DE2902706C2 - Verfahren zur Regelung der Ammoniakeinblasung bei einem Trockenverfahren zur Abgasdenitrierung - Google Patents
Verfahren zur Regelung der Ammoniakeinblasung bei einem Trockenverfahren zur AbgasdenitrierungInfo
- Publication number
- DE2902706C2 DE2902706C2 DE2902706A DE2902706A DE2902706C2 DE 2902706 C2 DE2902706 C2 DE 2902706C2 DE 2902706 A DE2902706 A DE 2902706A DE 2902706 A DE2902706 A DE 2902706A DE 2902706 C2 DE2902706 C2 DE 2902706C2
- Authority
- DE
- Germany
- Prior art keywords
- exhaust gas
- ratio
- temperature
- ammonia
- signal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 33
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title claims description 24
- 229910021529 ammonia Inorganic materials 0.000 title claims description 12
- 230000001105 regulatory effect Effects 0.000 title claims description 7
- 238000001035 drying Methods 0.000 title claims description 4
- 230000008569 process Effects 0.000 title description 12
- 238000002347 injection Methods 0.000 title description 7
- 239000007924 injection Substances 0.000 title description 7
- 239000007789 gas Substances 0.000 claims description 68
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 32
- 238000002485 combustion reaction Methods 0.000 claims description 14
- 230000008859 change Effects 0.000 claims description 11
- 238000007664 blowing Methods 0.000 claims description 2
- LRDAUUGUXQIHED-UHFFFAOYSA-N N.[N]=O Chemical compound N.[N]=O LRDAUUGUXQIHED-UHFFFAOYSA-N 0.000 claims 1
- 229920006328 Styrofoam Polymers 0.000 claims 1
- 239000008261 styrofoam Substances 0.000 claims 1
- 239000003054 catalyst Substances 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 10
- 230000003197 catalytic effect Effects 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000000446 fuel Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 230000033228 biological regulation Effects 0.000 description 3
- 238000012937 correction Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000009423 ventilation Methods 0.000 description 3
- 241001233037 catfish Species 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000009795 derivation Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 238000007726 management method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8696—Controlling the catalytic process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/56—Nitrogen oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
- Chimneys And Flues (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP583578A JPS5499771A (en) | 1978-01-24 | 1978-01-24 | Controlling method for ammonia injection at dry process exhaust gas dieitration method |
Publications (2)
Publication Number | Publication Date |
---|---|
DE2902706A1 DE2902706A1 (de) | 1979-07-26 |
DE2902706C2 true DE2902706C2 (de) | 1984-02-16 |
Family
ID=11622084
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE2902706A Expired DE2902706C2 (de) | 1978-01-24 | 1979-01-24 | Verfahren zur Regelung der Ammoniakeinblasung bei einem Trockenverfahren zur Abgasdenitrierung |
Country Status (5)
Country | Link |
---|---|
US (1) | US4314345A (en, 2012) |
JP (1) | JPS5499771A (en, 2012) |
DE (1) | DE2902706C2 (en, 2012) |
ES (1) | ES477443A1 (en, 2012) |
FR (1) | FR2414949A1 (en, 2012) |
Families Citing this family (49)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5940051B2 (ja) * | 1979-07-11 | 1984-09-27 | 株式会社荏原製作所 | 電子線照射排ガス処理装置 |
US4473537A (en) * | 1982-12-27 | 1984-09-25 | General Electric Company | Ammonia control system for NOx emission control for gas turbine exhaust |
US4473536A (en) * | 1982-12-27 | 1984-09-25 | General Electric Company | Catalytic pollution control system for gas turbine exhaust |
DE3337793A1 (de) * | 1983-10-18 | 1985-05-02 | L. & C. Steinmüller GmbH, 5270 Gummersbach | Verfahren zur regelung der zugabemenge an reduktionsmittel bei der katalytischen reduktion von in rauchgasen enthaltenem no(pfeil abwaerts)x(pfeil abwaerts) |
