DE2239942C3 - Verfahren zur Polymerisation von Vinylchlorid - Google Patents
Verfahren zur Polymerisation von VinylchloridInfo
- Publication number
- DE2239942C3 DE2239942C3 DE2239942A DE2239942A DE2239942C3 DE 2239942 C3 DE2239942 C3 DE 2239942C3 DE 2239942 A DE2239942 A DE 2239942A DE 2239942 A DE2239942 A DE 2239942A DE 2239942 C3 DE2239942 C3 DE 2239942C3
- Authority
- DE
- Germany
- Prior art keywords
- autoclave
- water
- polymerization
- during
- sprayed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000006116 polymerization reaction Methods 0.000 title claims description 42
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims description 18
- 238000000034 method Methods 0.000 title claims description 17
- 230000008569 process Effects 0.000 title claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 49
- 239000006185 dispersion Substances 0.000 claims description 16
- 239000000178 monomer Substances 0.000 claims description 15
- 239000007921 spray Substances 0.000 claims description 10
- 238000004821 distillation Methods 0.000 claims description 8
- 239000000084 colloidal system Substances 0.000 claims description 5
- 230000001681 protective effect Effects 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 238000007334 copolymerization reaction Methods 0.000 claims description 4
- 239000003995 emulsifying agent Substances 0.000 claims description 4
- 239000002518 antifoaming agent Substances 0.000 claims description 3
- 125000005634 peroxydicarbonate group Chemical group 0.000 claims description 3
- 150000002826 nitrites Chemical class 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 23
- 239000007789 gas Substances 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 13
- 238000004140 cleaning Methods 0.000 description 11
- 206010039509 Scab Diseases 0.000 description 8
- 239000007791 liquid phase Substances 0.000 description 7
- 238000005507 spraying Methods 0.000 description 7
- 239000000725 suspension Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 229920000915 polyvinyl chloride Polymers 0.000 description 6
- 239000004800 polyvinyl chloride Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 230000008602 contraction Effects 0.000 description 5
- -1 dialkyl Substances 0.000 description 5
- 241000251468 Actinopterygii Species 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 210000003128 head Anatomy 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 101100117236 Drosophila melanogaster speck gene Proteins 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000013459 approach Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000001771 impaired effect Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- QWVBGCWRHHXMRM-UHFFFAOYSA-N hexadecoxycarbonyloxy hexadecyl carbonate Chemical compound CCCCCCCCCCCCCCCCOC(=O)OOC(=O)OCCCCCCCCCCCCCCCC QWVBGCWRHHXMRM-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- PCJGHYSTCBLKIA-UHFFFAOYSA-N (1-acetylcyclohexyl)sulfonyloxy 1-acetylcyclohexane-1-sulfonate Chemical class C1CCCCC1(C(C)=O)S(=O)(=O)OOS(=O)(=O)C1(C(=O)C)CCCCC1 PCJGHYSTCBLKIA-UHFFFAOYSA-N 0.000 description 1
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- SIXWIUJQBBANGK-UHFFFAOYSA-N 4-(4-fluorophenyl)-1h-pyrazol-5-amine Chemical compound N1N=CC(C=2C=CC(F)=CC=2)=C1N SIXWIUJQBBANGK-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 241000283690 Bos taurus Species 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000000337 buffer salt Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- AQSPWOCSGZUTBB-UHFFFAOYSA-N carbonic acid;1-hexadecylperoxyhexadecane Chemical compound OC(O)=O.CCCCCCCCCCCCCCCCOOCCCCCCCCCCCCCCCC AQSPWOCSGZUTBB-UHFFFAOYSA-N 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000001010 compromised effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000012933 diacyl peroxide Substances 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- IGBZOHMCHDADGY-UHFFFAOYSA-N ethenyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OC=C IGBZOHMCHDADGY-UHFFFAOYSA-N 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002976 peresters Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 150000003900 succinic acid esters Chemical class 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F15/00—Other methods of preventing corrosion or incrustation
- C23F15/005—Inhibiting incrustation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/002—Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00054—Controlling or regulating the heat exchange system
