DE 7979102044T DE 2961540 T DE2961540 T DE 2961540T DE 2961540 D1 DE2961540 D1 DE 2961540D1
Authority
DE
Germany
Prior art keywords
catalyst
methacrylic acid
producing methacrylic
producing
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE7979102044T
Other languages
English (en)
Inventor
Mutsumi Matsumoto
Yoshimasa Seo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Kayaku Co Ltd
Original Assignee
Nippon Kayaku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=13542366&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE2961540(D1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Nippon Kayaku Co Ltd filed Critical Nippon Kayaku Co Ltd
Application granted granted Critical
Publication of DE2961540D1 publication Critical patent/DE2961540D1/de
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
    • B01J23/686—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
DE7979102044T 1978-06-21 1979-06-20 A process for producing methacrylic acid and a catalyst Expired DE2961540D1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7427478A JPS552619A (en) 1978-06-21 1978-06-21 Preparation of methacrylic acid and catalyst

Publications (1)

Publication Number Publication Date
DE2961540D1 true DE2961540D1 (en) 1982-02-04

Family

ID=13542366

Family Applications (1)

Application Number Title Priority Date Filing Date
DE7979102044T Expired DE2961540D1 (en) 1978-06-21 1979-06-20 A process for producing methacrylic acid and a catalyst

Country Status (4)