AT382089B (de) * | 1985-04-05 | 1987-01-12 | Waagner Biro Ag | Verfahren und einrichtung zur reinigung von mit staeuben und schadgasen verunreinigten abgasen |
JPS61257222A (ja) * | 1985-05-10 | 1986-11-14 | Ishikawajima Harima Heavy Ind Co Ltd | 脱硝装置におけるアンモニア供給量制御装置 |
AT384958B (de) * | 1985-05-28 | 1988-02-10 | Waagner Biro Ag | Verfahren und einrichtung zur reinigung von mit staeuben und schadgasen verunreinigten abgasen |
JPS6219229A (ja) * | 1985-07-16 | 1987-01-28 | Babcock Hitachi Kk | アンモニアの注入量制御装置 |
JPS6233532A (ja) * | 1985-08-06 | 1987-02-13 | Toshiba Corp | 排ガス脱硝制御装置 |
DE3604045C1 (de) * | 1986-02-08 | 1987-01-29 | Steag Ag | Verfahren zum Abscheiden von Stickstoffoxiden aus Rauchgasen |
JPH0667453B2 (ja) * | 1986-02-12 | 1994-08-31 | バブコツク日立株式会社 | 脱硝装置 |
JPS6344924A (ja) * | 1986-08-11 | 1988-02-25 | Takuma Co Ltd | 排気ガスの脱硝処理方法 |
DE3677985D1 (de) | 1986-10-07 | 1991-04-11 | Nippon Kokan Kk | Methode und einrichtung zur regelung der denitration von abgasen. |
US5057293A (en) * | 1987-02-13 | 1991-10-15 | Fuel Tech, Inc. | Multi-stage process for reducing the concentration of pollutants in an effluent |
US4780289A (en) * | 1987-05-14 | 1988-10-25 | Fuel Tech, Inc. | Process for nitrogen oxides reduction and minimization of the production of other pollutants |
US4877590A (en) * | 1987-03-06 | 1989-10-31 | Fuel Tech, Inc. | Process for nitrogen oxides reduction with minimization of the production of other pollutants |
US5017347A (en) * | 1987-02-13 | 1991-05-21 | Fuel Tech, Inc. | Process for nitrogen oxides reduction and minimization of the production of other pollutants |
WO1991006506A1 (en) * | 1987-03-06 | 1991-05-16 | Fuel Tech, Inc. | System for the efficient reduction of nitrogen oxides in an effluent |
AU1499388A (en) * | 1987-03-06 | 1988-09-26 | Fuel Tech. Inc. | Process for nitrogen oxides reduction with minimization of the production of other pollutants |
DE4117143C2 (de) * | 1991-05-25 | 1995-04-20 | Daimler Benz Ag | Verfahren zur selektiven katalytischen Reduktion von Stickoxiden in Abgasen aus Kraftfahrzeugdieselmotoren |
US5296206A (en) * | 1992-07-31 | 1994-03-22 | Foster Wheeler Energy Corporation | Using flue gas energy to vaporize aqueous reducing agent for reduction of NOx in flue gas |
JPH06205935A (ja) * | 1992-12-25 | 1994-07-26 | Toshiba Corp | 脱硝制御装置 |
ES2119944T3 (es) * | 1993-11-04 | 1998-10-16 | Siemens Ag | Procedimiento y dispositivo para la dosificacion de un reactivo en un medio fluido. |
US5849593A (en) * | 1994-11-04 | 1998-12-15 | Siemens Aktiengesellschaft | Method for metering a reagent into a flowing medium |
US5993049A (en) * | 1995-11-16 | 1999-11-30 | Gas Research Institute | Method and system for calculating mass and energy balance for glass furnace reburn |
DE19624619C1 (de) * | 1996-06-20 | 1997-07-10 | Metallgesellschaft Ag | Verfahren zur Regelung oder Steuerung des Gehaltes an NO¶x¶ in Abgasen, die beim Betrieb von Glasschmelzöfen mit mehreren Brennern, die im Wechsel betrieben werden, anfallen |
JP4087914B2 (ja) * | 1996-07-25 | 2008-05-21 | 日本碍子株式会社 | 脱硝システム及び脱硝方法 |
US6415602B1 (en) | 2000-10-16 | 2002-07-09 | Engelhard Corporation | Control system for mobile NOx SCR applications |
US6852292B2 (en) * | 2002-04-24 | 2005-02-08 | Kleenair Systems, Inc. | Ammonia storage and injection in NOx control |
US7726118B2 (en) * | 2006-09-18 | 2010-06-01 | Ford Global Technologies, Llc | Engine-off ammonia vapor management system and method |
US20080202097A1 (en) * | 2007-02-28 | 2008-08-28 | Caterpillar Inc. | Engine exhaust treatment system |
US7954311B2 (en) * | 2007-03-15 | 2011-06-07 | Ford Global Technologies, Llc | Ammonia vapor management system and method |
US8209956B2 (en) * | 2007-07-31 | 2012-07-03 | Caterpillar Inc. | SCR emissions control system |
