DE2821342A1 - Verfahren zur herstellung eines thermoplastischen elastomeren polymerisats - Google Patents
Verfahren zur herstellung eines thermoplastischen elastomeren polymerisatsInfo
- Publication number
- DE2821342A1 DE2821342A1 DE19782821342 DE2821342A DE2821342A1 DE 2821342 A1 DE2821342 A1 DE 2821342A1 DE 19782821342 DE19782821342 DE 19782821342 DE 2821342 A DE2821342 A DE 2821342A DE 2821342 A1 DE2821342 A1 DE 2821342A1
- Authority
- DE
- Germany
- Prior art keywords
- ethylene
- propylene
- melt index
- weight
- polyethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims description 29
- 229920002725 thermoplastic elastomer Polymers 0.000 title description 2
- 239000000203 mixture Substances 0.000 claims description 61
- -1 polypropylene, ethylene-propylene Polymers 0.000 claims description 50
- 239000004698 Polyethylene Substances 0.000 claims description 44
- 229920001155 polypropylene Polymers 0.000 claims description 42
- 239000000155 melt Substances 0.000 claims description 35
- 229920000573 polyethylene Polymers 0.000 claims description 33
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 29
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 18
- 239000005977 Ethylene Substances 0.000 claims description 17
- 229920001384 propylene homopolymer Polymers 0.000 claims description 17
- 229920001577 copolymer Polymers 0.000 claims description 14
- 229920001519 homopolymer Polymers 0.000 claims description 13
- 229920000642 polymer Polymers 0.000 claims description 8
- 229920002959 polymer blend Polymers 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 5
- 229920001169 thermoplastic Polymers 0.000 claims description 5
- 239000004416 thermosoftening plastic Substances 0.000 claims description 5
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 claims description 4
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 claims description 3
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims description 3
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 claims description 2
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 claims description 2
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 claims description 2
- 229920002943 EPDM rubber Polymers 0.000 description 27
- 239000004743 Polypropylene Substances 0.000 description 27
- 239000000523 sample Substances 0.000 description 12
- 238000004898 kneading Methods 0.000 description 6
- 238000001746 injection moulding Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 229920005629 polypropylene homopolymer Polymers 0.000 description 4
- 229920001897 terpolymer Polymers 0.000 description 4
- 101000658124 Apomastus schlingeri Mu-cyrtautoxin-As1a Proteins 0.000 description 3
- 101710143086 Paralytic peptide 2 Proteins 0.000 description 3
- 101000986389 Spodoptera exigua Paralytic peptide 3 Proteins 0.000 description 3
- 239000012963 UV stabilizer Substances 0.000 description 3
- 229920001400 block copolymer Polymers 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 241001441571 Hiodontidae Species 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 101000642226 Apomastus schlingeri U1-cyrtautoxin-As1b Proteins 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 150000004291 polyenes Chemical class 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical class Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL7705367A NL7705367A (nl) | 1977-05-16 | 1977-05-16 | Werkwijze voor het bereiden van een thermo- plastisch elastomeer polymeer. |
Publications (2)
Publication Number | Publication Date |
---|---|
DE2821342A1 true DE2821342A1 (de) | 1978-11-30 |
DE2821342C2 DE2821342C2 (enrdf_load_stackoverflow) | 1991-03-14 |
Family
ID=19828561
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19782821342 Granted DE2821342A1 (de) | 1977-05-16 | 1978-05-16 | Verfahren zur herstellung eines thermoplastischen elastomeren polymerisats |
