DE2735314A1 - Alpha-azolylsulfide und deren derivate - Google Patents
Alpha-azolylsulfide und deren derivateInfo
- Publication number
- DE2735314A1 DE2735314A1 DE19772735314 DE2735314A DE2735314A1 DE 2735314 A1 DE2735314 A1 DE 2735314A1 DE 19772735314 DE19772735314 DE 19772735314 DE 2735314 A DE2735314 A DE 2735314A DE 2735314 A1 DE2735314 A1 DE 2735314A1
- Authority
- DE
- Germany
- Prior art keywords
- azolyl
- weight
- butyl
- parts
- derivatives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000003568 thioethers Chemical class 0.000 title description 5
- -1 1,2,4-triazol-l-yl Chemical group 0.000 claims description 30
- 150000003839 salts Chemical class 0.000 claims description 17
- 150000001875 compounds Chemical class 0.000 claims description 16
- 239000003085 diluting agent Substances 0.000 claims description 8
- 239000000417 fungicide Substances 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 6
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 5
- 239000007800 oxidant agent Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
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- 239000002253 acid Substances 0.000 claims description 4
- 230000000855 fungicidal effect Effects 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 125000001401 1,2,4-triazol-4-yl group Chemical group N=1N=C([H])N([*])C=1[H] 0.000 claims description 3
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 2
- 125000000304 alkynyl group Chemical group 0.000 claims description 2
- 150000003851 azoles Chemical class 0.000 claims description 2
- 125000002962 imidazol-1-yl group Chemical group [*]N1C([H])=NC([H])=C1[H] 0.000 claims description 2
- 125000004353 pyrazol-1-yl group Chemical group [H]C1=NN(*)C([H])=C1[H] 0.000 claims description 2
- 125000003107 substituted aryl group Chemical group 0.000 claims description 2
- 125000004523 tetrazol-1-yl group Chemical group N1(N=NN=C1)* 0.000 claims description 2
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- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 48
- 239000004480 active ingredient Substances 0.000 description 26
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- 239000000243 solution Substances 0.000 description 17
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- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 235000013339 cereals Nutrition 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 239000000706 filtrate Substances 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 4
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- 235000011152 sodium sulphate Nutrition 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 150000003457 sulfones Chemical class 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- NSPMIYGKQJPBQR-UHFFFAOYSA-N 4H-1,2,4-triazole Chemical compound C=1N=CNN=1 NSPMIYGKQJPBQR-UHFFFAOYSA-N 0.000 description 3
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- 229910000104 sodium hydride Inorganic materials 0.000 description 1
- NVMNEWNGLGACBB-UHFFFAOYSA-N sodium;1,2-diaza-4-azanidacyclopenta-2,5-diene Chemical compound [Na+].C=1N=C[N-]N=1 NVMNEWNGLGACBB-UHFFFAOYSA-N 0.000 description 1
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- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
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- 229910052623 talc Inorganic materials 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 150000003536 tetrazoles Chemical class 0.000 description 1
