DE2714899C2 - - Google Patents

Info

Publication number
DE2714899C2
DE2714899C2 DE2714899A DE2714899A DE2714899C2 DE 2714899 C2 DE2714899 C2 DE 2714899C2 DE 2714899 A DE2714899 A DE 2714899A DE 2714899 A DE2714899 A DE 2714899A DE 2714899 C2 DE2714899 C2 DE 2714899C2
Authority
DE
Germany
Prior art keywords
radical
general formula
diisocyanate
carbon atoms
fluorinated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE2714899A
Other languages
German (de)
English (en)
Other versions
DE2714899A1 (de
Inventor
Karl Friedrich New York N.Y. Us Mueller
Robert A. New City N. Y. Us Falk
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of DE2714899A1 publication Critical patent/DE2714899A1/de
Application granted granted Critical
Publication of DE2714899C2 publication Critical patent/DE2714899C2/de
Granted legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D06M15/576—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3802—Low-molecular-weight compounds having heteroatoms other than oxygen having halogens
    • C08G18/3804—Polyhydroxy compounds
    • C08G18/3812—Polyhydroxy compounds having fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3855—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
    • C08G18/3863—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing groups having sulfur atoms between two carbon atoms, the sulfur atoms being directly linked to carbon atoms or other sulfur atoms
    • C08G18/3865—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing groups having sulfur atoms between two carbon atoms, the sulfur atoms being directly linked to carbon atoms or other sulfur atoms containing groups having one sulfur atom between two carbon atoms
    • C08G18/3868—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing groups having sulfur atoms between two carbon atoms, the sulfur atoms being directly linked to carbon atoms or other sulfur atoms containing groups having one sulfur atom between two carbon atoms the sulfur atom belonging to a sulfide group
    • C08G18/387—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing groups having sulfur atoms between two carbon atoms, the sulfur atoms being directly linked to carbon atoms or other sulfur atoms containing groups having one sulfur atom between two carbon atoms the sulfur atom belonging to a sulfide group in addition to a perfluoroalkyl group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
    • C08G18/5066—Polyethers having heteroatoms other than oxygen having nitrogen having halogens in addition to nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
    • C08G18/8054—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/38
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/11—Isocyanate and carbonate modification of fibers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2279—Coating or impregnation improves soil repellency, soil release, or anti- soil redeposition qualities of fabric
    • Y10T442/2287—Fluorocarbon containing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
DE19772714899 1976-04-06 1977-04-02 Fluorierte kondensationspolymere und ihre verwendung als schmutzabloesende mittel Granted DE2714899A1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/674,188 US4046944A (en) 1976-04-06 1976-04-06 Fluorinated condensation polymers and their use as soil release agents

Publications (2)

Publication Number Publication Date
DE2714899A1 DE2714899A1 (de) 1977-10-20
DE2714899C2 true DE2714899C2 (US20110009641A1-20110113-C00273.png) 1993-06-09

Family

ID=24705647

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19772714899 Granted DE2714899A1 (de) 1976-04-06 1977-04-02 Fluorierte kondensationspolymere und ihre verwendung als schmutzabloesende mittel

Country Status (8)

