DE2842500C2 - - Google Patents
Info
- Publication number
- DE2842500C2 DE2842500C2 DE2842500A DE2842500A DE2842500C2 DE 2842500 C2 DE2842500 C2 DE 2842500C2 DE 2842500 A DE2842500 A DE 2842500A DE 2842500 A DE2842500 A DE 2842500A DE 2842500 C2 DE2842500 C2 DE 2842500C2
- Authority
- DE
- Germany
- Prior art keywords
- bromine
- zinc
- oil
- viscosity
- complex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 80
- 229910052794 bromium Inorganic materials 0.000 claims description 79
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 78
- ZRXYMHTYEQQBLN-UHFFFAOYSA-N [Br].[Zn] Chemical compound [Br].[Zn] ZRXYMHTYEQQBLN-UHFFFAOYSA-N 0.000 claims description 25
- 230000031709 bromination Effects 0.000 claims description 20
- 238000005893 bromination reaction Methods 0.000 claims description 20
- 239000000126 substance Substances 0.000 claims description 20
- 239000007788 liquid Substances 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 14
- 239000007787 solid Substances 0.000 claims description 7
- 125000001246 bromo group Chemical group Br* 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 239000003921 oil Substances 0.000 description 62
- 239000003792 electrolyte Substances 0.000 description 32
- VNDYJBBGRKZCSX-UHFFFAOYSA-L zinc bromide Chemical compound Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 description 23
- 150000003839 salts Chemical class 0.000 description 21
- 210000004027 cell Anatomy 0.000 description 19
- 239000008139 complexing agent Substances 0.000 description 16
- 239000012071 phase Substances 0.000 description 14
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 10
- 239000011701 zinc Substances 0.000 description 10
- 229910052725 zinc Inorganic materials 0.000 description 10
- 229940102001 zinc bromide Drugs 0.000 description 10
- 238000000034 method Methods 0.000 description 7
- 125000005207 tetraalkylammonium group Chemical group 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000008346 aqueous phase Substances 0.000 description 5
- 230000000536 complexating effect Effects 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000009918 complex formation Effects 0.000 description 4
- 150000002367 halogens Chemical class 0.000 description 4
- -1 polyethylene Polymers 0.000 description 4
- 238000007792 addition Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- UMSGVWVBUHUHEH-UHFFFAOYSA-M ethyl(trimethyl)azanium;bromide Chemical compound [Br-].CC[N+](C)(C)C UMSGVWVBUHUHEH-UHFFFAOYSA-M 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical class CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000003868 ammonium compounds Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- AXGSHZVAGVXBJN-UHFFFAOYSA-M ethyl(tripropyl)azanium;bromide Chemical compound [Br-].CCC[N+](CC)(CCC)CCC AXGSHZVAGVXBJN-UHFFFAOYSA-M 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 150000005621 tetraalkylammonium salts Chemical group 0.000 description 2
- HWCKGOZZJDHMNC-UHFFFAOYSA-M tetraethylammonium bromide Chemical compound [Br-].CC[N+](CC)(CC)CC HWCKGOZZJDHMNC-UHFFFAOYSA-M 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 210000001787 dendrite Anatomy 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- VYFNGSZRWLYKGI-UHFFFAOYSA-M diethyl(dipropyl)azanium;bromide Chemical compound [Br-].CCC[N+](CC)(CC)CCC VYFNGSZRWLYKGI-UHFFFAOYSA-M 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- HWSZZLVAJGOAAY-UHFFFAOYSA-L lead(II) chloride Chemical compound Cl[Pb]Cl HWSZZLVAJGOAAY-UHFFFAOYSA-L 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 239000012229 microporous material Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- SEACXNRNJAXIBM-UHFFFAOYSA-N triethyl(methyl)azanium Chemical class CC[N+](C)(CC)CC SEACXNRNJAXIBM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/365—Zinc-halogen accumulators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Hybrid Cells (AREA)
- Secondary Cells (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US83824377A | 1977-09-30 | 1977-09-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2842500A1 DE2842500A1 (de) | 1979-04-12 |
| DE2842500C2 true DE2842500C2 (enrdf_load_stackoverflow) | 1987-10-15 |
Family
ID=25276627