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- YFNCATAIYKQPOO-UHFFFAOYSA-N thiophanate Chemical compound CCOC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OCC YFNCATAIYKQPOO-UHFFFAOYSA-N 0.000 description 1
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 1
- ILERPRJWJPJZDN-UHFFFAOYSA-N thioquinox Chemical compound C1=CC=C2N=C(SC(=S)S3)C3=NC2=C1 ILERPRJWJPJZDN-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 125000001425 triazolyl group Chemical group 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D257/00—Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms
- C07D257/02—Heterocyclic compounds containing rings having four nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D257/04—Five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/58—1,2-Diazines; Hydrogenated 1,2-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/713—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/005—Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Priority Applications (15)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19772735314 DE2735314A1 (de) | 1977-08-05 | 1977-08-05 | Alpha-azolylsulfide und deren derivate |
| DE7878100538T DE2860325D1 (en) | 1977-08-05 | 1978-07-28 | Alpha-azolylsulphides, sulphoxides and sulphones, their salts and metal complexes, method for their production and fungizides containing them |
| EP78100538A EP0000752B1 (de) | 1977-08-05 | 1978-07-28 | Alpha-azolysulfide, -sulfoxide und -sulfone, deren Salze und Metallkomplexe, Verfahren zu ihrer Herstellung, sowie sie enthaltende Mittel zur Pilzbekämpfung |
| IL55241A IL55241A (en) | 1977-08-05 | 1978-07-28 | Alpha-azolyl sulfides,sulfoxides and sulfones and derivatives thereof,their production and their use as fungicides |
| CA308,484A CA1112647A (en) | 1977-08-05 | 1978-07-31 | .alpha.-AZOLYL SULFIDES AND THEIR DERIVATIVES |
| IT50557/78A IT1107959B (it) | 1977-08-05 | 1978-08-01 | Alfa-azolilsolfuri e loro derivati |
| DD20708978A DD137525A5 (de) | 1977-08-05 | 1978-08-02 | Fungizides mittel |
| CS785091A CS200238B2 (en) | 1977-08-05 | 1978-08-02 | Fungicide |
| SU782646293A SU795436A3 (ru) | 1977-08-05 | 1978-08-03 | Фунгицидный состав |
| PL1978208828A PL107615B1 (pl) | 1977-08-05 | 1978-08-03 | Srodek grzybobojczy |
| DK345678A DK145597C (da) | 1977-08-05 | 1978-08-04 | Alfa-azolylsulfider og derivater deraf til anvendelse som fungicider til plantebeskyttelse |
| HU78BA3683A HU180205B (en) | 1977-08-05 | 1978-08-04 | Fungicide compositions containing alpha asolyl-sulfide derivatives and process for producing the alph-asolyl-derivatives |
| FI782403A FI64360C (fi) | 1977-08-05 | 1978-08-04 | Som fungicider anvaendbara alkyl- och arylsubstituerade alfa-azolylmetylsulfider |
| JP9469478A JPS5430174A (en) | 1977-08-05 | 1978-08-04 | Alphaaazorylsulfide and derivative thereof * and bactericide containing same |
| AT568678A AT360279B (de) | 1977-08-05 | 1978-08-04 | Mittel zur bekaempfung von pilzen |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19772735314 DE2735314A1 (de) | 1977-08-05 | 1977-08-05 | Alpha-azolylsulfide und deren derivate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2735314A1 true DE2735314A1 (de) | 1979-02-22 |
Family
ID=6015701
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19772735314 Pending DE2735314A1 (de) | 1977-08-05 | 1977-08-05 | Alpha-azolylsulfide und deren derivate |
