DE2309368C3 - Kontinuierliches Verfahren zur Herstellung von Copolymerisat-Dispersionen - Google Patents
Kontinuierliches Verfahren zur Herstellung von Copolymerisat-DispersionenInfo
- Publication number
- DE2309368C3 DE2309368C3 DE2309368A DE2309368A DE2309368C3 DE 2309368 C3 DE2309368 C3 DE 2309368C3 DE 2309368 A DE2309368 A DE 2309368A DE 2309368 A DE2309368 A DE 2309368A DE 2309368 C3 DE2309368 C3 DE 2309368C3
- Authority
- DE
- Germany
- Prior art keywords
- ethylene
- weight
- dispersions
- dispersion
- approx
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
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- 239000003513 alkali Substances 0.000 description 19
- -1 alkyl radical Chemical class 0.000 description 18
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- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 4
- 239000010425 asbestos Substances 0.000 description 4
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- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 description 4
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 3
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- ZSBRYDJXHOFQMW-UHFFFAOYSA-N chloroethene;ethene;ethenyl acetate Chemical group C=C.ClC=C.CC(=O)OC=C ZSBRYDJXHOFQMW-UHFFFAOYSA-N 0.000 description 3
- 239000011362 coarse particle Substances 0.000 description 3
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- 150000003839 salts Chemical class 0.000 description 3
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- 238000006467 substitution reaction Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 101100117236 Drosophila melanogaster speck gene Proteins 0.000 description 2
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- ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical compound O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 description 2
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- 239000000835 fiber Substances 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- ISXSFOPKZQZDAO-UHFFFAOYSA-N formaldehyde;sodium Chemical compound [Na].O=C ISXSFOPKZQZDAO-UHFFFAOYSA-N 0.000 description 1
- QJQZEJFUIOWFMS-UHFFFAOYSA-N formaldehyde;sulfanediol Chemical class O=C.OSO QJQZEJFUIOWFMS-UHFFFAOYSA-N 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 238000009432 framing Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical class CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- 150000004976 peroxydisulfates Chemical class 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 235000019394 potassium persulphate Nutrition 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- NQLVQOSNDJXLKG-UHFFFAOYSA-N prosulfocarb Chemical compound CCCN(CCC)C(=O)SCC1=CC=CC=C1 NQLVQOSNDJXLKG-UHFFFAOYSA-N 0.000 description 1
- 239000005297 pyrex Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003455 sulfinic acids Chemical class 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2309368A DE2309368C3 (de) | 1973-02-24 | 1973-02-24 | Kontinuierliches Verfahren zur Herstellung von Copolymerisat-Dispersionen |
| NLAANVRAGE7402395,A NL176950C (nl) | 1973-02-24 | 1974-02-21 | Continue werkwijze ter bereiding van 45-60 gew.% vaste stof bevattende, waterige, filmvormende, tegen afschuifkrachten, electrolyt en pigment en bij opslag stabiele dispersies. |
| GB799274A GB1428329A (en) | 1973-02-24 | 1974-02-21 | Continuous process for the production of copolymer dispersions |
| BE141279A BE811449A (fr) | 1973-02-24 | 1974-02-22 | Procede continu de preparation de dispersions de copolymeres |
| FR7406197A FR2219184B1 (https=) | 1973-02-24 | 1974-02-22 | |
| US444753A US3929706A (en) | 1973-02-24 | 1974-02-22 | Continuous process for the production of copolymer dispersions |
| IT48652/74A IT1003572B (it) | 1973-02-24 | 1974-02-25 | Procedimento continuo ed impianto per produrre dispersioni di copolimeri |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2309368A DE2309368C3 (de) | 1973-02-24 | 1973-02-24 | Kontinuierliches Verfahren zur Herstellung von Copolymerisat-Dispersionen |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2309368A1 DE2309368A1 (de) | 1974-09-19 |
| DE2309368B2 DE2309368B2 (de) | 1981-09-10 |
| DE2309368C3 true DE2309368C3 (de) | 1984-09-27 |
Family
ID=5873035
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2309368A Expired DE2309368C3 (de) | 1973-02-24 | 1973-02-24 | Kontinuierliches Verfahren zur Herstellung von Copolymerisat-Dispersionen |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3929706A (https=) |
| BE (1) | BE811449A (https=) |
| DE (1) | DE2309368C3 (https=) |
| FR (1) | FR2219184B1 (https=) |
| GB (1) | GB1428329A (https=) |
| IT (1) | IT1003572B (https=) |
