DE2932797C2 - Ausrüstmittel zur dauerhaften Verbesserung der hydrophilen Eigenschaften und der Schmutzentfernbarkeit eines Fasersubstrats und zur Erzeugung eines dauerhaft haftenden polyoxyethylenhaltigen Siloxanpolymerisats auf der Faseroberfläche - Google Patents
Ausrüstmittel zur dauerhaften Verbesserung der hydrophilen Eigenschaften und der Schmutzentfernbarkeit eines Fasersubstrats und zur Erzeugung eines dauerhaft haftenden polyoxyethylenhaltigen Siloxanpolymerisats auf der FaseroberflächeInfo
- Publication number
- DE2932797C2 DE2932797C2 DE2932797A DE2932797A DE2932797C2 DE 2932797 C2 DE2932797 C2 DE 2932797C2 DE 2932797 A DE2932797 A DE 2932797A DE 2932797 A DE2932797 A DE 2932797A DE 2932797 C2 DE2932797 C2 DE 2932797C2
- Authority
- DE
- Germany
- Prior art keywords
- polyoxyethylene
- water
- treated
- silane
- fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000835 fiber Substances 0.000 title claims description 57
- -1 polyoxyethylene Polymers 0.000 title claims description 46
- 239000000758 substrate Substances 0.000 title claims description 42
- 229920003171 Poly (ethylene oxide) Polymers 0.000 title claims description 27
- 239000003795 chemical substances by application Substances 0.000 title claims description 24
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 title claims description 13
- 230000006872 improvement Effects 0.000 title claims description 5
- 229920000642 polymer Polymers 0.000 title description 6
- 238000004519 manufacturing process Methods 0.000 title description 3
- 229910000077 silane Inorganic materials 0.000 claims description 43
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 42
- 239000002685 polymerization catalyst Substances 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 3
- 239000007859 condensation product Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 46
- 239000007788 liquid Substances 0.000 description 44
- 239000000203 mixture Substances 0.000 description 41
- 239000004744 fabric Substances 0.000 description 36
- 238000000034 method Methods 0.000 description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
- 229920000728 polyester Polymers 0.000 description 15
- 238000005406 washing Methods 0.000 description 11
- 239000000243 solution Substances 0.000 description 10
- 239000004094 surface-active agent Substances 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 239000002689 soil Substances 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 239000005662 Paraffin oil Substances 0.000 description 6
- 235000014121 butter Nutrition 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 239000013068 control sample Substances 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 230000007062 hydrolysis Effects 0.000 description 6
- 238000006460 hydrolysis reaction Methods 0.000 description 6
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 6
- 239000011654 magnesium acetate Substances 0.000 description 6
- 229940069446 magnesium acetate Drugs 0.000 description 6
- 235000011285 magnesium acetate Nutrition 0.000 description 6
- 150000003254 radicals Chemical class 0.000 description 6
- 239000008162 cooking oil Substances 0.000 description 5
- 230000014759 maintenance of location Effects 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 239000000523 sample Substances 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 238000010998 test method Methods 0.000 description 5
- 239000004753 textile Substances 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 229960000583 acetic acid Drugs 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 239000012208 gear oil Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 241000219198 Brassica Species 0.000 description 3
- 235000003351 Brassica cretica Nutrition 0.000 description 3
- 235000003343 Brassica rupestris Nutrition 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- 239000012362 glacial acetic acid Substances 0.000 description 3