| DE7878100538T Expired DE2860325D1 (en) | 1977-08-05 | 1978-07-28 | Alpha-azolylsulphides, sulphoxides and sulphones, their salts and metal complexes, method for their production and fungizides containing them |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE7878100538T Expired DE2860325D1 (en) | 1977-08-05 | 1978-07-28 | Alpha-azolylsulphides, sulphoxides and sulphones, their salts and metal complexes, method for their production and fungizides containing them |
Country Status (14)
| Country | Link |
|---|---|
| EP (1) | EP0000752B1 (xx) |
| JP (1) | JPS5430174A (xx) |
| AT (1) | AT360279B (xx) |
| CA (1) | CA1112647A (xx) |
| CS (1) | CS200238B2 (xx) |
| DD (1) | DD137525A5 (xx) |
| DE (2) | DE2735314A1 (xx) |
| DK (1) | DK145597C (xx) |
| FI (1) | FI64360C (xx) |
| HU (1) | HU180205B (xx) |
| IL (1) | IL55241A (xx) |
| IT (1) | IT1107959B (xx) |
| PL (1) | PL107615B1 (xx) |
| SU (1) | SU795436A3 (xx) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4749713A (en) * | 1986-03-07 | 1988-06-07 | Ciba-Geigy Corporation | Alpha-heterocycle substituted tolunitriles |
| US4937250A (en) * | 1988-03-07 | 1990-06-26 | Ciba-Geigy Corporation | Alpha-heterocycle substituted tolunitriles |
| US4978672A (en) * | 1986-03-07 | 1990-12-18 | Ciba-Geigy Corporation | Alpha-heterocyclc substituted tolunitriles |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2821829A1 (de) * | 1978-05-19 | 1979-11-22 | Basf Ag | Mittel zur regulierung des pflanzenwachstums |
| DE3100260A1 (de) * | 1981-01-08 | 1982-08-05 | Basf Ag, 6700 Ludwigshafen | Substituierte azolyl-glykolsulfonate, diese enthaltende fungizide und verfahren zu ihrer herstellung |
| EP0061835B1 (en) * | 1981-03-18 | 1989-02-01 | Imperial Chemical Industries Plc | Triazole compounds, a process for preparing them, their use as plant fungicides and fungicidal compositions containing them |
| ATE30322T1 (de) * | 1982-04-01 | 1987-11-15 | Schering Agrochemicals Ltd | Heterocyclische pilztoetende und wachstumsregulierende verbindungen und diese enthaltende zusammensetzungen. |
| US4517194A (en) * | 1982-06-25 | 1985-05-14 | Ciba-Geigy Corporation | Azolylmandelic acid derivatives and use thereof for controlling microorganisms |
| US4717733A (en) * | 1982-08-13 | 1988-01-05 | The Dow Chemical Company | Aryl(aryloxy or arylthio)azolomethanes and their use as pesticides |
| US4731372A (en) * | 1982-08-13 | 1988-03-15 | The Dow Chemical Company | Aryl(aryloxy or arylthio) azolomethanes, and their use as pesticides |
| US4636514A (en) * | 1982-08-13 | 1987-01-13 | The Dow Chemical Company | Aryl(aryloxy or arylthio)azolomethanes |
| US4701207A (en) * | 1982-08-13 | 1987-10-20 | The Dow Chemical Company | Phenyl (phenoxy or phenylthio) azolomethanes |
| US4717734A (en) * | 1982-08-13 | 1988-01-05 | The Dow Chemical Company | Aryl(aryloxy or arylthio)azolomethanes and their use as pesticides |
| US4717732A (en) * | 1982-08-13 | 1988-01-05 | The Dow Chemical Company | Aryl(aryloxy or arylthio)azolomethanes and their use as pesticides |
| US4720502A (en) * | 1982-08-13 | 1988-01-19 | The Dow Chemical Company | Aryl(aryloxy or arylthio)azolomethanes and their use as pesticides |
| US4716174A (en) * | 1982-08-13 | 1987-12-29 | The Dow Chemical Company | Aryl(aryloxy or arylthio)azolomethanes and their use as pesticides |
| US4701463A (en) * | 1982-08-13 | 1987-10-20 | The Dow Chemical Company | Pyridyl (pyridyloxy or pyriolylthio) azolomethanes |
| DK348883A (da) * | 1982-08-13 | 1984-02-14 | Dow Chemical Co | Aryl(aryloxy eller arylthio)azolomethaner, deres fremstilling og anvendelse |
