DE2621224A1 - Verfahren zur herstellung einer formylverbindung - Google Patents
Verfahren zur herstellung einer formylverbindungInfo
- Publication number
- DE2621224A1 DE2621224A1 DE19762621224 DE2621224A DE2621224A1 DE 2621224 A1 DE2621224 A1 DE 2621224A1 DE 19762621224 DE19762621224 DE 19762621224 DE 2621224 A DE2621224 A DE 2621224A DE 2621224 A1 DE2621224 A1 DE 2621224A1
- Authority
- DE
- Germany
- Prior art keywords
- formyl
- general formula
- compound
- catalyst
- rhodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/464—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
- C07C67/29—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by introduction of oxygen-containing functional groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
- C07C67/293—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
- C07C67/297—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US58145875A | 1975-05-28 | 1975-05-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2621224A1 true DE2621224A1 (de) | 1976-12-16 |
Family
ID=24325274
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19762621224 Withdrawn DE2621224A1 (de) | 1975-05-28 | 1976-05-13 | Verfahren zur herstellung einer formylverbindung |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4124619A (enExample) |
| JP (1) | JPS51146413A (enExample) |
| BE (1) | BE842232A (enExample) |
| DE (1) | DE2621224A1 (enExample) |
| FR (1) | FR2312486A1 (enExample) |
| GB (1) | GB1481507A (enExample) |
| NL (1) | NL7605688A (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0005452A1 (de) * | 1978-05-05 | 1979-11-28 | BASF Aktiengesellschaft | Acyloxy-2-butene, ihre Herstellung und ihre Verwendung zur Herstellung von 4-Acetoxytiglinaldehyd |
| EP0010656A1 (de) * | 1978-10-16 | 1980-05-14 | BASF Aktiengesellschaft | Verfahren zur Herstellung von 4-Acyloxy-2-methyl-crotonaldehyden |
| EP0168761A1 (de) * | 1984-07-19 | 1986-01-22 | BASF Aktiengesellschaft | Verfahren zur Herstellung von 2-Methyl-2-alkenalen aus Dihydropyranen |
| US4599458A (en) * | 1984-06-12 | 1986-07-08 | Basf Aktiengesellschaft | Preparation of 2-methylalk-2-enals |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3210707A1 (de) * | 1982-03-24 | 1983-10-06 | Basf Ag | 2-alkyl-2,4-diacyloxy-3-butenale sowie ihre herstellung |
| DE3523181A1 (de) * | 1985-06-28 | 1987-01-08 | Basf Ag | Verfahren zur herstellung von 2-methyl-2-alkenalen |
| DE19730783A1 (de) | 1997-07-18 | 1999-01-21 | Studiengesellschaft Kohle Mbh | Hydroformylierung mit unmodifizierten Rhodiumkatalysatoren in überkritischem Kohlendioxid |
| US7288672B2 (en) * | 2004-03-29 | 2007-10-30 | Council Of Scientific & Industriual Research | Process for preparation of esters of hydroxy tiglic Aldehydes |
| CN103467287B (zh) * | 2013-09-27 | 2015-06-17 | 上虞新和成生物化工有限公司 | 一种4-乙酰氧基-2-甲基-2-丁烯醛的制备方法 |
| CN110734374B (zh) * | 2018-07-20 | 2022-07-01 | 新发药业有限公司 | 一种高收率的2-甲基-4-乙酰氧基-2-丁烯醛的制备方法 |
| CN113233979B (zh) * | 2021-04-29 | 2022-05-17 | 上虞新和成生物化工有限公司 | 一种4-乙酰氧基-2-甲基-2-丁烯醛的制备方法 |
| EP4577517A1 (en) | 2022-08-24 | 2025-07-02 | Basf Se | Method for preparing 4-hydroxy-2-methylene-butanal, 4-hydroxy-2-methyl-but-2-enal and esters thereof |
| EP4678624A1 (en) | 2024-07-08 | 2026-01-14 | Basf Se | Double bond isomerizations using cobalt dimethylglyoxime catalysts |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1918695C3 (de) * | 1969-04-12 | 1975-04-30 | Basf Ag, 6700 Ludwigshafen | Herstellung von Carbonsäureester des 3-Formyl-buten-(3)-ol-(1) |
| BE754869A (fr) * | 1969-08-16 | 1971-02-15 | Basf Ag | Procede de preparation d'acetoxy-1-methyl-3-butene-2-al-4, pur |
| BE755502A (fr) * | 1969-09-09 | 1971-03-01 | Basf Ag | Bismonocarboxylates du formyl-3-butanediol-1,2 et procede pour leur preparation |
| US3880913A (en) * | 1973-06-20 | 1975-04-29 | Gen Electric | Dehydroformylation of acetoxybutyraldehydes |
-
1976
- 1976-05-13 DE DE19762621224 patent/DE2621224A1/de not_active Withdrawn
- 1976-05-26 NL NL7605688A patent/NL7605688A/xx not_active Application Discontinuation
- 1976-05-26 JP JP51060220A patent/JPS51146413A/ja active Pending
- 1976-05-26 FR FR7615939A patent/FR2312486A1/fr active Granted
- 1976-05-26 BE BE167337A patent/BE842232A/xx unknown
- 1976-05-27 GB GB22076/76A patent/GB1481507A/en not_active Expired
-
1977
- 1977-03-23 US US05/780,553 patent/US4124619A/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0005452A1 (de) * | 1978-05-05 | 1979-11-28 | BASF Aktiengesellschaft | Acyloxy-2-butene, ihre Herstellung und ihre Verwendung zur Herstellung von 4-Acetoxytiglinaldehyd |
| EP0010656A1 (de) * | 1978-10-16 | 1980-05-14 | BASF Aktiengesellschaft | Verfahren zur Herstellung von 4-Acyloxy-2-methyl-crotonaldehyden |
| US4599458A (en) * | 1984-06-12 | 1986-07-08 | Basf Aktiengesellschaft | Preparation of 2-methylalk-2-enals |
| EP0168761A1 (de) * | 1984-07-19 | 1986-01-22 | BASF Aktiengesellschaft | Verfahren zur Herstellung von 2-Methyl-2-alkenalen aus Dihydropyranen |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2312486B1 (enExample) | 1979-07-27 |
| JPS51146413A (en) | 1976-12-16 |
| US4124619A (en) | 1978-11-07 |
| FR2312486A1 (fr) | 1976-12-24 |
| NL7605688A (nl) | 1976-11-30 |
| BE842232A (fr) | 1976-11-26 |
| GB1481507A (en) | 1977-08-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8141 | Disposal/no request for examination |