DE2332638C2 - Verfahren zur kontinuierlichen Herstellung von Lösungen von Kobaltcarbonyl und Kobaltcarbonylwasserstoff in organischen Lösungsmitteln - Google Patents
Verfahren zur kontinuierlichen Herstellung von Lösungen von Kobaltcarbonyl und Kobaltcarbonylwasserstoff in organischen LösungsmittelnInfo
- Publication number
- DE2332638C2 DE2332638C2 DE2332638A DE2332638A DE2332638C2 DE 2332638 C2 DE2332638 C2 DE 2332638C2 DE 2332638 A DE2332638 A DE 2332638A DE 2332638 A DE2332638 A DE 2332638A DE 2332638 C2 DE2332638 C2 DE 2332638C2
- Authority
- DE
- Germany
- Prior art keywords
- cobalt
- cobalt carbonyl
- hydrogen
- carbonyl
- solutions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910017052 cobalt Inorganic materials 0.000 title claims description 48
- 239000010941 cobalt Substances 0.000 title claims description 48
- 239000001257 hydrogen Substances 0.000 title claims description 28
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 28
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title claims description 26
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 21
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 title claims description 11
- 238000000034 method Methods 0.000 title claims description 11
- 239000003960 organic solvent Substances 0.000 title claims description 9
- 238000010924 continuous production Methods 0.000 title 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 23
- 239000000243 solution Substances 0.000 claims description 17
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 10
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 10
- 150000001868 cobalt Chemical class 0.000 claims description 10
- -1 cobalt carbonyl hydrogen Chemical class 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000012266 salt solution Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 6
- 239000008346 aqueous phase Substances 0.000 description 4
- 229940011182 cobalt acetate Drugs 0.000 description 4
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
- AMIMRNSIRUDHCM-UHFFFAOYSA-N Isopropylaldehyde Chemical compound CC(C)C=O AMIMRNSIRUDHCM-UHFFFAOYSA-N 0.000 description 2
- ZZYSOUTXXFZJBK-UHFFFAOYSA-L butanoate;cobalt(2+) Chemical compound [Co+2].CCCC([O-])=O.CCCC([O-])=O ZZYSOUTXXFZJBK-UHFFFAOYSA-L 0.000 description 2
- PFQLIVQUKOIJJD-UHFFFAOYSA-L cobalt(ii) formate Chemical compound [Co+2].[O-]C=O.[O-]C=O PFQLIVQUKOIJJD-UHFFFAOYSA-L 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- 238000006213 oxygenation reaction Methods 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical class CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- 229910001429 cobalt ion Inorganic materials 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 1
- KXWCQSBVWFBSSQ-UHFFFAOYSA-K cobalt(3+) chloride sulfate Chemical compound [Cl-].S(=O)(=O)([O-])[O-].[Co+3] KXWCQSBVWFBSSQ-UHFFFAOYSA-K 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007037 hydroformylation reaction Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G51/00—Compounds of cobalt
- C01G51/02—Carbonyls
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/85—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to a chemical modification
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Catalysts (AREA)
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2332638A DE2332638C2 (de) | 1973-06-27 | 1973-06-27 | Verfahren zur kontinuierlichen Herstellung von Lösungen von Kobaltcarbonyl und Kobaltcarbonylwasserstoff in organischen Lösungsmitteln |
| IT23523/74A IT1014709B (it) | 1973-06-27 | 1974-06-03 | Processo per la preparazione continua di soluzioni di cobalto carbonile e cobalto carbonile idrogeno in solventi organici |
| NL7407923A NL7407923A (en:Method) | 1973-06-27 | 1974-06-13 | |
| US05/482,251 US3957684A (en) | 1973-06-27 | 1974-06-24 | Continuous manufacture of solutions of cobalt carbonyl and cobalt carbonyl hydride in organic solvents |
| FR7422060A FR2235087B1 (en:Method) | 1973-06-27 | 1974-06-25 | |
| BE145873A BE816845A (fr) | 1973-06-27 | 1974-06-25 | Procede de preparation continue de solutions de cobalt-carbonyle et d'hydrure de cobalt-carbonyle dans des solvants organiques |
| AT526674A AT338214B (de) | 1973-06-27 | 1974-06-25 | Verfahren zur kontinuierlichen herstellung von losungen von kobaltcarbonyl und kobaltcarbonylwasserstoff in organischen losungsmitteln |
| JP49071933A JPS5037699A (en:Method) | 1973-06-27 | 1974-06-25 | |