- 239000010705 motor oil Substances 0.000 description 3
- 235000010460 mustard Nutrition 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 150000004819 silanols Chemical class 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
- 210000002268 wool Anatomy 0.000 description 3
- IHEDBVUTTQXGSJ-UHFFFAOYSA-M 2-[bis(2-oxidoethyl)amino]ethanolate;titanium(4+);hydroxide Chemical compound [OH-].[Ti+4].[O-]CCN(CC[O-])CC[O-] IHEDBVUTTQXGSJ-UHFFFAOYSA-M 0.000 description 2
- 235000011371 Brassica hirta Nutrition 0.000 description 2
- 244000140786 Brassica hirta Species 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 229940107816 ammonium iodide Drugs 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000002036 drum drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 125000003709 fluoroalkyl group Chemical group 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002964 rayon Substances 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 description 1
- XZXYQEHISUMZAT-UHFFFAOYSA-N 2-[(2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound CC1=CC=C(O)C(CC=2C(=CC=C(C)C=2)O)=C1 XZXYQEHISUMZAT-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 101150065749 Churc1 gene Proteins 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 102100038239 Protein Churchill Human genes 0.000 description 1
- 229920004896 Triton X-405 Polymers 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000005083 alkoxyalkoxy group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000004104 aryloxy group Chemical group 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 150000007514 bases Chemical class 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004063 butyryl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 150000001923 cyclic compounds Chemical class 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 150000004673 fluoride salts Chemical class 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229920001477 hydrophilic polymer Polymers 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 239000011968 lewis acid catalyst Substances 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- KYRKXFXDTJSJAV-UHFFFAOYSA-N oxane;silicon Chemical compound [Si].C1CCOCC1 KYRKXFXDTJSJAV-UHFFFAOYSA-N 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920001291 polyvinyl halide Polymers 0.000 description 1
- 229920000131 polyvinylidene Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000004758 synthetic textile Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2962—Silane, silicone or siloxane in coating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
- Y10T428/2969—Polyamide, polyimide or polyester
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31533—Of polythioether
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2484—Coating or impregnation is water absorbency-increasing or hydrophilicity-increasing or hydrophilicity-imparting
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/008,654 US4207071A (en) | 1979-02-01 | 1979-02-01 | Durable modification of fibrous substrates using a polyoxyethylene-containing silane and articles therefrom |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2932797A1 DE2932797A1 (de) | 1980-08-07 |
| DE2932797C2 true DE2932797C2 (de) | 1984-04-05 |
Family
ID=21732892
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2932797A Expired DE2932797C2 (de) | 1979-02-01 | 1979-08-13 | Ausrüstmittel zur dauerhaften Verbesserung der hydrophilen Eigenschaften und der Schmutzentfernbarkeit eines Fasersubstrats und zur Erzeugung eines dauerhaft haftenden polyoxyethylenhaltigen Siloxanpolymerisats auf der Faseroberfläche |
Country Status (8)
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7291570B1 (en) | 2000-06-02 | 2007-11-06 | Milliken & Company | Yarns and fabrics having a wash-durable non-electrically conductive topically applied metal-based finish |
