DE2503233C3 - Verfahren zur Herstellung von Essigsäure, Äthanol und/oder Acetaldehyd - Google Patents

Verfahren zur Herstellung von Essigsäure, Äthanol und/oder Acetaldehyd

Info

Publication number
DE2503233C3
DE2503233C3 DE19752503233 DE2503233A DE2503233C3 DE 2503233 C3 DE2503233 C3 DE 2503233C3 DE 19752503233 DE19752503233 DE 19752503233 DE 2503233 A DE2503233 A DE 2503233A DE 2503233 C3 DE2503233 C3 DE 2503233C3
Authority
DE
Germany
Prior art keywords
catalyst
rhodium
reaction
ethanol
acetic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE19752503233
Other languages
German (de)
English (en)
Other versions
DE2503233B2 (de
DE2503233A1 (de
Inventor
Madan Mohan Bhasin
George Lawrence O'connor
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of DE2503233A1 publication Critical patent/DE2503233A1/de
Publication of DE2503233B2 publication Critical patent/DE2503233B2/de
Application granted granted Critical
Publication of DE2503233C3 publication Critical patent/DE2503233C3/de
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C07C29/157—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C07C29/157—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof
    • C07C29/158—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof containing rhodium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
DE19752503233 1974-01-28 1975-01-27 Verfahren zur Herstellung von Essigsäure, Äthanol und/oder Acetaldehyd Expired DE2503233C3 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US43714174A 1974-01-28 1974-01-28
US54166175A 1975-01-16 1975-01-16

Publications (3)

Publication Number Publication Date
DE2503233A1 DE2503233A1 (de) 1975-07-31
DE2503233B2 DE2503233B2 (de) 1977-07-28
DE2503233C3 true DE2503233C3 (de) 1978-03-16

Family

ID=27031196

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19752503233 Expired DE2503233C3 (de) 1974-01-28 1975-01-27 Verfahren zur Herstellung von Essigsäure, Äthanol und/oder Acetaldehyd

Country Status (7)

Country Link
CA (1) CA1060467A (enExample)
DE (1) DE2503233C3 (enExample)
FR (1) FR2259077B1 (enExample)
GB (1) GB1501892A (enExample)
IT (1) IT1031173B (enExample)
NL (1) NL7500916A (enExample)
SE (1) SE428682B (enExample)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4014913A (en) * 1975-06-26 1977-03-29 Union Carbide Corporation Process for producing oxygenated two carbon compounds
US4101450A (en) * 1977-05-09 1978-07-18 Celanese Corporation Catalyst for production of acetic acid
US4268689A (en) * 1978-12-11 1981-05-19 Texaco Development Corp. Manufacture of vicinal glycol esters from synthesis gas
US4235798A (en) 1979-06-28 1980-11-25 Union Carbide Corporation Process for producing two-carbon atom oxygenated compounds from synthesis gas with minimal production of methane
CA1146592A (en) * 1979-06-28 1983-05-17 Thomas P. Wilson Process for producing two-carbon atom oxygenated compounds from synthesis gas with minimal production of methane
US4446251A (en) * 1980-02-15 1984-05-01 Union Carbide Corporation Process for producing two-carbon atom oxygenated compounds from synthesis gas with minimal production of methane
US4471075A (en) * 1979-06-28 1984-09-11 Union Carbide Corporation Process for producing two-carbon atom oxygenated compounds from synthesis gas with minimal production of methane
US4444909A (en) * 1980-04-07 1984-04-24 Mobil Oil Corporation Synthesis gas conversion to oxygenates
ZA814981B (en) * 1980-08-01 1983-02-23 British Petroleum Co Process for the production of c1 to c4 oxygenated hydrocarbons by the catalytic conversion of synthesis gas
US4312955A (en) 1980-12-01 1982-01-26 Union Carbide Corporation Process for the production of methanol from synthesis gas
US4882360A (en) * 1984-07-30 1989-11-21 The Dow Chemical Company Process for producing alcohols from synthesis gas
US4831060A (en) * 1984-07-30 1989-05-16 The Dow Chemical Company Mixed alcohols production from syngas
US4762858A (en) * 1985-09-16 1988-08-09 The Dow Chemical Company Syngas conversion to oxygenates by reduced yttrium/lanthanide/actinide-modified catalyst
JP2660880B2 (ja) * 1991-06-21 1997-10-08 東京瓦斯株式会社 酢酸製造方法
DE69206070T2 (de) * 1991-06-21 1996-06-20 Tokyo Gas Co Ltd Verfahren zur Herstellung von Essigsäure.
DE102007055024A1 (de) 2007-11-15 2009-05-20 Rolf-Dieter Riesbeck Brandschutzeinrichtung
CN115636739B (zh) * 2022-09-27 2024-08-06 厦门大学 一种合成气一步法制丙酮的方法

Also Published As

Publication number Publication date
SE7500857L (enExample) 1975-07-29
IT1031173B (it) 1979-04-30
DE2503233B2 (de) 1977-07-28
GB1501892A (en) 1978-02-22
FR2259077B1 (enExample) 1978-07-13
FR2259077A1 (enExample) 1975-08-22
NL7500916A (nl) 1975-07-30
SE428682B (sv) 1983-07-18
DE2503233A1 (de) 1975-07-31
CA1060467A (en) 1979-08-14

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Legal Events

Date Code Title Description
C3 Grant after two publication steps (3rd publication)
8339 Ceased/non-payment of the annual fee