- B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
- B01J2219/00058—Temperature measurement
- B01J2219/00063—Temperature measurement of the reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00094—Jackets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00101—Reflux columns
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00121—Controlling the temperature by direct heating or cooling
- B01J2219/00123—Controlling the temperature by direct heating or cooling adding a temperature modifying medium to the reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00162—Controlling or regulating processes controlling the pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00177—Controlling or regulating processes controlling the pH
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00184—Controlling or regulating processes controlling the weight of reactants in the reactor vessel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/18—Details relating to the spatial orientation of the reactor
- B01J2219/185—Details relating to the spatial orientation of the reactor vertical
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2239942A DE2239942C3 (de) | 1972-08-14 | 1972-08-14 | Verfahren zur Polymerisation von Vinylchlorid |
US00369497A US3842055A (en) | 1972-08-14 | 1973-06-13 | Process for dispersion polymerization of vinyl chloride with low polymer deposition |
DD172866A DD108101A5 (US07943777-20110517-C00090.png) | 1972-08-14 | 1973-08-10 | |
IT51961/73A IT990215B (it) | 1972-08-14 | 1973-08-10 | Procedimento ed impianto per poli merizzare vinilcloruro |
NL7311150A NL7311150A (US07943777-20110517-C00090.png) | 1972-08-14 | 1973-08-13 | |
GB3839573A GB1434559A (en) | 1972-08-14 | 1973-08-14 | Polymerization of vinyl chloride |
CA178,762A CA1014700A (en) | 1972-08-14 | 1973-08-14 | Process for dispersion polymerization of vinyl chloride with low polymer deposition |
BE134549A BE803580A (fr) | 1972-08-14 | 1973-08-14 | Procede de polymerisation du chlorure de vinyle |
JP48091232A JPS5030106B2 (US07943777-20110517-C00090.png) | 1972-08-14 | 1973-08-14 | |
FR7329641A FR2196348B1 (US07943777-20110517-C00090.png) | 1972-08-14 | 1973-08-14 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2239942A DE2239942C3 (de) | 1972-08-14 | 1972-08-14 | Verfahren zur Polymerisation von Vinylchlorid |
Publications (3)
Publication Number | Publication Date |
---|---|
DE2239942A1 DE2239942A1 (de) | 1974-03-07 |
DE2239942B2 DE2239942B2 (de) | 1979-08-30 |
DE2239942C3 true DE2239942C3 (de) | 1988-02-11 |
Family
ID=5853524
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE2239942A Expired DE2239942C3 (de) | 1972-08-14 | 1972-08-14 | Verfahren zur Polymerisation von Vinylchlorid |
Country Status (10)
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2350720C3 (de) * | 1973-10-10 | 1979-11-08 | Hoechst Ag, 6000 Frankfurt | Polymerisationsverfahren |
US3931131A (en) * | 1973-12-18 | 1976-01-06 | Kureha Kagaku Kogyo Kabushiki Kaisha | Process and apparatus for suspension polymerization |
DE2405978A1 (de) * | 1974-02-08 | 1975-08-21 | Huels Chemische Werke Ag | Verfahren zur verhinderung von wandabscheidungen |
JPS5113881A (en) * | 1974-07-24 | 1976-02-03 | Kanegafuchi Chemical Ind | Enkabiniruno jugohoho |
DE2442575C3 (de) * | 1974-09-05 | 1980-01-17 | Chemische Werke Huels Ag, 4370 Marl | Verfahren zur Herstellung von Emulsionspolyvinylchlorid unter Vermeiden von Vinylchlorid-Emissionen |
CH611632A5 (US07943777-20110517-C00090.png) * | 1975-02-13 | 1979-06-15 | Solvay | |
JPS51115587A (en) * | 1975-03-24 | 1976-10-12 | Kuraray Co Ltd | Method of producing polyvinylchloride resins |
IT1044367B (it) * | 1975-08-08 | 1980-03-20 | Anic Spa | Procedimento per la rimozione delle incrostazioni dalle parti a contatto con la fase gassosa in polimerizzatori di cloruro di vinile in sospensione |
DE2625149C3 (de) * | 1976-06-04 | 1981-01-08 | Hoechst Ag, 6000 Frankfurt | Verfahren und Vorrichtung zur kontinuierlichen Herstellung von Vinylchloridpolymerisaten in wäßriger Emulsion |
DE2714812C3 (de) * | 1977-04-02 | 1981-02-05 | Basf Ag, 6700 Ludwigshafen | Vorrichtung zur Durchführung von Polymerisationen aus der Gasphase |
US4359560A (en) * | 1978-06-13 | 1982-11-16 | Air Products And Chemicals, Inc. | Method for reducing wall fouling in vinyl chloride polymerization |
US4224424A (en) * | 1978-09-01 | 1980-09-23 | Air Products And Chemicals, Inc. | Pretreatment of a reactor with alkali metal carbonate and bicarbonates to reduce wall fouling in vinyl chloride polymerization |
