DE2520785C3 - - Google Patents
Info
- Publication number
- DE2520785C3 DE2520785C3 DE19752520785 DE2520785A DE2520785C3 DE 2520785 C3 DE2520785 C3 DE 2520785C3 DE 19752520785 DE19752520785 DE 19752520785 DE 2520785 A DE2520785 A DE 2520785A DE 2520785 C3 DE2520785 C3 DE 2520785C3
- Authority
- DE
- Germany
- Prior art keywords
- weight
- borax
- sodium
- expanded
- detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 25
- 239000004328 sodium tetraborate Substances 0.000 claims description 25
- 239000000203 mixture Substances 0.000 claims description 19
- 239000003599 detergent Substances 0.000 claims description 17
- 239000000126 substance Substances 0.000 claims description 16
- 239000000080 wetting agent Substances 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 13
- 239000007921 spray Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 7
- 125000000129 anionic group Chemical group 0.000 claims description 6
- 238000009826 distribution Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K [O-]P([O-])([O-])=O Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- 238000005054 agglomeration Methods 0.000 claims description 3
- 230000002776 aggregation Effects 0.000 claims description 3
- 239000011734 sodium Substances 0.000 description 30
- 239000000843 powder Substances 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 239000003205 fragrance Substances 0.000 description 6
- 230000003287 optical Effects 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000011780 sodium chloride Substances 0.000 description 6
- 235000019832 sodium triphosphate Nutrition 0.000 description 6
- 238000005507 spraying Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 5
- 235000021317 phosphate Nutrition 0.000 description 5
- 229920000151 polyglycol Polymers 0.000 description 5
- 239000010695 polyglycol Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 150000001449 anionic compounds Chemical class 0.000 description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 4
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 4
- -1 Salts sodium tripolyphosphate Chemical class 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N Sodium silicate Chemical class [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 229910000050 copper hydride Inorganic materials 0.000 description 3
- 230000002209 hydrophobic Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 125000004432 carbon atoms Chemical group C* 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000005712 crystallization Effects 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000003623 enhancer Substances 0.000 description 2
- 230000002708 enhancing Effects 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 150000003335 secondary amines Chemical class 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- ZAWGLAXBGYSUHN-UHFFFAOYSA-M sodium;2-[bis(carboxymethyl)amino]acetate Chemical compound [Na+].OC(=O)CN(CC(O)=O)CC([O-])=O ZAWGLAXBGYSUHN-UHFFFAOYSA-M 0.000 description 2
- 230000003381 solubilizing Effects 0.000 description 2
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- PJANXHGTPQOBST-VAWYXSNFSA-N (E)-Stilbene Chemical class C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
- IJAAWBHHXIWAHM-UHFFFAOYSA-N 1,4-bis(2-phenylethenyl)benzene Chemical class C=1C=CC=CC=1C=CC(C=C1)=CC=C1C=CC1=CC=CC=C1 IJAAWBHHXIWAHM-UHFFFAOYSA-N 0.000 description 1
- KWXICGTUELOLSQ-UHFFFAOYSA-N 4-Dodecylbenzenesulfonic Acid Chemical compound CCCCCCCCCCCCC1=CC=C(S(O)(=O)=O)C=C1 KWXICGTUELOLSQ-UHFFFAOYSA-N 0.000 description 1
- REJHVSOVQBJEBF-OWOJBTEDSA-N 5-azaniumyl-2-[(E)-2-(4-azaniumyl-2-sulfonatophenyl)ethenyl]benzenesulfonate Chemical compound OS(=O)(=O)C1=CC(N)=CC=C1\C=C\C1=CC=C(N)C=C1S(O)(=O)=O REJHVSOVQBJEBF-OWOJBTEDSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 240000007170 Cocos nucifera Species 0.000 description 1
- MGNCLNQXLYJVJD-UHFFFAOYSA-N Cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N Diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N Dodecanol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M NaHCO3 Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N Nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- JBUKJLNBQDQXLI-UHFFFAOYSA-N Sodium perborate Chemical compound [Na+].[Na+].O[B-]1(O)OO[B-](O)(O)OO1 JBUKJLNBQDQXLI-UHFFFAOYSA-N 0.000 description 1
- FKHIFSZMMVMEQY-UHFFFAOYSA-N Talc Chemical compound [Mg+2].[O-][Si]([O-])=O FKHIFSZMMVMEQY-UHFFFAOYSA-N 0.000 description 1
- ZIHQYOJUGRUMKO-UHFFFAOYSA-N [Na+].[Na+].O[Si](O)(O)O[Si](O)([O-])[O-] Chemical compound [Na+].[Na+].O[Si](O)(O)O[Si](O)([O-])[O-] ZIHQYOJUGRUMKO-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 1
- 229940027983 antiseptics and disinfectants Quaternary ammonium compounds Drugs 0.000 description 1
- UTPOUAZEFGTYAY-UHFFFAOYSA-O azanium;2-chloroacetic acid Chemical compound [NH4+].OC(=O)CCl UTPOUAZEFGTYAY-UHFFFAOYSA-O 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 235000012970 cakes Nutrition 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000000875 corresponding Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- YLYFOJDUNYYVKY-UHFFFAOYSA-N dodecasodium;tetraborate;pentahydrate Chemical compound O.O.O.O.O.[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] YLYFOJDUNYYVKY-UHFFFAOYSA-N 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N ethanolamine Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229940093909 gynecological antiinfectives and antiseptics Triazole derivatives Drugs 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000001261 hydroxy acids Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N lead(II) oxide Inorganic materials [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 150000002780 morpholines Chemical class 0.000 description 1
