DE2439341A1 - Kontinuierliche substanzpolymerisation von vinylderivaten - Google Patents
Kontinuierliche substanzpolymerisation von vinylderivatenInfo
- Publication number
- DE2439341A1 DE2439341A1 DE2439341A DE2439341A DE2439341A1 DE 2439341 A1 DE2439341 A1 DE 2439341A1 DE 2439341 A DE2439341 A DE 2439341A DE 2439341 A DE2439341 A DE 2439341A DE 2439341 A1 DE2439341 A1 DE 2439341A1
- Authority
- DE
- Germany
- Prior art keywords
- monomers
- stage
- monomer
- pressure
- reaction zone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000006116 polymerization reaction Methods 0.000 title claims description 7
- 229920002554 vinyl polymer Polymers 0.000 title description 3
- 239000000126 substance Substances 0.000 title 1
- ORGHESHFQPYLAO-UHFFFAOYSA-N vinyl radical Chemical class C=[CH] ORGHESHFQPYLAO-UHFFFAOYSA-N 0.000 title 1
- 239000000178 monomer Substances 0.000 claims description 35
- 238000006243 chemical reaction Methods 0.000 claims description 27
- 229920000642 polymer Polymers 0.000 claims description 19
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 10
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 7
- 239000011541 reaction mixture Substances 0.000 claims description 6
- 239000000155 melt Substances 0.000 claims description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 4
- 125000005907 alkyl ester group Chemical group 0.000 claims description 3
- 230000008020 evaporation Effects 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 150000002825 nitriles Chemical class 0.000 claims description 2
- 238000005086 pumping Methods 0.000 claims description 2
- 238000002474 experimental method Methods 0.000 description 10
- 238000009826 distribution Methods 0.000 description 6
- 239000012190 activator Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 238000012958 reprocessing Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- -1 ςΖ-methylstyrene Chemical compound 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 206010000210 abortion Diseases 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F12/06—Hydrocarbons
- C08F12/08—Styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Priority Applications (16)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2439341A DE2439341A1 (de) | 1974-08-16 | 1974-08-16 | Kontinuierliche substanzpolymerisation von vinylderivaten |
| AR260023A AR208325A1 (es) | 1974-08-16 | 1975-01-01 | Procedimiento para la polimerizacion de compuestos vinilicos aromaticos y para su copolimerizacion con esteres alquilicos(c1-c6)o nitrilos de los acidos acrilico y/o metacrilicos |
| IN1392/CAL/1975A IN142506B (enExample) | 1974-08-16 | 1975-07-16 | |
| US05/603,367 US4042768A (en) | 1974-08-16 | 1975-08-11 | Continuous solvent-free polymerization of vinyl derivatives |
| IT50899/75A IT1041204B (it) | 1974-08-16 | 1975-08-11 | Procedimento ed impianto per la polimerizzazione continua di derivati vinilici |
| BE159160A BE832384A (fr) | 1974-08-16 | 1975-08-13 | Polymerisation de derives vinyliques en continu et en absence de solvant |
| NL7509660A NL7509660A (nl) | 1974-08-16 | 1975-08-13 | Werkwijze voor de continue polymerisatie en copo- lymerisatie zonder toepassing van een oplosmiddel van vinylderivaten. |
| JP50098146A JPS5146390A (en) | 1974-08-16 | 1975-08-14 | Binirukagobutsuno muyobairenzokujugoho |
| PL1975182733A PL103106B1 (pl) | 1974-08-16 | 1975-08-14 | Sposob polimeryzacji zwiazkow winyloaromatycznych i kopolimeryzacji ich z alkilowymi estrami i nitrylami kwasu akrylowego i/lub metakrylowego |
| AU83981/75A AU493232B2 (en) | 1974-08-16 | 1975-08-14 | Continuous solvent-free polymerisation of vinyl derivatives |
| FR7525381A FR2281940A1 (fr) | 1974-08-16 | 1975-08-14 | Polymerisation de derives vinyliques en continu et en absence de solvant |
| DD187856A DD121116A5 (enExample) | 1974-08-16 | 1975-08-14 | |
| CA233,481A CA1070897A (en) | 1974-08-16 | 1975-08-14 | Continuous solvent-free polymerisation of vinyl derivatives |
| ZA00755230A ZA755230B (en) | 1974-08-16 | 1975-08-15 | Continuous solvent-free polymerisation of vinyl derivatives |
| GB34049/75A GB1485222A (en) | 1974-08-16 | 1975-08-15 | Continuous solvent-free polymerisation of vinyl derivatives |
| BR7505238*A BR7505238A (pt) | 1974-08-16 | 1975-08-15 | Processo para polimerizacao de um composto de vinila aromatico |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2439341A DE2439341A1 (de) | 1974-08-16 | 1974-08-16 | Kontinuierliche substanzpolymerisation von vinylderivaten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2439341A1 true DE2439341A1 (de) | 1976-02-26 |
Family
ID=5923364
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2439341A Withdrawn DE2439341A1 (de) | 1974-08-16 | 1974-08-16 | Kontinuierliche substanzpolymerisation von vinylderivaten |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US4042768A (enExample) |
| JP (1) | JPS5146390A (enExample) |
| AR (1) | AR208325A1 (enExample) |
| BE (1) | BE832384A (enExample) |
| BR (1) | BR7505238A (enExample) |
| CA (1) | CA1070897A (enExample) |
| DD (1) | DD121116A5 (enExample) |
| DE (1) | DE2439341A1 (enExample) |
| FR (1) | FR2281940A1 (enExample) |
| GB (1) | GB1485222A (enExample) |
| IN (1) | IN142506B (enExample) |
| IT (1) | IT1041204B (enExample) |
| NL (1) | NL7509660A (enExample) |
| PL (1) | PL103106B1 (enExample) |
| ZA (1) | ZA755230B (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0001767A1 (de) * | 1977-11-02 | 1979-05-16 | BASF Aktiengesellschaft | Flammfeste Styrolpolymerisate und deren Verwendung |
| DE102013226502A1 (de) * | 2013-12-18 | 2015-06-18 | Tesa Se | Verfahren zur Herstellung kurzkettiger Makromoleküle auf Styrolbasis |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1524433A (en) * | 1975-03-26 | 1978-09-13 | Bayer Ag | Continuous bulk polymerisation process |
| DE2627336C2 (de) * | 1976-06-18 | 1983-11-10 | Hoechst Ag, 6230 Frankfurt | Verfahren zur Masse-Polymerisation von alkenylaromatischen Verbindungen |
| US4252924A (en) * | 1979-04-05 | 1981-02-24 | E. I. Du Pont De Nemours And Company | Continuous process for the preparation of nonrandom ethylene/acid copolymer |
| DE3140383A1 (de) * | 1981-10-10 | 1983-04-28 | Basf Ag, 6700 Ludwigshafen | Polymere organische saeuren, verfahren zu ihrer herstellung und ihre verwendung in wasch- und reinigungsmitteln |
| JPS58196204A (ja) * | 1982-05-12 | 1983-11-15 | Hitachi Ltd | 熱可塑性樹脂の連続塊状重合法 |
| USRE32217E (en) * | 1982-11-12 | 1986-07-29 | The Dow Chemical Company | Graft copolymerization process |
| SK278502B6 (en) * | 1983-09-19 | 1997-08-06 | Jarvis Marvin A. | A method for removal of volatile waste product from raw polymerisation product |
| US4546160A (en) * | 1984-02-29 | 1985-10-08 | S. C. Johnson & Son, Inc. | Bulk polymerization process for preparing high solids and uniform copolymers |
| US4619979A (en) * | 1984-03-28 | 1986-10-28 | Minnesota Mining And Manufacturing Company | Continuous free radial polymerization in a wiped-surface reactor |
| US4695608A (en) * | 1984-03-29 | 1987-09-22 | Minnesota Mining And Manufacturing Company | Continuous process for making polymers having pendant azlactone or macromolecular moieties |
| US5274029A (en) * | 1990-09-10 | 1993-12-28 | Kelley Joseph M | Styrene polymerization process |
| JP2636970B2 (ja) * | 1991-02-27 | 1997-08-06 | 出光石油化学株式会社 | スチレン系重合体の製造方法 |
| DE10105278A1 (de) * | 2001-02-02 | 2002-08-08 | Basf Ag | Klebstoffe, enthaltend Polyvinylalkylether |
| JP4011415B2 (ja) * | 2002-06-20 | 2007-11-21 | 日本ペイント株式会社 | アクリル共重合体の製造方法 |
| WO2009121834A1 (de) * | 2008-03-31 | 2009-10-08 | Basf Se | Verwendung von schmelzbaren acrylat-polymeren zur herstellung von haftklebstoffschichten |
| DE102009001776A1 (de) | 2009-03-24 | 2010-09-30 | Evonik Röhm Gmbh | Zusammensetzung umfassend als wässrige Dispersion vorzugsweise Benzophenon-haltige (Meth)acrylatpolymere in Mischung mit von diesen verschiedenen (Meth)acrylatpolymeren sowie die Verwendung der Zusammensetzung |
| DE102012222813A1 (de) | 2012-12-11 | 2014-06-12 | Tesa Se | UV-vernetzbare Haftklebemassen mit UV-Absorber, Verfahren zu deren Herstellung und Anwendung |
| EP3170552A1 (en) | 2015-11-23 | 2017-05-24 | Basf Se | Microcapsule comprising a polymeric shell and a hydrophilic or hydrophobic core material |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2496653A (en) * | 1943-10-12 | 1950-02-07 | Union Carbide & Carbon Corp | Continuous bulk polymerization of styrene |
| US2530409A (en) * | 1948-05-27 | 1950-11-21 | Dow Chemical Co | Method for polymerizing styrene |
| US2745824A (en) * | 1952-11-26 | 1956-05-15 | American Cyanamid Co | Process for the polymerization of styrene and acrylonitrile |
| US2931793A (en) * | 1956-03-30 | 1960-04-05 | American Cyanamid Co | Process for preparing thermoplastic polymers |
| US2921932A (en) * | 1954-01-28 | 1960-01-19 | Monsanto Chemicals | High pressure polymerization of styrene |
| NL106027C (enExample) * | 1958-04-30 | |||
| NL292366A (enExample) * | 1962-05-17 | |||
| US3759879A (en) * | 1971-05-28 | 1973-09-18 | Firestone Tire & Rubber Co | Continuous bulk polymerization process for vinyl chloride copolymers |
| US3859268A (en) * | 1973-03-09 | 1975-01-07 | Monsanto Co | Continuous mass polymerization of poly alkenyl aromatic polymers |
-
1974
- 1974-08-16 DE DE2439341A patent/DE2439341A1/de not_active Withdrawn
-
1975
- 1975-01-01 AR AR260023A patent/AR208325A1/es active
- 1975-07-16 IN IN1392/CAL/1975A patent/IN142506B/en unknown
- 1975-08-11 IT IT50899/75A patent/IT1041204B/it active
- 1975-08-11 US US05/603,367 patent/US4042768A/en not_active Expired - Lifetime
- 1975-08-13 NL NL7509660A patent/NL7509660A/xx not_active Application Discontinuation
- 1975-08-13 BE BE159160A patent/BE832384A/xx not_active IP Right Cessation
- 1975-08-14 JP JP50098146A patent/JPS5146390A/ja active Granted
- 1975-08-14 FR FR7525381A patent/FR2281940A1/fr active Granted
- 1975-08-14 PL PL1975182733A patent/PL103106B1/pl unknown
- 1975-08-14 CA CA233,481A patent/CA1070897A/en not_active Expired
- 1975-08-14 DD DD187856A patent/DD121116A5/xx unknown
- 1975-08-15 GB GB34049/75A patent/GB1485222A/en not_active Expired
- 1975-08-15 ZA ZA00755230A patent/ZA755230B/xx unknown
- 1975-08-15 BR BR7505238*A patent/BR7505238A/pt unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0001767A1 (de) * | 1977-11-02 | 1979-05-16 | BASF Aktiengesellschaft | Flammfeste Styrolpolymerisate und deren Verwendung |
| DE102013226502A1 (de) * | 2013-12-18 | 2015-06-18 | Tesa Se | Verfahren zur Herstellung kurzkettiger Makromoleküle auf Styrolbasis |
| US10316117B2 (en) | 2013-12-18 | 2019-06-11 | Tesa Se | Process for producing short-chain end-group-functionalized macromolecules based on styrene |
Also Published As
| Publication number | Publication date |
|---|---|
| BE832384A (fr) | 1976-02-13 |
| NL7509660A (nl) | 1976-02-18 |
| AR208325A1 (es) | 1976-12-20 |
| JPS5730126B2 (enExample) | 1982-06-26 |
| ZA755230B (en) | 1976-07-28 |
| AU8398175A (en) | 1977-02-17 |
| BR7505238A (pt) | 1976-08-03 |
| IT1041204B (it) | 1980-01-10 |
| IN142506B (enExample) | 1977-07-23 |
| DD121116A5 (enExample) | 1976-07-12 |
| US4042768A (en) | 1977-08-16 |
| FR2281940A1 (fr) | 1976-03-12 |
| JPS5146390A (en) | 1976-04-20 |
| GB1485222A (en) | 1977-09-08 |
| PL103106B1 (pl) | 1979-05-31 |
| FR2281940B1 (enExample) | 1979-05-11 |
| CA1070897A (en) | 1980-01-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| 8130 | Withdrawal |