Country Status (11)
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3012805A1 (de) * | 1980-04-02 | 1981-10-22 | Dynamit Nobel Ag, 5210 Troisdorf | Ternaere thermoplastische formmasse enthaltend polypropylen-homopolymer |
DE3012763A1 (de) * | 1980-04-02 | 1981-10-22 | Dynamit Nobel Ag, 5210 Troisdorf | Taernaere thermoplastische formmasse enthaltend aethylen-propylen-mischpolymerisat |
DE3012804A1 (de) * | 1980-04-02 | 1981-10-22 | Dynamit Nobel Ag, 5210 Troisdorf | Ternaere thermoplastische formmasse enthaltend polypropylen-copolymere |
JPS57159841A (en) * | 1981-03-30 | 1982-10-02 | Ube Ind Ltd | Polypropylene composition |
US5180629A (en) * | 1990-06-27 | 1993-01-19 | Nissan Motor Co., Ltd. | Injection-molded article |
DE4214170A1 (de) * | 1992-04-30 | 1993-11-04 | Alkor Gmbh | Verwendung eines zusatzes von vernetzten pp-epdm-mischungen zur kraftfahrzeugfolienherstellung |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62112644A (ja) * | 1985-11-11 | 1987-05-23 | Nippon Petrochem Co Ltd | 軟質ポリオレフイン系組成物 |
JPS6339942A (ja) * | 1986-08-05 | 1988-02-20 | Nippon Oil Co Ltd | 熱可塑性エラストマ−組成物 |
EP0654064A1 (en) * | 1992-07-30 | 1995-05-24 | Exxon Chemical Patents Inc. | Thermoplastic olefins |
US5288806A (en) * | 1992-09-22 | 1994-02-22 | Exxon Chemical Patents Inc. | Thermoplastic olefins with low viscosity |
EP1642709A1 (en) * | 2004-10-01 | 2006-04-05 | Centro Tecnologico de Grupo Copo, S.L. | Thermoformable layered sheet and manufacturing process |
EP3932986A1 (en) * | 2020-07-03 | 2022-01-05 | Sika Technology Ag | A thermoplastic composition having improved mechanical properties |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1156030A (en) * | 1965-12-27 | 1969-06-25 | Eastman Kodak Co | Polymeric Compositions. |
DE1694414A1 (de) * | 1965-04-16 | 1971-04-15 | Johnson & Johnson | Feuerwiderstandsfaehiges Polyolefin |
DE1694913B2 (de) * | 1966-01-31 | 1972-12-07 | Sumitomo Chemical Co Ltd , Osaka (Japan) | Formmasse mit verbesserter lichtdurchlaessigkeit auf der basis von polypropylen |
DE2363206A1 (de) * | 1972-12-22 | 1974-06-27 | Stamicarbon | Polypropylenmischungen mit verbesserten mechanischen eigenschaften |
US3957919A (en) * | 1974-09-24 | 1976-05-18 | Copolymer Rubber & Chemical Corporation | Thermoplastic elastomer composition and method for preparation |
DE2644644A1 (de) * | 1975-10-06 | 1977-04-07 | Goodrich Co B F | Thermoplastische polymergemische |
DE2543234A1 (de) * | 1974-08-02 | 1977-04-07 | Goodrich Co B F | Thermoplastische polymergemische |
DE2742910A1 (de) * | 1976-09-25 | 1978-03-30 | Stamicarbon | Verfahren zur herstellung eines polymerisatgemisches |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3256367A (en) * | 1962-08-14 | 1966-06-14 | Union Carbide Corp | Polypropylene compositions having improved impact strength containing polyethylene and ethylene-propylene copolymer |
US3627852A (en) * | 1967-02-02 | 1971-12-14 | Asahi Chemical Ind | Impact resistant polymer compositions |
DE2331933C3 (de) * | 1973-06-26 | 1979-11-08 | Sumitomo Chemical Co., Ltd., Osaka (Japan) | Verschäumbare Formmasse und Verfahren zur Herstellung einer Propylenpolymerisatschaumstofflage |
DE2417093B2 (de) * | 1974-04-08 | 1979-09-27 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von Polypropylen-Formmassen |
US4031169A (en) * | 1975-09-11 | 1977-06-21 | Uniroyal Inc. | Thermoplastic elastomeric polymer blend |
-
1977
- 1977-05-16 NL NL7705367A patent/NL7705367A/xx unknown
-
1978
- 1978-05-08 GB GB18255/78A patent/GB1600580A/en not_active Expired
- 1978-05-09 AT AT0335778A patent/AT367084B/de not_active IP Right Cessation
- 1978-05-11 FI FI781494A patent/FI781494A7/fi not_active Application Discontinuation
- 1978-05-12 ES ES469774A patent/ES469774A1/es not_active Expired
- 1978-05-12 BE BE187667A patent/BE867043A/xx not_active IP Right Cessation