| CA203,453A CA1025426A (en) | 1973-06-27 | 1974-06-26 | Continuous manufacture of solutions of cobalt carbonyl and cobalt carbonyl hydride in organic solvents |
| ES427711A ES427711A1 (es) | 1973-06-27 | 1974-06-26 | Procedimiento para la obtencion de soluciones de cobalto- carbonilo y cobaltocarbonilo hidrogenado en disolventes organicos. |
| GB2824974A GB1469147A (en) | 1973-06-27 | 1974-06-26 | Continuous manufacture of solutions of cobalt carbonyl and cobalt carbonyl hydride in an organic solvent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2332638A DE2332638C2 (de) | 1973-06-27 | 1973-06-27 | Verfahren zur kontinuierlichen Herstellung von Lösungen von Kobaltcarbonyl und Kobaltcarbonylwasserstoff in organischen Lösungsmitteln |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2332638A1 DE2332638A1 (de) | 1975-01-23 |
| DE2332638C2 true DE2332638C2 (de) | 1982-03-18 |
Family
ID=5885214
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2332638A Expired DE2332638C2 (de) | 1973-06-27 | 1973-06-27 | Verfahren zur kontinuierlichen Herstellung von Lösungen von Kobaltcarbonyl und Kobaltcarbonylwasserstoff in organischen Lösungsmitteln |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US3957684A (en:Method) |
| JP (1) | JPS5037699A (en:Method) |
| AT (1) | AT338214B (en:Method) |
| BE (1) | BE816845A (en:Method) |
| CA (1) | CA1025426A (en:Method) |
| DE (1) | DE2332638C2 (en:Method) |
| ES (1) | ES427711A1 (en:Method) |
| FR (1) | FR2235087B1 (en:Method) |
| GB (1) | GB1469147A (en:Method) |
| IT (1) | IT1014709B (en:Method) |
| NL (1) | NL7407923A (en:Method) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4150246A (en) * | 1976-08-30 | 1979-04-17 | Celanese Corporation | Homologation of alkanols |
| US4255279A (en) * | 1979-07-20 | 1981-03-10 | Exxon Research & Engineering Co. | Dual demetalling of oxo products with catalyst recycle |
| US4301312A (en) * | 1980-05-21 | 1981-11-17 | The United States Of America As Represented By The United States Department Of Energy | Method and system for ethanol production |
| EP0487727B1 (en) * | 1989-07-14 | 1995-01-25 | Dai Nippon Insatsu Kabushiki Kaisha | Thermal transfer cover film |
| JPH07507285A (ja) * | 1992-05-29 | 1995-08-10 | エクソン ケミカル パテンツ インコーポレイテッド | 触媒再生 |
| GB9211880D0 (en) * | 1992-06-04 | 1992-07-15 | Exxon Chemical Patents Inc | Method and apparatus for the recovery of metal catalysts |
| CN1047768C (zh) * | 1997-01-09 | 1999-12-29 | 华中理工大学 | 温和条件下催化合成羰基钴的方法 |
| EP3583069B1 (de) | 2017-02-16 | 2023-04-26 | Umicore AG & Co. KG | Verfahren zur herstellung von cobaltcarbonyl |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1071683B (de) * | 1956-08-22 | 1959-12-24 | Esso Research And Engeering Co | Verfahren zur Herstellung von Kobaitcarbonylhydrid oder eines seiner Salze |
| US2691046A (en) * | 1948-04-22 | 1954-10-05 | Eastman Kodak Co | Process for the manufacture of oxygenated compounds with improved catalysts |
| JPS5243198A (en) * | 1975-10-01 | 1977-04-04 | Yamashita Kougiyou Kenkiyuujiy | Impact hand tools |
-
1973
- 1973-06-27 DE DE2332638A patent/DE2332638C2/de not_active Expired
-
1974
- 1974-06-03 IT IT23523/74A patent/IT1014709B/it active
- 1974-06-13 NL NL7407923A patent/NL7407923A/xx unknown
- 1974-06-24 US US05/482,251 patent/US3957684A/en not_active Expired - Lifetime
- 1974-06-25 AT AT526674A patent/AT338214B/de not_active IP Right Cessation
- 1974-06-25 JP JP49071933A patent/JPS5037699A/ja active Pending
- 1974-06-25 BE BE145873A patent/BE816845A/xx not_active IP Right Cessation
- 1974-06-25 FR FR7422060A patent/FR2235087B1/fr not_active Expired
- 1974-06-26 CA CA203,453A patent/CA1025426A/en not_active Expired
- 1974-06-26 ES ES427711A patent/ES427711A1/es not_active Expired
- 1974-06-26 GB GB2824974A patent/GB1469147A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2332638A1 (de) | 1975-01-23 |
| FR2235087A1 (en:Method) | 1975-01-24 |
| JPS5037699A (en:Method) | 1975-04-08 |
| US3957684A (en) | 1976-05-18 |
| FR2235087B1 (en:Method) | 1981-02-13 |
| CA1025426A (en) | 1978-01-31 |
| ES427711A1 (es) | 1976-08-01 |
| IT1014709B (it) | 1977-04-30 |
| NL7407923A (en:Method) | 1974-12-31 |
| AT338214B (de) | 1977-08-10 |
| ATA526674A (de) | 1976-12-15 |
| GB1469147A (en) | 1977-03-30 |
| BE816845A (fr) | 1974-12-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OD | Request for examination | ||
| D2 | Grant after examination | ||
| 8330 | Complete disclaimer |