Country Link
US (1) US4925980A (de)
EP (1) EP0006248B1 (de)
JP (1) JPS552619A (de)
DE (1) DE2961540D1 (de)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5531006A (en) * 1978-08-25 1980-03-05 Ube Ind Ltd Preparation of methacrylic acid
US4252682A (en) * 1978-12-26 1981-02-24 Halcon Research And Development Corp. Catalyst for producing methacrylic acid
JPS55124734A (en) * 1979-03-22 1980-09-26 Nippon Kayaku Co Ltd Preparation of methacrylic acid
US4419270A (en) * 1980-06-26 1983-12-06 Nippon Shokubai Kagaku Kogyo Co. Ltd. Oxidation catalyst
US4301031A (en) * 1980-08-05 1981-11-17 The Standard Oil Company Methacrolein oxidation catalysts
JPS5745130A (en) * 1980-09-01 1982-03-13 Mitsubishi Rayon Co Ltd Preparation of methacrylic acid
US4358610A (en) * 1981-03-02 1982-11-09 The Standard Oil Company Process for the production of methacrylic acid from isobutyraldehyde
JPS59115750A (ja) * 1982-12-22 1984-07-04 Nippon Shokubai Kagaku Kogyo Co Ltd メタクリル酸合成用触媒
JPS60239439A (ja) * 1984-05-14 1985-11-28 Nippon Shokubai Kagaku Kogyo Co Ltd メタクリル酸の製造方法
JPS615043A (ja) * 1984-06-18 1986-01-10 Nippon Shokubai Kagaku Kogyo Co Ltd メタクリル酸製造用触媒の調製方法
JPS6176436A (ja) * 1984-09-20 1986-04-18 Mitsubishi Rayon Co Ltd 不飽和カルボン酸の製造法
JPH064558B2 (ja) * 1986-01-09 1994-01-19 三菱レイヨン株式会社 メタクリル酸の製造法
KR900002454B1 (ko) * 1986-01-08 1990-04-16 미쯔비시 레이욘 가부시끼가이샤 메타크릴산의 제조방법 및 이 방법에 사용되는 촉매
JPS62161738A (ja) * 1986-01-08 1987-07-17 Mitsubishi Rayon Co Ltd メタクリル酸の製造法
JPS62175436A (ja) * 1986-01-28 1987-08-01 Mitsubishi Rayon Co Ltd メタクリル酸の製造法
JPH064559B2 (ja) * 1986-01-28 1994-01-19 三菱レイヨン株式会社 メタクリル酸の製造法
JPH0791212B2 (ja) * 1988-07-11 1995-10-04 三菱レイヨン株式会社 メタクリル酸の製造法
DE4022212A1 (de) * 1990-07-12 1992-01-16 Basf Ag Massen der allgemeinen formel mo(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)2(pfeil abwaerts)(pfeil hoch)p(pfeil hoch)(pfeil abwaerts)a(pfeil abwaerts)(pfeil hoch)v(pfeil hoch)(pfeil abwaerts)b(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)1(pfeil hoch)(pfeil abwaerts)c(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)2(pfeil hoch)(pfeil abwaerts)d(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)3(pfeil hoch)(pfeil abwaerts)e(pfeil abwaerts)(pfeil hoch)s(pfeil hoch)(pfeil hoch)b(pfeil hoch)(pfeil abwaerts)f(pfeil abwaerts)(pfeil hoch)r(pfeil hoch)(pfeil hoch)e(pfeil hoch)(pfeil abwaerts)g(pfeil abwaerts)(pfeil hoch)s(pfeil hoch)(pfeil abwaerts)h(pfeil abwaerts)(pfeil hoch)o(pfeil hoch)(pfeil abwaerts)n(pfeil abwaerts)
JP2814317B2 (ja) * 1991-06-12 1998-10-22 三菱レイヨン株式会社 メタクリル酸製造用触媒の調製法
TW349033B (en) 1994-05-31 1999-01-01 Nippon Catalytic Chem Ind Catalyst for production of methacrylic acid and method for production of methacrylic acid by the use of the catalysta catalyst for the production of methacrylic acid by the vapor-phase catalytic oxidation and/or oxidative dehydrogenation of at least one compound
GB9807142D0 (en) * 1998-04-02 1998-06-03 Bp Chem Int Ltd Catalyst and process utilising the catalyst
US6339037B1 (en) 1999-04-27 2002-01-15 Nippon Shokubai Co. Ltd Catalysts for methacrylic acid production and process for producing methacrylic acid
KR100569632B1 (ko) 1999-05-13 2006-04-10 가부시키가이샤 닛폰 쇼쿠바이 불포화 알데히드 및 불포화 카르복실산을 제조하기 위한촉매 및 이 촉매를 사용하여 불포화 알데히드 및 불포화카르복실산을 제조하기 위한 방법
JP4185217B2 (ja) 1999-05-25 2008-11-26 株式会社日本触媒 複合酸化物触媒、並びに（メタ）アクロレインおよび（メタ）アクリル酸の製造方法
TWI268806B (en) * 1999-09-15 2006-12-21 Rohm & Haas A catalyst useful for oxidation of alkanes
US6762148B2 (en) 1999-09-17 2004-07-13 Nippon Kayaku Kabushiki Kaisha Catalyst process of making
KR100414806B1 (ko) * 1999-12-24 2004-01-13 삼성아토피나주식회사 메타크릴산의 제조방법
CN1270824C (zh) * 2000-09-21 2006-08-23 日本化药株式会社 生产甲基丙烯酸的催化剂、涂层催化剂及其制造方法
JP3800043B2 (ja) * 2001-06-28 2006-07-19 住友化学株式会社 メタクリル酸製造用触媒、その製造方法およびメタクリル酸の製造方法
TWI341219B (en) 2003-02-20 2011-05-01 Nippon Kayaku Kk Catalyst for producing methacrylic acid and preparation method thereof
US7649111B2 (en) * 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
US7649112B2 (en) * 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US20110137078A1 (en) * 2008-06-02 2011-06-09 Nippon Kayaku Kabushiki Kaisha Catalyst And Method For Producing Unsaturated Aldehyde And Unsaturated Carboxylic Acid
DE102008032200A1 (de) * 2008-07-09 2010-01-21 W.C. Heraeus Gmbh Oxidationskatalysator
JP5593605B2 (ja) * 2008-11-21 2014-09-24 三菱レイヨン株式会社 メタクリル酸製造用触媒およびその製造方法、ならびにメタクリル酸の製造方法
JP4900449B2 (ja) * 2009-10-30 2012-03-21 住友化学株式会社 メタクリル酸製造用触媒の製造方法及びメタクリル酸の製造方法
CN104646056B (zh) * 2013-11-18 2017-01-11 上海华谊丙烯酸有限公司 一种钼磷系杂多酸盐催化剂及其制备方法和用途
EP3945088A1 (de) 2020-07-30 2022-02-02 Röhm GmbH Vorgehen zur minimierung des aktivitätsverlusts bei im kreislaufbetrieb ausgeführten reaktionsschritten