| US4728657A (en) * | 1982-08-13 | 1988-03-01 | The Dow Chemical Company | Aryl(aryloxy or arylthio)azolomethanes |
| US4505919A (en) * | 1982-10-09 | 1985-03-19 | Pfizer Inc. | Antifungal S-arylmethyl- and S-heterocyclylmethyl ethers of 2-aryl-3-mercapto-1-(1H-1,2,4-triazol-1-yl) propan-2-ols |
| GB8326210D0 (en) * | 1983-09-30 | 1983-11-02 | Fbc Ltd | Azole compounds |
| PH23251A (en) * | 1985-03-18 | 1989-06-16 | Sds Biotech Corp | Propionate derivative and nonmedical fungicide containing the same |
| FR2677983B1 (fr) * | 1991-06-24 | 1995-03-03 | Oreal | Composes alkylthiopoly(ethylimidazolium), procede de preparation et leur utilisation comme agents biocides. |
| GB0108592D0 (en) * | 2001-04-05 | 2001-05-23 | Merck Sharp & Dohme | Therapeutic agents |
| WO2003055850A1 (fr) * | 2001-12-27 | 2003-07-10 | Daiichi Pharmaceutical Co., Ltd. | Inhibiteurs de la production/secretion de la proteine amyloide-$g(b) |
| MXPA05013631A (es) | 2003-06-30 | 2006-02-24 | Daiichi Seiyaku Co | Derivado heterociclico de metilsulfona. |
| US7314875B2 (en) * | 2004-04-13 | 2008-01-01 | Cephalon, Inc. | Tricyclic aromatic and bis-phenyl sulfinyl derivatives |
-
1977
- 1977-08-05 DE DE19772735314 patent/DE2735314A1/de active Pending
-
1978
- 1978-07-28 DE DE7878100538T patent/DE2860325D1/de not_active Expired
- 1978-07-28 EP EP78100538A patent/EP0000752B1/de not_active Expired
- 1978-07-28 IL IL55241A patent/IL55241A/xx unknown
- 1978-07-31 CA CA308,484A patent/CA1112647A/en not_active Expired
- 1978-08-01 IT IT50557/78A patent/IT1107959B/it active
- 1978-08-02 CS CS785091A patent/CS200238B2/cs unknown
- 1978-08-02 DD DD20708978A patent/DD137525A5/xx unknown
- 1978-08-03 PL PL1978208828A patent/PL107615B1/pl unknown
- 1978-08-03 SU SU782646293A patent/SU795436A3/ru active
- 1978-08-04 JP JP9469478A patent/JPS5430174A/ja active Pending
- 1978-08-04 FI FI782403A patent/FI64360C/fi not_active IP Right Cessation
- 1978-08-04 AT AT568678A patent/AT360279B/de active
- 1978-08-04 HU HU78BA3683A patent/HU180205B/hu unknown
- 1978-08-04 DK DK345678A patent/DK145597C/da active
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4749713A (en) * | 1986-03-07 | 1988-06-07 | Ciba-Geigy Corporation | Alpha-heterocycle substituted tolunitriles |
| US4978672A (en) * | 1986-03-07 | 1990-12-18 | Ciba-Geigy Corporation | Alpha-heterocyclc substituted tolunitriles |
| EP0236940B1 (en) * | 1986-03-07 | 1993-09-22 | Ciba-Geigy Ag | Alpha-heterocycle substituted tolunitriles |
| US4937250A (en) * | 1988-03-07 | 1990-06-26 | Ciba-Geigy Corporation | Alpha-heterocycle substituted tolunitriles |
Also Published As
| Publication number | Publication date |
|---|---|
| IL55241A (en) | 1982-01-31 |
| DD137525A5 (de) | 1979-09-12 |
| ATA568678A (de) | 1980-05-15 |
| EP0000752A3 (en) | 1979-04-04 |
| FI782403A (fi) | 1979-02-06 |
| IL55241A0 (en) | 1978-09-29 |
| HU180205B (en) | 1983-02-28 |
| PL107615B1 (pl) | 1980-02-29 |
| FI64360B (fi) | 1983-07-29 |
| DK145597C (da) | 1983-08-15 |
| CA1112647A (en) | 1981-11-17 |
| DE2860325D1 (en) | 1981-03-12 |
| IT1107959B (it) | 1985-12-02 |
| EP0000752A2 (de) | 1979-02-21 |
| AT360279B (de) | 1980-12-29 |
| FI64360C (fi) | 1983-11-10 |
| SU795436A3 (ru) | 1981-01-07 |
| DK145597B (da) | 1982-12-20 |
| CS200238B2 (en) | 1980-08-29 |
| JPS5430174A (en) | 1979-03-06 |
| IT7850557A0 (it) | 1978-08-01 |
| EP0000752B1 (de) | 1981-01-14 |
| DK345678A (da) | 1979-02-06 |
| PL208828A1 (pl) | 1979-05-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OHN | Withdrawal |