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19782842500 Granted DE2842500A1 (de) | 1977-09-30 | 1978-09-29 | Komplexbildende substanzen fuer zink-brom-batteriezellen |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS5461640A (enrdf_load_stackoverflow) |
| CA (1) | CA1129945A (enrdf_load_stackoverflow) |
| DE (1) | DE2842500A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2404928A1 (enrdf_load_stackoverflow) |
| GB (1) | GB2005064B (enrdf_load_stackoverflow) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3274702D1 (en) * | 1982-04-14 | 1987-01-22 | Meidensha Electric Mfg Co Ltd | Electrolytes circulation type metal-halogen secondary battery |
| EP0109223B1 (en) * | 1982-11-02 | 1987-07-22 | Kabushiki Kaisha Meidensha Meidensha Electric Mfg. Co., Ltd. | Electrolyte for zinc-bromine storage batteries |
| US4491625A (en) * | 1984-03-26 | 1985-01-01 | Exxon Research & Engineering Co. | Zinc-bromine batteries with improved electrolyte |
| JPS6318819U (enrdf_load_stackoverflow) * | 1986-07-22 | 1988-02-08 | ||
| CN107112576A (zh) * | 2014-10-06 | 2017-08-29 | Eos能源储存有限责任公司 | 用于可充电的电化学电池的电解质 |
| JP2018501638A (ja) * | 2014-11-03 | 2018-01-18 | セイケム インコーポレイテッド | 電気エネルギー貯蔵および発電デバイスのための混合アルキル第四級アンモニウムまたはホスホニウム塩に基づく電解質組成物 |
| WO2016080300A1 (ja) * | 2014-11-18 | 2016-05-26 | 国立大学法人 長崎大学 | 二次電池 |
| JP6457825B2 (ja) | 2015-01-29 | 2019-01-23 | 日東電工株式会社 | 粘着シート、及び、光学部材 |
| US10587022B2 (en) | 2015-05-11 | 2020-03-10 | Bromine Compounds Ltd. | Additive for a flow battery |
| US11394069B2 (en) | 2015-11-10 | 2022-07-19 | Bromine Compounds Ltd. | Additives for a flow battery |
| US10892524B2 (en) | 2016-03-29 | 2021-01-12 | Eos Energy Storage, Llc | Electrolyte for rechargeable electrochemical cell |
| AU2019338937A1 (en) * | 2018-09-12 | 2021-03-18 | Gelion Technologies Pty Ltd | Battery with halogen sequestering agent |
| JP7292859B2 (ja) | 2018-11-19 | 2023-06-19 | 藤森工業株式会社 | 表面保護フィルム、及びそれが貼着された光学部品 |
| CN114621496B (zh) * | 2020-12-10 | 2022-11-15 | 中国科学院大连化学物理研究所 | 一种具有阻溴固溴功能Daramic复合离子传导膜的制备和应用 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH509672A (it) * | 1969-04-23 | 1971-06-30 | Consiglio Nazionale Ricerche | Elettrodo per accumulatori elettrici a alogenuro di zinco in elettrolita acquoso del tipo a catodo solubile ed anodo disciolto |
| US3944430A (en) * | 1970-09-18 | 1976-03-16 | Union Carbide Corporation | Rechargeable galvanic cell and electrolyte therefor-II |
| CH554078A (fr) * | 1971-08-31 | 1974-09-13 | Consiglio Nazionale Ricerche | Accumulateur electrique. |
| US3915744A (en) * | 1971-08-31 | 1975-10-28 | Consiglio Nazionale Ricerche | Electric battery |
| US3816177A (en) * | 1972-11-17 | 1974-06-11 | Eco Control | Secondary cells and batteries |
| US4038459A (en) * | 1976-03-17 | 1977-07-26 | Eco-Control, Inc. | Halogen complexing alcohols and nitriles |
| US4038460A (en) * | 1976-03-17 | 1977-07-26 | Eco-Control, Inc. | Halogen complexing ethers |
| US4105829A (en) * | 1976-04-07 | 1978-08-08 | Exxon Research & Engineering Co. | Metal halogen batteries and method of operating same |
| US4064324A (en) * | 1976-04-07 | 1977-12-20 | Exxon Research & Engineering Co. | Metal-Halogenelectrochemical cell |
| US4104447A (en) * | 1977-09-26 | 1978-08-01 | Eco-Control, Inc. | Halogen complexing alkyl salts for use in halogen cells |
-
1978
- 1978-09-19 CA CA311,588A patent/CA1129945A/en not_active Expired
- 1978-09-29 DE DE19782842500 patent/DE2842500A1/de active Granted
- 1978-09-29 GB GB7838781A patent/GB2005064B/en not_active Expired
- 1978-09-30 JP JP11993278A patent/JPS5461640A/ja active Granted
- 1978-10-02 FR FR7828086A patent/FR2404928A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| CA1129945A (en) | 1982-08-17 |
| DE2842500A1 (de) | 1979-04-12 |
| FR2404928A1 (fr) | 1979-04-27 |
| JPS5461640A (en) | 1979-05-18 |
| GB2005064B (en) | 1982-01-27 |
| GB2005064A (en) | 1979-04-11 |
| FR2404928B1 (enrdf_load_stackoverflow) | 1983-07-29 |
| JPS6313310B2 (enrdf_load_stackoverflow) | 1988-03-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8328 | Change in the person/name/address of the agent |
Free format text: DERZEIT KEIN VERTRETER BESTELLT |
|
| 8339 | Ceased/non-payment of the annual fee |