| NL (1) | NL176950C (https=) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2541934A1 (de) * | 1975-09-19 | 1977-03-24 | Wacker Chemie Gmbh | Verseifungsfeste copolymerdispersionen |
| US4134863A (en) * | 1976-12-06 | 1979-01-16 | The United States Of America As Represented By The Secretary Of Agriculture | Highly absorbent graft copolymers of polyhydroxy polymers, acrylonitrile, and acrylic comonomers |
| DE2734656A1 (de) * | 1977-08-01 | 1979-02-22 | Wacker Chemie Gmbh | Waessrige vinylchlorid-copolymerdispersionen, deren herstellung und verwendung |
| DE2837992A1 (de) * | 1978-08-31 | 1980-03-20 | Wacker Chemie Gmbh | Verfahren zur herstellung von waessrigen aethylen-vinylchlorid-vinylacetat und/oder alkylacrylatcopolymerdispersionen mit uneinheitlicher teilchengroesseverteilung |
| AU594694B2 (en) * | 1985-08-06 | 1990-03-15 | Onoda Cement Co., Ltd. | Method of forming protective layer on concrete or mortar |
| DE3535389A1 (de) * | 1985-10-03 | 1987-04-09 | Wacker Chemie Gmbh | Verfahren zur herstellung von bindemitteln fuer anstrichfarben und putze |
| US4812510A (en) * | 1986-04-17 | 1989-03-14 | The Glidden Company | Small particle size latex based on vinyl acetate polymers |
| AU602943B2 (en) * | 1986-11-13 | 1990-11-01 | Onoda Cement Co., Ltd. | Process for producing corrosion-resistant concrete or mortar |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2587562A (en) * | 1948-11-22 | 1952-02-26 | Shawinigan Resins Corp | Continuous emulsion polymerization process for vinyl acetate |
| US2703794A (en) * | 1951-09-04 | 1955-03-08 | Du Pont | Ethylene/vinyl acetate polymerization process |
| DE1495645C3 (de) * | 1961-05-26 | 1974-11-07 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung stabiler, wäßriger Emulsionen bzw. Dispersionen von Äthylen-Mischpolymerisaten |
| DE1495707B2 (de) * | 1963-01-12 | 1972-01-27 | Farbenfabriken Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung stabiler emulsionen von copoly merisaten des aethylens |
| DE1240286B (de) * | 1965-01-02 | 1967-05-11 | Basf Ag | Verfahren zur kontinuierlichen Emulsions-polymerisation olefinisch ungesaettigter Verbindungen |
| US3428582A (en) * | 1966-05-06 | 1969-02-18 | Monsanto Co | Interpolymer aqueous dispersions and paper coated therewith |
| NL135976C (https=) * | 1967-05-05 | |||
| DE1745555B1 (de) * | 1967-05-10 | 1972-05-25 | Wacker Chemie Gmbh | Verfahren zur herstellung von waessrigen polymerisat-dispersionen |
| US3639326A (en) * | 1968-05-20 | 1972-02-01 | Allied Chem | Vinyl terpolymer compositions |
| US3816363A (en) * | 1968-05-27 | 1974-06-11 | Lanza Ltd | Saponification resistant,aqueous synthetic resin dispersion |
| DE1931857A1 (de) * | 1969-06-24 | 1971-01-14 | Bayer Ag | Stabile AEthylen-Vinylchlorid-Copolymerisatemulsionen |
| US3714105A (en) * | 1969-11-05 | 1973-01-30 | Borden Inc | Adhesive latexes of vinyl acetate/ethylene/n-methylolacrylamide terpolymers |
| US3665060A (en) * | 1969-11-17 | 1972-05-23 | Monsanto Co | Resin blend containing ethylene/vinyl chloride interpolymer |
| DE2007793A1 (de) * | 1970-02-20 | 1971-08-26 | Bayer Ag | Verfahren zur kontinuierlichen Her stellung von Copolymensatdispersionen |
| US3689447A (en) * | 1970-06-08 | 1972-09-05 | Samuel J Makower | Process for preparing emulsion interpolymers containing vinyl chloride and ethylene,having improved heat stability |
| US3830761A (en) * | 1971-10-26 | 1974-08-20 | Air Prod & Chem | Vinyl chloride-ethylene-vinyl acetate resin binders |
-
1973
- 1973-02-24 DE DE2309368A patent/DE2309368C3/de not_active Expired
-
1974
- 1974-02-21 GB GB799274A patent/GB1428329A/en not_active Expired
- 1974-02-21 NL NLAANVRAGE7402395,A patent/NL176950C/xx not_active IP Right Cessation
- 1974-02-22 FR FR7406197A patent/FR2219184B1/fr not_active Expired
- 1974-02-22 BE BE141279A patent/BE811449A/xx not_active IP Right Cessation
- 1974-02-22 US US444753A patent/US3929706A/en not_active Expired - Lifetime
- 1974-02-25 IT IT48652/74A patent/IT1003572B/it active
Also Published As
| Publication number | Publication date |
|---|---|
| DE2309368A1 (de) | 1974-09-19 |
| NL7402395A (https=) | 1974-08-27 |
| FR2219184A1 (https=) | 1974-09-20 |
| FR2219184B1 (https=) | 1977-09-16 |
| DE2309368B2 (de) | 1981-09-10 |
| BE811449A (fr) | 1974-08-22 |
| US3929706A (en) | 1975-12-30 |
| NL176950B (nl) | 1985-02-01 |
| IT1003572B (it) | 1976-06-10 |
| NL176950C (nl) | 1985-07-01 |
| GB1428329A (en) | 1976-03-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8263 | Opposition against grant of a patent | ||
| C3 | Grant after two publication steps (3rd publication) | ||
| 8339 | Ceased/non-payment of the annual fee |