DE2852622C2 (de) * | 1978-12-05 | 1982-09-09 | Wacker-Chemie GmbH, 8000 München | Polymerisationsautoklav |
DE3637060C2 (de) * | 1986-10-31 | 1999-02-04 | Wacker Chemie Gmbh | Vorrichtung zum Einsprühen oder Einspritzen von Flüssigkeit in einen Behälter und ihre Verwendung |
US4954595A (en) * | 1987-09-08 | 1990-09-04 | Shin-Etsu Chemical Co., Ltd. | Method for preparing vinyl chloride polymers |
US5100988A (en) * | 1987-09-08 | 1992-03-31 | Shin-Etsu Chemical Co., Ltd. | Initiated scale-free formation of vinyl chloride polymers using washing liquid at temperature affecting initiator half-life |
DE3815397C2 (de) * | 1988-05-05 | 1998-02-26 | Wacker Chemie Gmbh | Verfahren zur Herstellung einer Autoklavenbeschichtung |
JP2003033635A (ja) * | 2001-05-17 | 2003-02-04 | Shinko Pantec Co Ltd | 攪拌翼およびこれを用いた攪拌装置ならびに攪拌方法 |
JP5166662B2 (ja) * | 2001-09-27 | 2013-03-21 | 出光興産株式会社 | α−オレフィン低重合体の製造方法 |
CA2820852C (en) * | 2010-12-14 | 2018-07-03 | Sasol Technology (Proprietary) Limited | Cleaning of process equipment |
CN103264030A (zh) * | 2013-06-20 | 2013-08-28 | 苏州市金翔钛设备有限公司 | 反应釜清洗设备 |
CN103272807A (zh) * | 2013-06-20 | 2013-09-04 | 苏州市金翔钛设备有限公司 | 一种反应釜清洗装置 |
FR3008899B1 (fr) * | 2013-07-25 | 2017-04-21 | Arkema France | Methode et systeme pour la distribution d'un liquide dans des capacites pour la preparation de monomeres (meth)acryliques |
CN108654539A (zh) * | 2018-04-24 | 2018-10-16 | 浙江荣凯科技发展有限公司 | 一种具有减震功能的化工产品生产用反应釜 |
CN108854909A (zh) * | 2018-07-04 | 2018-11-23 | 合肥欧语自动化有限公司 | 一种具有清洗功能的反应釜 |
CN111495310A (zh) * | 2020-06-17 | 2020-08-07 | 烟台工程职业技术学院(烟台市技师学院) | 一种自动化的易于清洗的食品搅拌反应釜 |
CN112403418A (zh) * | 2020-10-27 | 2021-02-26 | 书香门地集团股份有限公司 | 一种再生地板的加工装置及其加工工艺 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
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FR964180A (US07943777-20110517-C00090.png) * | 1950-08-08 | |||
US3407179A (en) * | 1965-05-12 | 1968-10-22 | Du Pont | Batch polymerization of aqueous diamine-dicarboxylic acid salt |
GB1190587A (en) * | 1966-06-15 | 1970-05-06 | Norsk Hydro Elektrisk | Method and Apparatus for Reducing the Formation of Deposits During Polymerisation Processes. |
DE1940779A1 (de) * | 1968-08-15 | 1970-02-19 | Vyzk Ustav Organ Syntez | Verfahren und Vorrichtung zur Durchfuehrung von physikalischen und chemischen Vorgaengen |
DE1795371A1 (de) * | 1968-09-20 | 1972-07-27 | Wasagchemie Ag | Verfahren zur Herstellung von Polymerisation des Vinylchlorids |
US3645452A (en) * | 1970-04-27 | 1972-02-29 | Goodrich Co B F | Tank cleaner |
CH543375A (de) * | 1971-10-01 | 1973-10-31 | Bruderer Ag | Einrichtung zur Führung des Bärs einer Stanzmaschine |
JPS5142588B2 (US07943777-20110517-C00090.png) * | 1971-10-04 | 1976-11-16 | ||
JPS4893686A (US07943777-20110517-C00090.png) * | 1972-03-16 | 1973-12-04 | ||
DE2224144A1 (de) * | 1972-05-17 | 1973-11-29 | Shinetsu Chemical Co | Verfahren zur herstellung von homooder mischpolymerisaten des vinylchlorids und vorrichtungen zur durchfuehrung des verfahrens |
JPH0730343A (ja) * | 1993-07-14 | 1995-01-31 | Mitsubishi Electric Corp | 分布型増幅器及び双方向増幅器 |
-
1972
- 1972-08-14 DE DE2239942A patent/DE2239942C3/de not_active Expired
-
1973
- 1973-06-13 US US00369497A patent/US3842055A/en not_active Expired - Lifetime
- 1973-08-10 DD DD172866A patent/DD108101A5/xx unknown
- 1973-08-10 IT IT51961/73A patent/IT990215B/it active
- 1973-08-13 NL NL7311150A patent/NL7311150A/xx not_active Application Discontinuation
- 1973-08-14 CA CA178,762A patent/CA1014700A/en not_active Expired
- 1973-08-14 GB GB3839573A patent/GB1434559A/en not_active Expired
- 1973-08-14 FR FR7329641A patent/FR2196348B1/fr not_active Expired
- 1973-08-14 JP JP48091232A patent/JPS5030106B2/ja not_active Expired
- 1973-08-14 BE BE134549A patent/BE803580A/xx not_active IP Right Cessation
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DE2239942A1 (de) | 1974-03-07 |
NL7311150A (US07943777-20110517-C00090.png) | 1974-02-18 |
BE803580A (fr) | 1974-02-14 |
FR2196348B1 (US07943777-20110517-C00090.png) | 1976-06-18 |
CA1014700A (en) | 1977-07-26 |
JPS5030106B2 (US07943777-20110517-C00090.png) | 1975-09-29 |
FR2196348A1 (US07943777-20110517-C00090.png) | 1974-03-15 |
DE2239942B2 (de) | 1979-08-30 |
JPS49132173A (US07943777-20110517-C00090.png) | 1974-12-18 |
GB1434559A (en) | 1976-05-05 |
DD108101A5 (US07943777-20110517-C00090.png) | 1974-09-05 |
IT990215B (it) | 1975-06-20 |
US3842055A (en) | 1974-10-15 |
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