Country Link
US (1) US4046944A (US20110009641A1-20110113-C00273.png)
JP (4) JPS52123493A (US20110009641A1-20110113-C00273.png)
BE (1) BE853240A (US20110009641A1-20110113-C00273.png)
CA (1) CA1099444A (US20110009641A1-20110113-C00273.png)
CH (1) CH634453B (US20110009641A1-20110113-C00273.png)
DE (1) DE2714899A1 (US20110009641A1-20110113-C00273.png)
FR (1) FR2347392A1 (US20110009641A1-20110113-C00273.png)
GB (1) GB1565576A (US20110009641A1-20110113-C00273.png)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3319368A1 (de) * 1983-05-27 1984-11-29 Bayer Ag, 5090 Leverkusen Perfluoralkylgruppen-enthaltende polyurethane und verfahren zu ihrer herstellung
US4566981A (en) * 1984-03-30 1986-01-28 Minnesota Mining And Manufacturing Company Fluorochemicals and fibrous substrates treated therewith: compositions of cationic and non-ionic fluorochemicals
US4755567A (en) * 1985-11-08 1988-07-05 Exfluor Research Corporation Perfluorination of ethers in the presence of hydrogen fluoride scavengers
JP2502059B2 (ja) * 1986-02-05 1996-05-29 旭硝子株式会社 汚れ除去性の高い撥水撥油剤
US4769160A (en) * 1986-07-31 1988-09-06 Ciba-Geigy Corporation Use of organic fluorochemical compounds with oleophobic and hydrophobic groups in asphaltenic crude oils as viscosity reducing agents
US4767545A (en) * 1986-07-31 1988-08-30 Ciba-Geigy Corporation Use of organic fluorochemical compounds with oleophobic and hydrophobic groups in crude oils as antideposition agents, and compositions thereof
IT1213441B (it) * 1986-12-30 1989-12-20 Ausimont Spa Dispersioni acquose di poliuretani e fluorurati e loro impiego per spalmature tessili.
JPS63202611A (ja) * 1987-02-17 1988-08-22 Sanyo Chem Ind Ltd 硬化性組成物
JPH0796628B2 (ja) * 1987-03-03 1995-10-18 大日精化工業株式会社 樹脂変性剤
DE3881560T2 (de) * 1987-03-20 1994-02-03 Asahi Glass Co Ltd Fluor enthaltende Polyurethane und Polyisocyanatverbindungszusammensetzung zu ihrer Herstellung.
JPH0819325B2 (ja) * 1987-07-21 1996-02-28 大日精化工業株式会社 ポリウレタン乳濁液
US4898981A (en) * 1988-06-20 1990-02-06 Ciba-Geigy Corporation Heteroatom containing perfluoroalkyl terminated neopentyl glycols and compositions therefrom
US4946992A (en) * 1988-06-20 1990-08-07 Ciba-Geigy Corporation Heteroatom containing perfluoroalkyl terminated neopentyl glycols and compositions therefrom
JP2699539B2 (ja) * 1989-03-31 1998-01-19 三菱マテリアル株式会社 含フッ素ウレタン化合物の製造法
JP2699538B2 (ja) * 1989-03-31 1998-01-19 三菱マテリアル株式会社 含フッ素ウレタン化合物の製造方法
US5032666A (en) * 1989-06-19 1991-07-16 Becton, Dickinson And Company Amine rich fluorinated polyurethaneureas and their use in a method to immobilize an antithrombogenic agent on a device surface
US5334681A (en) * 1989-06-20 1994-08-02 Ciba-Geigy Corporation Fluorine and/or silicone containing poly(alkylene-oxide)-block copolymer hydrogels and contact lenses thereof
US5509939A (en) * 1989-12-29 1996-04-23 E. I. Du Pont De Nemours And Company Soil-release process
DK0493320T3 (da) 1990-12-20 1996-08-26 Ciba Geigy Ag Fluor- og/eller silikone-holdige poly(alkylenoxid)-blokcopolymerer og kontaktlinser deraf
US5459188A (en) * 1991-04-11 1995-10-17 Peach State Labs, Inc. Soil resistant fibers
JPH05119845A (ja) * 1991-10-29 1993-05-18 Kubota Corp 平衡式減圧弁
DE4136768A1 (de) * 1991-11-08 1993-05-13 Bayer Ag Die verwendung von polyisocyanatloesungen zur impraegnierung von mineralischen substanzen
US5310773A (en) * 1992-06-04 1994-05-10 Ciba-Geigy Corporation Perfluoroalkyl substituted hydroxyphenylalkanoic ester antioxidants and stabilized compositions
US6485789B1 (en) 1997-04-14 2002-11-26 3M Innovative Properties Company Fluorochemical composition containing a condensation product of a fluorochemical polyether and a poly-isocyanate to impart stain release properties to a substrate
US6162369A (en) * 1997-05-14 2000-12-19 3M Innovative Properties Company Fluorochemical composition comprising a polyurethane having a fluorochemical oligomer and a hydrophilic segment to impart stain release properties to a substrate
US6239247B1 (en) 1997-05-14 2001-05-29 3M Innovative Properties Company Fluorochemical composition comprising a urethane having a fluorochemical oligomer and a hydrophilic segment to impart stain release properties to a substrate
US6383633B1 (en) 1997-05-14 2002-05-07 3M Innovative Properties Company Fluorochemical composition comprising a polymer derived from a fluorochemical urethane (meth)acrylate monomer for imparting stain release properties to a substrate
US6224782B1 (en) 1997-05-14 2001-05-01 3M Innovative Properties Company Fluorochemical composition comprising a polyurethane having a fluorochemical oligomer and a hydrophilic segment to impart stain release properties to a substrate
US6462228B1 (en) 1997-12-22 2002-10-08 3M Innovative Properties Company Process for preparation of fluorinated sulfinates
US6524492B2 (en) 2000-12-28 2003-02-25 Peach State Labs, Inc. Composition and method for increasing water and oil repellency of textiles and carpet
WO2003011998A1 (fr) * 2001-07-31 2003-02-13 Asahi Glass Company, Limited Agents resistant aux taches, compositions de revetement contenant ceux-ci et articles revetus
US7396866B2 (en) * 2004-12-15 2008-07-08 3M Innovative Properties Company Fluorochemical diesters as repellent polymer melt additives
US20060135673A1 (en) * 2004-12-15 2006-06-22 Temperante John A Fluorochemical esters blends as repellent polymer melt additives
US7585919B2 (en) * 2006-09-26 2009-09-08 3M Innovative Properties Company Polymer derived from monomers with long-chain aliphatic, poly(oxyalkylene) and substrate-reactive groups
US8420069B2 (en) * 2008-09-26 2013-04-16 3M Innovative Properties Company Antimicrobial and antifouling polymeric materials
US8617002B2 (en) * 2009-06-24 2013-12-31 Acushnet Company Wedge type golf club head with improved performance
BR112012010471B1 (pt) * 2009-11-03 2020-10-20 Bayer Materialscience Ag formulação de fotopolímero compreendendo fluorouretanos e processo para exposição de mídia holográfica
KR20200055787A (ko) * 2017-09-27 2020-05-21 알케마 인코포레이티드 할로겐화된 반응물로부터 제조된 첨가 및 축합 중합체

