DE2302089A1 - Verfahren zur hydrierung von aromaten - Google Patents
Verfahren zur hydrierung von aromatenInfo
- Publication number
- DE2302089A1 DE2302089A1 DE19732302089 DE2302089A DE2302089A1 DE 2302089 A1 DE2302089 A1 DE 2302089A1 DE 19732302089 DE19732302089 DE 19732302089 DE 2302089 A DE2302089 A DE 2302089A DE 2302089 A1 DE2302089 A1 DE 2302089A1
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- ppm
- fluorine
- sulfur
- content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000005984 hydrogenation reaction Methods 0.000 title claims description 18
- 238000000034 method Methods 0.000 title claims description 16
- 239000000796 flavoring agent Substances 0.000 title 1
- 235000019634 flavors Nutrition 0.000 title 1
- 239000003054 catalyst Substances 0.000 claims description 47
- 229910052717 sulfur Inorganic materials 0.000 claims description 33
- 239000011593 sulfur Substances 0.000 claims description 33
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 32
- 239000011737 fluorine Substances 0.000 claims description 31
- 229910052731 fluorine Inorganic materials 0.000 claims description 31
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 21
- 239000007858 starting material Substances 0.000 claims description 20
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 10
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 239000003209 petroleum derivative Substances 0.000 claims description 4
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 28
- 230000000694 effects Effects 0.000 description 16
- 239000003502 gasoline Substances 0.000 description 9
- 238000009835 boiling Methods 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- 229910052697 platinum Inorganic materials 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- 238000006477 desulfuration reaction Methods 0.000 description 3
- 230000023556 desulfurization Effects 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 238000006317 isomerization reaction Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052680 mordenite Inorganic materials 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 229910019080 Mg-H Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- HHUIAYDQMNHELC-UHFFFAOYSA-N [O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O HHUIAYDQMNHELC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- OTIJDYHLLCTUJA-UHFFFAOYSA-N aluminum oxygen(2-) platinum(2+) Chemical compound [Pt+2].[O-2].[Al+3] OTIJDYHLLCTUJA-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910001680 bayerite Inorganic materials 0.000 description 1
- 125000005605 benzo group Chemical group 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000012025 fluorinating agent Substances 0.000 description 1
- 238000003682 fluorination reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- -1 with an ammonium Chemical compound 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/44—Hydrogenation of the aromatic hydrocarbons
- C10G45/46—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
- C10G45/52—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing platinum group metals or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB294272A GB1400455A (en) | 1972-01-21 | 1972-01-21 | Hydrogenation of aromatics |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2302089A1 true DE2302089A1 (de) | 1973-08-02 |
Family
ID=9748965
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19732302089 Pending DE2302089A1 (de) | 1972-01-21 | 1973-01-17 | Verfahren zur hydrierung von aromaten |
Country Status (7)
| Country | Link |
|---|---|
| AU (1) | AU458469B2 (cs) |
| BE (1) | BE794302A (cs) |
| DE (1) | DE2302089A1 (cs) |
| FR (1) | FR2168460B1 (cs) |
| GB (1) | GB1400455A (cs) |
| IT (1) | IT974456B (cs) |
| NL (1) | NL7300226A (cs) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2765586B1 (fr) * | 1997-07-02 | 2003-09-05 | Inst Francais Du Petrole | Procede de transformation, par hydrogenation catalytique, d'une base huile en huile blanche medicinale |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL144659B (nl) * | 1964-04-28 | 1975-01-15 | Shell Int Research | Werkwijze voor de bereiding van een kerosine met een verhoogd roetpunt. |
| FR1540167A (fr) * | 1966-10-14 | 1968-09-20 | British Petroleum Co | Procédé d'hydrogénation d'hydrocarbures aromatiques en présence de petites quantités de soufre |
-
1972
- 1972-01-21 GB GB294272A patent/GB1400455A/en not_active Expired
- 1972-12-22 AU AU50452/72A patent/AU458469B2/en not_active Expired
- 1972-12-29 IT IT5520772A patent/IT974456B/it active
-
1973
- 1973-01-08 NL NL7300226A patent/NL7300226A/xx not_active Application Discontinuation
- 1973-01-17 DE DE19732302089 patent/DE2302089A1/de active Pending
- 1973-01-17 FR FR7301641A patent/FR2168460B1/fr not_active Expired
- 1973-01-19 BE BE794302A patent/BE794302A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU458469B2 (en) | 1975-02-27 |
| AU5045272A (en) | 1974-06-27 |
| IT974456B (it) | 1974-06-20 |
| NL7300226A (cs) | 1973-07-24 |
| BE794302A (fr) | 1973-07-19 |
| GB1400455A (en) | 1975-07-16 |
| FR2168460A1 (cs) | 1973-08-31 |
| FR2168460B1 (cs) | 1977-02-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2546513C2 (cs) | ||
| DE2915982C2 (de) | Verfahren zur Herstellung eines Mitteldestillatöls aus einem Schwerdestillatöl mit einem Gehalt an stickstoffhaltigen Kohlenwasserstoffen | |
| DE2444911B2 (de) | Crackkatalysator und dessen Verwendung | |
| DE2606362C2 (de) | Verfahren zur Herstellung eines Crackkatalysators und dessen Verwendung | |
| DE1301409B (de) | Verfahren zur Aufbereitung von Kohlenwasserstoffen durch selektive Hydrocrackung | |
| DE2431562C2 (cs) | ||
| DE2405116A1 (de) | Verfahren zur herstellung von schmieroelen | |
| DE69001555T2 (de) | Verfahren zur Verbesserung der Cetanzahl von Visbreaking-Gasöl. | |
| DE2302089A1 (de) | Verfahren zur hydrierung von aromaten | |
| DE2617287A1 (de) | Katalysator zum hydrieren aromatischer kohlenwasserstoffe | |
| DE2741263A1 (de) | Verfahren zur herstellung von entschwefelungskatalysatoren und ihre verwendung bei der hydrokatalytischen entschwefelung | |
| DE2126603A1 (de) | Verfahren zur Herstellung von Schmierölen und Benzinen | |
| DE2831328C2 (cs) | ||
| DE2355686C2 (cs) | ||
| DE1594728A1 (de) | Bindemittel fuer den Strassenbau | |
| DE3010094A1 (de) | Katalysator zur kohlenwasserstoffumwandlung | |
| DE2615066A1 (de) | Verfahren zur katalytischen isomerisation von alkylaromatischen kohlenwasserstoffen | |
| DE1470666C3 (de) | 28.04.64 Niederlande 6404715 Verfahren zur Herstellung eines Erdöldestillates mit verbessertem Rauchpunkt | |
| DE69302595T2 (de) | Verfahren zur Aufarbeitung eines Kohlenwasserstoffeinsatzes | |
| DE2159168C2 (de) | Nickel und Molybdän enthaltender Aluminiumoxid-Trägerkatalysator sowie seine Verwendung zur katalytischen Umwandlung von Kohlenwasserstoffen | |
| DE1959869B2 (de) | Verfahren zur Herstellung einer Schmierölfraktion mit erhöhtem Viskositätsindex | |
| DE2317647A1 (de) | Hydrierverfahren | |
| DE2145639C3 (de) | Kontinuierliches Verfahren zur Reinigung einer leichten Paraffinfraktion durch Hydrierung | |
| DE1115870B (de) | Verfahren und Katalysator zur Herstellung von Schmieroelen | |
| DE68916026T2 (de) | Herstellung von Mitteldestillaten. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OHA | Expiration of time for request for examination |