- 1978-05-12 FR FR7814256A patent/FR2391243B1/fr not_active Expired
- 1978-05-16 DE DE19782821342 patent/DE2821342A1/de active Granted
- 1978-05-16 SE SE7805609A patent/SE428932B/sv not_active IP Right Cessation
- 1978-05-16 IT IT49399/78A patent/IT1103494B/it active
- 1978-05-16 CH CH528178A patent/CH641482A5/de not_active IP Right Cessation
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1694414A1 (de) * | 1965-04-16 | 1971-04-15 | Johnson & Johnson | Feuerwiderstandsfaehiges Polyolefin |
GB1156030A (en) * | 1965-12-27 | 1969-06-25 | Eastman Kodak Co | Polymeric Compositions. |
DE1694913B2 (de) * | 1966-01-31 | 1972-12-07 | Sumitomo Chemical Co Ltd , Osaka (Japan) | Formmasse mit verbesserter lichtdurchlaessigkeit auf der basis von polypropylen |
DE2363206A1 (de) * | 1972-12-22 | 1974-06-27 | Stamicarbon | Polypropylenmischungen mit verbesserten mechanischen eigenschaften |
DE2543234A1 (de) * | 1974-08-02 | 1977-04-07 | Goodrich Co B F | Thermoplastische polymergemische |
US3957919A (en) * | 1974-09-24 | 1976-05-18 | Copolymer Rubber & Chemical Corporation | Thermoplastic elastomer composition and method for preparation |
DE2644644A1 (de) * | 1975-10-06 | 1977-04-07 | Goodrich Co B F | Thermoplastische polymergemische |
DE2742910A1 (de) * | 1976-09-25 | 1978-03-30 | Stamicarbon | Verfahren zur herstellung eines polymerisatgemisches |
Non-Patent Citations (2)
Title |
---|
MANSON, J.A., SPERLING, L.G.: Polymer Blends and Composites, 1976, Plenum Press, S. 206 * |
The British Polymer Journal, Vol. 11, Juni 1979, S. 81-88 * |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3012805A1 (de) * | 1980-04-02 | 1981-10-22 | Dynamit Nobel Ag, 5210 Troisdorf | Ternaere thermoplastische formmasse enthaltend polypropylen-homopolymer |
DE3012763A1 (de) * | 1980-04-02 | 1981-10-22 | Dynamit Nobel Ag, 5210 Troisdorf | Taernaere thermoplastische formmasse enthaltend aethylen-propylen-mischpolymerisat |
DE3012804A1 (de) * | 1980-04-02 | 1981-10-22 | Dynamit Nobel Ag, 5210 Troisdorf | Ternaere thermoplastische formmasse enthaltend polypropylen-copolymere |
EP0039397A3 (en) * | 1980-04-02 | 1982-02-17 | Dynamit Nobel Aktiengesellschaft | Ternary thermoplastic moulding composition containing propylene copolymers |
EP0039396A3 (en) * | 1980-04-02 | 1982-02-17 | Dynamit Nobel Aktiengesellschaft | Ternary thermoplastic moulding composition containing a propylene homopolymer |
US4319004A (en) | 1980-04-02 | 1982-03-09 | Dynamit Nobel Aktiengesellschaft | Ternary thermoplastic molding composition containing polypropylene homopolymer |
US4319005A (en) | 1980-04-02 | 1982-03-09 | Dynamit Nobel Aktiengesellschaft | Ternary thermoplastic molding composition containing polypropylene copolymers |
JPS57159841A (en) * | 1981-03-30 | 1982-10-02 | Ube Ind Ltd | Polypropylene composition |
US5180629A (en) * | 1990-06-27 | 1993-01-19 | Nissan Motor Co., Ltd. | Injection-molded article |
DE4214170A1 (de) * | 1992-04-30 | 1993-11-04 | Alkor Gmbh | Verwendung eines zusatzes von vernetzten pp-epdm-mischungen zur kraftfahrzeugfolienherstellung |
Also Published As
Publication number | Publication date |
---|---|
IT7849399A0 (it) | 1978-05-16 |
GB1600580A (en) | 1981-10-21 |
AT367084B (de) | 1982-05-25 |
FR2391243B1 (fr) | 1986-03-28 |
SE428932B (sv) | 1983-08-01 |
DE2821342C2 (enrdf_load_stackoverflow) | 1991-03-14 |
ES469774A1 (es) | 1979-09-16 |
CH641482A5 (en) | 1984-02-29 |
FI781494A7 (fi) | 1978-11-17 |
NL7705367A (nl) | 1978-11-20 |
SE7805609L (sv) | 1978-11-17 |
ATA335778A (de) | 1981-10-15 |
FR2391243A1 (fr) | 1978-12-15 |
BE867043A (nl) | 1978-11-13 |
IT1103494B (it) | 1985-10-14 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8110 | Request for examination paragraph 44 | ||
D2 | Grant after examination | ||
8363 | Opposition against the patent | ||
8339 | Ceased/non-payment of the annual fee |