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1215861A (en) * 1967-02-09 1970-12-16 Minnesota Mining & Mfg Cleanable stain-resistant fabrics or fibers and polymers therefor
US3578701A (en) * 1967-07-26 1971-05-11 Du Pont Fluorinated acids and esters
US3478116A (en) * 1967-07-26 1969-11-11 Du Pont Fluorinated alcohols
FR2023562A1 (US20110009641A1-20110113-C00273.png) * 1968-11-18 1970-08-21 Daikin Ind Ltd
US3720639A (en) * 1971-06-24 1973-03-13 Us Navy Fluorinated polyols
US3759874A (en) * 1971-08-30 1973-09-18 Fmc Corp Fluorinated polyurethanes as soil release agents
BE789363A (fr) * 1971-09-27 1973-03-27 Fmc Corp Composes fluores utilisables comme agents antitaches pour textiles
DE2503872A1 (de) * 1974-02-04 1975-10-30 Ciba Geigy Ag Perfluoralkylthiogruppen enthaltende polyurethane, verfahren zu ihrer herstellung und ihre verwendung

Also Published As

Publication number Publication date
JPH01118516A (ja) 1989-05-11
CA1099444A (en) 1981-04-14
GB1565576A (en) 1980-04-23
BE853240A (fr) 1977-10-05
JPS648030B2 (US20110009641A1-20110113-C00273.png) 1989-02-10
CH634453B (de) 1900-01-01
US4046944A (en) 1977-09-06
JPH0238610B2 (US20110009641A1-20110113-C00273.png) 1990-08-31
CH634453GA3 (US20110009641A1-20110113-C00273.png) 1983-02-15
FR2347392B1 (US20110009641A1-20110113-C00273.png) 1980-01-04
JPS6354731B2 (US20110009641A1-20110113-C00273.png) 1988-10-31
JPS60149622A (ja) 1985-08-07
DE2714899A1 (de) 1977-10-20
JPS60149660A (ja) 1985-08-07
JPS52123493A (en) 1977-10-17
FR2347392A1 (fr) 1977-11-04
JPH0231092B2 (US20110009641A1-20110113-C00273.png) 1990-07-11

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Legal Events

Date Code Title Description
8110 Request for examination paragraph 44
8128 New person/name/address of the agent

Representative=s name: REDIES, B., DIPL.-CHEM. DR.RER.NAT., PAT.-ANW., 40

D2 Grant after examination
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee