DE2357117A1 - Vorrichtung zur messung der sauerstoffaktivitaet in fluessigem natrium - Google Patents
Vorrichtung zur messung der sauerstoffaktivitaet in fluessigem natriumInfo
- Publication number
- DE2357117A1 DE2357117A1 DE2357117A DE2357117A DE2357117A1 DE 2357117 A1 DE2357117 A1 DE 2357117A1 DE 2357117 A DE2357117 A DE 2357117A DE 2357117 A DE2357117 A DE 2357117A DE 2357117 A1 DE2357117 A1 DE 2357117A1
- Authority
- DE
- Germany
- Prior art keywords
- oxide
- layer
- thorium
- yttrium
- electrolyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 title claims description 41
- 229910052708 sodium Inorganic materials 0.000 title claims description 41
- 239000011734 sodium Substances 0.000 title claims description 41
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims description 29
- 239000001301 oxygen Substances 0.000 title claims description 29
- 229910052760 oxygen Inorganic materials 0.000 title claims description 29
- 239000007788 liquid Substances 0.000 title claims description 21
- 230000000694 effects Effects 0.000 title claims description 12
- PXLUKYMALPPDGB-UHFFFAOYSA-N [O-2].[Y+3].[O-2].[Th+4] Chemical compound [O-2].[Y+3].[O-2].[Th+4] PXLUKYMALPPDGB-UHFFFAOYSA-N 0.000 claims description 22
- 239000002131 composite material Substances 0.000 claims description 20
- 229910021525 ceramic electrolyte Inorganic materials 0.000 claims description 16
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 14
- 239000000292 calcium oxide Substances 0.000 claims description 14
- SKKXLLCGVBASOT-UHFFFAOYSA-N calcium oxygen(2-) zirconium(4+) Chemical compound [O-2].[Zr+4].[O-2].[Ca+2] SKKXLLCGVBASOT-UHFFFAOYSA-N 0.000 claims description 12
- 239000003792 electrolyte Substances 0.000 claims description 11
- 239000000919 ceramic Substances 0.000 claims description 9
- 239000004020 conductor Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 238000005266 casting Methods 0.000 claims description 5
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical group [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims description 4
- 239000011505 plaster Substances 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 238000000462 isostatic pressing Methods 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 claims description 3
- 229910003452 thorium oxide Inorganic materials 0.000 claims description 3
- 238000010304 firing Methods 0.000 claims description 2
- 238000005245 sintering Methods 0.000 claims description 2
- 239000010409 thin film Substances 0.000 claims description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims 2
- 230000015572 biosynthetic process Effects 0.000 claims 2
- 230000001747 exhibiting effect Effects 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims 1
- 239000000565 sealant Substances 0.000 claims 1
- 229910052727 yttrium Inorganic materials 0.000 claims 1
- 229910001928 zirconium oxide Inorganic materials 0.000 claims 1
- 238000005259 measurement Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 230000035939 shock Effects 0.000 description 3
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229910052776 Thorium Inorganic materials 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Inorganic materials [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical compound O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 description 1
- OWDMWYGPNPPHFN-UHFFFAOYSA-N calcium;oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[O-2].[Ca+2].[Zr+4] OWDMWYGPNPPHFN-UHFFFAOYSA-N 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 239000011532 electronic conductor Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000011507 gypsum plaster Substances 0.000 description 1
- 239000010416 ion conductor Substances 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 229910001338 liquidmetal Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052574 oxide ceramic Inorganic materials 0.000 description 1
- 239000011224 oxide ceramic Substances 0.000 description 1
- 238000007750 plasma spraying Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000009489 vacuum treatment Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4073—Composition or fabrication of the solid electrolyte
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Molecular Biology (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Monitoring And Testing Of Nuclear Reactors (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US30697672A | 1972-11-15 | 1972-11-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2357117A1 true DE2357117A1 (de) | 1974-05-30 |
Family
ID=23187718
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2357117A Pending DE2357117A1 (de) | 1972-11-15 | 1973-11-15 | Vorrichtung zur messung der sauerstoffaktivitaet in fluessigem natrium |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3776831A (enExample) |
| JP (1) | JPS4982391A (enExample) |
| DE (1) | DE2357117A1 (enExample) |
| FR (1) | FR2206506B1 (enExample) |
| GB (1) | GB1398835A (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2808621A1 (de) * | 1977-03-01 | 1978-09-07 | Toyota Motor Co Ltd | Sauerstoffmessfuehler und verfahren zu dessen herstellung |
| DE2908368A1 (de) * | 1979-03-03 | 1980-09-04 | Jenaer Glaswerk Schott & Gen | Messonde zur bestimmung des sauerstoff-partialdruckes in schmelzen |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4007106A (en) * | 1973-06-22 | 1977-02-08 | Canadian Patents And Development Limited | Device for measuring oxygen concentration in molten-metal |
| US4166019A (en) * | 1975-09-26 | 1979-08-28 | General Electric Company | Electrochemical oxygen meter |
| FR2365798A1 (fr) * | 1976-09-27 | 1978-04-21 | Westinghouse Electric Corp | Dispositif pour afficher la teneur en oxygene d'un milieu fluide |
| DE2700807A1 (de) * | 1977-01-11 | 1978-07-13 | Bosch Gmbh Robert | Festelektrolytrohr fuer einen messfuehler zur bestimmung des sauerstoffgehaltes in abgasen und verfahren zur herstellung desselben |
| GB1569524A (en) * | 1977-04-04 | 1980-06-18 | Gen Electric | Electrochemical oxygen meter |
| IT1121360B (it) * | 1978-06-12 | 1986-04-02 | Broken Hill Pty Co Ltd | Perfezionamenti ai sensori di gas |
| DE2904069A1 (de) * | 1979-02-03 | 1980-08-07 | Bosch Gmbh Robert | Festelektrolyt fuer elektrochemische anwendungen und verfahren zur herstellung desselben |
| DE2908308A1 (de) * | 1979-03-03 | 1980-09-04 | Jenaer Glaswerk Schott & Gen | Messonde zur bestimmung des sauerstoff- partialdruckes in gasen |
| CA1119249A (fr) * | 1979-03-30 | 1982-03-02 | Ireq Institut De Recherche De L'hydro-Quebec | Methode et dispositif pour detecter et mesurer la concentration d'un anhydride gazeux au sein d'un gaz contenant de l'oxygene |
| US4264424A (en) * | 1979-10-12 | 1981-04-28 | General Electric Company | Hydrogen ion sensor having a membrane sheath of an oxygen ion conducting ceramic |
| US4310402A (en) * | 1979-11-13 | 1982-01-12 | Westinghouse Electric Corp. | Gas tight sealant for zirconia sensors |
| US5106480A (en) * | 1980-09-05 | 1992-04-21 | Thomson-Csf | Device of the solid-electrolyte electrochemical cell type |
| US4377460A (en) * | 1981-10-19 | 1983-03-22 | Westinghouse Electric Corp. | Solid electrolyte gas sensing apparatus |
| US5352344A (en) * | 1988-10-06 | 1994-10-04 | Ipsen Industries International Gesellschaft Mit Beschrankter Haftung | Method and apparatus for measuring the oxygen potential of a heat-treatment furnance |
| DE4100107A1 (de) * | 1991-01-04 | 1992-07-09 | Bosch Gmbh Robert | Verfahren zur herstellung eines schichtsystems fuer gassensoren |
| GB9206367D0 (en) * | 1992-03-24 | 1992-05-06 | Pilkington Plc | Oxygen measuring probe |
| US5871633A (en) * | 1993-06-17 | 1999-02-16 | Rutgers, The State University | Impedance type humidity sensor with protonconducting electrolyte and method of using same |
| US5393404A (en) * | 1993-06-17 | 1995-02-28 | Rutgers, The State University Of New Jersey | Humidity sensor with nasicon-based proton-conducting electrolyte |
| US5672258A (en) * | 1993-06-17 | 1997-09-30 | Rutgers, The State University Of New Jersey | Impedance type humidity sensor with proton-conducting electrolyte |
| US6080294A (en) * | 1998-07-15 | 2000-06-27 | Atwood Industries, Inc. | Gas sensor with dual electrolytes |
| DE19941051C2 (de) * | 1999-08-28 | 2003-10-23 | Bosch Gmbh Robert | Sensorelement zur Bestimmung der Sauerstoffkonzentration in Gasgemischen und Verfahren zur Herstellung desselben |
| EP1211508A3 (en) * | 2000-11-27 | 2004-10-27 | Kabushiki Kaisha Riken | Gas sensing and oxygen pumping device |
| RU2278374C2 (ru) * | 2004-05-21 | 2006-06-20 | Государственное образовательное учреждение высшего профессионального образования Томский государственный университет (ТГУ) | Способ вольтамперометрического анализа фазового и элементного состава объекта и устройство для его осуществления |
-
1972
- 1972-11-15 US US00306976A patent/US3776831A/en not_active Expired - Lifetime
-
1973
- 1973-10-29 GB GB5018673A patent/GB1398835A/en not_active Expired
- 1973-11-14 JP JP48128126A patent/JPS4982391A/ja active Pending
- 1973-11-15 FR FR7340771A patent/FR2206506B1/fr not_active Expired
- 1973-11-15 DE DE2357117A patent/DE2357117A1/de active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2808621A1 (de) * | 1977-03-01 | 1978-09-07 | Toyota Motor Co Ltd | Sauerstoffmessfuehler und verfahren zu dessen herstellung |
| DE2908368A1 (de) * | 1979-03-03 | 1980-09-04 | Jenaer Glaswerk Schott & Gen | Messonde zur bestimmung des sauerstoff-partialdruckes in schmelzen |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2206506A1 (enExample) | 1974-06-07 |
| JPS4982391A (enExample) | 1974-08-08 |
| GB1398835A (en) | 1975-06-25 |
| US3776831A (en) | 1973-12-04 |
| FR2206506B1 (enExample) | 1975-03-21 |
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