DE2444734C3 - Wasserbefeuchtbarer Schmelzkleber auf Basis von Copolymerisaten aus Vinylacetat und Vinylpyrrolidon - Google Patents
Wasserbefeuchtbarer Schmelzkleber auf Basis von Copolymerisaten aus Vinylacetat und VinylpyrrolidonInfo
- Publication number
- DE2444734C3 DE2444734C3 DE2444734A DE2444734A DE2444734C3 DE 2444734 C3 DE2444734 C3 DE 2444734C3 DE 2444734 A DE2444734 A DE 2444734A DE 2444734 A DE2444734 A DE 2444734A DE 2444734 C3 DE2444734 C3 DE 2444734C3
- Authority
- DE
- Germany
- Prior art keywords
- water
- wax
- parts
- molecular weight
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001577 copolymer Polymers 0.000 title claims description 27
- 239000004831 Hot glue Substances 0.000 title claims description 10
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 title claims description 9
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 title claims description 7
- 239000001993 wax Substances 0.000 claims description 56
- 239000000203 mixture Substances 0.000 claims description 47
- 229920001223 polyethylene glycol Polymers 0.000 claims description 34
- 239000002202 Polyethylene glycol Substances 0.000 claims description 26
- 239000007787 solid Substances 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 239000000654 additive Substances 0.000 claims description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 239000000853 adhesive Substances 0.000 description 32
- 230000001070 adhesive effect Effects 0.000 description 32
- 230000000903 blocking effect Effects 0.000 description 21
- 239000007795 chemical reaction product Substances 0.000 description 11
- 239000000758 substrate Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 6
- 238000005336 cracking Methods 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 5
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 5
- 239000003963 antioxidant agent Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000012943 hotmelt Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- MTUBBMSQXXJFQP-UHFFFAOYSA-N OC(CCCCCCCCCCCCCCCCC(=O)OCC(O)CO)(O)O Chemical compound OC(CCCCCCCCCCCCCCCCC(=O)OCC(O)CO)(O)O MTUBBMSQXXJFQP-UHFFFAOYSA-N 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 239000001087 glyceryl triacetate Substances 0.000 description 2
- 235000013773 glyceryl triacetate Nutrition 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 2
- 229940081974 saccharin Drugs 0.000 description 2
- 235000019204 saccharin Nutrition 0.000 description 2
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 229960002622 triacetin Drugs 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- OZSKVMIBRHDIET-UHFFFAOYSA-N 12-hydroxy-n-(2-hydroxyethyl)octadecanamide Chemical compound CCCCCCC(O)CCCCCCCCCCC(=O)NCCO OZSKVMIBRHDIET-UHFFFAOYSA-N 0.000 description 1
- XJOOKFNMTRPLEG-UHFFFAOYSA-N 12-hydroxy-n-octadecyloctadecanamide Chemical compound CCCCCCCCCCCCCCCCCCNC(=O)CCCCCCCCCCC(O)CCCCCC XJOOKFNMTRPLEG-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 238000010420 art technique Methods 0.000 description 1
- 230000031709 bromination Effects 0.000 description 1
- 238000005893 bromination reaction Methods 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- -1 polyoxyethylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
- C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09J131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J139/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Adhesives based on derivatives of such polymers
- C09J139/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
- C09J139/06—Homopolymers or copolymers of N-vinyl-pyrrolidones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US400926A US3888811A (en) | 1973-09-26 | 1973-09-26 | Water-moistenable hot-melt applicable adhesive composition |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2444734A1 DE2444734A1 (de) | 1975-04-10 |
| DE2444734B2 DE2444734B2 (de) | 1977-11-03 |
| DE2444734C3 true DE2444734C3 (de) | 1978-06-22 |
Family
ID=23585569
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2444734A Expired DE2444734C3 (de) | 1973-09-26 | 1974-09-19 | Wasserbefeuchtbarer Schmelzkleber auf Basis von Copolymerisaten aus Vinylacetat und Vinylpyrrolidon |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3888811A (enExample) |
| JP (1) | JPS5337102B2 (enExample) |
| CA (1) | CA991771A (enExample) |
| DE (1) | DE2444734C3 (enExample) |
| FR (1) | FR2244810B1 (enExample) |
| GB (1) | GB1440411A (enExample) |
| NL (1) | NL156424B (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4325851A (en) * | 1980-10-24 | 1982-04-20 | Herman Colon | Water-activatable hot-melt adhesives |
| US4331576A (en) * | 1981-01-29 | 1982-05-25 | Herman Colon | Water-soluble, pressure-sensitive, hot-melt adhesives |
| US4623688A (en) | 1985-12-12 | 1986-11-18 | National Starch And Chemical Corporation | Remoistenable hot melt adhesives |
| US4743238A (en) * | 1986-03-17 | 1988-05-10 | Malcolm Nicol & Co. | Wetness indicating hot-melt adhesives |
| US5835679A (en) | 1994-12-29 | 1998-11-10 | Energy Converters, Inc. | Polymeric immersion heating element with skeletal support and optional heat transfer fins |
| US8502012B2 (en) * | 2009-06-16 | 2013-08-06 | The Procter & Gamble Company | Absorbent structures including coated absorbent material |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3156661A (en) * | 1961-11-13 | 1964-11-10 | Chemical Corp Of America | Insecticidal water-based, self-polishing coating compositions |
| US3245930A (en) * | 1963-05-21 | 1966-04-12 | Exxon Research Engineering Co | Compositions containing paraffin wax, semi-microcrystalline wax, ethylenevinyl acetate copolymer and polyethylene |
| US3345320A (en) * | 1964-05-25 | 1967-10-03 | Gen Aniline & Film Corp | Remoistenable hot-melt adhesives containing plasticized copolymers of nvinyl lactams |
| US3462342A (en) * | 1965-01-18 | 1969-08-19 | Battelle Development Corp | Adhesive bonding |
| US3590101A (en) * | 1967-01-18 | 1971-06-29 | Monsanto Co | Process for recovering suspension polymers |
| US3428591A (en) * | 1968-01-30 | 1969-02-18 | Atlantic Richfield Co | Wax compositions containing graft polymer of polyethylene and to paperboards coated therewith |
-
1973
- 1973-09-26 US US400926A patent/US3888811A/en not_active Expired - Lifetime
-
1974
- 1974-08-16 GB GB3624274A patent/GB1440411A/en not_active Expired
- 1974-08-23 CA CA207,699A patent/CA991771A/en not_active Expired
- 1974-09-16 NL NL7412242.A patent/NL156424B/xx not_active IP Right Cessation
- 1974-09-19 DE DE2444734A patent/DE2444734C3/de not_active Expired
- 1974-09-25 JP JP10964174A patent/JPS5337102B2/ja not_active Expired
- 1974-09-25 FR FR7432302A patent/FR2244810B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5337102B2 (enExample) | 1978-10-06 |
| US3888811A (en) | 1975-06-10 |
| DE2444734A1 (de) | 1975-04-10 |
| NL7412242A (nl) | 1975-04-01 |
| NL156424B (nl) | 1978-04-17 |
| CA991771A (en) | 1976-06-22 |
| JPS5060537A (enExample) | 1975-05-24 |
| GB1440411A (en) | 1976-06-23 |
| FR2244810A1 (enExample) | 1975-04-18 |
| FR2244810B1 (enExample) | 1979-02-16 |
| DE2444734B2 (de) | 1977-11-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) | ||
| 8328 | Change in the person/name/address of the agent |
Free format text: DERZEIT KEIN VERTRETER BESTELLT |
|
| 8339 | Ceased/non-payment of the annual fee |