DE2204141B2 - Verfahren zur Herstellung von Tetrafl uoräthy len - Google Patents
Verfahren zur Herstellung von Tetrafl uoräthy lenInfo
- Publication number
- DE2204141B2 DE2204141B2 DE2204141A DE2204141A DE2204141B2 DE 2204141 B2 DE2204141 B2 DE 2204141B2 DE 2204141 A DE2204141 A DE 2204141A DE 2204141 A DE2204141 A DE 2204141A DE 2204141 B2 DE2204141 B2 DE 2204141B2
- Authority
- DE
- Germany
- Prior art keywords
- steam
- polytetrafluoroethylene
- temperature
- pyrolysis
- products
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 26
- 230000008569 process Effects 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title description 7
- -1 polytetrafluoroethylene Polymers 0.000 claims description 40
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 40
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 40
- 238000000197 pyrolysis Methods 0.000 claims description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000002131 composite material Substances 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000012159 carrier gas Substances 0.000 claims description 2
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 239000000047 product Substances 0.000 description 24
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 24
- 239000000463 material Substances 0.000 description 23
- 239000007789 gas Substances 0.000 description 16
- 229920000642 polymer Polymers 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 13
- 238000000354 decomposition reaction Methods 0.000 description 12
- 239000010935 stainless steel Substances 0.000 description 9
- 229910001220 stainless steel Inorganic materials 0.000 description 9
- 239000002699 waste material Substances 0.000 description 8
- 239000006227 byproduct Substances 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229910000906 Bronze Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000010974 bronze Substances 0.000 description 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical compound FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000007514 turning Methods 0.000 description 2
- MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical group FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 description 1
- WFLOTYSKFUPZQB-UHFFFAOYSA-N 1,2-difluoroethene Chemical group FC=CF WFLOTYSKFUPZQB-UHFFFAOYSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229910000792 Monel Inorganic materials 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 241000589614 Pseudomonas stutzeri Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000000998 batch distillation Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 125000004773 chlorofluoromethyl group Chemical group [H]C(F)(Cl)* 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- CVSVTCORWBXHQV-UHFFFAOYSA-N creatine Chemical compound NC(=[NH2+])N(C)CC([O-])=O CVSVTCORWBXHQV-UHFFFAOYSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000003113 dilution method Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 229910001026 inconel Inorganic materials 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910000623 nickel–chromium alloy Inorganic materials 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/361—Preparation of halogenated hydrocarbons by reactions involving a decrease in the number of carbon atoms
- C07C17/367—Preparation of halogenated hydrocarbons by reactions involving a decrease in the number of carbon atoms by depolymerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US00111963A US3832411A (en) | 1971-02-02 | 1971-02-02 | Method for the depolymerization of polytetrafluoroethylene |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2204141A1 DE2204141A1 (de) | 1972-08-17 |
| DE2204141B2 true DE2204141B2 (de) | 1974-05-30 |
Family
ID=22341390
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2204141A Pending DE2204141B2 (de) | 1971-02-02 | 1972-01-28 | Verfahren zur Herstellung von Tetrafl uoräthy len |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3832411A (show.php) |
| JP (1) | JPS5238525B1 (show.php) |
| DE (1) | DE2204141B2 (show.php) |
| FR (1) | FR2124212B1 (show.php) |
| GB (1) | GB1361341A (show.php) |
| IT (1) | IT948929B (show.php) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4128589A (en) * | 1977-06-22 | 1978-12-05 | Hughes Aircraft Company | Generation of CF4 from Teflon for reactive atmosphere processing and growth of metal fluorides |
| DE4334015A1 (de) * | 1993-10-06 | 1995-04-13 | Hoechst Ag | Verfahren zur Herstellung von fluorierten Monomeren |
| CA2118081C (en) * | 1993-10-14 | 2006-10-03 | Jacobus Swanepoel | Production of fluorocarbon compounds |
| RU2082709C1 (ru) * | 1994-05-19 | 1997-06-27 | Научно-внедренческая фирма "Поликом, Инк" | Способ получения мономера пиролитическим разложением соответствующего полимера и установка для его осуществления |
| CN1323993C (zh) * | 2002-03-01 | 2007-07-04 | 大金工业株式会社 | 含氟单体的制造方法 |
| US6919015B2 (en) * | 2002-12-16 | 2005-07-19 | 3M Innovative Properties Company | Process for manufacturing fluoroolefins |
| RU2387632C2 (ru) * | 2008-07-14 | 2010-04-27 | Общество с ограниченной ответственностью "Завод полимеров Кирово-Чепецкого химического комбината" (ООО "Завод полимеров КЧХК") | Способ переработки отходов политетрафторэтилена |
| GB0817873D0 (en) * | 2008-10-01 | 2008-11-05 | 3M Innovative Properties Co | Process of making fluoroelefins by thermal decomposition of fluorinated materials |
| RU2469056C1 (ru) * | 2011-06-16 | 2012-12-10 | Государственное образовательное учреждение высшего профессионального образования "Национальный исследовательский Томский политехнический университет" | Способ получения композиционного материала на основе политетрафторэтилена и диоксида кремния |
| RU2497846C1 (ru) * | 2012-04-24 | 2013-11-10 | Федеральное государственное бюджетное учреждение науки Байкальский институт природопользования Сибирского отделения Российской академии наук (БИП СО РАН) | Способ утилизации отходов политетрафторэтилена |
| RU2656488C1 (ru) * | 2017-05-03 | 2018-06-05 | Общество с ограниченной ответственностью "Малое инновационное предприятие "Байкальский научный центр прочности" | Способ утилизации отходов политетрафторэтилена |
| CN114829323B (zh) | 2019-12-23 | 2023-09-01 | 3M创新有限公司 | 通过氟化离聚物热分解制备氟代烯烃的方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2394581A (en) * | 1943-10-04 | 1946-02-12 | Kinetic Chemicals Inc | Pyrolysis of tetrafluoroethylene polymer |
| US2406153A (en) * | 1944-06-23 | 1946-08-20 | Du Pont | Depolymerization of polymeric tetrafluoroethylene |
| DE1003700B (de) * | 1954-07-30 | 1957-03-07 | Hoechst Ag | Verfahren zur Herstellung von niedermolekularen Fluorchlorkohlenstoffen fluessiger oder wachsartiger Konsistenz |
| NL288069A (show.php) * | 1962-01-24 | |||
| GB1041591A (en) * | 1962-02-21 | 1966-09-07 | Daikin Ind Ltd | Process for manufacturing tetrafluoroethylene |
-
1971
- 1971-02-02 US US00111963A patent/US3832411A/en not_active Expired - Lifetime
- 1971-08-02 FR FR7128299A patent/FR2124212B1/fr not_active Expired
-
1972
- 1972-01-06 GB GB61872A patent/GB1361341A/en not_active Expired
- 1972-01-25 IT IT67211/72A patent/IT948929B/it active
- 1972-01-28 DE DE2204141A patent/DE2204141B2/de active Pending
- 1972-01-31 JP JP47010620A patent/JPS5238525B1/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| FR2124212B1 (show.php) | 1973-11-23 |
| GB1361341A (en) | 1974-07-24 |
| IT948929B (it) | 1973-06-11 |
| JPS5238525B1 (show.php) | 1977-09-29 |
| FR2124212A1 (show.php) | 1972-09-22 |
| DE2204141A1 (de) | 1972-08-17 |
| US3832411A (en) | 1974-08-27 |
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