- 230000001264 neutralization Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N oxane Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 150000004686 pentahydrates Chemical class 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000001007 puffing Effects 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000001187 sodium carbonate Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000019351 sodium silicates Nutrition 0.000 description 1
- VQOIVBPFDDLTSX-UHFFFAOYSA-M sodium;3-dodecylbenzenesulfonate Chemical class [Na+].CCCCCCCCCCCCC1=CC=CC(S([O-])(=O)=O)=C1 VQOIVBPFDDLTSX-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229940042055 systemic antimycotics Triazole derivatives Drugs 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 210000001519 tissues Anatomy 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-M triacetate(1-) Chemical compound CC(=O)CC(=O)CC([O-])=O ILJSQTXMGCGYMG-UHFFFAOYSA-M 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/470,308 US3986987A (en) | 1974-05-15 | 1974-05-15 | Light-density, low phosphate, puffed borax-containing detergent compositions |
| US47030874 | 1974-05-15 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2520785A1 DE2520785A1 (de) | 1975-11-20 |
| DE2520785B2 DE2520785B2 (de) | 1977-02-24 |
| DE2520785C3 true DE2520785C3 (ro) | 1977-10-06 |
Family
ID=23867076
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19752520785 Granted DE2520785B2 (de) | 1974-05-15 | 1975-05-09 | Waschmittel |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3986987A (ro) |
| CA (1) | CA1050385A (ro) |
| DE (1) | DE2520785B2 (ro) |
| GB (1) | GB1473282A (ro) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA775371B (en) * | 1976-09-29 | 1979-04-25 | Colgate Palmolive Co | Bottled particulate detergent |
| US4547352A (en) * | 1982-03-15 | 1985-10-15 | Capital City Products Company | Reticulated puffed borax having enhanced absorptive capacity |
| US4412978A (en) * | 1982-03-15 | 1983-11-01 | Stokely-Van Camp, Inc. | Method and apparatus for manufacturing improved puffed borax |
| US4615814A (en) * | 1984-04-02 | 1986-10-07 | Purex Corporation | Porous substrate with absorbed antistat or softener, used with detergent |
| US4636328A (en) * | 1984-04-05 | 1987-01-13 | Purex Corporation | Multi functional laundry product and employment of same during fabric laundering |
| US4996001A (en) * | 1989-01-23 | 1991-02-26 | Capital City Products Company | Puffed borax as an agglomerating aid |
| US5529710A (en) * | 1992-07-15 | 1996-06-25 | The Procter & Gamble Company | Production of detergent granules with excellent white appearance |
| DK0578872T3 (da) * | 1992-07-15 | 1999-06-23 | Procter & Gamble | Detergentsammensætninger |
| US5665691A (en) * | 1995-10-04 | 1997-09-09 | The Procter & Gamble Company | Process for making a low density detergent composition by agglomeration with a hydrated salt |
| US5962393A (en) * | 1996-11-14 | 1999-10-05 | The Clorox Company | Powdered abrasive cleanser comprising calcium carbonate and borax pentahydrate |
| US6022843A (en) * | 1998-09-09 | 2000-02-08 | The Clorox Company | Non-phosphate, agglomerated laundry booster |
| CA2380292A1 (en) * | 1999-07-23 | 2001-02-01 | The Clorox Company | Dry-cleaning processes and components therefor |
| WO2005005588A2 (en) * | 2003-07-15 | 2005-01-20 | A.S.T. Kimya Ve Teknoloji Sanayi Ticaret Limited Sirketi | An anti-foam composition comprising puffed |
| WO2014172902A1 (en) * | 2013-04-26 | 2014-10-30 | The Procter & Gamble Company | Detergent granules with a water-swellable component |
| US10913921B2 (en) * | 2014-06-18 | 2021-02-09 | HEX Performance, LLC | Performance gear, textile technology, and cleaning and protecting systems and methods |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA586622A (en) | 1959-11-10 | Diamond Alkali Company | Anionic detergent mixture with phosphates and water softeners | |
| US2623856A (en) * | 1952-12-30 | Tetraborate detergent compositionx | ||
| US3356613A (en) * | 1966-09-27 | 1967-12-05 | Procter & Gamble | Built detergent compositions containing a synergistic mixture of stp, nta, and sodium silicate |
| US3574119A (en) * | 1967-02-03 | 1971-04-06 | Kao Corp | Method of granulating detergent compositions containing an alkali metal metaborate |
| US3538005A (en) * | 1967-06-26 | 1970-11-03 | American Home Prod | Dry powder bleaching compositions |
| US3533942A (en) * | 1968-04-29 | 1970-10-13 | American Potash & Chem Corp | Process for loading expanded water-solution hydrate salt particles |
| US3562171A (en) * | 1968-12-31 | 1971-02-09 | Procter & Gamble | Oxygen carrier for detergent compositions |
| US3671439A (en) * | 1969-07-22 | 1972-06-20 | American Home Prod | Oxygen bleach-activator systems stabilized with puffed borax |
| GB1358291A (en) * | 1971-01-18 | 1974-07-03 | British Petroleum Co | Antioxidant composition |
| US3838072A (en) * | 1971-03-15 | 1974-09-24 | Colgate Palmolive Co | Manufacture of free flowing particulate detergent containing nonionic surface active compound |
-
1974
- 1974-05-15 US US05/470,308 patent/US3986987A/en not_active Expired - Lifetime
-
1975
- 1975-04-28 CA CA226,305A patent/CA1050385A/en not_active Expired
- 1975-04-29 GB GB1785775A patent/GB1473282A/en not_active Expired
- 1975-05-09 DE DE19752520785 patent/DE2520785B2/de active Granted
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