US8001769B2 (en) * | 2007-08-20 | 2011-08-23 | Caterpillar Inc. | Control of SCR system having a filtering device |
US7992380B2 (en) * | 2007-08-23 | 2011-08-09 | Caterpillar Inc. | Emission control system implementing reduction agent injection |
US8713917B2 (en) * | 2007-08-30 | 2014-05-06 | GM Global Technology Operations LLC | Method for reducing NH3 release from SCR catalysts during thermal transients |
US8505278B2 (en) * | 2009-04-30 | 2013-08-13 | Cummins Ip, Inc. | Engine system properties controller |
US20090293457A1 (en) * | 2008-05-30 | 2009-12-03 | Grichnik Anthony J | System and method for controlling NOx reactant supply |
US8356471B2 (en) * | 2008-12-05 | 2013-01-22 | Cummins Ip, Inc. | Apparatus, system, and method for controlling reductant dosing in an SCR catalyst system |
US20110036279A1 (en) * | 2009-08-12 | 2011-02-17 | Jeffrey Shallcross | NOx reduction control system for boilers |
US8491845B2 (en) * | 2009-09-10 | 2013-07-23 | Cummins Ip, Inc. | Low temperature selective catalytic reduction catalyst and associated systems and methods |
US8733083B2 (en) | 2010-04-26 | 2014-05-27 | Cummins Filtration Ip, Inc. | SCR catalyst ammonia surface coverage estimation and control |
DE112019007304T5 (de) | 2019-05-09 | 2022-02-17 | Cummins Emission Solutions Inc. | Ventilanordnung für split-flow-katalysator in eng gekoppelter bauweise |
CN110180311B (zh) * | 2019-06-28 | 2021-07-02 | 江苏瑞立环保工程股份有限公司 | 一种垃圾焚烧发电厂的烟气分级处理装置 |
CN111589304B (zh) * | 2020-06-10 | 2022-03-22 | 郑州光力景旭电力技术有限公司 | 基于延时敏感参数的脱硝系统及控制方法、喷氨控制装置 |
CN111905539B (zh) * | 2020-07-23 | 2022-12-13 | 天津国能津能滨海热电有限公司 | 锅炉脱硝喷氨自动调节优化方法及系统 |
CN115095881A (zh) * | 2022-06-02 | 2022-09-23 | 华能国际电力股份有限公司上安电厂 | 一种基于最小二乘法的空气预热器变速运行控制方法及系统 |
CN115155275A (zh) * | 2022-06-06 | 2022-10-11 | 深圳华明环保科技有限公司 | 一种烟气处理工艺 |
CN119847099B (zh) * | 2025-03-19 | 2025-06-06 | 上海全熙环保科技股份有限公司 | 一种锅炉用脱硝控制系统的智能喷氨调节方法 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3599427A (en) * | 1969-09-22 | 1971-08-17 | Ford Motor Co | Exhaust gas purification |
US3846981A (en) * | 1970-10-19 | 1974-11-12 | Nanaimo Enviro Syst Corp | Emission control process and system |
US4208381A (en) * | 1970-12-04 | 1980-06-17 | Hitachi, Ltd. | Method and apparatus for cleaning waste flue gases |
US4188190A (en) * | 1976-03-23 | 1980-02-12 | Kurashiki Boseki Kabushiki Kaisha | Input control method and means for nitrogen oxide removal means |
JPS5372773A (en) * | 1976-12-10 | 1978-06-28 | Hitachi Ltd | Direct reductive denitration method of ammonia |
US4112053A (en) * | 1977-01-04 | 1978-09-05 | Kureha Kagaku Kogyo Kabushiki Kaisha | Dry method for the denitrification of exhaust gas containing nitrogen oxides |
JPS5394258A (en) * | 1977-01-31 | 1978-08-18 | Kurabo Ind Ltd | Control method and apparatus for nitrogen oxides removing apparatus |
-
1978
- 1978-01-24 JP JP583578A patent/JPS5499771A/ja active Granted
-
1979
- 1979-01-23 ES ES477443A patent/ES477443A1/es not_active Expired
- 1979-01-23 FR FR7901588A patent/FR2414949A1/fr active Granted
- 1979-01-24 DE DE2902706A patent/DE2902706C2/de not_active Expired
-
1980
- 1980-07-28 US US06/172,853 patent/US4314345A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US4314345A (en) | 1982-02-02 |
DE2902706A1 (de) | 1979-07-26 |
FR2414949B1 (en, 2012) | 1983-10-14 |
JPS5650609B2 (en, 2012) | 1981-11-30 |
ES477443A1 (es) | 1979-10-16 |
JPS5499771A (en) | 1979-08-06 |
FR2414949A1 (fr) | 1979-08-17 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
OAP | Request for examination filed | ||
OD | Request for examination | ||
8128 | New person/name/address of the agent |
Representative=s name: HENKEL, G., DR.PHIL. FEILER, L., DR.RER.NAT. HAENZ |
|
D2 | Grant after examination | ||
8363 | Opposition against the patent | ||
8320 | Willingness to grant licences declared (paragraph 23) | ||
8365 | Fully valid after opposition proceedings |