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3875220A (en) * 1973-10-11 1975-04-01 Standard Oil Co Ohio Process for the preparation of methacrylic acid from methacrolein
JPS5529062B2 (de) * 1973-10-31 1980-07-31
GB1487765A (en) * 1973-11-22 1977-10-05 Nippon Zeon Co Process for preparing methacrylic acid and catalyst for use therein
JPS5523815B2 (de) * 1973-11-22 1980-06-25
JPS582933B2 (ja) * 1974-03-14 1983-01-19 ニツポンゼオン カブシキガイシヤ メタクリルサンノ セイゾウホウホウ
DE2460541C3 (de) * 1973-12-29 1979-10-18 Nippon Shokubai Kagaku Kogyo Co. Ltd., Osaka (Japan) Phosphor, Molybdän und Vanadium sowie gegebenenfalls Kupfer, Kobalt, Zirkon, Wismut, Antimon und/oder Arsen enthaltender Oxydkatalysator und dessen Verwendung zur Herstellung von Methacrylsäure
US4113770A (en) * 1974-03-14 1978-09-12 Nippon Zeon Co. Ltd. Process for preparing unsaturated carboxylic acids
JPS5335924B2 (de) * 1974-04-02 1978-09-29
JPS5333569B2 (de) * 1974-04-02 1978-09-14
GB1464711A (en) * 1974-04-02 1977-02-16 Asahi Glass Co Ltd Process for preparing 3-4-methacrylic acid
JPS5826329B2 (ja) * 1974-07-03 1983-06-02 三菱レイヨン株式会社 フホウワシボウサンノ セイゾウホウ
JPS5113715A (en) * 1974-07-16 1976-02-03 Asahi Glass Co Ltd Arufua*beeta fuhowakarubonsanno seizohoho
JPS5413876B2 (de) * 1974-10-23 1979-06-02
GB1489559A (en) * 1975-03-03 1977-10-19 Mitsubishi Rayon Co Catalytic process for the preparation of acrylic acid or methacrylic acid
GB1513335A (en) * 1975-03-17 1978-06-07 Mitsubishi Rayon Co Process and a catalyst for the preparation of unsaturated carboxylic acid
JPS51115414A (en) * 1975-04-03 1976-10-12 Mitsubishi Rayon Co Ltd Process for preparation of unsaturated fatty acids
JPS51130694A (en) * 1975-05-12 1976-11-13 Nippon Kayaku Co Ltd Process for producing methacrolein oxidation catalyst
US4017423A (en) * 1975-08-18 1977-04-12 The Standard Oil Company (Ohio) Process for the preparation of unsaturated acids from unsaturated aldehydes
JPS5262220A (en) * 1975-11-19 1977-05-23 Sumitomo Chem Co Ltd Process for preparation of methacrylic acid
JPS5824419B2 (ja) * 1975-12-03 1983-05-20 三菱レイヨン株式会社 フホウワカルボンサンノ セイゾウホウホウ
JPS52138499A (en) * 1976-05-17 1977-11-18 Mitsubishi Chem Ind Ltd Production of heteropolyacid
JPS6018212B2 (ja) * 1977-06-08 1985-05-09 ジェイエスアール株式会社 メタクリル酸製造用触媒の再生法
JPS5419912A (en) * 1977-07-15 1979-02-15 Sagami Chem Res Center Preparation of methacrylic acid
JPS5924140B2 (ja) * 1977-10-31 1984-06-07 日本化薬株式会社 メタクリル酸の製造法及び触媒
JPS54106418A (en) * 1978-02-03 1979-08-21 Nippon Zeon Co Ltd Preparation of unsaturated carboxylic acid
YU41495B (en) * 1979-01-23 1987-08-31 Nippon Kayaku Kk Process for obtaining methacrolein and methacrylic acid

Also Published As

Publication number Publication date
JPS6214535B2 (de) 1987-04-02
JPS552619A (en) 1980-01-10
EP0006248A1 (de) 1980-01-09
EP0006248B1 (de) 1981-12-09
US4925980A (en) 1990-05-15

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Legal Events

Date Code Title Description
8331 Complete revocation
8368 Opposition refused due to inadmissibility