| US4397985A (en) * | 1980-04-04 | 1983-08-09 | Allied Corporation | Polyester yarn finish composition |
| JPS59191292A (ja) * | 1983-04-15 | 1984-10-30 | 松下電工株式会社 | 自動点滅器 |
| JPS62173117U (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1986-04-23 | 1987-11-04 | ||
| US5258227A (en) * | 1987-12-03 | 1993-11-02 | Ppg Industries, Inc. | Chemically treated glass fibers with improved reinforcement properties |
| GB9008423D0 (en) * | 1990-04-12 | 1990-06-13 | Albright & Wilson | Treatment of fabrics |
| US5383903A (en) * | 1992-08-20 | 1995-01-24 | United States Surgical Corporation | Dimethylsiloxane-alkylene oxide copolymer coatings for filaments |
| US5408012A (en) * | 1993-05-27 | 1995-04-18 | Comfort Technologies, Inc. | Polymers having enhanced durable hydrophilicity and durable rewetting properties and process of producing the same |
| US5512319A (en) * | 1994-08-22 | 1996-04-30 | Basf Corporation | Polyurethane foam composite |
| US5672641A (en) * | 1995-01-23 | 1997-09-30 | Ppg Industries, Inc. | Secondary coating compositions for glass fibers, glass fibers coated with the same and composites reinforced therewith |
| US5725951A (en) * | 1995-08-28 | 1998-03-10 | Milliken Research Corporation | Lubricant and soil release finish for yarns |
| US6025284A (en) * | 1997-12-01 | 2000-02-15 | Marco; Francis W. | Sun protective fabric |
| US5968207A (en) * | 1998-02-20 | 1999-10-19 | Milliken & Company | Esterified triclosan derivatives as improved textile antimicrobial agents |
| US6033608A (en) * | 1998-03-11 | 2000-03-07 | Milliken & Company | Method for making foam rubber tree bark-configured articles having manmade textiles backings |
| US6194330B1 (en) * | 1998-07-31 | 2001-02-27 | Milliken & Company | Polymer latex for ultraviolet absorbtion on fabric |
| US6180178B1 (en) | 1998-10-22 | 2001-01-30 | Milliken & Company | Method of producing support garments by applying polyurethane coatings to specific areas of fabric |
| US6263707B1 (en) | 1999-09-20 | 2001-07-24 | Milliken & Company | Opaque heat-moldable circular knit support fabrics having very high spandex content |
| US6640371B2 (en) * | 2000-06-02 | 2003-11-04 | Milliken & Company | Topical incorporation of solid antimicrobial compounds on yarn surfaces through high pressure |
| US6558409B1 (en) | 2001-09-28 | 2003-05-06 | Tyco Healthcare Group Lp | Plasma treated surgical needles and methods for their manufacture |
| US7294357B2 (en) | 2001-09-28 | 2007-11-13 | Tyco Healthcare Group Lp | Plasma coated sutures |
| US7012033B2 (en) * | 2002-12-17 | 2006-03-14 | Milliken And Company | Fluorochemical-containing textile finishes that exhibit wash-durable soil release and moisture wicking properties |
| US7244371B2 (en) * | 2003-09-11 | 2007-07-17 | Xinggao Fang | Compositions and methods for treating a textile using such compositions |
| US20090246258A1 (en) * | 2008-03-28 | 2009-10-01 | Piyush Shukla | Antimicrobial and odor adsorbing textile |
| US10370789B2 (en) | 2008-06-30 | 2019-08-06 | Bar Ilan University | Sonochemical coating of textiles with metal oxide nanoparticles for antimicrobial fabrics |
| ES2612907T3 (es) * | 2008-06-30 | 2017-05-19 | Bar-Ilan University | Recubrimiento sonoquímico de textiles con nanopartículas de óxidos metálicos para tejidos antimicrobianos |
| CN102965910B (zh) * | 2012-09-11 | 2014-12-24 | 陕西科技大学 | 一种超疏水涤纶纺织品的制备方法 |
| CN103074768A (zh) * | 2012-12-17 | 2013-05-01 | 陕西科技大学 | 一种超耐用超疏水纺织品及其制备方法 |
| JP5910530B2 (ja) * | 2013-02-15 | 2016-04-27 | 信越化学工業株式会社 | 親水化処理基材の製造方法 |
| CN103114436B (zh) * | 2013-03-08 | 2014-12-10 | 天津微能新材料有限公司 | 一种超疏水织物的制备方法及超疏水功能织物 |
| EP2994475B1 (en) * | 2013-05-08 | 2018-09-05 | Dow Silicones Corporation | Hydrophilic organosilanes |
| CA3068866A1 (en) | 2017-06-26 | 2019-01-03 | Dow Silicones Corporation | Silicone-polyether copolymer, method of preparing same, and sealant comprising same |
| US11220086B2 (en) | 2018-04-13 | 2022-01-11 | Amtex Innovations Llc | Stitchbonded, washable nonwoven towels and method for making |
| US11884899B2 (en) | 2018-06-01 | 2024-01-30 | Amtex Innovations Llc | Methods of laundering stitchbonded nonwoven towels using a soil release polymer |
| US10822578B2 (en) | 2018-06-01 | 2020-11-03 | Amtex Innovations Llc | Methods of washing stitchbonded nonwoven towels using a soil release polymer |
| EP3802770A1 (en) | 2018-06-01 | 2021-04-14 | Amtex Innovations LLC | Methods of washing stitchbonded nonwoven towels using a soil release polymer |
| US11760841B2 (en) | 2018-12-21 | 2023-09-19 | Dow Silicones Corporation | Silicone-polycarbonate copolymer, sealants comprising same, and related methods |
| KR102813023B1 (ko) | 2018-12-21 | 2025-05-28 | 다우 실리콘즈 코포레이션 | 실리콘-폴리아크릴레이트 공중합체, 이를 포함하는 밀봉제 및 관련된 방법 |
| KR102412214B1 (ko) | 2018-12-21 | 2022-06-23 | 다우 실리콘즈 코포레이션 | 실리콘-폴리에스테르 공중합체, 이를 포함하는 밀봉제 및 관련된 방법 |
| US11807775B2 (en) | 2018-12-21 | 2023-11-07 | Dow Silicones Corporation | Silicone-organic copolymer, sealants comprising same, and related methods |
| CN114870834B (zh) * | 2022-05-17 | 2023-07-18 | 安徽紫朔环境工程技术有限公司 | 一种陶瓷滤管用耐磨催化剂涂层 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA703563A (en) * | 1965-02-09 | Imperial Chemical Industries Limited | Treatment of textile materials | |
| GB804369A (en) * | 1954-03-22 | 1958-11-12 | Union Carbide Corp | Siloxane-oxyalkylene block copolymers |
| GB802688A (en) * | 1954-06-10 | 1958-10-08 | Union Carbide Corp | Improvements in or relating to organo-silicon compounds |
| BE618428A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1961-06-01 | |||
| DE1249530B (de) * | 1963-07-24 | 1968-03-14 | 7arbenfabriken Bayer Aktiengesellschaft, 090 Leverkusen | Verfahren zur Herstellung von Acyloxyalkylmercaptomethylsiloxanen |
| US3364059A (en) * | 1966-06-01 | 1968-01-16 | Owens Corning Fiberglass Corp | Glass fiber-elastomeric systems treated with mercaptan-containing organo silane anchoring agents |
| US3565845A (en) * | 1968-09-18 | 1971-02-23 | Union Carbide Corp | Siloxane-polyoxyalkylene block copolymers containing methoxysiloxy groups |
| US3639156A (en) * | 1970-05-19 | 1972-02-01 | Us Agriculture | Siloxane polymers for soil-repellent and soil-release textile finishes |
| CA1101743A (en) * | 1974-05-24 | 1981-05-26 | Kevin M. Foley | Organo silane coupling agents |
| US4062693A (en) * | 1976-09-29 | 1977-12-13 | Union Carbide Corporation | Dry liquid alumina trihydrate concentrates |
| US4110227A (en) * | 1977-09-19 | 1978-08-29 | Basf Wyandotte Corporation | Oxidation stable polyoxyalkylene fiber lubricants |
-
1979
- 1979-02-01 US US06/008,654 patent/US4207071A/en not_active Expired - Lifetime
- 1979-07-05 CA CA331,220A patent/CA1129159A/en not_active Expired
- 1979-08-13 DE DE2932797A patent/DE2932797C2/de not_active Expired
- 1979-08-21 IT IT25200/79A patent/IT1123549B/it active
- 1979-09-03 JP JP11272179A patent/JPS55103367A/ja active Granted
- 1979-09-20 GB GB7932730A patent/GB2040974B/en not_active Expired
-
1980
- 1980-01-29 CH CH70680A patent/CH657739GA3/de unknown
- 1980-01-31 FR FR8002133A patent/FR2447992A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| IT7925200A0 (it) | 1979-08-21 |
| DE2932797A1 (de) | 1980-08-07 |
| JPS5740271B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1982-08-26 |
| JPS55103367A (en) | 1980-08-07 |
| FR2447992A1 (fr) | 1980-08-29 |
| US4207071A (en) | 1980-06-10 |
| CA1129159A (en) | 1982-08-10 |
| GB2040974A (en) | 1980-09-03 |
| FR2447992B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1981-10-16 |
| GB2040974B (en) | 1983-05-05 |
| CH657739GA3 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1986-09-30 |
| IT1123549B (it) | 1986-04-30 |
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